KR940014942A - Method of manufacturing island-in-the-sea composite fiber - Google Patents

Method of manufacturing island-in-the-sea composite fiber Download PDF

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Publication number
KR940014942A
KR940014942A KR1019920027431A KR920027431A KR940014942A KR 940014942 A KR940014942 A KR 940014942A KR 1019920027431 A KR1019920027431 A KR 1019920027431A KR 920027431 A KR920027431 A KR 920027431A KR 940014942 A KR940014942 A KR 940014942A
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South Korea
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island
compound
component
glycol
carbon atoms
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KR1019920027431A
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Korean (ko)
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KR950000724B1 (en
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김광태
임대우
연원희
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박흥기
제일합섬 주식회사
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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30—Conjugate filaments; Spinnerette packs therefor
    • D01D5/34—Core-skin structure; Spinnerette packs therefor

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Multicomponent Fibers (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

본 발명은 방향족 디카르복실산 또는 이의 에스테르 생성 유도체로 구성되는 산성분과 두개 내지 그 이상의 탄소원자를 갖는 1종 이상의 알킬렌글리콜 또는 이의 에스테르 생성유도체로 구성되는 글리콜성분을 중합시 전체 산성분에 대하여 1~15몰%의 유기설폰산 금속염, 생성되는 코폴리에스테르에 대하여 0.1~15중량%의 일반식(I)로 표현되는 화합물, 유기설폰산 금속염 100당량에 대하여 1~50당량의 일반식(II)로 표현되는 화합물과 생성되는 코폴리에스테르에 대하여 0.01~0.3중량%의 일반식(III) 화합물을 투입하여 제조한 코폴리에스테르를 해성분으로 하고 섬유형성성 폴리에스테르를 도성분으로 하여 복합 방사함을 특징으로 하는 해도형 복합섬유의 제조방법에 관한 것이다.The present invention relates to an acid component composed of an aromatic dicarboxylic acid or an ester derivative thereof and a glycol component composed of one or more alkylene glycols having two or more carbon atoms or an ester generating derivative thereof, based on the total acid component. To 15 mol% of the organic sulfonic acid metal salt, 1 to 50 equivalents of the general formula (II) with respect to 100 equivalent of the organic sulfonic acid metal salt represented by 0.1 to 15% by weight of the compound represented by general formula (I) Compound spun from 0.01 to 0.3% by weight of the general formula (III) compound with respect to the compound represented by) and the resulting copolyester as a sea component and a fiber-forming polyester as a island component It relates to a method for producing an island-in-the-sea composite fiber characterized by

상기식중, R은 1가의 방향족 탄화수소기 또는 탄소수 2~10개로 이루어진 지방족 탄화수수기이고, n은 8~160의 정수이며, M은 알칼리 금속이고, R1,R2,R3,R4는 수소원자 또는 탄소수가 1~10인 알칼리 또는 아릴기이며 R5는 탄소수 1~10의 알킬렌기 또는 벤젠링이다.Wherein R is a monovalent aromatic hydrocarbon group or an aliphatic hydrocarbon group consisting of 2 to 10 carbon atoms, n is an integer of 8 to 160, M is an alkali metal, and R 1 , R 2 , R 3 , R 4 Is a hydrogen atom or an alkali or aryl group having 1 to 10 carbon atoms, and R 5 is an alkylene group or benzene ring having 1 to 10 carbon atoms.

Description

해도형 복합섬유의 제조방법Method of manufacturing island-in-the-sea composite fiber

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제1도는 본 발명의 해도형 복합섬유의 단면도로서, (가)는 해성분을, (나)는 도성분을 나타낸다.1 is a cross-sectional view of the island-in-the-sea composite fiber of the present invention, (a) indicates sea component, and (b) indicates island component.

Claims (7)

방향족 디카르복실산 또는 이의 에스테르 생성 유도체로 구성되는 산성분과 두개 이상의 탄소원자를 갖는 1종 이상의 알킬렌글리콜 또는 이의 에스테르 생성유도체로 구성되는 글리콜성분을 중합시 유기설폰산 금속염, 일반식(I)로 표시되는 화합물, 일반식(II)로 표시되는 화합물, 일반식(III)으로 표시되는 화합물을 투입하여 제조한 코폴리에스테르를 해성분으로 하고 섬유형성성 폴리에스테르를 도성분으로 하여 복합 방사함을 특징으로 하는 해도형 복함섬유의 제조방법.When a glycol component composed of an aromatic dicarboxylic acid or an ester component thereof and an acid component composed of one or more alkylene glycols or ester esters thereof having two or more carbon atoms is polymerized with an organic sulfonic acid metal salt, general formula (I) Composite spinning with copolyester prepared by adding the compound represented by the compound represented by the formula (II) and the compound represented by the formula (III) as the sea component and the fiber-forming polyester as the island component A method for producing island-in-the-sea composite fiber. 상기식중, R은 1가의 방향족 탄화수소기 또는 탄소수 2~10개로 이루어진 지방족 탄화수수기이고, n은 8~160의 정수이며, M은 알칼리 금속이고, R1,R2,R3,R4는 수소원자 또는 탄소수가 1~10인 알칼리 또는 아릴기이며, R5는 탄소수 1~10의 알킬렌기 또는 벤젠링이다.Wherein R is a monovalent aromatic hydrocarbon group or an aliphatic hydrocarbon group consisting of 2 to 10 carbon atoms, n is an integer of 8 to 160, M is an alkali metal, and R 1 , R 2 , R 3 , R 4 Is a hydrogen atom or an alkali or aryl group having 1 to 10 carbon atoms, and R 5 is an alkylene group or benzene ring having 1 to 10 carbon atoms. 제1항에 있어서, 유기설폰산 금속염은 디메틸소듐 5-설포이소프탈레이트, 소듐 3,5-디메틸설포네이트, 디메틸포타슘 5-설포이소프탈 레이트 디-n-펜틸리튬 3-설포테레프탈레이트 또는 디메틸소듐 2,6-디메틸-5-설포이소프탈레이트이며, 전체산성분에 대하여 1~15몰% 첨가됨을 특징으로 하는 해도형 복합섬유의 제조방법.The organosulfonic acid metal salt of claim 1 is a dimethylsodium 5-sulfoisophthalate, sodium 3,5-dimethylsulfonate, dimethylpotassium 5-sulfoisophthalate di-n-pentyllithium 3-sulfoterephthalate or Dimethyl sodium 2,6-dimethyl-5-sulfoisophthalate, 1-15 mol% is added to the total acid component. 제1항에 있어서, 일반식(I) 화합물은 분자량 400~6000정도의 폴리에틸렌글리콜, 폴리프로필렌글리콜 폴리테트라메틸렌글리콜, 폴리에틸렌프로필렌글리콜 또는 이들의 혼합물이며, 코폴리에스테르에 대하여 0.1~15중량%가 투입됨을 특징으로 하는 해도형 복합섬유의 제조방법.The compound of formula (I) is polyethylene glycol, polypropylene glycol polytetramethylene glycol, polyethylene propylene glycol, or a mixture thereof having a molecular weight of about 400 to 6000, 0.1 to 15% by weight relative to the copolyester Process for producing an island-in-the-sea composite fiber characterized in that it is added. 제1항에 있어서, 일반식(II) 화합물은 리튬하이드록사이드, 소듐하이드록사이드, 포타슘 하이드록사이드, 루비튬하이드록사이드, 세슘하이드록사이드 또는 이들의 혼합물이며, 유기설폰산 금속염 100당량에 대하여 1~50당량 투입됨을 특징으로 하는 해도형 복합섬유의 제조방법.A compound according to claim 1, wherein the compound of formula (II) is lithium hydroxide, sodium hydroxide, potassium hydroxide, rubithium hydroxide, cesium hydroxide or a mixture thereof, 100 equivalents of organosulfonic acid metal salt Method for producing an island-in-the-sea composite fiber, characterized in that about 1 to 50 equivalents to be added. 제1항에 있어서, 일반식(III) 화합물은 포스포릴디메틸에탄올아민, 2-디메틸아미노페놀디페닐포스페이트, 2-디에틸아미노에탄올다메틸포스페이트, 2-에틸프로필아미노페놀디하이드로젠포스페이트 또는 2-디부틸아미노페놀디하이드로젠포스페이트이며, 코폴리에스테르에 대하여 0.01~0.3중량% 투입됨을 특징으로 하는 해도형 복합섬유의 제조방법.The compound of formula (III) according to claim 1, wherein the compound of formula (III) is phosphoryldimethylethanolamine, 2-dimethylaminophenoldiphenylphosphate, 2-diethylaminoethanoldimethylphosphate, 2-ethylpropylaminophenoldihydrogenphosphate or 2 -Dibutylaminophenol dihydrogen phosphate, 0.01 to 0.3% by weight relative to the copolyester production method of the island-in-the-sea composite fiber. 제1항에 있어서, 섬유형성성 폴리에스테르는 테레프탈산과 에틸렌글리콜을 주성분으로 하는 이소프탈산, 나프탈렌디카르본산 또는 폴리에스테르를 형성할 수 있는 이들의 작용성 유도체를 테레프탈산 대비 2~10중량%, 네오펜틸글리콜, 헥산-1,6-디올, 비스-1,4-하이드록시메틸사이클로헥산, 디에틸렌글리콜 또는 트리에틸렌글리콜을 에틸렌글리콜 대비 5~8몰% 첨가하며, 일반식(III) 화합물을 생성 폴리에스테르에 대하여 0.01~0.3중량% 투입하여 제조한 것임을 특징으로 하는 해도형 복합섬유의 제조방법.The method of claim 1, wherein the fiber-forming polyester is 2 to 10% by weight compared to terephthalic acid, isophthalic acid, naphthalenedicarboxylic acid or a functional derivative thereof that can form a polyester mainly composed of terephthalic acid and ethylene glycol 5-8 mol% of pentyl glycol, hexane-1,6-diol, bis-1,4-hydroxymethylcyclohexane, diethylene glycol or triethylene glycol are added in comparison to ethylene glycol to generate a general formula (III) compound. A method for producing an island-in-the-sea composite fiber characterized in that it is prepared by adding 0.01 to 0.3% by weight based on polyester. 제1항에 있어서, 해성분과 도성분의 비는 5:5~1:9로 하여 복합방사함을 특징으로하는 해도형 복합섬유의 제조방법.The method for producing island-in-the-sea composite fiber according to claim 1, wherein the ratio of the sea component to the island component is 5: 5 to 1: 9. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019920027431A 1992-12-31 1992-12-31 Method for preparation of sea-island type conjugated fiber KR950000724B1 (en)

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KR1019920027431A KR950000724B1 (en) 1992-12-31 1992-12-31 Method for preparation of sea-island type conjugated fiber

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KR1019920027431A KR950000724B1 (en) 1992-12-31 1992-12-31 Method for preparation of sea-island type conjugated fiber

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KR940014942A true KR940014942A (en) 1994-07-19
KR950000724B1 KR950000724B1 (en) 1995-01-28

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KR20030062998A (en) * 2002-01-22 2003-07-28 주식회사 코오롱 A easy extractable polyester by alkali solution

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