KR940014596A - Thermoplastic resin composition with improved heat resistance and impact resistance - Google Patents

Thermoplastic resin composition with improved heat resistance and impact resistance Download PDF

Info

Publication number
KR940014596A
KR940014596A KR1019920024941A KR920024941A KR940014596A KR 940014596 A KR940014596 A KR 940014596A KR 1019920024941 A KR1019920024941 A KR 1019920024941A KR 920024941 A KR920024941 A KR 920024941A KR 940014596 A KR940014596 A KR 940014596A
Authority
KR
South Korea
Prior art keywords
weight
thermoplastic resin
resin composition
parts
vinyl
Prior art date
Application number
KR1019920024941A
Other languages
Korean (ko)
Other versions
KR960006627B1 (en
Inventor
구정기
윤종태
Original Assignee
채오병
제일모직 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 채오병, 제일모직 주식회사 filed Critical 채오병
Priority to KR1019920024941A priority Critical patent/KR960006627B1/en
Publication of KR940014596A publication Critical patent/KR940014596A/en
Application granted granted Critical
Publication of KR960006627B1 publication Critical patent/KR960006627B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/24—Homopolymers or copolymers of amides or imides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes

Abstract

본 발명은 내열성이 우수하면서 내충격특성이 우수한 열가소성 수지 조성물에 관한 것이다. 본 발명은,이미드화 공중합체(A) 10 내지 90중량%와 ; 디엔고무-방향족비닐-비닐시안화물 그래프트 공중합체(B) 90 내지 10중량%와 ; 열가소성 수지(C) 0 내지 80중량%와 : 상기 A),B),C)로 구성된 수지 100중량부에 대하여 실리콘 오일(D)이 0.01 내지 20중량부 첨가되는 것을 특징으로 한다. 이와 같이 구성된 본발명의 조성물은 자동차 내장부품 등과 같이 고온하에서 사용되는 제품으로서 적절히 사용될 수 있다.The present invention relates to a thermoplastic resin composition having excellent heat resistance and excellent impact resistance. The present invention, 10 to 90% by weight of the imidized copolymer (A); 90 to 10% by weight of diene rubber-aromatic vinyl-vinyl cyanide graft copolymer (B); The silicone oil (D) is added in an amount of 0.01 to 20 parts by weight based on 0 to 80% by weight of the thermoplastic resin (C) and 100 parts by weight of the resin consisting of A), B) and C). The composition of the present invention configured as described above may be suitably used as a product to be used under high temperature such as automobile interior parts.

Description

내열성 및 내충격성이 향상된 열가소성 수지조성물Thermoplastic resin composition with improved heat resistance and impact resistance

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (5)

이미드화 공중합체(A) 10 내지 90중량%와 ; 디엔고무-방향족비닐-비닐시안화물 그래프트 공중합체(B) 90 내지 10중량%와 ; 열가소성 수지(C) 0 내지 80중량%와 : 상기 A),B),C)로 구성된 수지 100중량부에 대하여 실리콘 오일(D)이 0.01 내지 20중량부 첨가되는 것을 특징으로 하는 열가소성 수지 조성물.10 to 90% by weight of the imidized copolymer (A); 90 to 10% by weight of diene rubber-aromatic vinyl-vinyl cyanide graft copolymer (B); A thermoplastic resin composition comprising from 0 to 80% by weight of a thermoplastic resin (C) and 0.01 to 20 parts by weight of a silicone oil (D) based on 100 parts by weight of a resin composed of the above-mentioned A), B) and C). 제1항에 있어서, 성분(A)는 고무상 중합체 0~40중량%, 방향족 비닐 단량체 30~69중량%, 불포화 디카르본산 이미드 단량체 30~60중량%, 불포화 디카르본산 무수물 단량체 1~20중량% 및 이들 외의 비닐 단량체 0~40중량%로 부터 얻어진 이미드화 공중합체인 것을 특징으로 하는 열가소성 수지조성물.A component (A) is 0-40 weight% of rubbery polymers, 30-69 weight% of aromatic vinyl monomers, 30-60 weight% of unsaturated dicarboxylic acid imide monomers, and 1-unsaturated dicarboxylic acid anhydride monomers of Claim 1, A thermoplastic resin composition, which is an imidized copolymer obtained from 20% by weight and 0 to 40% by weight of other vinyl monomers. 제1항에 있어서, 성분(B)는 방향족 비닐 단량체와 비닐시안화물과의 단량체 혼합물 25~60중량%를 디엔고무 폴리머 40 내지 75중량%의 존재하에 그래프트 공중합시켜 얻은 것을 특징으로 하는 열가소성 수지 조성물.The thermoplastic resin composition according to claim 1, wherein component (B) is obtained by graft copolymerization of 25 to 60 wt% of a monomer mixture of an aromatic vinyl monomer and a vinyl cyanide in the presence of 40 to 75 wt% of a diene rubber polymer. . 제1항에 있어서, 성분(C)는 방향족 비닐 단량체 40~90중량%에 시안화비닐계 단량체 60~10중량% 및 이들과 중합 가능한 다른 비닐계 단량체 0~40중량%를 혼합시켜 얻은 것을 특징으로 하는 열가소성 수지 조성물.The component (C) is obtained by mixing 40 to 90% by weight of an aromatic vinyl monomer with 60 to 10% by weight of a vinyl cyanide monomer and 0 to 40% by weight of other vinyl monomers polymerizable therewith. Thermoplastic resin composition. 제1항에 있어서, 성분(D)는 20℃에서 점도가 20~10,000cst인 액상의 폴리디메틸실록산 또는 폴리페닐실록산 0.02 내지 20중량부를 포함하는 것을 특징으로 하는 수지 조성물.The resin composition according to claim 1, wherein component (D) comprises 0.02 to 20 parts by weight of liquid polydimethylsiloxane or polyphenylsiloxane having a viscosity of 20 to 10,000 cst at 20 ° C. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019920024941A 1992-12-21 1992-12-21 Thermoplastic resin composition of improved heat-resistance and impact-resistance KR960006627B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019920024941A KR960006627B1 (en) 1992-12-21 1992-12-21 Thermoplastic resin composition of improved heat-resistance and impact-resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019920024941A KR960006627B1 (en) 1992-12-21 1992-12-21 Thermoplastic resin composition of improved heat-resistance and impact-resistance

Publications (2)

Publication Number Publication Date
KR940014596A true KR940014596A (en) 1994-07-18
KR960006627B1 KR960006627B1 (en) 1996-05-22

Family

ID=19346134

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920024941A KR960006627B1 (en) 1992-12-21 1992-12-21 Thermoplastic resin composition of improved heat-resistance and impact-resistance

Country Status (1)

Country Link
KR (1) KR960006627B1 (en)

Also Published As

Publication number Publication date
KR960006627B1 (en) 1996-05-22

Similar Documents

Publication Publication Date Title
DE69626774T2 (en) Polymer composition modified with rubber
KR950018083A (en) Cycloolefin copolymer and preparation method thereof
KR960701107A (en) Maleimide Copolymer and Resin Compositions thereof
ATE21412T1 (en) RESIN COMPOSITION.
KR960029404A (en) Rubber-modified thermoplastic resins and compositions containing them
KR880006315A (en) Heat resistant copolymer composition
KR910004754A (en) Thermoplastic Polymer Compositions Containing Melt-Flow Regulators
DK0572720T3 (en) Process for the preparation of thermoplastic resin compositions with excellent hydrofluorocarbon resistance
KR880007662A (en) Thermoplastic resin composition
KR900004857A (en) Thermoplastic resin composition
KR890700149A (en) Heat resistant impact resistant resin composition
KR940014473A (en) Multimodally Coupled Dendritic Block Copolymers of Monovinyl Aromatic Compounds and Conjugated Dienes
JPS5731914A (en) Production of impact-resistant resin composition
KR940005750A (en) Polyphenylene ether resin composition
KR940014596A (en) Thermoplastic resin composition with improved heat resistance and impact resistance
KR960031496A (en) Particulate graft copolymer and thermoplastic molding material containing it and improved coloring property
KR940014573A (en) Freon-resistant thermoplastic resin composition and preparation method thereof
KR950031448A (en) Manufacturing method of molded heat resistant resin product
KR970001393A (en) Rubber-like polymer latex, rubber-reinforced vinyl-based polymer and thermoplastic polymer composition of rubber-reinforced vinyl polymer
KR970027206A (en) Fiberglass Reinforced ABS Resin Composition
KR900006433A (en) Heat and impact resistant resin composition
KR920012249A (en) Method for producing a thermoplastic resin composition excellent in heat resistance and low temperature impact resistance
KR980002154A (en) Thermoplastic Polyester Resin Composition
KR850008497A (en) Thermoplastic Composition
KR940011565A (en) Thermoplastic Composition

Legal Events

Date Code Title Description
A201 Request for examination
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20120427

Year of fee payment: 17

EXPY Expiration of term