KR940014466A - Water soluble cationic polymer composition and preparation method thereof - Google Patents

Water soluble cationic polymer composition and preparation method thereof Download PDF

Info

Publication number
KR940014466A
KR940014466A KR1019920024280A KR920024280A KR940014466A KR 940014466 A KR940014466 A KR 940014466A KR 1019920024280 A KR1019920024280 A KR 1019920024280A KR 920024280 A KR920024280 A KR 920024280A KR 940014466 A KR940014466 A KR 940014466A
Authority
KR
South Korea
Prior art keywords
weight
water
formula
general formula
soluble polymer
Prior art date
Application number
KR1019920024280A
Other languages
Korean (ko)
Other versions
KR950011448B1 (en
Inventor
이상구
김하원
Original Assignee
하기주
주식회사 코오롱
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 하기주, 주식회사 코오롱 filed Critical 하기주
Priority to KR1019920024280A priority Critical patent/KR950011448B1/en
Publication of KR940014466A publication Critical patent/KR940014466A/en
Application granted granted Critical
Publication of KR950011448B1 publication Critical patent/KR950011448B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/38—Esters containing sulfur
    • C08F220/387—Esters containing sulfur and containing nitrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/56—Acrylamide; Methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36—Sulfonation; Sulfation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

본 발명은 아래 일반식(2)의 아크릴아마이드 0-50중량%, 일반식(3)의 다이메틸아미노에틸아크릴레이트 황산염 0-50중량% 및 일반식(4)의 아크릴로일옥시에틸다이메틸술포벤진 암모니움 클로라이드 25-50중량%로 하여 그 전체 농도가 10-20중량%인 수용액을 분산안정제와 라디칼중합개시제로서 수용성 아조 화합물을 사용하여 중합함을 특징으로 하는 아래 일반식 (1)의 수용성 중합체 조성물 및 그 제조방법에 관한 것이다.The present invention is 0-50% by weight of acrylamide of the general formula (2), 0-50% by weight of dimethylaminoethyl acrylate sulfate of the general formula (3) and acryloyloxyethyldimethyl of the general formula (4) 25-50% by weight of sulfobenzine ammonium chloride, and an aqueous solution having a total concentration of 10-20% by weight is polymerized using a water-soluble azo compound as a dispersion stabilizer and a radical polymerization initiator. A water-soluble polymer composition and a method for producing the same.

위의 식에서, a, b 및 c는 0 이상의 정수로서 반응물 각각의 몰수에 의존한다.Wherein a, b and c are integers greater than or equal to 0 depending on the number of moles of each of the reactants.

본 발명은 낮은 온도에서 반응 원료를 중합시켜 고분자량의 중합체를 얻으며, 양이온성 단량체에 술폰기를 도입시키고 제품 자체도 미세하게 분산되어 있으므로 용해성을 극대화하였으며, 카르복시메틸셀룰로즈 등을 사용하여 고농도의 중합체를 안정하게 분산시켜 장기간에 걸쳐 보관안정성을 유지되는 등의 우수한 장점을 보유한다.The present invention polymerizes the reaction raw material at a low temperature to obtain a high molecular weight polymer, introducing sulfone groups into the cationic monomer, and the product itself is finely dispersed, thereby maximizing solubility, using carboxymethyl cellulose, etc. It has excellent advantages such as stable dispersion and maintenance of storage stability over a long period of time.

Description

수용성 양이온 중합체 조성물 및 그 제조방법Water soluble cationic polymer composition and preparation method thereof

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (5)

아크릴아마이드, 다이메틸아미노에틸아크릴레이트 황산염 및 아크릴로일옥시에 틸다이메틸술포벤질 암모니움 클로라이드 수용액을 중합하여 양이온성 수용성 중합체를 제조하는 방법에 있어서, 아래 일반식(2)의 아크릴아마이드 0-50중량%, 일반식(3)의 다이메틸아미노에틸아크릴레이트 황산염 0-50중량% 및 일반식(4)의 아크릴로일옥시에틸다이메틸술포벤진 암모니움 클로라이드 25-50중량%로 하여 그 전체 농도가 10-20중량%인 수용액을 분산안정제와 라디칼중합개시제로서 수용성 아조 화합물을 사용하여 중합함을 특징으로 하는 아래 일반식(1)의 수용성 중합체를 제조하는 방법.A method for producing a cationic water-soluble polymer by polymerizing acrylamide, dimethylaminoethylacrylate sulfate and acryloyloxyethyldimethylsulfobenzyl ammonium chloride aqueous solution, acrylamide of formula (2) below 0-50 The total concentration of dimethylaminoethyl acrylate sulfate 0-50% by weight of the general formula (3) and 25-50% by weight of acryloyloxyethyldimethylsulfobenzine ammonium chloride of the general formula (4) A method of producing a water-soluble polymer of the general formula (1) below, wherein the aqueous solution of 10-20% by weight is polymerized using a water-soluble azo compound as a dispersion stabilizer and a radical polymerization initiator. 위의 식에서, a, b 및 c는 0이상의 정수로서 반응물 각각의 몰수에 의존한다.Where a, b and c are integers greater than or equal to 0 and depend on the number of moles of each of the reactants. 제1항에 있어서, 분산안정제로서 카르복시메틸셀룰로즈 또는 셀룰로즈아세테이트를 순수 대비 0.05-중량% 사용하여 제조하는 방법.The method of claim 1, wherein the carboxymethylcellulose or cellulose acetate is used as a dispersion stabilizer using 0.05-% by weight of pure water. 제1항에 있어서, 수용성 아조 와합물이 아조비스 (아미디노프로판)염산염, 아조비스(프로판산)초산염, 아조비스(N,N′-다이메틸이소부틸이미딘)염산염 또는 아조비스(시아노바레인산 나트륨)임을 특징으로 하는 일반식(1)의 수용성 중합체의 제조방법.Azobis (amidinopropane) hydrochloride, azobis (propanoic acid) acetate, azobis (N, N'-dimethylisobutylimidine) hydrochloride or azobis (cyanobar) according to claim 1, Sodium laurate), wherein the water-soluble polymer of the general formula (1). 제1항에 있어서, 일반식(4)의 화합물을 아래 일반식(5)의 아클리로일욱시에틸다이메틸벤질 암모니움 클로라이드와 일반식(6)의 클로로술폰산을 몰비로 1:1 반응시킴을 특징으로 하는 일반식(1)의 수용성 중합체의 제조방법.The method of claim 1, wherein the compound of formula (4) is reacted 1: 1 with acryloyloxyethyldimethylbenzyl ammonium chloride of the formula (5) at a molar ratio of chlorosulfonic acid of the formula (6). Method for producing a water-soluble polymer of the general formula (1), characterized in that. 아래 일반식(2)의 아크릴아마이드 0-50중량%, 일반식(3)의 다이메틸아미노에틸아크릴레이트 황산염 0-50중량% 및 일반식(4)의 아크릴로일에틸다이메틸술포벤질 암모니움 클로라이드 25-50중량%로 이루어진 수용성 중합체 조성물.0-50% by weight of acrylamide of formula (2), 0-50% by weight of dimethylaminoethylacrylate sulfate of formula (3) and acryloylethyldimethylsulfobenzyl ammonium of formula (4) Water-soluble polymer composition consisting of 25-50% by weight chloride. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019920024280A 1992-12-15 1992-12-15 Compositions of water-soluble cationic polymer and their preparation process KR950011448B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019920024280A KR950011448B1 (en) 1992-12-15 1992-12-15 Compositions of water-soluble cationic polymer and their preparation process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019920024280A KR950011448B1 (en) 1992-12-15 1992-12-15 Compositions of water-soluble cationic polymer and their preparation process

Publications (2)

Publication Number Publication Date
KR940014466A true KR940014466A (en) 1994-07-18
KR950011448B1 KR950011448B1 (en) 1995-10-04

Family

ID=19345577

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920024280A KR950011448B1 (en) 1992-12-15 1992-12-15 Compositions of water-soluble cationic polymer and their preparation process

Country Status (1)

Country Link
KR (1) KR950011448B1 (en)

Also Published As

Publication number Publication date
KR950011448B1 (en) 1995-10-04

Similar Documents

Publication Publication Date Title
US3658772A (en) Acrylic acid polymers
US5297740A (en) Process for the production of polyacrylic acids
BR9815112B1 (en) process for the preparation of synthetic polymers with very low residual monomer content.
KR900006012A (en) Process for preparing water soluble cationic polymer dispersion
EP0183466A2 (en) Process for the production of a water-soluble polymer dispersion
US4970260A (en) Novel viscosifiers for salt-containing solutions based on polymer complexes
US20030120028A1 (en) Thermal responsive, water-soluble polymers
JPS63234007A (en) Highly water-soluble cationic polymer
US4622356A (en) Polyacrylamide and polyacrylic acid polymers
US4260713A (en) Process for producing water-soluble polymers
US3755280A (en) Drying of acrylamide polymer gels
CN102464797B (en) Enether monomer, water-soluble thermothickening copolymer, preparation method, application thereof
US3993712A (en) Water-soluble vinyl-pyrrolidone block copolymers
JPS6011516A (en) Intramolecular polymer composite body-acid, base and viscosity rendering agent for salt solution
KR940014466A (en) Water soluble cationic polymer composition and preparation method thereof
JPS61138607A (en) Polymerization of water-soluble cationic polymer
Erim et al. Aqueous polymerization of acrylamide initiated by 4, 4′-azobis (4-cyano pentanol) and chain extension of polyacrylamide by means of ceric ion redox systems
US4066522A (en) Process for the production of high molecular weight acrylamide polymers
KR900012959A (en) Polymer emulsions
JPS6220511A (en) Production of water-soluble polymer dispersion
KR960014159A (en) High solid content latex manufacturing method
CA1337711C (en) Process for making acrylamido methane sulfonic acid polymers
JPS63235313A (en) Preparation of maleic acid copolymer
KR900002459B1 (en) Water soluble acrylate acrylamide copolymer
SU927802A1 (en) Process for producing fiber-forming (co)polymers of acrylonitrile

Legal Events

Date Code Title Description
A201 Request for examination
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 19980811

Year of fee payment: 4

LAPS Lapse due to unpaid annual fee