KR940011577A - Flame Retardant Thermoplastic Composition - Google Patents

Flame Retardant Thermoplastic Composition Download PDF

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Publication number
KR940011577A
KR940011577A KR1019920021560A KR920021560A KR940011577A KR 940011577 A KR940011577 A KR 940011577A KR 1019920021560 A KR1019920021560 A KR 1019920021560A KR 920021560 A KR920021560 A KR 920021560A KR 940011577 A KR940011577 A KR 940011577A
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KR
South Korea
Prior art keywords
flame retardant
weight
parts
resin composition
thermoplastic resin
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KR1019920021560A
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Korean (ko)
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KR960015113B1 (en
Inventor
이규철
심우철
조광수
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채오병
제일모직 주식회사
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Priority to KR1019920021560A priority Critical patent/KR960015113B1/en
Publication of KR940011577A publication Critical patent/KR940011577A/en
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Publication of KR960015113B1 publication Critical patent/KR960015113B1/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 난연성이 향상된 폴리카보네이트(이하 ″PC″로 칭함)/아크릴로니트릴-부타디엔-스티렌에 관한 것이다.The present invention relates to polycarbonate (hereinafter referred to as "PC") / acrylonitrile-butadiene-styrene with improved flame retardancy.

본 발명은 폴리카보네이트와 아크릴로니트릴-부타디엔-스티렌 공중합체의 혼합물 100중량부에 인계 난연제 1 내지 15중량부와, 다음의 구조식(I)과 같은 구조를 가지는 질소화합물을 1 내지 16중량부가 함유된 것을 특징으로 한다.The present invention contains 1 to 15 parts by weight of a phosphorus flame retardant, and 1 to 16 parts by weight of a nitrogen compound having a structure as shown in the following structural formula (I) in 100 parts by weight of a mixture of a polycarbonate and an acrylonitrile-butadiene-styrene copolymer. It is characterized by.

여기서, X=R1-NH, R1=알킬 또는 시클로알킬, R2=2가의 피페라진 라디칼(PIPERAZINE RADICAL), n=20 내지 50의 정수.Wherein X = R 1 -NH, R 1 = alkyl or cycloalkyl, R 2 = bivalent PIPERAZINE RADICAL, integer of n = 20-50.

상기와 같은 본 발명의 조성물은 드리핑 현상이 방지되고, 가공성과 내열성의 저하가 없다.The composition of the present invention as described above is prevented from the driping phenomenon, there is no degradation in workability and heat resistance.

Description

난연성 열가소성 수지조성물Flame Retardant Thermoplastic Composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (11)

폴리카보네이트와 아크릴로니트릴-부타디엔-스티렌 공중합체의 혼합물 100중량부에 인계 난연제 1 내지 15중량부와, 다음의 구조식(I)과 같은 구조를 가지는 질소화합물을 1 내지 16중량부가 함유된 것을 특징으로 하는 난연성 열가소성 수지 조성물.1 to 15 parts by weight of a phosphorus flame retardant and 1 to 16 parts by weight of a nitrogen compound having a structure as shown in the following formula (I) are contained in 100 parts by weight of the mixture of the polycarbonate and the acrylonitrile-butadiene-styrene copolymer. Flame retardant thermoplastic resin composition. 여기서, X=R1-NH, R1=알킬 또는 시클로알킬, R2=2가의 피페라진 라디칼(PIPERAZINE RADICAL), n=20 내지 50의 정수.Wherein X = R 1 -NH, R 1 = alkyl or cycloalkyl, R 2 = bivalent PIPERAZINE RADICAL, integer of n = 20-50. 제1항에· 있어서, 공중합체 혼합물의 폴리카보네이트와 아크릴로니트릴-부타디엔-스티렌의 중량비가 5-8 : 2-5인 것을 특징으로 하는 난연성 열가소성 수지 조성물.The flame retardant thermoplastic resin composition according to claim 1, wherein the weight ratio of polycarbonate and acrylonitrile-butadiene-styrene in the copolymer mixture is 5-8: 2-5. 제 1항에 있어서, 인계난연제는 비스(1,3-페닐렌-디페닐)포스페이트 또는 트리페닐포스페이트 중 선택된 1종인 것을 특징으로 하는 난연성 열가소성 수지 조성물.The flame retardant thermoplastic resin composition according to claim 1, wherein the phosphorus flame retardant is one selected from bis (1,3-phenylene-diphenyl) phosphate or triphenylphosphate. 제1항에 있어서, 저융점 유약이 2내지 20중량부 더욱 더 포함된 것을 특징으로 하는 난연성 열가소성 수지 조성물.The flame retardant thermoplastic resin composition of claim 1, further comprising 2 to 20 parts by weight of the low melting glaze. 제1항에 있어서, 저융점 유약의 융점이 300내지 500℃인 것을 특징으로하는 난연성 열가소성 수지 조성물.The flame retardant thermoplastic resin composition according to claim 1, wherein the melting point of the low melting glaze is 300 to 500 ° C. 폴리카보네이트와 아크릴로니트릴-부타디엔-스티렌 공중합체의 혼합물 100중량부에 제1항 기재의 인계 난연제 1 내지 15중량부와, 저융점 유약 2 내지 20중량부가 함유된 것을 특징으로 하는 난연성 열가소성 수지 조성물.Flame retardant thermoplastic resin composition comprising 100 parts by weight of the mixture of polycarbonate and acrylonitrile-butadiene-styrene copolymer, 1 to 15 parts by weight of the phosphorus flame retardant according to claim 1, and 2 to 20 parts by weight of the low melting point glaze. . 제6항에 있어서, 상기 구조식(I)과 같은 구조를 가지는 질소화합물을 1 내지 16중량부가 더욱 더 함유된 것을 특징으로 하는 난연성 열가소성 수지 조성물.The flame retardant thermoplastic resin composition according to claim 6, further comprising 1 to 16 parts by weight of a nitrogen compound having the same structure as that of the formula (I). 제6항에 있어서, 공중합체 혼합물의 폴리카보네이트와 아크릴로니트릴-부타디엔-스티렌의 중량비가 5-8 : 2-5인 것을 특징으로 하는 난연성 열가소성 수지 조성물.The flame retardant thermoplastic resin composition according to claim 6, wherein the weight ratio of polycarbonate and acrylonitrile-butadiene-styrene in the copolymer mixture is 5-8: 2-5. 제6항에 있어서, 인계난연제는 비스(1,3-페닐렌-디페닐) 포스페이트 또는 트리페닐포스페이트 중 선택된 1종인 것을 특징으로 하는 난연성 열가소성 수지 조성물.The flame retardant thermoplastic resin composition according to claim 6, wherein the phosphorus flame retardant is one selected from bis (1,3-phenylene-diphenyl) phosphate or triphenylphosphate. 제6항에 있어서, 저융점 유약이 2 내지 20중량부 더욱 더 포함된 것을 특징으로 하는 난연성 열가소성 수지 조성물.The flame retardant thermoplastic resin composition according to claim 6, wherein the low melting glaze further comprises 2 to 20 parts by weight. 제6항에 있어서, 저융점 유약의 융점이 300 내지 500℃인 것을 특징으로 하는 난연성 열가소성 수지 조성물.The flame retardant thermoplastic resin composition according to claim 6, wherein the melting point of the low melting glaze is 300 to 500 ° C. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019920021560A 1992-11-17 1992-11-17 Flame retardant thermoplastic resin composition KR960015113B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019920021560A KR960015113B1 (en) 1992-11-17 1992-11-17 Flame retardant thermoplastic resin composition

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Application Number Priority Date Filing Date Title
KR1019920021560A KR960015113B1 (en) 1992-11-17 1992-11-17 Flame retardant thermoplastic resin composition

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KR940011577A true KR940011577A (en) 1994-06-21
KR960015113B1 KR960015113B1 (en) 1996-10-28

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