KR940011448B1 - Concrete composition - Google Patents

Concrete composition Download PDF

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Publication number
KR940011448B1
KR940011448B1 KR1019920014788A KR920014788A KR940011448B1 KR 940011448 B1 KR940011448 B1 KR 940011448B1 KR 1019920014788 A KR1019920014788 A KR 1019920014788A KR 920014788 A KR920014788 A KR 920014788A KR 940011448 B1 KR940011448 B1 KR 940011448B1
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South Korea
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composition
floor
floor finishing
pigment
construction
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KR1019920014788A
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Korean (ko)
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KR940004161A (en
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전재선
윤명오
박대원
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대한주택공사
김동규
한국케미칼패크주식회사
최귀남
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Priority to KR1019920014788A priority Critical patent/KR940011448B1/en
Publication of KR940004161A publication Critical patent/KR940004161A/en
Priority to KR1019940019971A priority patent/KR940008745B1/en
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Publication of KR940011448B1 publication Critical patent/KR940011448B1/en

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/06Quartz; Sand
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/26Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2641Polyacrylates; Polymethacrylates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/28Polysaccharides or derivatives thereof
    • C04B26/285Cellulose or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/44Thickening, gelling or viscosity increasing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/50Defoamers, air detrainers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/60Flooring materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Civil Engineering (AREA)
  • Floor Finish (AREA)

Abstract

The material is composed of (in wt.%) 49-51 % sand, 23-27 % white cement, 13.5-15.0 % aqueous emulsion of acrylic resin, 2.15-2.25 % aqueous emulsion of acrylic resin, 2.15-2.25 % coloring pigment, 0.14-0.16 % methy cellulose group viscosity builder, 0.075-0.085 % silicon group substance for preventing bubble formation, and 7-8 % water. Usage of the finishing material can express a pattern and a color to the surface of the floor.

Description

바닥마감재용 조성물Floor Finishing Composition

제 1 도는 본 발명에 따른 바닥마감재용 조성물에 의해 시공된 바닥표면의 사진이다.1 is a photograph of the floor surface constructed by the composition for a floor finishing material according to the present invention.

본 발명은 실내 또는 복도 등의 바닥에 사용하는 바닥마감재용 조성물에 관한 것으로 특히 바닥면에 다양한 무늬와 색상을 표현하게 할 수 있음과 더불어 시공이 편리한 분무시공법을 이용할 수 있는 바닥마감재용 조성물에 관한 것이다.The present invention relates to a composition for floor finishing materials used for floors, such as indoors or hallways, and in particular, to a variety of patterns and colors can be expressed on the floor surface and to a composition for floor finishing materials that can use a convenient spray construction method will be.

일반적으로 실내나 복도 등의 바닥에는 용도를 고려하여 장식성과 실용성의 요구수준에 따라 아주 다양한 재료들이 사용되고 있는데, 이를 시공방법에 따라 구분하여 보면, 시멘트 모르타르와 같은 바름공법으로 시공하는 바닥마감재, 타일과 같은 붙임공법으로 시공하는 바닥마감재, 에폭시수지와 같은 도장공법으로 시공하는 바닥마감재 등이 있다. 이들 각각의 바닥마감재들은 시공의 편리성, 외관효과의 미려함, 실용성 및 경제성의 측면에서 볼 때 각각 일장일단이 있지만, 통상의 건물바닥에 가장 보편적으로 사용되는 것은 바름공법 및 물갈기공법으로 시공되는 인조석이라고 할 것인바, 이것은 천연 석재류에 비해 가격이 저렴하면서도 천연 석재류의 외관효과를 발휘하며, 뛰어난 내구성을 가지기 때문이다.In general, a variety of materials are used for indoor and corridor floors according to the requirements of decoration and practicality in consideration of the purpose of use, and according to the construction method, floor finishing materials and tiles, which are constructed by the coating method such as cement mortar, are used. There is a floor finishing material to be applied by the same method, such as, the floor finishing material to be applied by the coating method such as epoxy resin. Each of these floor finishing materials is finished in terms of convenience, beauty of appearance effect, practicality and economical efficiency. However, the most commonly used flooring materials are artificial stone which is applied by the painting method and the grinding method. This is because it is cheaper than natural stone, but exhibits the appearance effect of natural stone, and has excellent durability.

그러나 상기와 같은 인조석은, 대리석 등의 쇄석과 시멘트의 혼합물을 재료로 하여 이를 물에 개어서 바닥에 바르고 양생한 후 물갈기를 하는 복잡한 시공과정을 거쳐서 만들어지기 때문에, 과다한 인력투입이 요구되고, 또한 물갈기 할때 발생되는 시멘트물로 인해 주위의 벽면이 더러워지고 이를 다시 청소를 해야 하는 불편함이 있음은 물론 작업여건이 열악해져 작업자들이 기피하게 되었고, 이는 인력수급의 어려움으로 이어지고 결국은 시공비 상승을 초래하는 문제점을 야기시켰다. 또한 이와 같은 인조석은 그 무늬나 색조의 변화가 거의 제한되어 표면무늬의 다양한 표현욕구를 충족시켜 줄 수 없는 문제점이 있었다.However, the artificial stone as described above is made through a complex construction process of mixing a mixture of crushed stone such as marble and cement with water, applying it to the floor, curing it, and then grinding it. Cement water generated during the watering causes the surrounding walls to become dirty and the inconvenience of having to clean them again, as well as the poor working conditions, has led to workers' avoidance, which leads to difficulties in supply and demand and eventually increases construction costs. It caused a problem that caused. In addition, such artificial stone has a problem that the change of the pattern or the color tone is almost limited to satisfy various expression desires of the surface pattern.

이에 본 발명은 상기와 같은 문제점에 착안하여 천연 석재류의 외관 효과와 내구성을 유지하면서도 분무시공법을 이용함으로써 시공이 편리하고, 다양한 표면무늬를 표현할 수 있는 바닥마감재용 조성물을 제공하는데 그 목적이 있다.Accordingly, the present invention has been made in view of the above problems, while maintaining the appearance effect and durability of the natural stone materials by using a spray construction method, the construction is convenient, it is an object to provide a composition for a floor finishing material that can express a variety of surface patterns. .

상기와 같은 목적을 달성하기 위한 본 발명에 따른 바닥마감재용 조성물은, 모래와 백시멘트(白시멘트)의 혼합물에 수성아크릴수지(에멀젼), 색소안료, 점도증강제 및 기포방지제(소포제)가 첨가되고 다시 물이 배합된 조성물로 이루어진다.In the composition for a floor finishing material according to the present invention for achieving the above object, an aqueous acrylic resin (emulsion), a pigment pigment, a viscosity enhancer and an antifoaming agent (antifoaming agent) is added to a mixture of sand and white cement (baek cement) Again, the composition consists of water.

상기의 모래는 본 발명의 목적상 가는 모래로 하는 것이 바람직하고, 그 혼합비율은 시공바탕면인 콘크리트와의 부착안정성을 높여 균열이 발생하지 않도록 하는 범위가 되어야 하는 바, 그 함량은 49-51중량%가 가장 바람직하다.The sand is preferably made of fine sand for the purposes of the present invention, the mixing ratio should be within the range to increase the adhesion stability with the concrete, which is the construction surface so that cracks do not occur, the content is 49-51 Weight percent is most preferred.

상기의 백시멘트는 시멘트의 본래적 기능대로 여러 재료를 교착시키는 기능을 하는 것으로, 바탕층과의 부착성 및 내마모성을 고려하여 그 비율을 23-27중량%로 하는 것이 바람직하며, 통상의 시멘트 대신 백색으로한 것은 다른 첨가요소인 색소안료의 색상이 그대로 발현되도록 하기 위함이다.The back cement functions to interlock various materials in accordance with the original function of the cement. In view of the adhesion to the base layer and the abrasion resistance, the ratio of the back cement is preferably 23 to 27% by weight. The reason for the whiteness is to express the color of the pigment pigment, which is another additional element.

상기의 수성아크릴수지(에멀젼)은 흡수성, 내마모성 및 신축성을 부여하는 기능을 하는 것으로서, 이것의 혼합비율은 바닥마감재용 조성물의 품질, 특히 내구성에 중대한 영향을 끼치는 바, 13.5-15.0중량%, 더욱 구체적으로는 14.2중량%가 바람직하다.The aqueous acrylic resin (emulsion) has a function of imparting absorbency, wear resistance and elasticity, the mixing ratio thereof is 13.5-15.0% by weight, which significantly affects the quality of the flooring composition, in particular durability Specifically, 14.2 weight% is preferable.

상기의 색소안료는 공지의 여러가지 색소가 사용될 수 있으며, 각각의 바닥마감재용 조성물에 첨가되는 색소를 달리하여 바닥마감재용 조성물을 여러가지 색상으로 준비하여 두고 바닥의 시공시 적절한 배합에 의해 다양한 표면무늬를 표현할 수 있게 한다. 색소안료의 양은 일광으로 인한 변색, 표면마찰과 물걸레질 등으로 인한 탈색 또는 변색, 얼룩의 생성 등을 방지하기 위해 적절하게 조절되어야 하며, 가장 바람직하기로는 2.15-2.25중량%이다.The pigment pigments described above may be used in a variety of known pigments, by preparing a composition for the floor finishing material in a variety of colors by varying the pigments added to the composition for each floor finishing material and various surface patterns by the appropriate formulation during the construction of the floor To express. The amount of the pigment pigment should be appropriately adjusted to prevent discoloration due to sunlight, discoloration or discoloration due to surface friction and mopping, generation of spots, and most preferably 2.15-2.25% by weight.

상기의 점도증강제는 무기질인 모래와 유기질인 다른 성분들과의 친화성을 높이는 기능을 하는 것으로, 메틸셀룰로오스(C6H7O2(OH)2OCH3)계가 대표적으로 사용되는데, 시판되는 제품으로 신월화학사(일본)의 "메트로우즈(Metlose)", 다우케미칼(Dow Chemical)의 "메쏘셀(Methocell)" 등이 있다. 점도증강제의 함량은 0.14-0.16중량%가 바람직한데, 이 함량 범위에서 점도증강제는 다른 원료와 양호한 혼합성을 가지게 되어 바닥마감용 조성물로 하여금 균질의 평활성이 확보되게 함은 물론 표면균열현상을 막아주고 내구성도 향상시켜 주게된다.The viscosity enhancer is to increase the affinity between the inorganic sand and other organic components, methyl cellulose (C 6 H 7 O 2 (OH) 2 OCH 3 ) type is typically used, commercially available products Examples include "Metlose" by Shinwol Chemical Co., Ltd. (Japan) and "Methocell" by Dow Chemical. The content of the viscosity enhancer is preferably 0.14-0.16% by weight. In this content range, the viscosity enhancer has good mixing properties with other raw materials, thereby ensuring the uniformity of the floor finishing composition and preventing surface cracking. It also gives durability.

상기의 기포방지제(소포제)는 재료의 혼합 또는 바닥마감용 조성물의 분무시공 과정에서 기포가 발생되는 것을 막아주는 것으로, 실리콘계를 이용하는데, 대표적인 제품으로 노프코(NOPCO)사의 "엔엑스젯트(NXZ)"가 시판되고 있으며, 그 함량은 0.075-0.085중량%가 바람직하다.The anti-foaming agent (foaming agent) is to prevent the bubbles are generated during the mixing of the material or spraying the composition of the floor finishing, using a silicone-based, is a representative product "NOXCO (NXZ) as a representative product ) "Is commercially available and its content is preferably 0.075-0.085 wt%.

상기의 배합되는 물은 그 함량이 7-8중량%가 바람직하며, 또한 시공시 배합하는 것이 바람직하다.The content of the above-mentioned water is preferably 7-8% by weight, and it is preferable to mix the water during construction.

본 발명의 가장 바람직한 실시예를 들면 다음과 같다.The most preferred embodiment of the present invention is as follows.

실시예 본 발명에 따른 바닥마감용 조성물의 조성비율EXAMPLES Composition ratio of the floor finishing composition according to the present invention

* 색소안료는 연녹색, 연황색 및 회색으로 하여 3종의 바닥마감재용 조성물을 제조하고, 시공시 적절한 조합에 의해 다양한 표현무늬를 형성할 수 있게 한다.* Pigment pigments are light green, light yellow and gray to prepare three types of floor finishing compositions, and can be used to form a variety of expression patterns by a suitable combination during construction.

* 물은 시공할때 배합하는 것이 바람직하다.* It is desirable to mix water when constructing.

상기와 같이 조성된 바닥마감재용 조성물은 시공방법면에서 뿐만 아니라 시공된 바닥의 품질면에서도 양호한 효과가 있는 바, 즉 적당히 첨가된 점도증강체에 의해 적절한 점도를 가짐과 더불어 전개성도 양호하고, 기포방지제에 의해서는 기포의 생성이 방지되므로, 스프레이 등을 이용해 분무식으로 시공이 가능하여 시공의 편리함과 함께 시공단가의 절감효과가 있으며, 또한 바닥마감재용 조성물이 상기와 같이 각 성분들이 적절히 첨가, 배합되어 있기 때문에 시공된 완성바닥은 바탕면인 콘크리트와의 양호한 부착안정성으로 인해 박리 및 균열현상이 방지되며, 내마모성, 내구성, 평활성, 착색성 등에 있어서 양호한 품질효과가 발생되는 것이다. 또한 본 발명에 따른 바닥마감재용 조성물로 바닥시공을 할때, 사전에 색소안료를 달리 함으로써 여러가지 색상의 바닥마감용 조성물을 별도 준비하여, 분무장치를 이용하여 동시에 분사함으로써 편리하면서도 다양한 표면무늬를 표현할 수 있게 해주는 효과가 있는 것이다. 제 1 도는 본 발명에 따른 바닥 마감재용 조성물에 의해 시공된 바닥표면의 사진으로서, 연녹색, 연황색, 회색의 바닥마감재용 조성물이 동시에 분사되어서 양호한 색감과 천연대리석의 외관과 유사한 미감이 표현된 바닥면 상태를 보여주고 있다.The composition for the floor finishing material prepared as described above has a good effect not only in terms of construction method but also in terms of quality of the constructed floor, that is, it has good viscosity and good developability due to the appropriately added viscosity strengthening body, and bubbles. Since the generation of bubbles is prevented by the inhibitor, it is possible to spray by spraying, etc., so that the construction is convenient and the cost of construction is reduced. In addition, the composition for the floor finishing material is properly added, Since it is compounded, the finished floor is prevented from peeling and cracking due to good adhesion stability with concrete as a base surface, and good quality effect is generated in wear resistance, durability, smoothness, colorability, and the like. In addition, when the floor construction with the composition for the floor finishing material according to the invention, by preparing a separate composition for the floor finishing of various colors by changing the pigment in advance, by spraying at the same time using a spray device to express a convenient and various surface pattern It has the effect of making it possible. 1 is a photograph of the floor surface constructed by the floor finishing composition according to the present invention, the light green, light yellow, gray floor finishing composition is sprayed at the same time to express a good color and aesthetic similar to the appearance of natural marble It shows the state of the noodle.

Claims (1)

모래 49-51중량%, 백시멘트 23-27중량%, 수성아크릴수지(에멀젼) 13.5-15.0중량%, 색소안료 2.15-2.25중량%, 메틸셀룰로오스계 점도증강제 0.14-0.16중량%, 실리콘계 기포방지제 0.075-0.085중량% 및 물 7-8중량%로 이루어진 바닥마감재용 조성물.Sand 49-51 wt%, Back cement 23-27 wt%, Aqueous acrylic resin (emulsion) 13.5-15.0 wt%, Pigment pigment 2.15-2.25 wt%, Methyl cellulose viscosity enhancer 0.14-0.16 wt%, Silicone foam prevention agent 0.075 -0.085% by weight and 7-8% by weight of the water composition for the floor finish.
KR1019920014788A 1992-08-17 1992-08-17 Concrete composition KR940011448B1 (en)

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