KR940006639A - A method of converting hydrocarbon oil using the catalyst composition, a composition of a suitable material as a catalyst substrate, a hydrogenation conversion catalyst composition containing the same, and a catalyst composition during hydrogenation. - Google Patents

A method of converting hydrocarbon oil using the catalyst composition, a composition of a suitable material as a catalyst substrate, a hydrogenation conversion catalyst composition containing the same, and a catalyst composition during hydrogenation. Download PDF

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KR940006639A
KR940006639A KR1019930018454A KR930018454A KR940006639A KR 940006639 A KR940006639 A KR 940006639A KR 1019930018454 A KR1019930018454 A KR 1019930018454A KR 930018454 A KR930018454 A KR 930018454A KR 940006639 A KR940006639 A KR 940006639A
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South Korea
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composition
catalyst
zeolite
modified
catalyst composition
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KR1019930018454A
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Korean (ko)
Inventor
안토니우스 로베르트 반 비인 요하네스
Original Assignee
알베르투스 빌헬무스
셀 인터나쵸 나아레 레사아치 마아츠샤피 비이부이
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Publication of KR940006639A publication Critical patent/KR940006639A/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/076—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used

Abstract

단위 셀 사이즈 24.37Å 미만, 개질 Y 제올라이트의 적어도 8중량%의 물 흡착능(P/Po값 0.2 및 25℃에서), 총 공극량의 10% 내지 60%가 적어도 8㎚의 직경을 갖는 공극으로 구성되는 적어도 0.25㎖/g의 공극량을 갖고, 적외선 주파 영역 3630±10㎝-1내 흡광도에 의해 나누어진 적외서 주파 영역 3670±10㎝-1내 흡광도로서 표시된 흡광도 비가 최대한 0.040인 개질 Y 제올라이트로 구성된 결정성 알루미노실리케이트, 및 결합제로 구성된, 수소첨가 가공시 기재로서 적당한 물질의 조성물.Unit cell size less than 24.37 mm 3, water adsorption capacity (at P / Po values of 0.2 and 25 ° C.) of at least 8 wt. having at least gonggeukryang 0.25㎖ / g, infrared frequency range 3630 ± 10㎝ -1 crystal consisting of binary ever oeseo frequency of modified Y zeolite region 3670 ± 10㎝ -1 absorbance ratio is the most 0.040 as shown in the absorbance divided by the absorbance in A composition of matter suitable as a substrate in hydroprocessing, consisting of a sex aluminosilicate, and a binder.

본 발명은 또한 수소첨가 전환 촉매 및 상기 수소첨가 전환 촉매를 기재로 한 방법에 관한 것이다.The invention also relates to a hydrogenation conversion catalyst and a process based on said hydrogenation conversion catalyst.

Description

수소첨가가공시 촉매 기재로서 적당한 물질의 조성물, 이를 함유하는 수소첨가전환 촉매 조성물 및 상기 촉매조성물을 사용하여 탄화수소 오일을 전환시키는 방법A method of converting hydrocarbon oil using the catalyst composition, a composition of a suitable material as a catalyst substrate, a hydrogenation conversion catalyst composition containing the same, and a catalyst composition during hydrogenation.

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (17)

단위 셀 사이즈 24.37Å 미만, 개질 Y 제올라이트의 적어도 8중량%의 물 흡착능(P/Po값 0.2 및 25℃에서), 총 공극량의 10% 내지 60%가 적어도 8㎚의 직경을 갖는 공극으로 구성되는 적어도 0.25㎖/g의 공극량을 갖고, 적외선 주파 영역 3630±10㎝-1내 흡광도에 의해 나누어진 적외선 주파 영역 3670±10㎝-1내 흡광도로서 표시된 흡광도 비가 최대한 0.040인 개질 Y 제올라이트로 구성된 결정성 알루미노실리케이트, 및 결합제로 구성된, 수소첨가 가공시 기재로서 적당한 물질의 조성물.Unit cell size less than 24.37 mm 3, water adsorption capacity (at P / Po values of 0.2 and 25 ° C.) of at least 8 wt. at least has a gonggeukryang of 0.25㎖ / g, infrared frequency range 3630 ± 10㎝ -1 in infrared absorption frequency range divided by the 3670 ± 10㎝ crystal consisting of an absorbance in the modification ratio is -1 absorbance maximum 0.040 Y zeolite shown castle A composition of matter suitable as a substrate in hydroprocessing, consisting of an aluminosilicate and a binder. 제1항에 있어서, 흡광도 비가 0.03인 조성물.The composition of claim 1 wherein the absorbance ratio is 0.03. 제1 또는 2항에 있어서, 단위 셀 사이즈가 24.27 내지 24.35Å 범위인 조성물.The composition of claim 1 or 2 wherein the unit cell size ranges from 24.27 to 24.35 mm 3. 제3항에 있어서, 단위 셀 사이즈가 24.29내지 24.33Å 범위인 조성물.The composition of claim 3, wherein the unit cell size is in the range of 24.29 to 24.33 mm 3. 제1－4항중 어느 한 항에 있어서, 개질 Y 제올라이트의 총 공극량의 10%내지 40%가 적어도 8㎚의 직경을 갖는 공극으로 구성되는 조성물.The composition according to any one of claims 1 to 4, wherein 10% to 40% of the total pore amount of the modified Y zeolite consists of pores having a diameter of at least 8 nm. 제1－5항중 어느 한 항에 있어서, 개질 Y 제올라이트가 개질 Y 제올라이트의 8－12중량%의 물 흡착능을 갖는 조성물.The composition according to any one of claims 1 to 5, wherein the modified Y zeolite has a water adsorption capacity of 8-12% by weight of the modified Y zeolite. 제1－6항중 어느 한 항에 있어서, 개질 Y 제올라이트가 SiO2/Al2O2몰비 4내지 25를 갖는 조성물.The composition of any one of claims 1-6, wherein the modified Y zeolite has a SiO 2 / Al 2 O 2 molar ratio 4 to 25. 제7항에 있어서, 개질 Y 제올라이트가 SiO2/Al2O3몰비 8내지 15를 갖는 조성물.8. The composition of claim 7, wherein the modified Y zeolite has a SiO 2 / Al 2 O 3 molar ratio of 8 to 15. 제1－8항중 어느 한 항에 있어서, 조성물이 개질 Y 제올라이트 5내지 90중량% 및 결합제 10내지 95중량%로 구성되는 조성물.The composition of claim 1, wherein the composition consists of 5 to 90 weight percent of modified Y zeolite and 10 to 95 weight percent binder. 제1－9항중 어느 한 항에 있어서, 결합제는 무기 산화물 또는 무기 산화물의 혼합물로 구성되는 조성물.10. The composition of any one of claims 1-9, wherein the binder consists of an inorganic oxide or a mixture of inorganic oxides. 결합제, 제1－10항중 어느 한 항에 따른 개질 Y 제올라이트 및 Ⅵ족 금속 수소첨가 성분 적어도 하나 및/또는 Ⅷ족 금속 수소첨가 성분으로 적어도 하나로 구성되는 촉매 조성물.A catalyst composition comprising at least one binder, at least one modified Y zeolite according to any one of claims 1-10 and a Group VI metal hydrogenation component and / or a Group VIII metal hydrogenation component. 제11항에 있어서, 수소첨가 성분이 니켈 및/또는 코발트 성분 하나 이상 및 올리브덴 및/또는 텅스텐 성분 하나 이상 또는 플라티늄 및/또는 팔라듐 성분 하나 이상으로 구성되는 촉매 조성물.The catalyst composition of claim 11, wherein the hydrogenation component comprises at least one nickel and / or cobalt component and at least one oliveden and / or tungsten component or at least one platinum and / or palladium component. 제12항에 있어서, 수소첨가 성분이 총 촉매의 중량 100부당 금속으로서 계산된, 니켈 0.05내지 10중량% 및 텅스텐 2내지 40중량%로 구성되는 촉매 조성물.13. The catalyst composition of claim 12, wherein the hydrogenation component consists of 0.05 to 10% nickel and tungsten 2 to 40% by weight, calculated as metal per 100 parts by weight of the total catalyst. 제11－13항중 언 한 항에 있어서, 수소첨가 성분(들)이 황화물 형태로 존재하는 촉매 조성물.The catalyst composition of any one of claims 11-13, wherein the hydrogenation component (s) are in the form of sulfides. 탄화수소 오일을 높은 온도 및 압력에서 수소의 존재하에 제11－14항중 어느 한 항에 따른 촉매 조성물과 접촉시키는 것으로 구성되는 보다 낮은 평균 분자량 및 보다 낮은 평균 비점의 생성물로 탄화수소 오일을 전환시키는 방법.A process for converting a hydrocarbon oil into a product of lower average molecular weight and lower average boiling point consisting of contacting the hydrocarbon oil at high temperature and pressure in the presence of hydrogen in the catalyst composition according to claim 11. 제15항에 있어서, 온도 250℃－500℃범위, 수소분압 300 바아 이하 및 공간속도 시간 당 촉매 리터당 공급물 0.1내지 10㎏에서 실행되는 방법.The process according to claim 15, wherein the process is carried out at a temperature in the range of 250 ° C.-500 ° C., a partial pressure of hydrogen below 300 bar and a feed rate of 0.1 to 10 kg per liter of catalyst per hour of space velocity. 제16항에 있어서, 온도 300℃내지 450℃, 수소분압 200바아 및 공간 속도 시간당 촉매 리터 당 공급물 0.2내지 5㎏에서 실행되는 방법.The process according to claim 16, wherein the process is carried out at a temperature of 300 ° C. to 450 ° C., a hydrogen partial pressure of 200 bar and a space velocity of 0.2 to 5 kg of feed per liter of catalyst per hour. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019930018454A 1992-09-17 1993-09-14 A method of converting hydrocarbon oil using the catalyst composition, a composition of a suitable material as a catalyst substrate, a hydrogenation conversion catalyst composition containing the same, and a catalyst composition during hydrogenation. KR940006639A (en)

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JP (1) JPH06210178A (en)
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CN (1) CN1112954A (en)
AU (1) AU663970B2 (en)
BR (1) BR9303790A (en)
CA (1) CA2106259A1 (en)
FI (1) FI934047A (en)
NZ (1) NZ248669A (en)
SG (1) SG94675A1 (en)
ZA (1) ZA936790B (en)

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US6790803B2 (en) * 2001-08-17 2004-09-14 Intevep, S.A. Catalytic system for hydroconversion of naphtha

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NL8601384A (en) * 1986-05-29 1987-12-16 Texas Instruments Holland COMBUSTION ENGINE WITH FUEL INJECTION SYSTEM AND AN INJECTION VALVE INTENDED FOR SUCH AN ENGINE.
GB8613132D0 (en) * 1986-05-30 1986-07-02 Shell Int Research Hydrocarbon conversion catalysts
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NZ248669A (en) 1994-09-27
AU4738493A (en) 1994-03-24
FI934047A0 (en) 1993-09-15
ZA936790B (en) 1994-04-14
JPH06210178A (en) 1994-08-02
FI934047A (en) 1994-03-18
AU663970B2 (en) 1995-10-26
SG94675A1 (en) 2003-03-18
CN1112954A (en) 1995-12-06
CA2106259A1 (en) 1994-03-18
BR9303790A (en) 1994-05-10

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