KR940003443A - Optical polarized particles and manufacturing method thereof - Google Patents

Optical polarized particles and manufacturing method thereof Download PDF

Info

Publication number
KR940003443A
KR940003443A KR1019920019525A KR920019525A KR940003443A KR 940003443 A KR940003443 A KR 940003443A KR 1019920019525 A KR1019920019525 A KR 1019920019525A KR 920019525 A KR920019525 A KR 920019525A KR 940003443 A KR940003443 A KR 940003443A
Authority
KR
South Korea
Prior art keywords
dicarboxylic acid
particle
light polarizing
pyrazine
polymer dispersant
Prior art date
Application number
KR1019920019525A
Other languages
Korean (ko)
Inventor
이정훈
유병석
Original Assignee
최영증
한국유리공업 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 최영증, 한국유리공업 주식회사 filed Critical 최영증
Priority to KR1019920019525A priority Critical patent/KR940003443A/en
Publication of KR940003443A publication Critical patent/KR940003443A/en

Links

Landscapes

  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

본 발명은, 필름매질이 될 고분자 수지와 친화력이 없으며 광편광 입자의 분산효과를 높여주는 고분자분산제의 존재하에서, 광편광입자의 기초형성 물질인 피라진 2,3-디카복실산, 피라진 2,5-디카복실산, 피리딘 2,5-디카복실산, 옥시퀴놀린, 디하이드로신초나이딘설페이트 그리고 2-옥시피리딘 중에서 선택된 하나의 물질과 요오드 화합물을 반응시켜서 된 광편광물질을 제공한다.The present invention is a pyrazine 2,3-dicarboxylic acid, pyrazine 2,5- which is a base forming material of the light polarizing particles in the presence of a polymer dispersant which has no affinity with the polymer resin to be a film medium and enhances the dispersion effect of the light polarizing particles. An optical polarizer is prepared by reacting an iodine compound with a substance selected from dicarboxylic acid, pyridine 2,5-dicarboxylic acid, oxyquinoline, dihydrocinchonitine sulfate and 2-oxypyridine.

상기의 고분자 분산제는 폴리하이드록시에틸메타크릴레이트, 폴리아크릴산. 셀룰로스아세테이트, 옥시프로필아크릴레이트 그리고 니트로셀룰로스 중 어느 하나인 것 이 바람직하다. 상기의 광편광 입자 크기는 1㎛ 이하, 더욱 상세하게는 0.1 ∼0.3㎛인 것이 바람직하다. 본 발명에 의한 광편광 입자는 폴리하이드록시에틸메타크릴레이트, 폴리아크릴산, 셀룰로스아세테이트, 하이드록시프로필아크릴레이트 및 니트로셀룰로스 중에서 선택한 하나의 용매로 녹여 고분자 분산제의 용액을 만들고, 상기의 고분자 분산제 용액에 광편광 입자의 기초 형성물질이 될 피라진 2,3-디카복실산, 피라진 2,5-디카복실산, 피리딘 2, 5-디카복실산, 옥시퀴놀린, 디하이드로신초나이딘 설페이트 그리고 2-옥시피리딘 중에서 하나의 물질을 선택하여 요오드 화합물과 함께 첨가하고 고분자 분산제의 용액내에서 광편광 입자 기초형성물질과 요오드 화합물을 반응시켜 제조할 수 있다.Said polymeric dispersing agent is polyhydroxyethyl methacrylate, polyacrylic acid. Preference is given to any one of cellulose acetate, oxypropyl acrylate and nitrocellulose. Said optical polarization particle size is 1 micrometer or less, More preferably, it is 0.1-0.3 micrometers. The optically polarized particles according to the present invention are dissolved in one solvent selected from polyhydroxyethyl methacrylate, polyacrylic acid, cellulose acetate, hydroxypropyl acrylate, and nitrocellulose to form a solution of a polymer dispersant, and the polymer dispersant solution One of pyrazine 2,3-dicarboxylic acid, pyrazine 2,5-dicarboxylic acid, pyridine 2, 5-dicarboxylic acid, oxyquinoline, dihydrocinchonaidine sulfate and 2-oxypyridine, which will form the basis for the photopolarized particles The material may be selected and added together with the iodine compound and prepared by reacting the optically polarized particle base-forming material with the iodine compound in a solution of the polymer dispersant.

Description

광편광입자 및 그의 제조방법Optical polarized particles and manufacturing method thereof

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제4도는 본 발명에 의한 투과도 가변창의 단면구조 개략도,4 is a schematic cross-sectional view of a variable transmittance window according to the present invention;

제5도는 제4도의 투과도 가변창에 전계가 인가되지 않은 경우, 현탁액내에 들어있는 광편광 입자의 배열상태 설명도.FIG. 5 is an explanatory view of the arrangement state of the light polarized particles contained in the suspension when no electric field is applied to the variable transmittance window shown in FIG.

Claims (6)

필름매질이 될 고분자 수지와 친화력이 없으며 광편광 입자의 분산효과를 높여주는 고분자분산제의 존재하에서, 광편광입자의 기초형성물질인 피라진 2,3-디카복실산, 피라진 2,5-디카복실산, 피리딘 2,5-디카복실산, 옥시퀴놀린, 디하이드로신초나이딘 설페이트 그리고 2-옥시피리딘 중에서 선택된 하나의 물질과 요오드 화합물을 반응시켜서 된 것을 특징으로 하는 광편광입자.Pyrazine 2,3-dicarboxylic acid, pyrazine 2,5-dicarboxylic acid, pyridine, which are basic forming materials of light polarizing particles, in the presence of a polymer dispersant which has no affinity with the polymer resin to be a film medium and enhances the dispersion effect of the light polarizing particles. An optically polarized particle characterized by reacting an iodine compound with one substance selected from 2,5-dicarboxylic acid, oxyquinoline, dihydrocinchonaidine sulfate and 2-oxypyridine. 제1항에 있어서, 상기 고분자 분산제는 폴리하이드록시에틸메타크릴레이트, 폴리아크릴산, 셀룰로스아세테이트, 옥시프로필아크릴레이트 그리고 니트로셀룰로스 중 어느 하나인 것임을 특징으로 하는 광편광입자.The optically polarized particle of claim 1, wherein the polymer dispersant is any one of polyhydroxyethyl methacrylate, polyacrylic acid, cellulose acetate, oxypropyl acrylate, and nitrocellulose. 제1항에 있어서, 상기 광편광 입자는 요오드화착화물에 고분자 분산제가 피복되어 있는 입자인 것임을 특징으로 하는 광편광 입자.The light polarizing particle of claim 1, wherein the light polarizing particle is a particle in which a polymer dispersant is coated on an iodide complex. 제1항에 있어서, 상기 광편광 입자의 크기는 1㎛ 이하인 것을 특징으로 하는 광편광 입자.The light polarizing particle of claim 1, wherein the size of the light polarizing particle is 1 μm or less. 제4항에 있어서, 상기 광편광 입자의 크기는 0.1∼0.3㎛인 것을 특징으로 하는 광편광 입자.The light polarizing particle of claim 4, wherein the size of the light polarizing particle is 0.1 to 0.3 μm. 폴리하이드록시에틸메타크릴레이트, 폴리아크릴산, 셀룰로스 아세테이트, 하이드록시프로필아크릴레이트 및 니트로셀룰로스 중에서 선택한 하나의 용매로 녹여 고분자 분산제의 용액을 만들고, 상기의 고분자 분산제 용액에 광편광 입자의 기초 형성물질이 될 피라진 2,3-디카복실산, 피라진 2,5-디카복실산, 피리딘 2,5-디카복실산, 옥시퀴놀린, 디하이드로 신초나이딘 설페이트 그리고 2-옥시피리딘 중에서 하나의 물질을 선택하여 요오드 화합물과 함께 첨가하고 고분자 분산제의 용액내에서 광편광 입자 기초 형성물질과 요오드 화합물이 반응하여 이루어진 반응착화합물의 광편광 입자의 제조방법.It is dissolved in one solvent selected from polyhydroxyethyl methacrylate, polyacrylic acid, cellulose acetate, hydroxypropyl acrylate, and nitrocellulose to form a solution of a polymer dispersant. Select one of the pyrazine 2,3-dicarboxylic acid, pyrazine 2,5-dicarboxylic acid, pyridine 2,5-dicarboxylic acid, oxyquinoline, dihydrocinchonaidine sulfate and 2-oxypyridine to be used together with the iodine compound. A method for producing optically polarized particles of a reaction complex compound, which is added and reacted with an optically polarized particle base-forming substance and an iodine compound in a solution of a polymer dispersant. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019920019525A 1992-10-23 1992-10-23 Optical polarized particles and manufacturing method thereof KR940003443A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019920019525A KR940003443A (en) 1992-10-23 1992-10-23 Optical polarized particles and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019920019525A KR940003443A (en) 1992-10-23 1992-10-23 Optical polarized particles and manufacturing method thereof

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
KR1019920011659A Division KR960014118B1 (en) 1992-01-10 1992-07-01 Method for making film with polarized light-suspension

Publications (1)

Publication Number Publication Date
KR940003443A true KR940003443A (en) 1994-02-21

Family

ID=67210408

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920019525A KR940003443A (en) 1992-10-23 1992-10-23 Optical polarized particles and manufacturing method thereof

Country Status (1)

Country Link
KR (1) KR940003443A (en)

Similar Documents

Publication Publication Date Title
KR930016495A (en) Transmittance film with optical polarization suspension dispersed in polymer resin and its manufacturing method
US2604817A (en) Light polarizing composition
JPH03266826A (en) Optical modulation display element and display method
DE3876934T2 (en) OPTICAL OBJECT WITH A HIGH LEVEL OF SECOND ORDER POLARIZATION SENSITIVITY.
US4273422A (en) Light valve containing liquid suspension including polymer stabilizing system
CA2228920A1 (en) Twisting-cylinder display
EP0177063A2 (en) Process for producing optically readable information
US5002701A (en) Light polarizing materials and suspensions thereof
US5093041A (en) Light-polarizing material based on ethylenediamine polyacetic acid derivatives
EP0010739A1 (en) Light diffuser
KR940003443A (en) Optical polarized particles and manufacturing method thereof
US5322760A (en) Nonlinear optical element
Schäfer et al. supported elastomeric opal films for enhanced and reversible solvatochromic response
JPH11293116A (en) Non-birefringent optical resin material
AU737670B2 (en) Light-polarizing particles of improved particle size distribution
CN101236270A (en) Directional fiber based scatter-type polarizing disc and method for making same
RU2059274C1 (en) Controlled light filter on the base of photochrome material
EP0403711B1 (en) Light polarizing materials and suspensions thereof
US6334967B1 (en) Light-polarizing particles of improved particle size distribution
JP4859114B2 (en) Photochromic material
JPH0493822A (en) Nonlinear optical material and nonlinear optical element
JPH01217328A (en) Organic nonlinear optical material
CA1336858C (en) Light polarizing materials and suspensions thereof
JPS61123835A (en) Photosensitive resin composition
DE69933127T2 (en) POLYHALOGENIDE PARTICLES AND LIGHT VALVES CONTAINING THEREOF

Legal Events

Date Code Title Description
A107 Divisional application of patent
A201 Request for examination
WITB Written withdrawal of application