KR930019809A - Structured Liquid Cleanser Composition Containing Amido and Imido Peroxy Acids - Google Patents

Structured Liquid Cleanser Composition Containing Amido and Imido Peroxy Acids Download PDF

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Publication number
KR930019809A
KR930019809A KR1019930005023A KR930005023A KR930019809A KR 930019809 A KR930019809 A KR 930019809A KR 1019930005023 A KR1019930005023 A KR 1019930005023A KR 930005023 A KR930005023 A KR 930005023A KR 930019809 A KR930019809 A KR 930019809A
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South Korea
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group
groups
percarboxybenzoyl
cleaning composition
alkyl
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KR1019930005023A
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Korean (ko)
Inventor
린 구프 자네트
알란 마디손 스테펜
프레데릭 헤셀 죤
죠세 쿠즈멘카 다니엘
윌리암 릴리 험프리스 로버트
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제이.더블류.하이넨
유니레버 엔브이
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Publication of KR930019809A publication Critical patent/KR930019809A/en

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3945Organic per-compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/32Amides; Substituted amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0026Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3947Liquid compositions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

본 발명은 1×10-4M에 대한 용해도를 가지는 아미도 또는 아미도 유기 퍼옥시산, 구조화 계면활정제, 및 저장시 pH를 3.5-8.5로 유지시키고 세탁수로 희석시 pH를 0.5pH단위까지 증가시키기 위한 pH-조절 시스템을 함유하는 수성 세정제 조성물에 관한 것이다. 본 발명의 조성물은 오염된 기질을 세정하는데 유용하다.The present invention maintains the pH at 3.5-8.5 in amido or amido organic peroxy acids, structured surfactants, and storage upon solubility in 1 × 10 −4 M and dilutes with wash water to 0.5 pH units. An aqueous detergent composition containing a pH-adjusting system for increasing up to. The compositions of the present invention are useful for cleaning contaminated substrates.

Description

아미도 및 이미도 퍼옥시산을 함유하는 구조화된 액체 세정제 조성물.Structured liquid detergent composition containing amido and imido peroxy acid.

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (9)

다음과 같은 성분을 함유하는 세정제 조성물 (ⅰ) 표백에 효과적인 양으로 존재하는 1×10-4M 이항의 물에 대한 용해도를 가지는 아미도 또는 이미도 유기 퍼옥시산, (ⅱ) 퍼옥시산을 현탁시키기에 효과적인 양으로 존재하는 계면활성제, (ⅲ) 저장시 pH를 3.5-8.5로 유지시키며 세탁수로 희석시 pH를 0.5pH 단위 이상까지 증가시키기에 효과적인 양으로 존재하는 pH-조절시스템.Amido or imido organic peroxy acid having solubility in water of 1 × 10 -4 M binomial, which is present in an effective amount for bleaching of the cleaning composition containing the following components: (ii) peroxy acid Surfactant present in an effective amount to suspend, (i) pH-controlling system is present in an amount effective to maintain a pH of 3.5-8.5 on storage and to increase the pH to more than 0.5pH units when diluted with wash water. 제1항에 있어서, pH-조절 시스템은 붕산염과 폴리올로 구성되며 이때 봉산염 대 폴리올의 비는 1 : 10-약 10: 1 범위인 것을 특징으로 하는 세정제 조성물.The detergent composition of claim 1, wherein the pH-adjusting system consists of borate and polyol, wherein the ratio of borate to polyol is in the range of 1:10 to about 10: 1. 제1항에 있어서, 퍼옥시산은 다음과 같은 물질로 구성되는 군으로부터 선택되는 것을 특징으로 하는 세정제 조성물,The cleaning composition of claim 1, wherein the peroxy acid is selected from the group consisting of: 및 〔이식에서, R은 C1-C16알킬, C1-C16시클로알킬 및 C16-C12아릴기로 구성되는 군으로부터 선택되며 R¹H, C₁-알킬, C₁-시크로알킬 및-아릴기로 구성되는 군으로 부터 선택되고 H2는 H, C1-C16알킬 C1-C16시클로알킬 C6-C12아릴기 및 R3가 아릴렌기인 경우 R과 함께 고리를 형성할 수 있는 카르보닐기로 구성되는 군으로부터 선택되며, R³는 C₂-알킬렌-사클로알킬렌 및-알릴렌기로 구성되는 군으로부터 선택되고, n및 m은 그 합이 1이되는 정수이며, M은 수소 알칼리금속 알칼리토금속, 암모늄 양이온 및 기로 구성되는 군으로부터 선택된다〕 And [wherein R is selected from the group consisting of C 1 -C 16 alkyl, C 1 -C 16 cycloalkyl and C 16 -C 12 aryl groups and R¹H, C₁- Alkyl, C,- Cycloalkyl and - Is selected from the group consisting of aryl groups and H 2 may form a ring with R when H, C 1 -C 16 alkyl C 1 -C 16 cycloalkyl C 6 -C 12 aryl group and R 3 is an arylene group Selected from the group consisting of carbonyl groups, R³ is C₂- Alkylene - Sachloroalkylene and - Is selected from the group consisting of allylene groups, n and m are integers whose sum is 1, and M is selected from the group consisting of hydrogen alkali metal alkaline earth metals, ammonium cations and groups. 〔이 식에서, R4는 C1-C12알킬렌,-C12시클로알킬렌, C6-C12알릴렌기 및 이러한 기의 배합체로 구성되는 군으로부터 선택되며, R5는 수소, C1-C16알킬 및 C6-C12아릴기, 및 R3와 함께 고리를 형성할수 있는 카르보닐기로 구성되는 군으로부터 선택되고, R6는 C1-C16알킬 C6-C12아릴기, 및 R|3와 함께 C3-C12고리를 형성할수 있는 기로 구성되는 군으로 부터 선택되며,R3는 C1-C12알킬렌, C5-C|12시클로알킬렌 및 C6-C12아릴렌기로 구성되는 군으로부터 선택되고, n′및 n″는 각각 그합이1이 되도록 선택되는 정수이며, m′및 m″는 각각 그 합이 1이 되도록 선택되는 정수이고, M은 수소, 알칼리금속, 알칼리토금속, 암모늄 및 알칸올 암모늄 양이온 및 기로 구성되는 군으로부터 선택된다.〕[Wherein R 4 is C 1 -C 12 alkylene, Is selected from the group consisting of a -C 12 cycloalkylene, a C 6 -C 12 allylene group and a combination of such groups, R 5 is hydrogen, a C 1 -C 16 alkyl and a C 6 -C 12 aryl group, and R 3 Is selected from the group consisting of carbonyl groups capable of forming a ring together, R 6 is a C 1 -C 16 alkyl C 6 -C 12 aryl group, and R | 3 is selected from the group consisting of a group capable of forming a C 3 -C 12 ring together with 3 , wherein R 3 is C 1 -C 12 alkylene, C 5 -C | Selected from the group consisting of 12 cycloalkylene and C 6 -C 12 arylene groups, n ′ and n ″ are each an integer selected such that the sum is 1, and m ′ and m ″ are each summed to 1 Is an integer selected, and M is selected from the group consisting of hydrogen, alkali metals, alkaline earth metals, ammonium and alkanol ammonium cations and groups. 제1항에 있어서, 아미도 또는 이미도 유기 퍼옥시산을 0.1-40중량%의 양으로 함유되는 것을 특징으로 하는 세정제 조성물.The cleaning composition according to claim 1, which contains amido or imido organic peroxy acid in an amount of 0.1-40% by weight. 제1항에 있어서, pH-조절시스템은 약1-약40중량%의 양으로 함유되는 것을 특징으로 하는 세정제 조성물.The cleaning composition of claim 1, wherein the pH-adjusting system is contained in an amount of about 1-about 40% by weight. 제1항에 있어서, 계면활성제는 약1-약50중량%의 양으로 함유되는 것을 특징으로 하는 세정제 조성물.The cleaning composition of claim 1, wherein the surfactant is contained in an amount of about 1-about 50% by weight. 제1항에 있어서, 퍼옥시산은 다음과 같은 화합물로 부터 선택되는 것을 특징으로 하는 세정제 조성물. N,N′-디(4-퍼카르복시벤조일)-1,4-부탄디아민 N,N'-디(4-퍼카르복시벤조일)-1,2-페닐렌디아민,N,N′-숙시노일-디(4-퍼카르복시)아닐린, 4-퍼카르복시벤조일 아닐린, N,N′-프탈로일-4-아미노퍼벤조산, N,N,N′,N′-1,2,4,5-테트라카르복시벤조일-디(6-아미노퍼카르복시카프론산), N,N′-디(4-퍼카르복시벤조일)에틸렌디아민, N,N′-디(4-퍼카르복시벤조일)테레프탈레이트, N,N′-디(4-퍼카르복시벤조일)피페라진, N,N′-디(4-퍼카르복시벤조일)-1,4-디아민 시클로헥산, N,N′-디(퍼카르복시아디포일)페닐렌디아민, N,N′-디(퍼카르복시아디포일)에닐렌디아민, N,N′-테레프탈로일-디(6-아미노퍼옥시카프론산).The cleaning composition of claim 1, wherein the peroxy acid is selected from the following compounds. N, N'-di (4-percarboxybenzoyl) -1,4-butanediamine N, N'-di (4-percarboxybenzoyl) -1,2-phenylenediamine, N, N'-succinoyl- Di (4-percarboxy) aniline, 4-percarboxybenzoyl aniline, N, N'-phthaloyl-4-aminoperbenzoic acid, N, N, N ', N'-1,2,4,5-tetra Carboxybenzoyl-di (6-aminopercarboxycapronic acid), N, N'-di (4-percarboxybenzoyl) ethylenediamine, N, N'-di (4-percarboxybenzoyl) terephthalate, N, N ' -Di (4-percarboxybenzoyl) piperazine, N, N'-di (4-percarboxybenzoyl) -1,4-diamine cyclohexane, N, N'-di (percarboxiadifoyl) phenylenediamine, N, N'-di (percarboxiadifoyl) enylenediamine, N, N'-terephthaloyl-di (6-aminoperoxycapronic acid). 제1항에 있엇, 탈응집성 중합체를 또한 추가적으로 함유하는 것을 특징으로 하는 세정제 조성물.The detergent composition of claim 1, further comprising a deagglomerated polymer. 제1항의 조성물로 오염된 기질을 처리함으로써 오염된 기질을 세정시키는 방법.A method of cleaning a contaminated substrate by treating the contaminated substrate with the composition of claim 1. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019930005023A 1992-03-31 1993-03-30 Structured Liquid Cleanser Composition Containing Amido and Imido Peroxy Acids KR930019809A (en)

Applications Claiming Priority (2)

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US86082892A 1992-03-31 1992-03-31
CA860828 1992-03-31

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EP (1) EP0564250A3 (en)
JP (1) JPH06100888A (en)
KR (1) KR930019809A (en)
CN (1) CN1078997A (en)
AU (1) AU666922B2 (en)
BR (1) BR9301368A (en)
CA (1) CA2092864A1 (en)
MX (1) MX9301749A (en)
ZA (1) ZA932317B (en)

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CA2092864A1 (en) 1993-10-01
BR9301368A (en) 1993-10-13
AU3549793A (en) 1993-10-07
CN1078997A (en) 1993-12-01
ZA932317B (en) 1994-09-30
JPH06100888A (en) 1994-04-12
EP0564250A3 (en) 1995-11-08
EP0564250A2 (en) 1993-10-06
AU666922B2 (en) 1996-02-29
MX9301749A (en) 1993-09-01

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