KR930006069A - 해사성이 우수한 탄성섬유용 중합체 용액의 제조방법 - Google Patents

해사성이 우수한 탄성섬유용 중합체 용액의 제조방법 Download PDF

Info

Publication number
KR930006069A
KR930006069A KR1019910015786A KR910015786A KR930006069A KR 930006069 A KR930006069 A KR 930006069A KR 1019910015786 A KR1019910015786 A KR 1019910015786A KR 910015786 A KR910015786 A KR 910015786A KR 930006069 A KR930006069 A KR 930006069A
Authority
KR
South Korea
Prior art keywords
compound
polymer solution
followed
elastic fibers
chain growth
Prior art date
Application number
KR1019910015786A
Other languages
English (en)
Other versions
KR950002604B1 (ko
Inventor
김광태
손영호
추낙준
Original Assignee
서주인
제일합섬 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 서주인, 제일합섬 주식회사 filed Critical 서주인
Priority to KR1019910015786A priority Critical patent/KR950002604B1/ko
Publication of KR930006069A publication Critical patent/KR930006069A/ko
Application granted granted Critical
Publication of KR950002604B1 publication Critical patent/KR950002604B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8141—Unsaturated isocyanates or isothiocyanates masked
    • C08G18/815—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
    • C08G18/8158—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
    • C08G18/8166—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with unsaturated monofunctional alcohols or amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/70—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Artificial Filaments (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

본 발명 탄성섬유의 고유한 물성인 우수한 탄성을 유지하면서도 해사성이 우수한 탄성섬유용 중합체 용액의 제조방법에 관한 것으로, 수평균 분자량이 1,000∼3,000인 고분자량의 디올화합물 1몰과 디이소시아네이트 화합물 1.5∼2.7몰을 예비중합시킨 후에 불활성 유기용매중에 용해시켜 예비중합물의 용액을 제조한 다음, 예비중합물 1몰에 대하여 0.7∼0.95몰의 디아민화합물을 사용하여 말단의 디이소시아네이트를 쇄성장시키고, 쇄성장을 위해 사용되는 디아민화합물의 1∼10몰%에 해당되는 양의 모노아민화합물을 사용하여 쇄성장을 중지시킨 후에 중합체 용액중 폴리머 고형분에 대하여 0.05∼3중량%의 실리카계 화합물을 첨가하여 해사성이 우수한 탄성섬유용 중합체 용액을 제조하였다.

Description

해사성이 우수한 탄성섬유용 중합체 용액의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (2)

  1. 고분자량의 디올화합물과 디이소시아네이트 화합물을 예비중합하여 용제와 혼합시킨 후 디아민 화합물을 사용하여 말단의 이소시아네이트를 쇄성장시키고 모노아민화합물을 사용하여 말단을 봉쇄시키고, 실리카계 화합물을 첨가함을 특징으로 하는 해사성이 우수한 탄성섬유용 중합체 용액의 제조방법.
  2. 제1항에 있어서, 실리카계 화합물의 첨가비율은 중합물 고형분에 대하여 0.05∼3중량% 임을 특징으로 하는 탄성섬유용 중합체 용액의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910015786A 1991-09-10 1991-09-10 해사성이 우수한 탄성섬유용 중합체 용액의 제조방법 KR950002604B1 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019910015786A KR950002604B1 (ko) 1991-09-10 1991-09-10 해사성이 우수한 탄성섬유용 중합체 용액의 제조방법

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019910015786A KR950002604B1 (ko) 1991-09-10 1991-09-10 해사성이 우수한 탄성섬유용 중합체 용액의 제조방법

Publications (2)

Publication Number Publication Date
KR930006069A true KR930006069A (ko) 1993-04-20
KR950002604B1 KR950002604B1 (ko) 1995-03-23

Family

ID=19319789

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910015786A KR950002604B1 (ko) 1991-09-10 1991-09-10 해사성이 우수한 탄성섬유용 중합체 용액의 제조방법

Country Status (1)

Country Link
KR (1) KR950002604B1 (ko)

Also Published As

Publication number Publication date
KR950002604B1 (ko) 1995-03-23

Similar Documents

Publication Publication Date Title
US4739013A (en) Polyurethanes
DE69809232D1 (de) Lösungspolymerisation von hochmolekularen polyphosphorestern in toluol
EP0872581A4 (en) ELASTIC POLYURETHANE FIBERS AND PROCESS FOR PRODUCING THE SAME
KR910014487A (ko) 새깅 저항성이 있는 미충전 저비점 우레탄 구조용 접착제
SE7603327L (sv) Polypropenbaserade stabiliserade polymerkompositioner
GB9726810D0 (en) Compounds composition & use
KR910018484A (ko) 이소시아네이트로 말단화된 폴리우레탄 예비중합체 혼합물
KR910008001A (ko) 분절된 폴리우레탄 우레아 탄성중합체 용액의 제조방법 및 이의 필라멘트 및 필름
BR9100059A (pt) Poliol modificado com epoxi,poliois polimeros de baixa viscosidade,estaveis,e processo para a producao dos mesmos,e produtos de poliuretano
KR930006069A (ko) 해사성이 우수한 탄성섬유용 중합체 용액의 제조방법
KR890010027A (ko) 폴리카보네이트 연질 세그먼트를 함유하는 스판덱스 제품
KR970006564A (ko) 폴리우레탄계 탄성섬유의 제조방법
KR900004791A (ko) 이미노/엔아민 기능을 갖는 이소시아네이트 반응성 중합체
MXPA04004453A (es) Polimeros de injerto con cadenas laterales que comprenden n-vinilamidas ciclicas.
KR960014187A (ko) 점도 안정성이 우수한 폴리우레탄계 탄성중합체의 제조방법
KR970062102A (ko) 내열성과 항균방취성이 우수한 폴리우레탄계 탄성섬유의 제조방법
JPS57190012A (en) Preparation of thermoplastic polyurethane resin
KR970006566A (ko) 항균방취성이 우수한 폴리우레탄 탄성섬유의 제조방법
KR970006565A (ko) 폴리우레탄계 탄성섬유의 제조방법
KR950008744A (ko) 내열성과 내염소성이 우수한 탄성섬유의 제조방법
KR960023325A (ko) 점도안정성과 탄성회복력이 우수한 탄성섬유의 제조방법
JPS6414208A (en) Liquid hydrogenated polyisoprene and its production
KR960023323A (ko) 방사성이 우수한 폴리우레탄계 탄성섬유의 제조방법
KR940000630A (ko) 염색성이 우수한 폴리우레탄 탄성사의 제조방법
JPS5554321A (en) Preparation of polyurethane elastomer

Legal Events

Date Code Title Description
A201 Request for examination
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20050112

Year of fee payment: 11

LAPS Lapse due to unpaid annual fee