KR920702288A - Polymer composition with increased surface energy and its preparation method - Google Patents

Polymer composition with increased surface energy and its preparation method

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Publication number
KR920702288A
KR920702288A KR1019920700729A KR920700729A KR920702288A KR 920702288 A KR920702288 A KR 920702288A KR 1019920700729 A KR1019920700729 A KR 1019920700729A KR 920700729 A KR920700729 A KR 920700729A KR 920702288 A KR920702288 A KR 920702288A
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group
hydrogen
same
composition
aliphatic
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KR1019920700729A
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Korean (ko)
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에릭 에스 가디너
죤 티. 죠그헤간
데일 엘. 하너
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원본미기재
아리조나 케미칼 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/241—Polyolefin, e.g.rubber

Abstract

내용 없음No content

Description

표면 에너지가 증가된 중합체 조성물 및 그의 제조방법Polymer composition with increased surface energy and its preparation method

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (34)

약 99.5 내지 약 90.0중량%의 저 또는 중밀도, 저표면 에너지 폴리올레핀; 및 하기 일반식을 갖는 약 0.5 내지 약 10.0 중량%의 양친매성 물질(amphiphile)로 이루어진 저 또는 중밀도 폴리올레핀 조성물.About 99.5 to about 90.0 weight percent low or medium density, low surface energy polyolefin; And from about 0.5 to about 10.0 weight percent amphiphile having the general formula: RA(CHR2[CH2]nA1]mR1 RA (CHR 2 [CH 2 ] nA 1 ] mR 1 식중, R 및 R1은 분자량이 약 150 내지 약 500달톤인 지방족 또는 지방족/방향족 1가 산의 알킬, 아릴, 알킬아릴, 아실 및 아릴아실 유도체로 이루어진 군 중에서 선택되고, A 및 A1은 O, S, -NR-(여기서, R3는 H, CH3및 C2H5로 이루어진 군 중에서 선택됨) 또는 카르복실기로 이루어진 군 중에서 선택되며, R2는 H, CH3및 C2H5로 이루어진 군 중에서 선택되고, n은 0 내지 3이며, m은 2내지 20이다.Wherein R and R 1 are selected from the group consisting of alkyl, aryl, alkylaryl, acyl and arylacyl derivatives of aliphatic or aliphatic / aromatic monovalent acids having a molecular weight of about 150 to about 500 Daltons, and A and A 1 are O , S, -NR- (wherein R 3 is selected from the group consisting of H, CH 3 and C 2 H 5 ) or a carboxyl group, R 2 is composed of H, CH 3 and C 2 H 5 It is selected from the group, n is 0-3, m is 2-20. 제1항에 있어서, R 및 R1이 동일하고, R2가 수소이며, A 및 A1이 산소인 조성물.The composition of claim 1, wherein R and R 1 are the same, R 2 is hydrogen, and A and A 1 are oxygen. 제1항에 있어서, R 및 R1이 동일하고, R2가 수소이며, A 및 A1이 산소 및 황으로 이루어진 군 중에서 선택된 조성물.The composition of claim 1 wherein R and R 1 are the same, R 2 is hydrogen, and A and A 1 are selected from the group consisting of oxygen and sulfur. 제1항에 있어서, R 및 R1이 동일하고, R2가 수소이며, A 및 A1이 -NH-인 조성물.The composition of claim 1, wherein R and R 1 are the same, R 2 is hydrogen, and A and A 1 are —NH—. 제1항에 있어서, R 및 R1이 동일하고, R2가 수소이며, A 및 A1이 카르복실인 조성물.The composition of claim 1, wherein R and R 1 are the same, R 2 is hydrogen, and A and A 1 are carboxyl. 제1,2,3,4 또는 5항에 있어서, 상기 폴리올레핀이 폴리에틸렌, 폴리프로필렌, 알파-올레핀 개질 폴리프로필렌, 폴리스티렌 및 폴리(4-메틸펜텐-1)로 이루어진 군 중에서 선택된 조성물.The composition of claim 1, 2, 3, 4 or 5 wherein said polyolefin is selected from the group consisting of polyethylene, polypropylene, alpha-olefin modified polypropylene, polystyrene and poly (4-methylpentene-1). 제1,2,3,4 또는 5항에 있어서, m이 4내지 12인 조성물.The composition of claim 1, 2, 3, 4 or 5 wherein m is 4 to 12. 7. 제1,2,3,4 또는 5항에 있어서, m이 9인 조성물.The composition of claim 1, 2, 3, 4 or 5, wherein m is 9. 7. 제1,2,3,4 또는 5항에 있어서, 약 99 내지 약 95%의 상기 폴리올레핀; 및 약 1내지 약 5%의 상기 양친매성 물질로 이루어진 조성물.The polyolefin of claim 1, 2, 3, 4 or 5, comprising from about 99 to about 95% of the polyolefin; And from about 1 to about 5% of the amphipathic material. 유기 중합체 물질과 혼합하여 표면 에너지가 증가된 유기 중합체 물질을 형성하는, 저 또는 중밀도, 저 표면에너지 유기 중합체 물질의 표면 에너지를 증가시키기 위한 하기 일반식을 갖는 조성물.A composition having the following general formula for increasing the surface energy of a low or medium density, low surface energy organic polymer material which forms an organic polymer material with increased surface energy by mixing with the organic polymer material. RA(CHR2[CH2]nA1]mR1 RA (CHR 2 [CH 2 ] nA 1 ] mR 1 식중, R 및 R1은 분자량이 약 150 내지 약 500달톤인 지방족 또는 지방족/방향족 1가 산의 알킬, 아릴, 알킬아릴, 아실 및 아릴아실 유도체로 이루어진 군 중에서 선택되고, A 및 A1은 O, S, -NR-(여기서, R3는 H, CH3및 C2H5로 이루어진 군 중에서 선택됨) 및 카르복실기로 이루어진 군 중에서 선택되며, R2는 H, CH3및 C2H5로 이루어진 군 중에서 선택되고, n은 0 내지 3이며, m은 2내지 20이다.Wherein R and R 1 are selected from the group consisting of alkyl, aryl, alkylaryl, acyl and arylacyl derivatives of aliphatic or aliphatic / aromatic monovalent acids having a molecular weight of about 150 to about 500 Daltons, and A and A 1 are O , S, -NR- (wherein R 3 is selected from the group consisting of H, CH 3 and C 2 H 5 ) and a carboxyl group, R 2 is composed of H, CH 3 and C 2 H 5 It is selected from the group, n is 0-3, m is 2-20. 제10항에 있어서, R 및 R1이 동일하고, R2가 수소이며, A 및 A1이 산소인 조성물.The composition of claim 10, wherein R and R 1 are the same, R 2 is hydrogen, and A and A 1 are oxygen. 제10항에 있어서, R 및 R1이 동일하고, R2가 수소이며, A 및 A1이 산소 및 황으로 이루어진 군 중에서 선택된 조성물.The composition of claim 10 wherein R and R 1 are the same, R 2 is hydrogen, and A and A 1 are selected from the group consisting of oxygen and sulfur. 제10항에 있어서, R 및 R1이 동일하고, R2가 수소이며, A 및 A1이 -NH-인 조성물.The composition of claim 10, wherein R and R 1 are the same, R 2 is hydrogen, and A and A 1 are —NH—. 제10항에 있어서, R 및 R1이 동일하고, R2가 수소이며, A 및 A1이 카르복실인 조성물.The composition of claim 10, wherein R and R 1 are the same, R 2 is hydrogen, and A and A 1 are carboxyl. 제10,11,12,13 또는 14항에 있어서, m이 4내지 12인 조성물.The composition of claim 10, 11, 12, 13 or 14, wherein m is 4 to 12. 제10,11,12,13 또는 14항에 있어서, m이 9인 조성물.The composition of claim 10, 11, 12, 13 or 14, wherein m is 9. 약 99.5 내지 약 90.0중량%의저 또는 중밀도, 저 표면 에너지 폴리올레핀 및 하기 일반식을 갖는 약 0.5 내지 약 10.0중량%의 양친매성 물질로 이루어지는 저 또는 중밀도 폴리올레핀 조성물; 및 수분산 접착제로 이루어진 접착 테이프.Low or medium density polyolefin compositions consisting of about 99.5 to about 90.0 weight percent low or medium density, low surface energy polyolefin and about 0.5 to about 10.0 weight percent amphiphilic material having the general formula: And an adhesive tape consisting of a water dispersible adhesive. RA(CHR2[CH2]nA1]mR1 RA (CHR 2 [CH 2 ] nA 1 ] mR 1 식중, R 및 R1은 분자량이 약 200 내지 약 500달톤인 지방족 또는 지방족/방향족 1가 산의 알킬, 아릴, 알킬, 아릴, 아실 및 아릴아실 유도체로 이루어진 군 중에서 선택되고, A 및 A1은 O, -NR-, 카르복실 및 S로 이루어진 군중에서 선택되며, R2및 R3은 H, CH3및 C2H5로 이루어진 군 중에서 선택되고, n은 0 내지 3이며, m은 2내지 20이다.Wherein R and R 1 are selected from the group consisting of alkyl, aryl, alkyl, aryl, acyl and arylacyl derivatives of aliphatic or aliphatic / aromatic monovalent acids having a molecular weight of about 200 to about 500 Daltons, and A and A 1 are Is selected from the group consisting of O, -NR-, carboxyl and S, R 2 and R 3 are selected from the group consisting of H, CH 3 and C 2 H 5 , n is 0 to 3 and m is 2 to 20. 제17항에 있어서, R 및 R1이 동일하고, R2가 수소이며, A 및 A1이 산소인 접착테이프.18. The adhesive tape of claim 17 wherein R and R 1 are the same, R 2 is hydrogen and A and A 1 are oxygen. 제10항에 있어서, R 및 R1이 동일하고, R2가 수소이며, A 및 A1이 산소및 황으로 이루어진 군 중에서 선택된 접착 테이프.The adhesive tape of claim 10 wherein R and R 1 are the same, R 2 is hydrogen, and A and A 1 are selected from the group consisting of oxygen and sulfur. 제17항에 있어서, R 및 R1이 동일하고, R2가 수소이며, A 및 A1이 NH인 접착 테이프.The adhesive tape according to claim 17, wherein R and R 1 are the same, R 2 is hydrogen, and A and A 1 are NH. 제17항에 있어서, R 및 R1이 동일하고, R2가 수소이며, A 및 A1이 카르복실인 접착 테이프.The adhesive tape according to claim 17, wherein R and R 1 are the same, R 2 is hydrogen, and A and A 1 are carboxyl. 제17,18,19,20 또는 21항에 있어서, 상기 폴리올레핀이 폴리에틸렌, 폴리프로필렌, 알파-올레핀 개질 폴리프로필렌, 폴리스티렌 및 폴리(4-메틸펜텐-1)로 이루어진 군 중에서 선택된 접착 테이프.22. The adhesive tape of claim 17, 18, 19, 20 or 21 wherein said polyolefin is selected from the group consisting of polyethylene, polypropylene, alpha-olefin modified polypropylene, polystyrene and poly (4-methylpentene-1). 제17,18,19,20 또는 21항에 있어서, m이 4 내지 12인 접착 테이프.The adhesive tape according to claim 17, 18, 19, 20 or 21, wherein m is 4 to 12. 제17,18,19,20 또는 21항에 있어서, 약 99 내지 약95%의 상기 폴리올레핀; 및 약 1내지 약 5%의 상기 양친매성 물질로 이루어진 접착 테이프.The method of claim 17, 18, 19, 20 or 21, wherein from about 99 to about 95% of the polyolefin; And from about 1 to about 5% of the amphipathic material. 제17,18,19,20 또는 21항에 있어서, 접착제가 아크릴계 접착제인 접착 테이프.The adhesive tape according to claim 17, 18, 19, 20 or 21, wherein the adhesive is an acrylic adhesive. 약 99.5 내지 약 90.0중량%의 저 또는 중밀도, 저표면 에너지 유기 중합체 물질을, 약 0.5 내지 약 10.0중량%의 하기 일반식을 갖는 양친매성 물질과 혼합하는 것으로 이루어지는 상기 중합체 물질의 표면 에너지를 증가시키는 방법.Increase the surface energy of the polymeric material consisting of mixing about 99.5 to about 90.0 weight percent low or medium density, low surface energy organic polymeric material with about 0.5 to about 10.0 weight percent amphiphilic material having the formula How to let. RA(CHR2[CH2]nA1]mR1 RA (CHR 2 [CH 2 ] nA 1 ] mR 1 식중, R 및 R1은 분자량이 약 150 내지 약 500달톤인 지방족 또는 지방족/방향족 1가 산의 알킬, 아릴, 알킬아릴, 아실 및 아릴아실 유도체로 이루어진 군 중에서 선택되고, R2는 H, CH3및 C2H5로 이루어진 군 중에서 선택되며, A 및 A1은 O, S, -NR-(여기서, R3는 H, CH3및 C2H5로 이루어진 군 중에서 선택됨) 또는 카르복실기로 이루어진 군 중에서 선택되고, m은 2내지 20이며, n은 0내지 3이다.Wherein R and R 1 are selected from the group consisting of alkyl, aryl, alkylaryl, acyl and arylacyl derivatives of aliphatic or aliphatic / aromatic monovalent acids having a molecular weight of about 150 to about 500 Daltons, and R 2 is H, CH 3 and C 2 H 5 , wherein A and A 1 are O, S, -NR-, wherein R 3 is selected from the group consisting of H, CH 3 and C 2 H 5 or a carboxyl group It is selected from the group, m is 2-20, n is 0-3. 제26항에 있어서, R 및 R1이 동일하고, R2가 수소이고, A 및 A1이 산소인 방법.The method of claim 26, wherein R and R 1 are the same, R 2 is hydrogen, and A and A 1 are oxygen. 제26항에 있어서, R 및 R1이 동일하고, R2가 수소이고, A 및 A1이 산소 및 황으로 이루어진 군 중에서 선택된 방법.The method of claim 26, wherein R and R 1 are the same, R 2 is hydrogen, and A and A 1 are selected from the group consisting of oxygen and sulfur. 제26항에 있어서, R 및 R1이 동일하고, R2가 수소이고, A 및 A1이 -NH-인 방법.The method of claim 26, wherein R and R 1 are the same, R 2 is hydrogen, and A and A 1 are —NH—. 제26항에 있어서, R 및 R1이 동일하고, R2가 수소이고, A 및 A1이 카르복실인 방법.The method of claim 26, wherein R and R 1 are the same, R 2 is hydrogen, and A and A 1 are carboxyl. 제26,27,28,29 또는 30항에 있어서, 상기 중합체 물질이 폴리에틸렌, 폴리프로필렌, 필렌, 알파-올레핀개질 폴리프로필렌, 폴리스티렌 및 폴리(4-메틸펜텐-1)로 이루어진 군 중에서 선택되는 방법.The process of claim 26,27,28,29 or 30 wherein said polymeric material is selected from the group consisting of polyethylene, polypropylene, propylene, alpha-olefin modified polypropylene, polystyrene and poly (4-methylpentene-1). . 제26,27,28,29 또는 30항에 있어서, m이 4 내지 12인 방법.The method of claim 26, 27, 28, 29 or 30 wherein m is 4 to 12. 제26,27,28,29 또는 30항에 있어서, m이 9인 방법.The method of claim 26, 27, 28, 29 or 30, wherein m is 9. 제26,27,28,29 또는 30항에 있어서, 약 99 내지 약95%가 상기 유기 중합체 물질이고, 약 1내지 약 5%가 상기 양친매성 물질인 방법.The method of claim 26, 27, 28, 29, or 30, wherein about 99 to about 95% is said organic polymeric material and about 1 to about 5% is said amphipathic material. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019920700729A 1989-10-02 1990-10-02 Polymer composition with increased surface energy and its preparation method KR920702288A (en)

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US41562689A 1989-10-02 1989-10-02
US415626 1989-10-02
US58318490A 1990-09-14 1990-09-14
US58357190A 1990-09-14 1990-09-14
US583184 1990-09-14
US583571 1990-09-14
PCT/US1990/005597 WO1991004853A1 (en) 1989-10-02 1990-10-02 Polymeric composition having enhanced surface energy and method for obtaining same

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US4781957A (en) * 1987-07-27 1988-11-01 Minnesota Mining And Manufacturing Company Easy tear masking tape

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JPH05500677A (en) 1993-02-12
WO1991004853A1 (en) 1991-04-18
EP0494959A1 (en) 1992-07-22
EP0494959A4 (en) 1993-03-03

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