KR920014846A - Polymers of ethylenically unsaturated cyclic ortho esters - Google Patents

Polymers of ethylenically unsaturated cyclic ortho esters Download PDF

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Publication number
KR920014846A
KR920014846A KR1019920000908A KR920000908A KR920014846A KR 920014846 A KR920014846 A KR 920014846A KR 1019920000908 A KR1019920000908 A KR 1019920000908A KR 920000908 A KR920000908 A KR 920000908A KR 920014846 A KR920014846 A KR 920014846A
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South Korea
Prior art keywords
polymer
unsaturated
hydrogen
methyl
copolymer
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KR1019920000908A
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Korean (ko)
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KR960000568B1 (en
Inventor
포우아드 코우리 파리드
제임스 할레이 로버트
죤 셔 티모씨
로버트 캄벨 죤
Original Assignee
다더 엠. 킹
제네랄 일렉트릭 캄파니
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Priority claimed from US07/645,180 external-priority patent/US5132361A/en
Priority claimed from US07/716,157 external-priority patent/US5153290A/en
Application filed by 다더 엠. 킹, 제네랄 일렉트릭 캄파니 filed Critical 다더 엠. 킹
Publication of KR920014846A publication Critical patent/KR920014846A/en
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Publication of KR960000568B1 publication Critical patent/KR960000568B1/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
    • C08F212/22—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/26—Esters containing oxygen in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C08F255/06—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethene-propene-diene terpolymers

Abstract

내용 없음No content

Description

에틸렌형 불포화 환상 오르토 에스테르의 중합체Polymers of ethylenically unsaturated cyclic ortho esters

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (21)

(A)하기 일반식(Ⅰ)의 구조단위, 및 임의로는 (B)불포화 알콜 및 그의 에스테르, 불포화산 및 그이 에스테르, 불포화 저급 다가 알콜 및 그이 에스테르, 불포화 에테르, 불포화 케톤, 불포화 아미드, 불포화 지방족 탄화수소, 불포화 알킬 할로겐화물, 불포화 산 무수물, 불포화 니트릴 및 비닐 환상 화합물중에서 선택된 하나 이상의 단량체로부터 유도된 구조단위로 이루어진 중합체.(A) the structural units of the following general formula (I), and optionally (B) unsaturated alcohols and esters thereof, unsaturated acids and esters thereof, unsaturated lower polyhydric alcohols and esters thereof, unsaturated ethers, unsaturated ketones, unsaturated amides, unsaturated aliphatic A polymer consisting of structural units derived from at least one monomer selected from hydrocarbons, unsaturated alkyl halides, unsaturated acid anhydrides, unsaturated nitriles and vinyl cyclic compounds. 상기식에서, R1및 R2는 독립적으로 C1-101급 또는 2급 알킬 또는 아르알킬, 또는 C6-10아릴 라디칼이거나, 또는 상기 라디칼들은 결합하여 5원, 6원 또는 7원 환을 형성하고, R3는 수소 또는 C1-41급 또는 2급 라디칼이며; R4는 치환되지 않거나 치환된 C1-6알킬렌 또는 C6-10아릴렌 라디칼이고; R5는 수소 또는 메틸이며; R6는 수소, C1-6알킬 또는 C1-6아릴 라디칼이고; X는 불활성 연결 그룹이며; m 및 p는 0 또는 1이고; n은 1 내지 2-m이다.Wherein R 1 and R 2 are independently C 1-10 primary or secondary alkyl or aralkyl, or C 6-10 aryl radicals, or the radicals combine to form a five, six or seven membered ring; And R 3 is hydrogen or a C 1-4 primary or secondary radical; R 4 is unsubstituted or substituted C 1-6 alkylene or C 6-10 arylene radical; R 5 is hydrogen or methyl; R 6 is hydrogen, C 1-6 alkyl or C 1-6 aryl radical; X is an inert linking group; m and p are 0 or 1; n is 1 to 2-m. 제1항에 있어서, R1및 R2가 둘다 알킬인 중합체.The polymer of claim 1 wherein R 1 and R 2 are both alkyl. 제2항에 있어서, m이 0이고, n이 1인 중합체.The polymer of claim 2 wherein m is 0 and n is 1. 4. 제3항에 있어서, R3및 R6가 둘다 수소인 중합체.The polymer of claim 3 wherein R 3 and R 6 are both hydrogen. 제4항에 있어서, p가 1인 중합체.The polymer of claim 4 wherein p is 1. 제5항에 있어서, 랜덤 첨가 중합체인 중합체.The polymer of claim 5 which is a random addition polymer. 제6항에 있어서, 스티렌과의 공중합체인 중합체.The polymer of claim 6 which is a copolymer with styrene. 제5항에 있어서, 그라프트 공중합체인 중합체.The polymer of claim 5 which is a graft copolymer. 제8항에 있어서, 에틸렌과 프로필렌과의 이미 형성된 공중합체상의 그라프트 공중합체인 중합체.The polymer of claim 8 which is a graft copolymer on an already formed copolymer of ethylene and propylene. 제9항에 있어서, R2가 메틸 또는 페닐인 중합체.The polymer of claim 9 wherein R 2 is methyl or phenyl. 제10항에 있어서, R4가 메틸렌인 중합체.The polymer of claim 10 wherein R 4 is methylene. 제11항에 있어서, 에틸렌, 프로필렌 및 적어도 하나의 비공액 디앤으로부터 유도된 구조단위를 포함한 공중합체상의 그라프트 공중합체인 중합체.The polymer of claim 11 which is a graft copolymer on a copolymer comprising structural units derived from ethylene, propylene and at least one nonconjugated diene. 제12항에 있어서,(Ⅱ)인 중합체.The method of claim 12, (II). A polymer. 제13항에 있어서, R2가 메틸인 중합체.The polymer of claim 13, wherein R 2 is methyl. 제13항에 있어서, R2가 페닐인 중합체.The polymer of claim 13, wherein R 2 is phenyl. 제13항에 있어서, R5가 수소인 중합체.The polymer of claim 13, wherein R 5 is hydrogen. 제13항에 있어서, R5가 메틸인 중합체.The polymer of claim 13, wherein R 5 is methyl. 제12항에 있어서,인 중합체.The method of claim 12, Phosphorus polymer. 제18항에 있어서, R2가 메틸인 중합체.The polymer of claim 18, wherein R 2 is methyl. 제18항에 있어서, R2가 페닐인 중합체.19. The polymer of claim 18, wherein R 2 is phenyl. 제18항에 있어서, R5가 수소인 중합체.19. The polymer of claim 18, wherein R 5 is hydrogen. ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.※ Note: This is to be disclosed by the original application.
KR1019920000908A 1991-01-24 1992-01-23 Polymers of ethylenically unsaturated cyclic ortho esters KR960000568B1 (en)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US64517791A 1991-01-24 1991-01-24
US7/645,180 1991-01-24
US07/645,180 US5132361A (en) 1991-01-24 1991-01-24 Copolymers prepared from polymers of ethylenically polymerizable cyclic ortho esters
US07/645180 1991-01-24
US07/645177 1991-01-24
US7/645,177 1991-01-24
US07/716157 1991-06-17
US07/716,157 US5153290A (en) 1991-01-24 1991-06-17 Polymers of ethylenically unsaturated cyclic ortho esters
US7/716,157 1991-06-17

Publications (2)

Publication Number Publication Date
KR920014846A true KR920014846A (en) 1992-08-25
KR960000568B1 KR960000568B1 (en) 1996-01-09

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KR1019920000908A KR960000568B1 (en) 1991-01-24 1992-01-23 Polymers of ethylenically unsaturated cyclic ortho esters

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