KR920010096B1 - Process for preparation of prevention of fire-paints for wood - Google Patents
Process for preparation of prevention of fire-paints for wood Download PDFInfo
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- KR920010096B1 KR920010096B1 KR1019890012726A KR890012726A KR920010096B1 KR 920010096 B1 KR920010096 B1 KR 920010096B1 KR 1019890012726 A KR1019890012726 A KR 1019890012726A KR 890012726 A KR890012726 A KR 890012726A KR 920010096 B1 KR920010096 B1 KR 920010096B1
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- flame retardant
- hot water
- fire
- fire retardant
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Fireproofing Substances (AREA)
- Paints Or Removers (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
Description
본 발명은 방연, 방부 및 방충효과가 뛰어나고 변색과 박락을 방지하며 내열, 내구성이 높고 인체에 전혀 해가 없는 목재용 방연도료의 제조방법에 관한 것이다.The present invention relates to a method for producing a flame retardant paint for wood that is excellent in flame retardancy, antiseptic and insect repellent effects, prevents discoloration and peeling, and has high heat resistance, durability, and no harm to human body.
종래에도 여러가지 종류의 방연도료가 있었으나 단순한 무색, 무취, 무독한 병연효과로서 만족하였기 때문에 방연 방부 및 방충효과가 부족하고 변색 및 박락을 방지하지 못하는 등 문제점이 있는 것이었다.There have been various types of flame retardant paints in the past, but they were satisfactory as simple colorless, odorless, and non-toxic effects, and thus had problems such as lack of flame retardant antiseptic and insect repellent effects and preventing discoloration and peeling.
특히 종래의 목재용 방연도료는 침투성, 접착성등의 부족으로 일차 도장이 된것에는 도포사용하여도 소기의 효과를 기대할 수 없으며 기존 도장의 변색이나 박락을 초리해는 결점이 있었다.In particular, the conventional wood flame-retardant paint is a primary paint due to the lack of permeability, adhesiveness, etc. can not expect the desired effect even if the coating used, there was a drawback to discolor the existing paint.
또 종래의 방연도료는 도포시의 접착성을 위하여 아교를 첨가하므로서 곰팡이가 발생 또는 증식되는 원인이 되게하였다.In addition, the conventional flame-retardant paint was caused by the addition of glue for the adhesiveness at the time of the development or growth of mold.
본 발명은 이러한 제반문제점을 해결하기 위하여 디에틸렌트리아민(Diethylenetriamine), 무수프탈산(Phthalic anhydride), 무수클로렌산(Chlorendic anhyride), 페닐인산(Phenyl Phosphonic acid)을 중합하여 여과한 용액에 아클리에마졸(Acrylemazol)과 아교용액을 혼합하고 조습제인 제오실(Zeosile)과 방부제인 소듐 디 하이드로 아세테이트(Sodium di hydro acetare)를 투입하고 물을 혼합하여 제조하는 것으로서 이를 실시예에 따라 공정별로 상세히 설명하면 다음과 같다.In order to solve these problems, the present invention polymerizes diethylenetriamine, phthalic anhydride, chloric anhydride, phenyl phosphate, and phenyl phosphate to filter the solution. The mixture of acrylemazol and glue solution, a humectant Zeosile and a preservative Sodium di hydroacetic acid are added, and water is mixed. As follows.
[실시예]EXAMPLE
[제1공정][Step 1]
디에틸렌트리아민(Diethylenetriamine) 30부, 무수프탈산(Phthalic anhydride) 15qn 무수클로렌산(Chlorendic anhyride) 40부 페닐인산(Phenyl Phosphonic acid) 15부에 중합과정의 약품간의 효과를 극대화시키기 위하여 티뷰빈 열안정젤르 적량투입하고 약 200℃ - 240℃의 온도로 5시간정도 가열용해하여 중합된 용액을 얻고 이 중합용액에 중합용액량의 약 50배 정도의 온수(70℃ - 90℃)를 혼합 한다음 50℃ - 60℃정도로 자연냉각시키고 여과기로 여과하여 불순물을 제거하므로서 방연액을 얻는다.30 parts of diethylenetriamine, Phthalic anhydride 15qn Chlordic anhyride 40 parts Phenyl Phosphonic acid 15 parts Tivubin heat to maximize the effect of the polymerization process After adding appropriate amount of stable gel and heating and dissolving at about 200 ℃ -240 ℃ for 5 hours to obtain a polymerized solution, hot water (70 ℃ -90 ℃) of about 50 times the amount of polymerization solution is mixed with the polymerization solution. Naturally cool to about 50 ℃ -60 ℃ and filter by filter to remove impurities to obtain flame retardant.
[제2공정][Step 2]
아크릴에마졸(Acrylemazol) 15부(30℃ - 40℃) 아교 10부(80℃ - 90℃)를 각각 분리하여 제1공정에서 얻은 방연액을 약 10% 정도의 량에 투입용해하고 따로 용해시킨 아크릴에마졸용액과 아교용액을 서로 혼합하여 제1혼합용액을 얻는다.15 parts (Acrylemazol) 15 parts (30 ℃-40 ℃) glue 10 parts (80 ℃-90 ℃) was separated, respectively, and the flame retardant obtained in the first step was dissolved in a quantity of about 10% and dissolved separately The acryl azole solution and the glue solution are mixed with each other to obtain a first mixed solution.
이때 혼합용액은 50℃ - 60℃의 온도를 유지하도록 적절히 가열해준다.At this time, the mixed solution is properly heated to maintain a temperature of 50 ℃-60 ℃.
[제3공정][Step 3]
제2공정의 혼합용액에 조습제로서 제오실(Zeoil) 2-3부와 방부제로서 소듐 디하이드로 아세테이트(Sodium di hydro acetare) 1-1.5부를 누입혼합하여 제2혼합 용액을 얻고 제2혼합용액을 제1공정의 방연액과 혼합하여 제3혼합용액을 얻는다.Into the mixed solution of the second process, 2-3 parts of Zeoil as a humectant and 1-1.5 parts of sodium dihydroacetare as an antiseptic were mixed and leaked to obtain a second mixed solution to obtain a second mixed solution. The third mixed solution is obtained by mixing with the flame retardant solution of the first step.
제3공정이 진행되는 동안에도 각혼합용액은 50℃-60℃를 유지하도록 하여 준다.While the third process is in progress, each mixture solution is to maintain 50 ℃-60 ℃.
[제4공정][Step 4]
제3혼합용액을 여과기로 여과하여 불순물을 제거 한다음 액 1000%의 온수를 투입혼합하므로서 본 발명이 완성된다.The third mixed solution is filtered through a filter to remove impurities, and then the present invention is completed by mixing and mixing hot water of 1000% of the liquid.
이와 같이 제조된 본 발명의 방연도료는 필요한 경우 적량의 안료와 혼합하여 사용하며 화재가 발생하여 200℃ - 400℃로 가열되면 트리아민, 무수프탈산, 무수클로렌산, 페닐인산의 중합체인 방연액에서 발생하는 포스켄 가스와 염소가스가 산소공급을 차단하고 동시에 열기를 차단하는 냉각 작용을 하므로 뛰어난 방연효과가 있으며 방연제의 화학작용으로 모디파이(Modify)된 디에텔렌 트리아민이 조습제 제오실과 함께 강력한 침투력을 부여하므로 문화재와 같이 오래된 목재건물의 균열된 부분에도 세밀하게 침투하고 방부, 방충효과를 증대시킬 뿐아니라 일차 도장이 된곳에 도포하여도 소기의 방연효과를 얻을 수 있다. 또 디에틸렌트리아민은 내열성이 높아 일광에 강하므로 변색을 방지하는 효과가 매우 높다.The flame-retardant paint of the present invention prepared as described above is used when mixed with an appropriate amount of pigment if necessary, when a fire occurs and heated to 200 ℃-400 ℃ flame retardant which is a polymer of triamine, phthalic anhydride, chloric anhydride, phenyl phosphoric acid The phosken gas and chlorine gas generated in the quenching system block the oxygen supply and at the same time block the heat, so it has an excellent flame retardant effect, and diethylene triamine modified by the chemical action of the flame retardant In addition, it gives strong penetrating power, so it penetrates into the cracked part of old wooden buildings like cultural assets in detail and increases the antiseptic and insect repellent effect, and also obtains the desired flame retardant effect even when applied to the place where the primary coating is applied. In addition, since diethylenetriamine has high heat resistance and is resistant to sunlight, it is very effective in preventing discoloration.
무수프탈산은 중축합된 고분자 물질로서 높은 접착력을 가지므로 강력접착제인 아크릴에마졸 및 아교과 함께 강한 접착력을 부여하여 박락을 방지한다.Phthalic anhydride is a polycondensed polymer material and has high adhesive force, and thus, strong adhesion with acrylamide and glue, which is a strong adhesive, is prevented from falling off.
소듐 디 하이드로 아세테이트는 디에틸렌트리아민과 함께 강력한 방충효과를 갖게 하므로 곰팡이 등에 의한 부식을 방지하여 내구성을 높게한다.Sodium dihydroacetate has a strong insect repellent effect with diethylenetriamine, thereby preventing corrosion by mold and the like to increase durability.
이상과 같이 본 발명은 포스켄 가스와 염소가스에 의한 방연효과가 뛰어나면서 강한 침투력으로 일차 도장된 곳에서도 소기의 방연효과를 얻을 수 있으며 목재의 균열된 부분에 세밀하게 침투하여 방연, 방부, 방충효과를 증대케하고 내열성이 강하고 변색을 방지하며 접착성이 강하여 박락을 방지하고 방부 및 방충효과가 높아 곰팡이등에 의하여 부식되지 않으며 강한 침투성, 내열성, 접착성으로 인하여 내마모성, 내구성, 내굴곡성이 높아 전통가옥 또는 문화재와 같은 오래된 목재건물에 도포 사용하므로서 이들을 오랫동안 보호 보존케하며 무색 무취하고 pH7±중성이므로 전혀 인체에 무해할 뿐아니라 수성으로 물에 잘녹으므로 사용이 편리한 등의 효과가 있는 것이다.As described above, the present invention has excellent flame retardant effect by phosken gas and chlorine gas, and can obtain the desired flame retardant effect even in the place where it is firstly painted with strong penetrating power. It increases the effect, heat resistance, prevents discoloration, and strong adhesion prevents falling off, and has high antiseptic and insect repellent effect, so it does not corrode by mold, etc., and has high wear resistance, durability, and flex resistance due to strong permeability, heat resistance, and adhesion. As it is applied to old wood buildings such as houses or cultural properties, they are protected and preserved for a long time. It is colorless and odorless and pH7 ± neutral, so it is not harmful to the human body at all.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019890012726A KR920010096B1 (en) | 1989-09-04 | 1989-09-04 | Process for preparation of prevention of fire-paints for wood |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019890012726A KR920010096B1 (en) | 1989-09-04 | 1989-09-04 | Process for preparation of prevention of fire-paints for wood |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR910006431A KR910006431A (en) | 1991-04-29 |
| KR920010096B1 true KR920010096B1 (en) | 1992-11-14 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019890012726A KR920010096B1 (en) | 1989-09-04 | 1989-09-04 | Process for preparation of prevention of fire-paints for wood |
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| Country | Link |
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| KR (1) | KR920010096B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108624017A (en) * | 2018-05-07 | 2018-10-09 | 扬州工业职业技术学院 | A kind of polyester-montmorillonite flame-retardant lactic acid composite material and preparation method thereof |
-
1989
- 1989-09-04 KR KR1019890012726A patent/KR920010096B1/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108624017A (en) * | 2018-05-07 | 2018-10-09 | 扬州工业职业技术学院 | A kind of polyester-montmorillonite flame-retardant lactic acid composite material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| KR910006431A (en) | 1991-04-29 |
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