KR910700296A - Metal acrylate as rubber and metal adhesion promoter - Google Patents

Metal acrylate as rubber and metal adhesion promoter

Info

Publication number
KR910700296A
KR910700296A KR1019900701972A KR900701972A KR910700296A KR 910700296 A KR910700296 A KR 910700296A KR 1019900701972 A KR1019900701972 A KR 1019900701972A KR 900701972 A KR900701972 A KR 900701972A KR 910700296 A KR910700296 A KR 910700296A
Authority
KR
South Korea
Prior art keywords
parts
rubber
acrylate
sulfur
weight
Prior art date
Application number
KR1019900701972A
Other languages
Korean (ko)
Inventor
프란시스 스티에버 조셉
홍승희
페이스 사이버트 레베카
Original Assignee
존 에이. 쉬든
유니로열 케미칼 컴페니. 인크.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 존 에이. 쉬든, 유니로열 케미칼 컴페니. 인크. filed Critical 존 에이. 쉬든
Publication of KR910700296A publication Critical patent/KR910700296A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/10Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C08F291/02Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to elastomers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098Metal salts of carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00Characterised by the use of unspecified rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음.No content.

Description

고무와 금속의 접착성 촉진제로서의 아크릴산 금속Metal acrylate as rubber and metal adhesion promoter

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (14)

하기 a)~d)를 포함하는 배합물을 경화하여 생성된 보강 엘라스토마 조성물 : a) 가황성 고무; b) 놋쇠도금 금속 보강재; c) 2가 또는 3가 금속의 아크릴레이이트 또는 메타아크릴레이트 염; d) 유황 또는 유황 공여체.A reinforcing elastomer composition produced by curing a blend comprising a) to d): a) vulcanizable rubber; b) brass plated metal reinforcements; c) acrylate or methacrylate salts of divalent or trivalent metals; d) sulfur or sulfur donors. 제1항에 있어서, 유황 경화 촉진제를 또한 포함하는 보강 엘라스토마 조성물.The reinforcing elastomer composition of claim 1, further comprising a sulfur cure accelerator. 하기 a)~e)를 포함하는 배합물을 경화하여 생성된 보강 엘라스토마 조성물 : a) 가황성 고무; b) 놋쇠도금 금속 보강재; c) 100중량부의 고무당 0.05~20부의 2가 또는 3가 금속의 아크릴레이이트 또는 메타아크릴레이트 염; d) 100중량부의 고무당 0.2~10.0부의 유황; 및 e) 100중량부의 고무당 0.1~5.0부의 유황 경화 촉진제.A reinforcing elastomer composition produced by curing a blend comprising a) to e): a) vulcanizable rubber; b) brass plated metal reinforcements; c) 0.05-20 parts of divalent or trivalent metal acrylate or methacrylate salts per 100 parts by weight of rubber; d) 0.2-10.0 parts sulfur per 100 parts by weight rubber; And e) 0.1 to 5.0 parts sulfur cure accelerator per 100 parts by weight rubber. 하기 a)~f)를 포함하는 배합물을 경화하여 생성된 보강 엘라스토마 조성물 : a) 가황성 고무; b) 놋쇠도금 금속 보강재; c) 100중량부의 고무당 0.05~20부의 2가 또는 3가 금속의 아크릴레이이트 또는 메타아크릴레이트 염; d) 100중량부의 고무당 0.2~10.0부의 유황; e) 100중량부의 고무당 0.1~5.0부의 유황 경화 촉진제; 및 f) 0.05~20부의, 코발트염, 2,3,5,6-테트라클로로-1,4-벤조퀴논, 포름알데히드 공여체 및 레조시놀공여체로 구성되어 있는 군으로부터 선택된 하나 이상의 결합제.A reinforcing elastomer composition produced by curing a blend comprising a) to f): a) vulcanizable rubber; b) brass plated metal reinforcements; c) 0.05-20 parts of divalent or trivalent metal acrylate or methacrylate salts per 100 parts by weight of rubber; d) 0.2-10.0 parts sulfur per 100 parts by weight rubber; e) 0.1 to 5.0 parts sulfur cure accelerator per 100 parts by weight rubber; And f) at least one binder selected from the group consisting of 0.05-20 parts cobalt salt, 2,3,5,6-tetrachloro-1,4-benzoquinone, formaldehyde donor and resorcinol donor. 제2항에 있어서, 유황 경화 촉진제가 벤질티아졸 술펜아미드, 2-메르캅토벤조티아졸 또는 벤질티아질디술피드인 보강 엘라스토마 조성물.3. The reinforced elastomeric composition of claim 2, wherein the sulfur cure accelerator is benzylthiazole sulfenamide, 2-mercaptobenzothiazole or benzylthiazyl disulfide. 제3항에 있어서, 유황 경화 촉진제가 벤질티아졸 술펜아미드, 2-메르캅토벤조티아졸 또는 벤질티아질디술피드인 보강 엘라스토마 조성물.4. The reinforced elastomeric composition of claim 3, wherein the sulfur cure accelerator is benzylthiazole sulfenamide, 2-mercaptobenzothiazole or benzylthiazyl disulfide. 제1항에 있어서, 가황성 고무가, 천연고무, 합성고무 및 그들의 배합물로 구성되어 있는 군으로부터 선택된 보강 엘라스토마 조성물.The reinforcing elastomer composition according to claim 1, wherein the vulcanizable rubber is selected from the group consisting of natural rubber, synthetic rubber and combinations thereof. 제1항에 있어서, 아크릴레이트 또는 메타아크릴레이트 염이, 알루미늄 디아크릴레이트, 알루미늄 디메타아크릴레이트, 징크 디아크릴레이트, 징크 디메타아크릴레이트, 마그네슘 디아크릴레이트 및 마그네슘 디메틸아크릴레이트로 구성되어 있는 군으로부터 선택된 보강 엘라스토마 조성물.The acrylate or methacrylate salt of claim 1, wherein the acrylate or methacrylate salt is composed of aluminum diacrylate, aluminum dimethacrylate, zinc diacrylate, zinc dimethacrylate, magnesium diacrylate and magnesium dimethylacrylate. Reinforcing elastomer composition selected from the group. 제3항에 있어서, 아크릴레이트 또는 메타아크릴레이트 염이, 알루미늄 디아크릴레이트, 알루미늄 디메타아크릴레이트, 징크 디아크릴레이트, 징크 디메타아크릴레이트, 마그네슘 디아크릴레이트 및 마그네슘 디메틸아크릴레이트로 구성되어 있는 군으로부터 선택된 보강 엘라스토마 조성물.4. The acrylate or methacrylate salt of claim 3, wherein the acrylate or methacrylate salt is comprised of aluminum diacrylate, aluminum dimethacrylate, zinc diacrylate, zinc dimethacrylate, magnesium diacrylate and magnesium dimethylacrylate. Reinforcing elastomer composition selected from the group. 하기 단계를 포함하는, 보강 엘라스토마 조성물의 제조방법 : A) 하기 a)~d)를 포함하는 배합물의 제조; a) 가황성 고무; b) 놋쇠도금 금속 보강재; c) 2가 또는 3가 금속의 아크릴레이트 또는 메타아크릴레이트 염; 및 d) 유황 또는 유황 공여체; 및 B) 상기 배합물을 경화처리.A process for preparing a reinforcing elastomer composition, comprising the steps of: A) preparation of a formulation comprising the following a) to d); a) vulcanizable rubber; b) brass plated metal reinforcements; c) acrylate or methacrylate salts of divalent or trivalent metals; And d) sulfur or sulfur donors; And B) curing the blend. 하기 단계를 포함하는 보강 엘라스토마 조성물의 제조방법. A) 하기 a)~e)를 포함하는 배합물을 제조 : a) 가황성 고무; b) 놋쇠도금 금속 보강재; c) 100중량부의 고무당 0.05~20부의 2가 또는 3가 금속의 아크릴레이트 또는 메타아크릴레이트 염; d) 100중량부의 고무당 0.2~10.0부의 유황; 및 e) 100중량부의 고무당 0.1~5.0부의 유황 경화 촉진제; B) 상기 배합물을 경화처리.Method for producing a reinforcing elastomer composition comprising the following steps. A) preparing a blend comprising the following a) -e): a) vulcanizable rubber; b) brass plated metal reinforcements; c) 0.05-20 parts divalent or trivalent metal acrylate or methacrylate salts per 100 parts by weight of rubber; d) 0.2-10.0 parts sulfur per 100 parts by weight rubber; And e) 0.1 to 5.0 parts sulfur cure accelerator per 100 parts by weight of rubber; B) Curing the blend. 하기 단계를 포함하는, 보강 엘라스토마 조성물의 제조방법. A) 하기 a)~f)를 포함하는 배합물을 제조 : a) 가황성 고무; b) 놋쇠도금 금속 보강재; c) 100중량부의 고무당 0.05~20부의 2가 또는 3가 금속의 아크릴레이트 또는 메타아크릴레이트 염; d) 100중량부의 고무당 0.2~10.0부의 유황; 및 e) 100중량부의 고무당 0.1~5.0부의 유황 경화 촉진제; 및 f) 0.05~20부의, 코발트염, 2,3,5,6-테트라클로로-1,4-벤조퀴논, 포름알데히드 공여체 및 레조시놀공여체로 구성되어 있는 군으로부터 선택된 하나 이상의 결합제; 및 B) 상기 배합물을 경화처리.Method of producing a reinforced elastomeric composition, comprising the following steps. A) Preparation of a blend comprising a) to f): a) vulcanizable rubber; b) brass plated metal reinforcements; c) 0.05-20 parts divalent or trivalent metal acrylate or methacrylate salts per 100 parts by weight of rubber; d) 0.2-10.0 parts sulfur per 100 parts by weight rubber; And e) 0.1 to 5.0 parts sulfur cure accelerator per 100 parts by weight of rubber; And f) at least one binder selected from the group consisting of 0.05-20 parts cobalt salt, 2,3,5,6-tetrachloro-1,4-benzoquinone, formaldehyde donor and resorcinol donor; And B) curing the blend. 제11항에 있어서, 유황 경화 촉진제가, 벤질티아졸 술펜아미드, 2-메르캅토벤조티아질 또는 벤질티아질 디술피드인 보강 엘라스토마 조성물인 방법.12. The method of claim 11, wherein the sulfur cure accelerator is benzylthiazole sulfenamide, 2-mercaptobenzothiazyl or benzylthiazyl disulfide. 제11항에 있어서, 아크릴레이트 또는 메타아크릴레이트 염이, 알루미늄 디아크릴레이트, 알루미늄 디메티아크릴레이트, 징크 디아크릴레이트, 징크 디메타아크릴레이트, 마그네슘 디아크릴레이트 및 마그네슘 디메티아크릴레이트로 구성되어 있는 군으로부터 선택된 방법.12. The acrylate or methacrylate salt of claim 11, consisting of aluminum diacrylate, aluminum dimethacrylate, zinc diacrylate, zinc dimethacrylate, magnesium diacrylate and magnesium dimethacrylate. Method selected from the group of which are present. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019900701972A 1989-01-17 1990-01-08 Metal acrylate as rubber and metal adhesion promoter KR910700296A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US29790089A 1989-01-17 1989-01-17
US297,900 1989-01-17
PCT/US1990/000208 WO1990008170A1 (en) 1989-01-17 1990-01-08 Metal acrylates as rubber-to-metal adhesion promoters

Publications (1)

Publication Number Publication Date
KR910700296A true KR910700296A (en) 1991-03-14

Family

ID=23148196

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900701972A KR910700296A (en) 1989-01-17 1990-01-08 Metal acrylate as rubber and metal adhesion promoter

Country Status (2)

Country Link
KR (1) KR910700296A (en)
WO (1) WO1990008170A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5126501A (en) * 1991-01-23 1992-06-30 General Tire, Inc. Elastomeric compositions and tire belt structure
JPH05311008A (en) * 1992-05-13 1993-11-22 Sumitomo Chem Co Ltd Rubber composition for adhesion by vulcanization, method for adhesion by vulcanization, and bonded metal-rubber article
DE19615134C2 (en) * 1996-04-17 2003-04-17 Continental Ag Adhesion promoter substance between vulcanizable polymer and metallic reinforcement, process for their application and their use
EP2082900B1 (en) 2007-12-31 2012-02-08 Bridgestone Corporation Metal soaps incorporated in rubber compositions and method for incorporating such soaps in rubber compositions
US9803060B2 (en) 2009-09-10 2017-10-31 Bridgestone Corporation Compositions and method for making hollow nanoparticles from metal soaps
US8802755B2 (en) 2011-01-18 2014-08-12 Bridgestone Corporation Rubber compositions including metal phosphate esters
US9670341B2 (en) 2012-11-02 2017-06-06 Bridgestone Corporation Rubber compositions comprising metal carboxylates and processes for making the same

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
UST900003I4 (en) * 1971-03-05 1972-07-18 Defensive publication
JPS5350246A (en) * 1976-10-20 1978-05-08 Bridgestone Corp Rubber composition having good adhesion to metal
ZA812017B (en) * 1980-05-08 1982-04-28 Firestone Tire New compounding formulas for rubber-metal adhesion (use of cobalt propionate).
DE3100572A1 (en) * 1981-01-10 1982-08-12 Bayer Ag, 5090 Leverkusen METHOD FOR INCREASING ADHESIVITY BETWEEN RUBBER AND METALS
US4495326A (en) * 1984-01-09 1985-01-22 The Firestone Tire & Rubber Company Rubber compounds containing zinc dimethacrylate
DE3737595A1 (en) * 1986-11-18 1988-05-26 Bridgestone Corp RUBBER MIX FOR TIRE BULB FILLER
JPH01287154A (en) * 1987-12-28 1989-11-17 Kawaguchi Kagaku Kogyo Kk Rubber composition

Also Published As

Publication number Publication date
WO1990008170A1 (en) 1990-07-26

Similar Documents

Publication Publication Date Title
KR860003294A (en) Rubber Curing Agent Composition and Manufacturing Method of Vulcanized Rubber
KR910700296A (en) Metal acrylate as rubber and metal adhesion promoter
KR890000573A (en) Rubber composition and golf ball comprising same
JPS57109842A (en) Rubber composition and use
DE3880570D1 (en) VULCANIZATION METHOD FOR PRODUCING A ROAD BINDING AGENT.
KR910009733A (en) Accelerator Compositions and Rubber Compositions Comprising the Same
ES8103142A1 (en) Rubber-steel composite article, e.g. a vehicle tire including at least one steel reinforcing element.
JPS5679135A (en) Rubber composition
PT72824A (en) Process for the preparation of a cured rubber skim stock composition having improved metal adhesion and metal adhesion retention and of a product having said properties
KR930001940A (en) Golf ball with improved cover
KR900016489A (en) Maraging River
EP0386887A3 (en) High-hardness rubber composition
KR890014639A (en) Manufacturing method of rubber / metal composite material with strong rubber / metal bonding
ES8707281A1 (en) Method for improved metal adhesion and metal adhesion retention.
KR890002307A (en) Vulcanization accelerator
ATE28595T1 (en) PROCESS FOR PRODUCTION OF RUBBER ARTICLES REINFORCED WITH STEEL CORD.
KR930000585A (en) Rubber composition
US4316968A (en) Modified phenolic aldehyde resin to produce an improved adhesive coating and method of making same
SU621694A1 (en) Synthetic rubber-base compound
KR900016342A (en) Vulcanizable Rubber Bladder Stock With Reduced Viscosity
JPS55144037A (en) Rubber composition for rubber coated fabric
KR960041258A (en) SBR rubber composition with good adhesion to fiber cords
JPS5240548A (en) Rubber composition
KR880012699A (en) Epoxy Resin Molding Material Composition
ITMI931835A1 (en) PROCEDURE FOR STABILIZING MIXTURES OF BITUMEN AND POLYMER

Legal Events

Date Code Title Description
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid