KR910018201A - Conductive ink and conductive thick film pattern formation method - Google Patents

Conductive ink and conductive thick film pattern formation method Download PDF

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KR910018201A
KR910018201A KR1019910005839A KR910005839A KR910018201A KR 910018201 A KR910018201 A KR 910018201A KR 1019910005839 A KR1019910005839 A KR 1019910005839A KR 910005839 A KR910005839 A KR 910005839A KR 910018201 A KR910018201 A KR 910018201A
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poly
conductive
conductive ink
iso
organic binder
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KR1019910005839A
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KR970001404B1 (en
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사또루 후지이
히로또시 와따나베
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다니아 아끼오
마쯔시다덴기산교 가부시기가이샤
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/08Printing inks based on natural resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/10Intaglio printing ; Gravure printing

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Conductive Materials (AREA)
  • Parts Printed On Printed Circuit Boards (AREA)

Abstract

내용 없음No content

Description

도전성 잉크 및 도전성 후막패턴형성방법Conductive ink and conductive thick film pattern formation method

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제1도는 잉크로 오목부를 충전하는 방법을 도시한 개략도, 제2도는 오목부에서 블랭킷으로의 패턴저사방법을 도시한 개략도, 제3도는 블랭킷상의 패턴을 회로기판에 압착, 전사하는 방법의 개략도.1 is a schematic diagram showing a method of filling a recess with ink, and FIG. 2 is a schematic diagram showing a method of pattern writing from a recess to a blanket, and FIG. 3 is a schematic diagram of a method of pressing and transferring a blanket pattern onto a circuit board.

Claims (25)

도전성금속분말, 글라스프릿, 전이금속산화물 및 분산제와, 폴리-이소-부틸메타크릴레이트, 폴리-이소-프로필메타크릴레이트, 폴리메틸 메타크릴레이트, 폴리테트라플루오로 에틸렌 및 폴리-α-메틸스티렌중 적어도 1종류로 이루어진 유기바인더를 함유하는 비히클로 구성된 것을 특징으로 하는 도전성잉크.Conductive metal powder, glass frit, transition metal oxide and dispersant, poly-iso-butyl methacrylate, poly-iso-propyl methacrylate, polymethyl methacrylate, polytetrafluoro ethylene and poly-α-methylstyrene A conductive ink comprising a vehicle containing an organic binder composed of at least one of the foregoing. 제1항에 있어서, 유기바인더가, 폴리-α-메틸스티렌과 폴리-이소-부틸메타크릴레이트의 공중합체로 구성된 것을 특징으로 하는 도전성잉크.The conductive ink according to claim 1, wherein the organic binder is composed of a copolymer of poly-α-methylstyrene and poly-iso-butyl methacrylate. 제2항에 있어서, 유기바인더가, 폴리-α-메틸스티렌 5~20wt%와 폴리이소-부틸메타크릴레이트 80~95wt%의 비로 이루어진 공중합체로 구성된 것을 특징으로 하는 도전성잉크.The conductive ink according to claim 2, wherein the organic binder is composed of a copolymer composed of 5 to 20 wt% of poly-α-methylstyrene and 80 to 95 wt% of polyiso-butyl methacrylate. 제1항에 있어서, 유기바인더가, 폴리-α-메틸스티렌, 폴리-이소-부틸메타크릴레이트 및 폴리메틸메타크릴레이트의 공중합체로 구성된 것을 특징으로 하는 도전성잉크.The conductive ink according to claim 1, wherein the organic binder is composed of a copolymer of poly-?-Methylstyrene, poly-iso-butyl methacrylate, and polymethyl methacrylate. 제4항에 있어서, 유기바인더가, 폴리-α-메틸스티렌 5~20wt%와 폴리-이소-부틸메타크릴레이트 60~90wt% 및 폴리메틸메타크릴레이트 20~25%의 비로 이루어진 공중합체로 구성된 것을 특징으로 하는 도전성잉크.The method of claim 4, wherein the organic binder is composed of a copolymer consisting of a ratio of 5-20 wt% of poly-α-methylstyrene, 60-90 wt% of poly-iso-butyl methacrylate, and 20-25% of polymethyl methacrylate. Conductive ink, characterized in that. 제1항에 있어서, 유기바인더가, 폴리-α-메틸스티렌 및 폴리-이소-프로필메타크릴레이트의 공중합체로 구성된 것을 특징으로 하는 도전성잉크.The conductive ink according to claim 1, wherein the organic binder is composed of a copolymer of poly-α-methylstyrene and poly-iso-propyl methacrylate. 제6항에 있어서, 유기바인더가, 폴리-α-메틸스티렌 5~20wt% 및 폴리-이소-프로필메타크릴레이트 80~95wt%의 비로 이루어진 공중합체로 구성된 것을 특징으로 하는 도전성잉크.The conductive ink according to claim 6, wherein the organic binder is composed of a copolymer consisting of 5 to 20 wt% of poly-α-methylstyrene and 80 to 95 wt% of poly-iso-propyl methacrylate. 제1항에 있어서, 유기바인더가, 폴리-α-메틸스티렌, 폴리-이소-프로필메타크릴레이트 및 폴리메틸메타크릴레이트의 공중합체로 구성된 것을 특징으로 하는 도전성잉크.The conductive ink according to claim 1, wherein the organic binder is composed of a copolymer of poly-α-methylstyrene, poly-iso-propylmethacrylate, and polymethylmethacrylate. 제8항에 있어서, 유기바인더가, 폴리-α-메틸스티렌 5~20wt%, 폴리-이소-프로필메타크릴레이트 60~90wt% 및 폴리메틸메타크릴레이트 20~25wt%의 비로 이루어진 공중합체로 구성된 것을 특징으로 하는 도전성잉크.The method of claim 8, wherein the organic binder is composed of a copolymer consisting of a ratio of 5 to 20 wt% of poly-α-methylstyrene, 60 to 90 wt% of poly-iso-propyl methacrylate and 20 to 25 wt% of polymethyl methacrylate. Conductive ink, characterized in that. 제1항에 있어서, 유기바인더의 중량평균분자량이 100,000~1,300인 것을 특징으로 하는 도전성잉크.The conductive ink according to claim 1, wherein the weight average molecular weight of the organic binder is 100,000 to 1,300. 제1항에 있어서, 비히클을 구성하는 유기용매량이 3~13wt%, 글라스프릿량이 3~4wt%, 전이금속산화물이 0.5~2.0wt%, 분산제가 0.05~5.0wt%, 도저성금속분말이 78~86wt%로 구성된 것을 특징으로 하는 도전성잉크.The method according to claim 1, wherein the organic solvent constituting the vehicle is 3 to 13 wt%, the glass frit amount is 3 to 4 wt%, the transition metal oxide is 0.5 to 2.0 wt%, the dispersant is 0.05 to 5.0 wt%, the doped metal powder is 78 Conductive ink, characterized in that consisting of ~ 86wt%. 제1항에 있어서, 유기바인더의 함유량이 전체잉크량에 대해서 2~15wt%인 것을 특징으로 하는 도전성잉크.The conductive ink according to claim 1, wherein the content of the organic binder is 2 to 15 wt% based on the total amount of the ink. 제1항에 있어서, 비히클을 구서하는 유기용매가 전체분말양에 대해서 중량비로 0.04~0.18인 것을 특징으로 하는 도전성잉크.The conductive ink according to claim 1, wherein the organic solvent for preparing the vehicle is 0.04 to 0.18 in weight ratio with respect to the total powder amount. 제1항에 있어서, 도전성금속분말이 구리, 금 및 은중의 적어도 1종류로 구성된 것을 특징으로 하는 도전성잉크.The conductive ink according to claim 1, wherein the conductive metal powder is composed of at least one of copper, gold and silver. 제1항에 있어서, 도전성금속분말의 평균입자직경이 0.05~3.0㎛인 것을 특징으로 하는 도전성잉크.The conductive ink according to claim 1, wherein the average particle diameter of the conductive metal powder is 0.05 to 3.0 mu m. 제1항에 있어서, 비히클을 구성하는 유기용매가, α-테트핀올, 부틸카르비톨, 부틸가르비톨아세테이트, 2,2,4-트리메틸 1-3-히드록시펜틸이소부틸레이트, 2-부톡시에탄올 및 2-에톡시에탄올중 적어도 1종류로 구성된 것을 특징으로 하는 도전성잉크.The organic solvent constituting the vehicle according to claim 1, wherein the organic solvent constituting the vehicle is α-tetpinol, butyl carbitol, butylgarbitol acetate, 2,2,4-trimethyl 1-3-hydroxypentylisobutylate, 2-butoxy A conductive ink comprising at least one of ethanol and 2-ethoxyethanol. 제1항에 있어서, 전이금속산화물이, 산화아연, 산화티탄, 산화제2크롬, 산화카드뮴 일사화니켈중 적어도 1종류로 구성된 것을 특징으로 하는 도전성잉크.The conductive ink according to claim 1, wherein the transition metal oxide is composed of at least one of zinc oxide, titanium oxide, dichromium oxide, and nickel cadmium monoxide oxide. 도전성잉크르 오목판의 오목부에 충전하는 공정과, 오목판의 오목부중의 도전성 잉크를 실리콘수지를 주성분으로 하는 탄성체로 표면이 피복된 블랭킷상에 전사하는 공정과, 상기 블랭킷상에 전사된 도전성후막패턴을 기판상에 전사 및 인쇄하는 공정과 도전성패턴을 소성하여 유기물을 비산시키는 공정과, 도전성패턴을 소결시키는 공정으로 구성된 것을 특징으로 하는 도전성 후막패턴 형성방법.A process of filling a concave portion of the conductive ink concave plate, a process of transferring the conductive ink in the concave portion of the concave plate onto a blanket coated with an elastic body containing silicone resin as a main component, and a conductive thick film pattern transferred onto the blanket A method for forming a conductive thick film pattern comprising a process of transferring and printing a substrate onto a substrate, baking a conductive pattern to scatter organic matter, and sintering the conductive pattern. 제18항에 있어서, 도전성잉크는, 도전성 금속분말, 글라스프릿, 전이금속산화물 및 분산제와, 폴리-이소-부틸메타크릴레이트, 폴리-이소-프로필메타크릴레이트, 폴리메틸메타크릴레이트, 폴리테트라플루오로에틸렌 및 폴리-α-메틸스티렌중 적어도 1종류로 이루어진 유기바인더를 함유하는 비히클로 구성된 것을 특징으로 하는 도전성 후막패턴 형성방법.The method of claim 18, wherein the conductive ink is a conductive metal powder, glass frit, transition metal oxide and dispersant, poly-iso-butyl methacrylate, poly-iso-propyl methacrylate, polymethyl methacrylate, polytetra A conductive thick film pattern forming method comprising a vehicle containing an organic binder made of at least one of fluoroethylene and poly-α-methylstyrene. 제18항에 있어서, 실리콘수지를 주성분으로 하는 탄성체의 경도가 30~60도인 것을 특징으로 하는 도전성 후막패턴 형성방법.The conductive thick film pattern forming method according to claim 18, wherein the hardness of the elastic body containing silicone resin as a main component is 30 to 60 degrees. 제18항에 있어서, 오목판의 오목부속의 잉크를 실리콘수지를 주성분으로 하는 탄성체로 표면이 피복된 블랭킷에 전사하는 공정에 있어서의 전사압력과, 상기 블랭킷상에 전사된 도전성 후막패턴을 기판상에 전사 및 인쇄하는 공정에 있어서의 인쇄압력이 2~6㎏/㎠인 것을 특징으로 하는 도전성 후막패턴 형성방법.19. The substrate according to claim 18, wherein the transfer pressure in the step of transferring the ink in the concave portion of the concave plate to a blanket coated with an elastic body containing silicone resin as a main component, and the conductive thick film pattern transferred onto the blanket on the substrate. The printing pressure in the process of transferring and printing is 2-6 kg / cm <2>, The conductive thick film pattern formation method characterized by the above-mentioned. 제18항에 있어서, 비산화성 분위기에서 소성하는 공정에 있어서의 산소농도가 10ppm이하인 것을 특징으로 하는 도전성 후막패턴 형성방법.The method for forming a conductive thick film pattern according to claim 18, wherein the oxygen concentration in the step of firing in a non-oxidizing atmosphere is 10 ppm or less. 제18항에 있어서, 비산화성분위기에서 소성하는 공정에 있어서의 고온유지부의 온도가 850~975℃인 것을 특징으로 하는 도전성 후막패턴 형성방법.The method for forming a conductive thick film pattern according to claim 18, wherein the temperature of the high temperature holding part in the step of firing in a non-oxidizing component atmosphere is 850 to 975 ° C. 제18항에 있어서, 산화성분위기에서 소성하는 공정에 있어서의 고온유지부의 온도가 800~925℃인 것을 특징으로 하는 도전성 후막패턴 형성방법.The method for forming a conductive thick film pattern according to claim 18, wherein the temperature of the high temperature holding part in the step of firing in an oxidizing component crisis is 800 to 925 ° C. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019910005839A 1990-04-12 1991-04-12 Conductive ink KR970001404B1 (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP2-97106 1990-04-12
JP9710590 1990-04-12
JP2-97104 1990-04-12
JP2-97105 1990-04-12
JP9710490 1990-04-12
JP9710690 1990-04-12

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KR1019950002519A Division KR950008176B1 (en) 1990-04-12 1995-02-11 Method of forming a conductive thick film pattern

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KR910018201A true KR910018201A (en) 1991-11-30
KR970001404B1 KR970001404B1 (en) 1997-02-06

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JP4828269B2 (en) * 2006-03-16 2011-11-30 住友ゴム工業株式会社 Manufacturing method of conductive pattern
JP5320672B2 (en) * 2006-12-19 2013-10-23 三菱マテリアル株式会社 Evaluation method for printing ink
JP5298426B2 (en) * 2006-12-19 2013-09-25 三菱マテリアル株式会社 Printing ink
JP2008184501A (en) * 2007-01-29 2008-08-14 Mitsubishi Materials Corp Printing ink and electrode for plasma display panel using the same, and method for producing the electrode
JP2010520934A (en) * 2007-03-09 2010-06-17 ドウジン セミケム カンパニー リミテッド Black conductive paste composition, interfering electromagnetic wave shielding filter including the same, and display device
KR100905399B1 (en) * 2007-09-07 2009-06-30 연세대학교 산학협력단 Conductive ink compositions incorporating nano glass frit and nano metal for enhanced adhesion with glass and ceramic substrates used in displays
JP5403717B2 (en) * 2009-04-08 2014-01-29 エルジー・ケム・リミテッド Printing paste composition and electrode formed thereby
KR101625939B1 (en) * 2009-12-22 2016-06-01 삼성디스플레이 주식회사 Printing plate for gravure printing, method of manufacturing the same, and method of forming printing pattern using the printing plate
CN102892847B (en) * 2010-05-10 2014-12-17 Lg化学株式会社 Conductive metal ink composition, and method for forming a conductive pattern
EP2590177B1 (en) * 2011-11-04 2015-08-12 Heraeus Precious Metals North America Conshohocken LLC Organic vehicle for electroconductive paste
WO2015182954A1 (en) * 2014-05-27 2015-12-03 주식회사 엘지화학 Conductive polymer ink composition

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KR970001404B1 (en) 1997-02-06
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