KR910011646A - 크라운 화합물을 사용하여 용액중에 존재하는 플루토늄(ⅳ)을 회수하는 방법 - Google Patents

크라운 화합물을 사용하여 용액중에 존재하는 플루토늄(ⅳ)을 회수하는 방법 Download PDF

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KR910011646A
KR910011646A KR1019900020595A KR900020595A KR910011646A KR 910011646 A KR910011646 A KR 910011646A KR 1019900020595 A KR1019900020595 A KR 1019900020595A KR 900020595 A KR900020595 A KR 900020595A KR 910011646 A KR910011646 A KR 910011646A
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South Korea
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solution
plutonium
crown compound
solid phase
aqueous solution
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KR1019900020595A
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English (en)
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푸 쟈끄
르메르 마르끄
기 알랭
기용 벵쌍
쇼멜 로돌프
델로쥬 앙드레
두뜨레뤼뉴 삐에르
르 로이 앙리
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꼬게마 꽁파니 제네랄 데 마띠에르 뉘끌레르
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Publication of KR910011646A publication Critical patent/KR910011646A/ko

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    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21C—NUCLEAR REACTORS
    • G21C19/00—Arrangements for treating, for handling, or for facilitating the handling of, fuel or other materials which are used within the reactor, e.g. within its pressure vessel
    • G21C19/42—Reprocessing of irradiated fuel
    • G21C19/44—Reprocessing of irradiated fuel of irradiated solid fuel
    • G21C19/46—Aqueous processes, e.g. by using organic extraction means, including the regeneration of these means
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G56/00—Compounds of transuranic elements
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04—Treating liquids
    • G21F9/06—Processing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00—Energy generation of nuclear origin
    • Y02E30/30—Nuclear fission reactors
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Plasma & Fusion (AREA)
  • Inorganic Chemistry (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

내용 없음

Description

크라운 화합물을 사용하여 용액중에 존재하는 플루토늄(Ⅳ)을 회수하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
첨부 도면은 핵분열 생성물(PF)의 농축용액을 가공처리하기 위한 본 발명에 따른 방법의 첫번째 실시형태의 관한 계통도.

Claims (14)

  1. 조사(照射)된 핵연료를 재처리하기 위한 제1사이클에서 유래된 핵분열 생성물의 농축용액, 혹은 조사된 핵연료 재처리 핵연료 재처리 장치로 부터 유래된 수성 배출액 혹은 아메리슘을 함유한 플루토늄 농축액으로 구성된 수용액을 1이상의 크라운 화합물을 함유하는 유기용액과 접촉시키고, 유기용액으로 부터 추출된 풀루토늄을 수용액으로 부터 재추출시킴으로써 회수하여, 상기 수용액중에 존재하는 플루토늄(Ⅳ)을 회수하는 방법.
  2. 제1항에 있어서, 유기용액이 벤조니트릴, 니트로벤젠 또는 디클로로에탄으로 구성된 희석제를 포함하는 방법.
  3. 제2항에 있어서, 유기용액내 크라운 화합물의 농도가 10-3내지 2.5몰/리터인 방법.
  4. 제1항에 있어서, 수성 재추출 용액이 0.05 내지 2몰/리터의 황산을 함유하는 황산 용액인 방법.
  5. 제1항 내지 제4항중 어느 한 하나에 있어서, 플루토늄 재추출 단계를 실시하기 전, 플루토늄을 추출시키는 유기용액을 질산 수용액으로 세척하기 위한 추가 단계를 1이상 포함하는 방법.
  6. 제5항에 있어서, 질산 수용액이 2 내지 5몰/리터의 질산 농도를 갖는 방법.
  7. 미량의 플루토늄(Ⅳ)이 존재하는 수용액을 1이상의 크라운 화합물이 포함된 고상과 접촉시켜 플루토늄이 이러한 고상위에 보유되도록 함으로써, 상기 수용액중의 미량의 플루토늄(Ⅳ)을 회수하는 방법.
  8. 제7항에 있어서, 고상이 유기 또는 무기 물질이며, 크라운 화합물이 화학적 결합 또는 흡착에 의하여 이러한 고상에 고착되는 방법.
  9. 제8항에 있어서, 고상이 Florisil인 방법.
  10. 제7항 내지 제9항중 어느 하나에 있어서, 고상을 환원제 또는 친수성 산의 용액과 접촉시킴으로써 플루토늄을 회수하는 방법.
  11. 제1항 내지 제10항중 어느 하나에 있어서, 크라운 화합물이 하기 일반식을 충족시키는 방법.
    상기식에서, n은 0또는 1 내지 40의 정수이다.
  12. 제11항에 있어서, 크라운 화합물이 n=1인 일반식(I)을 충족시키는 방법.
  13. 제11항에 있어서, 크라운 화합물이 n=1인 일반식(I)의 크라운 화합물의 시스-신-시스 이성질체인 방법.
  14. 제1항 내지 제6항중 어느 하나에 있어서, 수용액이 아메리슘을 함유하는 플루토늄의 농축용액이며, 하기식을 갖는 크라운 화합물의 시스-앤티-시스 이성질체가 사용되는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900020595A 1989-12-15 1990-12-14 크라운 화합물을 사용하여 용액중에 존재하는 플루토늄(ⅳ)을 회수하는 방법 KR910011646A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8916639 1989-12-15
FR8916639A FR2656150B1 (fr) 1989-12-15 1989-12-15 Procede de recuperation au moyen d'un ether couronne du plutonium present dans des solutions telles que les effluents aqueux, les solutions concentrees de produits de fission et les solutions concentrees de plutonium.

Publications (1)

Publication Number Publication Date
KR910011646A true KR910011646A (ko) 1991-08-07

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KR1019900020595A KR910011646A (ko) 1989-12-15 1990-12-14 크라운 화합물을 사용하여 용액중에 존재하는 플루토늄(ⅳ)을 회수하는 방법

Country Status (10)

Country Link
US (2) US5183645A (ko)
EP (1) EP0433175B1 (ko)
JP (1) JPH04118593A (ko)
KR (1) KR910011646A (ko)
CN (1) CN1053859A (ko)
CA (1) CA2031749A1 (ko)
DE (1) DE69022375D1 (ko)
FI (1) FI906107A (ko)
FR (1) FR2656150B1 (ko)
TW (1) TW287146B (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996014931A1 (en) * 1994-11-10 1996-05-23 Minnesota Mining And Manufacturing Company Solid phase extraction using composite sheet for direct measurement of radioactivity
FR2797786B1 (fr) 1999-08-27 2001-10-05 Commissariat Energie Atomique Procede et installation d'elimination des cations metalliques d'un liquide par des resines de polyazacycloalcanes greffes sur un support
EP1793387B1 (de) * 2004-09-09 2010-12-29 OOO "Proektno-Konstruktorskoe I Proizvodstvenno-Vnedrencheskoe Predpriyatie "Deimos Ltd" Extraktion von radionukliden unter verwendung von kronenether enthaltenden extraktionsmitteln
FR2906927B1 (fr) * 2006-10-05 2014-07-25 Commissariat Energie Atomique Procede de vitrification de produits de fission.
CN100460057C (zh) * 2007-06-07 2009-02-11 浙江大学 一种同时分离发热元素Cs和Sr的吸附剂及其制备方法和应用

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1131647A (en) * 1978-11-10 1982-09-14 Arie Van Zon Macrocyclic polyether complexes and method for macrocyclic polyether isolation via said complexes
US4421923A (en) * 1980-12-12 1983-12-20 Pcr Research Chemicals, Inc. Ring substituted crown ethers and method of producing same
DE3172916D1 (en) * 1981-08-31 1985-12-19 Kernforschungsz Karlsruhe Process for removing cesium ions from solutions by using an addition compound in solid form of a macrocyclic polyether and an inorganic heteropolyacid
DE3202776A1 (de) * 1982-01-28 1983-08-04 Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe Verfahren zur anreicherung und abtrennung von schweren wasserstoff-isotopen aus diese enthaltenden stoffstroemen durch isotopenaustausch
US4438251A (en) * 1983-05-16 1984-03-20 Armstrong World Industries, Inc. Polyurethane polymers comprising macrocyclic crown ethers in the polymer backbone
US4683124A (en) * 1985-06-13 1987-07-28 The United States Of America As Represented By The United States Department Of Energy Actinide recovery process
US4749518A (en) * 1985-08-06 1988-06-07 University Of South Carolina Extraction of cesium and strontium from nuclear waste
US5179213A (en) * 1987-09-04 1993-01-12 Brigham Young University Macrocyclic ligands bonded to an inorganic support matrix and a process for selectively and quantitatively removing and concentrating ions present at low concentrations from mixtures thereof with other ions
FR2633090B1 (fr) * 1988-06-16 1992-07-31 Cogema Procede pour separer au moyen d'ethers-couronnes l'uranium et le plutonium presents dans un milieu aqueux provenant du retraitement des combustibles nucleaires irradies
US4917825A (en) * 1988-10-05 1990-04-17 The United States Of America, As Represented By The Department Of Energy Solvent composition and process for the isolation of radium

Also Published As

Publication number Publication date
DE69022375D1 (de) 1995-10-19
CN1053859A (zh) 1991-08-14
CA2031749A1 (en) 1991-06-16
FR2656150B1 (fr) 1994-04-15
FI906107A0 (fi) 1990-12-12
FI906107A (fi) 1991-06-16
TW287146B (ko) 1996-10-01
US5344624A (en) 1994-09-06
EP0433175B1 (fr) 1995-09-13
EP0433175A1 (fr) 1991-06-19
FR2656150A1 (fr) 1991-06-21
US5183645A (en) 1993-02-02
JPH04118593A (ja) 1992-04-20

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