KR910007606B1 - Process for making veber age from the root bark of various araliaceous shrubs - Google Patents

Process for making veber age from the root bark of various araliaceous shrubs Download PDF

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KR910007606B1
KR910007606B1 KR1019910007567A KR910007567A KR910007606B1 KR 910007606 B1 KR910007606 B1 KR 910007606B1 KR 1019910007567 A KR1019910007567 A KR 1019910007567A KR 910007567 A KR910007567 A KR 910007567A KR 910007606 B1 KR910007606 B1 KR 910007606B1
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water
extract
mixing
raw material
alcohol
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KR1019910007567A
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Korean (ko)
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오상룡
김성수
민병용
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한국식품개발연구원
권태완
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Priority claimed from KR1019880017225A external-priority patent/KR910006938B1/en
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/38Other non-alcoholic beverages
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/385Concentrates of non-alcoholic beverages
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2250/00Food ingredients
    • A23V2250/20Natural extracts
    • A23V2250/21Plant extracts
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2300/00Processes
    • A23V2300/14Extraction

Abstract

A process for preparing beverage from the root bark of various araliaceous shrubs (I) comprises: (a) soaking the material (e.g., (I) , cinnamon bark (II), cassia leguminosae (III), ginseng (IV), etc.) for 30min, and washing; (b) mixing the washed material with 5-10 times of water and extracting at 60-100 deg.C for 2-3hrs to obtain the water-soluble component (V); (c) mixing the extracted material with 5-10 times of 80% EtOH-soluble component (VI); (d) mixing the (V) with the (VI) and concentrating to Brix 50 under vacuum at 50 deg.C or less; (e) mixing 0.8-1.5% (I)-, 0.05-0.1 (II)-, 0.5-1.0% (III)-, and 0.4-0.5 (IV) extract, and adding 1.0- 5.0% sugar, 10-13% HFCS, 0.02-0.2% citrate, 0.03% Na-citrate, etc to obtain the final product.

Description

오갈피 음료의 제조방법How to Make Ogalfi Drink

본 발명은 생약재등을 이용한 오갈피 음료의 제조방법에 관한 것이다.The present invention relates to a method for producing an organopi drink using herbal medicines and the like.

생약재중 구기자, 오미자, 오갈피, 당귀는 예로부터 차로서 즐겨 음용해온 재료이며, 이러한 재료로 제조되어 현재 시중에 나와있는 전통차의 대부분은 추출물을 다른 부재료와 같이 분무 건조한 분말형으로 되어 있기 때문에 용기에 넣어 끊는 물로 타서 먹어야하는 불편한 점이 있을 뿐만 아니라 기호성에 있어서도 장년층에 편중된 경향이 있다고 하는 결점이 있었다.Gojija, Schisandra chinensis, Ogalpi, and Angelica among the herbal medicines have been enjoyed as tea since ancient times, and most of the traditional teas made from these materials are spray dried powder like other ingredients, Not only is it inconvenient to eat with water, but also has a flaw that it tends to be biased toward the elderly in palatability.

본 발명은 상기한 전통차가 갖는 결점들을 고려하여 발명된 것으로서, 생약재인 오갈피등의 추출물을 주원료로하여 원료의 맛특성에 어울리는 부재료 및 당, 산미료를 적정량 혼합한 후 관에 넣어 적정조건에서 살균 보존재료 및 기타식품첨가물을 첨가하지 않고 상온에서 장기저장 및 유통가능하며, 언제, 어디서나 간편하게 맛에 있어서도 연령층에 관계없이 기호성이 좋고 건강에도 유익한 생약재를 재료로한 오갈피 음료의 제조방법을 제공함에 그 목적이 있다.The present invention has been invented in consideration of the drawbacks of the above-mentioned traditional tea, using the extract of the herbal medicines such as the gallbladder as a main raw material, and after mixing the appropriate amount of ingredients, sugars and acidulants suitable for the taste characteristics of the raw material into a tube and sterilization preservation under appropriate conditions To provide long-term storage and distribution at room temperature without adding ingredients and other food additives, and to provide a method of preparing an organopi beverage made from herbal medicines that are tasty and beneficial to health regardless of age group. There is this.

이하 본 발명의 제조방법에 따른 오갈피 음료의 제조공정을 상세하게 설명한다.Hereinafter will be described in detail the manufacturing process of the alcoholic beverage according to the production method of the present invention.

제1공정1st process

오갈피, 결명자, 인삼, 계피의 각 원료를 별도로 구비하되, 각 원료는 이물질의 혼입이 없고 이미, 이취가 없도록 하며, 부패되거나 벌레먹은 재료는 정선하여서 얻은 원료를 물에 30분 정도 침지하여 불린후에 흔들어 주면서 분무 세척한다. 분무시 수압은 약 20Lb/in2를 상회하여야 효과적인 원료의 세척이 가능하다.Prepare each raw material of Ogalpi, Cultivator, Ginseng, and Cinnamon separately, but each raw material should be free of foreign matters and have no odors. Spray clean by shaking. When spraying, the water pressure should be higher than about 20Lb / in 2 to effectively wash the raw materials.

제2공정2nd process

상기 제1공정후 즉, 원료의 세척후 물을 빼서 시료로 하고, 각 시료마다에 시료 중량의 5-10배 정도되는 물을 가하여 이중바닥이된 스팀솥 내부에 교반기가 설치됨과 더불어 향기증발을 최소화하기 위하여 수류냉각기가 부착되어 있는 밀폐된 용기내에서 60-100℃ 분위기로 2-3시간 동안 1차 추출하여 당, 탄닌, 배당체, 단백질 등 수용성 물질을 추출하고, 수용성 물질을 추출한 시료에다 다시 시료물 중량의 5-10배 되는 80% 에틸알코올을 가하여 40-90℃에서 2-3시간 동안 2차 추출하여 사포닌, 유기산, 알칼로이드등의 알코올에 용출되는 성분을 추출후 1, 2차 추출분을 합하여 여과포로 1차 여과하고 원심분리기에서 55000-70000rpm으로 5-10분간 원심분리하여 각 시료마다의 청징물을 얻는다.After the first process, that is, after removing the water after washing the raw material to make a sample, and 5-10 times the weight of the sample is added to each sample, the stirrer is installed inside the double-bottomed steam cooker and fragrance evaporation In order to minimize, extract water-soluble substances such as sugar, tannin, glycoside, and protein by extracting them first at 60-100 ℃ for 2-3 hours in an airtight container with a water cooler, and then extracting the water-soluble substances. Add 80% ethyl alcohol, which is 5-10 times the weight of the sample, and extract it for 2 hours at 40-90 ℃ for 2 hours to extract the components eluted to alcohol such as saponin, organic acid, alkaloid, etc. The mixture was first filtered through a filter cloth and centrifuged at 55000-70000 rpm for 5-10 minutes in a centrifuge to obtain a clarifier for each sample.

제3공정3rd process

제2공정에 얻은 청징물들을 각각 원심식 감압순간 농축기에서 50℃ 이하를 유지하면서 가용성 고형물량이 50°Bx가 되도록 농축한다.The clarifications obtained in the second step are concentrated in a centrifugal vacuum moment concentrator so that the amount of soluble solids is 50 ° Bx while maintaining the temperature below 50 ° C.

제4공정4th process

제3공정에서 얻은 각 농축물을 35℃ 이하로 냉각시킨 후 냉각된 농축물에 정제수 및 선택된 여러 가지주, 부재료를 적정량 넣어 스테인레스로된 혼합로에서 40-50℃로 가온한 다음 배합물들이 완전히 용해될 때 까지 교반하면서 녹인다.After cooling each concentrate obtained in the third process to 35 ° C or lower, add the appropriate amount of purified water and various kinds of liquor and subsidiary materials to the cooled concentrate, and warm the mixture to 40-50 ° C in a stainless steel mixing mixture, and then completely dissolve the blends. Melt with stirring until

제5공정5th process

제4공정에서 배합이 완료되면, 다시 침전물이나 부유물을 제거하기 위하여 부패하지 않는 냉장온도(1-4℃)로 냉각후 12시간 이상 방치하여 5000-8000rpm으로 5-10분간 윈심분리한다.When the mixing is completed in the fourth step, in order to remove the precipitate or suspended solids, after cooling to a non-corrosive refrigeration temperature (1-4 ℃) and left for at least 12 hours and separated by Winsimsim 5-10 minutes at 5000-8000rpm.

제6공정6th process

제5공정의 원심분리후 청징된 음료를 통조림의 상층공간이 5mm 정도가 되도록 충전하여 88-90℃온도에서 30-40초간 가열, 탈기한후 이중권체기에서 탈기된 통조림을 90℃ 온도에서 3-15초내에 즉시 밀봉한다.After the centrifugation of the fifth step, the clarified beverage is filled so that the upper layer space of the canned food is about 5 mm, heated and degassed for 30-40 seconds at a temperature of 88-90 ° C., and then the canned air degassed in the double winding machine at 90 ° C. Seal immediately within 15 seconds.

제7공정7th process

제6공정에서 밀봉된 통조림관을 75-80℃ 열수에서 20-30분간 저온살균한 후 냉각수로서 30℃로 냉각하여 제품으로 한다.The canned tube sealed in the 6th process is pasteurized for 20-30 minutes in 75-80 ° C hot water and then cooled to 30 ° C as a cooling water.

이상과 같은 공정을 거쳐 제조된 청량음료중에 함유된 주, 부재료 추출물 성분의 약화 및 성분을 보면 다음과 같다.Looking at the weakening and components of the main, subsidiary ingredient extract components contained in the soft drink prepared through the above process as follows.

[주재료][Main material]

오갈피 : 맛이 쓴맛이 강하며 약간의 떫은 맛이 있다. 수피에서는 eleutheroside E가 분리되고 sesamin도 분리되어 있으며 병리적증상의 개선, 신경계에 대한 제반 개선효과, 기능성 신경질환, 제반대사기능의 조정등의 약리효과가 있다.Ogalpi: The taste is bitter and has a little bitter taste. In bark, eleutheroside E is isolated and sesamin is isolated, and there are pharmacological effects such as improvement of pathological symptoms, various effects on the nervous system, functional neurological diseases, and adjustment of various metabolic functions.

[부재료][Subsidiary materials]

인삼 : 맛은 쓴맛이 매우 강하며 독특한 인삼향을 가지고 있다. 그 약효 주성분은 ginsenoside류인 배당체로서 여러 종류가 있는데 간기능의 강화보호, 향피료, 정신 및 육체 노동력의 개선, 당뇨의 장기치료, 강장효과, 건위, 신진대사 촉진등 광범위한 생물학적 활성을 띠고 있다.Ginseng: The taste is very bitter and has a unique ginseng flavor. The main active ingredient is ginsenoside glycoside, which has various kinds, and has a wide range of biological activities such as strengthening and protecting liver function, improving perfume, mental and physical labor, long-term treatment of diabetes, tonic effect, health, and promoting metabolism.

결명자 : 맛은 생것은 매우 비린맛이 나나 볶은 것은 약간 구수하면서 고소한 맛이 있다. 그 성분은 chrysophanol, physcion, obtusin등이 있으며, 건위, 정장, 이뇨, 완화제로 응용하며 야맹증이나 녹내장등의 안과질환에도 효능이 있다.Name: Taste is very fishy taste, but roasted a little bit of taste and savory taste. The ingredients are chrysophanol, physcion, obtusin, etc., and applied as a sanitary, formal, diuretic, palliative, and also effective in ophthalmic diseases such as night blindness or glaucoma.

계피 : 맛은 약간 달면서 매웁고 쌉쌀하며 독특한 계피향이 있다. cinnamic aldehyde가 주성분이며 정유가 1.0-3.4%이다.Cinnamon: Slightly sweet, spicy, with a distinctive cinnamon flavor. Cinnamic aldehyde is the main component and the essential oil is 1.0-3.4%.

건위, 발한해열, 구풍, 진토효과를 지니고 있다.It has a healthy stomach, sweating, antipyretic effect, and a mud effect.

본 발명은 상기한 특성을 갖는 생약재를 1차로 열수, 2차로 알코올로 추출하여 단일용매에 의한 추출방법보다 용출되는 수율이 높고 수용성물질이나 알코올 용해성분을 모두 추출할 수 있으며, 부재료로 첨가하는 생약재의 양을 각각 다르게 하여 기호 특성에 따라 맛과 향이 잘 조화된 오갈피 음료를 제조할 수 있으며, 전통차의 재료를 이용한 액상 청량음료이고, 주, 부재료를 배합후 냉장온도에서 12시간 이상 방치후 탄수화물이나 기타 침전물을 고속 원심분리하여 완전히 제거한 청징음료를 제공할 수 있는 것이다.According to the present invention, herbal medicines having the above characteristics are firstly extracted with hot water and secondly with alcohol, so that the yield is higher than the extraction method with a single solvent, and both the water-soluble substances and the alcohol-soluble components can be extracted and added as an ingredient. It is possible to manufacture Ogalpi drink, which has a good balance of taste and aroma according to the characteristics of tastes, and it is a liquid soft drink using the ingredients of traditional tea, and after mixing main and subsidiary ingredients for at least 12 hours at refrigeration temperature, Other precipitates can be provided by centrifugation at high speed to provide a complete clarified beverage.

또한 산미료를 첨가하여 청량감을 주고, PH를 4.0 이하로 저하시켜 미생물의 번식이 억제되도록 하여 저장성을 높이고 저온 살균으로 맛, 향, 색택 및 기타 품질의 변화를 최소화시킨 것이다.In addition, the acidity is added to give a refreshing feeling, the pH is lowered to 4.0 or less to suppress the growth of microorganisms to increase the shelf life and to minimize the change in taste, flavor, color and other quality by pasteurization.

[실험예 1]Experimental Example 1

정선된 시료 각각 1kg을 제1공정으로 물에 30분 정도 침지하여 외피에 붙어 있는 협잡물을 제거하고 수세후 2공정으로 각각의 시료에 시료량의 5-10배량되는 물 용매를 가하여 1차 추출, 시료량의 5-10배량되는 80%에탄올 용매를 가하여 2차 추출하여 1차, 2차 추출물을 합하여 여과, 윈심분리하여 청징물을 얻고 제3공정에서 감압순간 농축기에서 가용성 고형물량이 50°Bx가 되도록 농축하여 아래 표 1과 같이 물, 알코올, 물과 알코올을 용매로 추출 수율을 측정하였다.1kg of each selected sample was immersed in water for 30 minutes in the first process to remove any contaminants attached to the outer skin, and water washing 5-10 times the amount of the sample was added to each sample in two steps after washing. Secondary extraction was performed by adding 80% ethanol solvent, 5-10 times of filtration, and the primary and secondary extracts were combined, filtered and win-separated to obtain a clarified product, and concentrated in a third step under reduced pressure in a concentrator so that the amount of soluble solids was 50 ° Bx. As shown in Table 1 below, the extraction yield of water, alcohol, water and alcohol was measured using a solvent.

[표 1]TABLE 1

* 수율 : 시료 1kg에 대한 50°Bx 농축물 중량(g)* Yield: 50 ° Bx concentrate weight (g) per 1kg of sample

* 물+알코올(g) : 시료량의 5-10배되는 물용매에서 1차 추출, 시료량의 5-10배 되는 80% 알코올용매에서 2차 추출한 합계인 경우.* Water + Alcohol (g): The sum of 1st extraction from water solvent 5-10 times the sample amount and 2nd extraction from 80% alcohol solvent 5-10 times the sample amount.

표 1에서 보는 바와같이 물과 알코올을 각각 단일 용매로하여 추출한 처리구보다는 물과 알코올을 병행하여 사용한 추출방법이 그 수율이나 추출성분에 있어서 더 효과적이었다.As shown in Table 1, the extraction method using water and alcohol in combination was more effective in the yield or the extraction component than the treatment group in which water and alcohol were extracted as a single solvent, respectively.

위의 방법에 따라 추출농축된 시료별 맛특성에 영향을 미치는 성분중 정미성분과 관련있는 유리아미노산 및 핵산관련 물질을 실험예 2, 3에서 분석하였다.Free amino acids and nucleic acid-related substances related to the taste components among the components affecting the taste characteristics of each sample extracted and concentrated according to the above method were analyzed in Experimental Examples 2 and 3.

[실험예 2]Experimental Example 2

실험예 1에서 물, 알코올, 물과 알코올의 용매별 추출, 농축된 시료에 대한 유리아미노산 조성을 아미노산 자동분석기에 의해서 분석한 결과는 표 2와 같다.In Experimental Example 1, the results of analyzing the free amino acid composition of water, alcohol, solvent-based extraction of water and alcohol, and the concentrated sample by an amino acid automatic analyzer are shown in Table 2.

[표 2]TABLE 2

* 물+알코올 : 시료량의 5-10배되는 물용매에서 1차 추출, 시료량의 5-10배 되는 80% 알코올에서 2차 추출한 합계인 경우* Water + Alcohol: The sum of 1st extraction from water solvent 5-10 times the sample volume and 2nd extraction from 80% alcohol 5-10 times the sample volume.

[실험예 3]Experimental Example 3

실험예 1에서 물, 알코올, 물과 알코올의 용매별 추출, 농축된 시료에 대한 핵산관련 물질중 AMP, ADP, ATP, IMP, Inosine 및 Hypoxanthine을 HPLC를 이용하여 분석한 결과는 표 3과 같다.In Experimental Example 1, AMP, ADP, ATP, IMP, Inosine, and Hypoxanthine among the nucleic acid-related substances for water, alcohol, solvent-based extraction of water and alcohol, and concentrated samples were analyzed using HPLC.

[표 3]TABLE 3

* 물+알코올 : 물용매에서 1차 추출, 80%알코올용매에서 2차 추출한 합계인 경우* Water + Alcohol: It is the sum of 1st extraction from water solvent and 2nd extraction from 80% alcohol solvent.

이상의 실험예 1, 2, 3에서 시료량의 5-10배되는 물과 알코올용매에서 각각 1차 추출, 2차 추출하는 물과 알코올의 병용 추출방법이 추출수율이나 추출성분중 유리아미노산 및 핵산관련 물질에 있어서도 그 함량이 높게 나타났다.In the above Experimental Examples 1, 2, and 3, the combined extraction method of the water and the alcohol which are primary and secondary extracts in the water and the alcohol solvent, which are 5-10 times the amount of the sample, respectively, yielded the free amino acid and the nucleic acid-related substances in the extraction components. The content was also high in.

본 발명의 제1, 제2공정으로 각 시료로부터 추출한 추출물을 주,부재료로 하여 다음의 실시예와 같은 배합비로 오갈피 음료를 완성시킬 수 있는 것으로서, 이를 실시예로 나타내면 다음과 같다.In the first and second processes of the present invention, the extract extracted from each sample may be used as a main and sub-material to complete the organgalpi beverage at the same compounding ratio as in the following examples.

[실시예]EXAMPLE

오갈피 음료를 표 1과 같은 배합비료 혼합하여 제조하였다.Agalpi drink was prepared by mixing the compounding fertilizer shown in Table 1.

[표 4]TABLE 4

* 배합비(%)는 전체 음료에 대한 중량비이다.* The compounding ratio (%) is the weight ratio of the whole beverage.

Claims (1)

생약재인 오갈피, 계피, 결명자, 인삼의 각 원료를 30분정도 물에 침지하여 수세하고, 수세한 원료 각각에다 원료중량의 5-10배정도 되는 물을 가하여 60-100℃에서 2-3시간 동안 1차로 추출하여 수용성 물질을 추출한 다음 2차로 원료중량의 5-10배정도 되는 80%에 탄올을 가하여 40-90℃에서 2-3시간 동안 추출하여 에탄올에 용출되는 성분을 추출하며, 상기 1차, 2차 추출물을 합하여 감압순간 농축기에서 50℃이하를 유지하면서 가용성 고형물량이 50°Bx가 되도록 농축하고, 농축한 추출물중 전체 음료에 대한 중량비로 오갈피 0.8-1.5%를 주재료로, 결명자 0.5-1.0%, 계피 0.05-0.10%, 인삼 0.4-0.5%를 부재료로하여 혼합한 다음 설탕 1.0-5.0%, 고과당 10.0-13.0%, 구연산 0.02-0.20%, 구연산소다 0.03%, 비타민 C 0.01-0.05%, 니코틴아미드 0.01-0.05%등을 기호 특성에 따라 적당량 첨가하여 제조함을 특징으로 하는 오갈피 음료의 제조방법.Each raw material of herbal medicines (Ogalpi, Cinnamon, Cassia, Ginseng) is immersed in water for 30 minutes and washed with water. 5-10 times the weight of the raw material is added to each of the washed raw materials for 1 hour at 60-100 ℃. Extract the water-soluble substance by extraction with tea, and then add the ethanol to 80%, which is about 5-10 times the weight of the raw material, and extract the components eluted in ethanol for 2-3 hours at 40-90 ° C. The tea extracts were combined and concentrated to 50 ° Bx while maintaining the temperature at 50 ° C in a reduced pressure concentrator, and 0.8-1.5% as a main ingredient by weight ratio of the whole beverage in the concentrated extract, Cinnamon 0.05-0.10%, Ginseng 0.4-0.5% as a sub ingredient, mixed with sugar 1.0-5.0%, high fructose 10.0-13.0%, citric acid 0.02-0.20%, sodium citrate 0.03%, vitamin C 0.01-0.05%, nicotine Add 0.01-0.05% of amide according to your preference A method for producing an organopi drink, characterized by a roughness.
KR1019910007567A 1988-12-22 1991-05-10 Process for making veber age from the root bark of various araliaceous shrubs KR910007606B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7556828B2 (en) * 2003-03-28 2009-07-07 Zuguang Zhang Pharmaceutical composition for treatment of BPH and preparation thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7556828B2 (en) * 2003-03-28 2009-07-07 Zuguang Zhang Pharmaceutical composition for treatment of BPH and preparation thereof

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