KR910002973A - Surface treatment method of rubber molded article, hardening rubber molded article manufactured using the surface treatment agent and surface treatment agent, and the surface treatment agent - Google Patents

Surface treatment method of rubber molded article, hardening rubber molded article manufactured using the surface treatment agent and surface treatment agent, and the surface treatment agent Download PDF

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KR910002973A
KR910002973A KR1019890010645A KR890010645A KR910002973A KR 910002973 A KR910002973 A KR 910002973A KR 1019890010645 A KR1019890010645 A KR 1019890010645A KR 890010645 A KR890010645 A KR 890010645A KR 910002973 A KR910002973 A KR 910002973A
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molded article
polyolefin
rubber molded
cured rubber
surface treatment
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KR1019890010645A
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Korean (ko)
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KR910007306B1 (en
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하지메 이나가끼
다다오 사이도오
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다께바야시 쇼오고
미쓰이세끼유 가가꾸고오교오 가부시끼가이샤
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Priority to KR1019890010645A priority Critical patent/KR910007306B1/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/01—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2451/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2451/06—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Paints Or Removers (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)

Abstract

내용 없음.No content.

Description

고무성형품의 표면처리법 및 그 표면처리제와 표면처리제의 제법 및 그 표면처리제를 사용하여 제조한 경화고무 성형품Surface treatment method of rubber molded article, hardening rubber molded article manufactured using the surface treatment agent and surface treatment agent, and the surface treatment agent

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (16)

폴리올레핀 경화고무 성형품의 표면을 프로필렌 함량이 10~90몰%인 프로필렌/에틸렌 공중합체와 0.5-15중량%의 말레인산 또는 그의 무수물을 그래프트 공중합시켜 제조한 0.3이상의 고유정도〔n〕을 갖는 변성 중합체를 유기용매에 녹여 만든 용액으로 코팅하는 것을 포함하는 것이 특징인 폴리올레핀 경화고무 성형품의 표면처리 방법.A modified polymer having an intrinsic degree [n] of 0.3 or more prepared by graft copolymerization of a propylene / ethylene copolymer having a propylene content of 10 to 90 mol% and 0.5-15% by weight of maleic acid or an anhydride thereof on the surface of a polyolefin cured rubber molded article. A method for surface treatment of a polyolefin cured rubber molded article comprising coating with a solution made by dissolving in an organic solvent. 제1항에 있어서, 말레인산 또는 그의 무수물로 변성된 공중합체가 0.1-50g/㎡의 도포량으로 사용되는 것이 특징인 폴리올레핀 경화고무 성형품의 표면처리 방법.The surface treatment method of a polyolefin cured rubber molded article according to claim 1, wherein the copolymer modified with maleic acid or its anhydride is used in an application amount of 0.1-50 g / m 2. 프로필렌 함량이 10-90몰%인 플로필렌/에틸렌 공중합체와 0.5-15중량%의 말레인산 또는 그의 무수물을 그래프트 공중합시켜 제조한 0.3이상의 고유점도〔n〕을 갖는 변성 중합체를 유기용매에 녹여만든 용액을 포함하는 것이 특징인 폴리올레핀 경화고무 성형품이 표면처리제.A solution made by dissolving a modified polymer having an intrinsic viscosity [n] of 0.3 or more prepared by graft copolymerization of a propylene content of 10-90 mol% of propylene copolymer with 0.5-15% by weight of maleic acid or an anhydride thereof in an organic solvent. Polyolefin cured rubber molded article characterized in that it comprises a surface treatment agent. 제3항에 있어서, 상기 유기용매의 일부 또는 전부가 말레인산 또는 그이 무수물로 변성된 유기용매인 것이 특징인 표면처리제.The surface treating agent according to claim 3, wherein part or all of the organic solvent is an organic solvent modified with maleic acid or anhydride thereof. 프로필렌 함량이 10-90몰%인 프로필렌/에팁렌 공중합체를 유기용매에 용해시키는 단계와, 말레인산 또는 그의 무수물과 상기 공중합체를 라디칼발생제 존재하에서 그래프트 공중합시키는 단계와, 그리고 생성된 용액을 유기용매로 임의 희석시키는 단계를 포함하는 것이 특징인 폴리올레핀 경화고무 성형품의 표면처리제의 제조방법.Dissolving a propylene / ephylene copolymer having a propylene content of 10-90 mol% in an organic solvent, graft copolymerizing maleic acid or its anhydride with the copolymer in the presence of a radical generator, and producing the organic Method for producing a surface treatment agent for a polyolefin cured rubber molded article, characterized in that it comprises the step of dilution with a solvent. 제5항에서, 상기 유기용매가 방향족 탄화수소인 것이 특징인 폴리올레핀 경화고무 성형품의 표면처리제의 제조방법.The method for producing a surface treating agent for a polyolefin cured rubber molded article according to claim 5, wherein the organic solvent is an aromatic hydrocarbon. 제5항에서, 상기 유기용매가 톨루엔인 것이 특징인 폴리올레핀 경화고무 성형품의 표면처리제의 제조방법.The method for producing a surface treating agent for a polyolefin cured rubber molded article according to claim 5, wherein the organic solvent is toluene. 제5항에서, 상기 프로필렌/에틸렌 공중합체의 고유점도〔n〕이 0.3-20인 것이 특징인 폴리올레핀 경화고무 성형품의 표면처리제의 제조방법.The method according to claim 5, wherein the intrinsic viscosity [n] of the propylene / ethylene copolymer is 0.3-20. 제5항에서, 상기 변성 중합체내의 상기 말레인산 또는 그의 무수물의 함량이 0.5-15중량%인것이 특징인 폴리올레핀 경화고무 성형품의 표면처리제의 제조방법.The method of claim 5, wherein the maleic acid or its anhydride content in the modified polymer is 0.5-15% by weight. 프로필렌 함량이 10-90몰%인 프로필렌/에틸렌 공중합체에 말레인산 또는 무수물과 라디칼 발생제를 공급하는 단계와 용융상태에서 그래프트 공중합반응을 행하는 단계와, 그리고 그 얻어진 변성 중합체를 유기용매에 용해시키는 단계를 포함하는 것이 특징인 폴리올레핀 경화고무 성형품의 표면처리제의 제조방법.Supplying maleic acid or anhydride and a radical generator to a propylene / ethylene copolymer having a propylene content of 10-90 mol%, performing a graft copolymerization reaction in a molten state, and dissolving the modified polymer obtained in an organic solvent. Method for producing a surface treatment agent of a polyolefin cured rubber molded article characterized in that it comprises a. 제10항에서, 상기 프로필렌/에틸렌 공중합체의 고유점도〔n〕가 0.3-20인것이 특징인 폴리올레핀 경화고무 성형품의 표면처리제의 제조방법.The method according to claim 10, wherein the intrinsic viscosity [n] of the propylene / ethylene copolymer is 0.3-20. 제10항에서, 상기 변성 중합체내의 말레인산 또는 그의 무수물의 함량이 0.5-15중량%인 것이 특징인 폴리올레핀 경화고무 성형품의 표면처리제의 제조방법.The method of claim 10, wherein the maleic acid or its anhydride content in the modified polymer is 0.5-15% by weight. 폴리올레핀 경화고무 성형품과, 이 성형품의 표면에 코팅되는 프로필렌 함량이 10-90몰%인 프로필렌/에틸렌 공중합체와 0.5-15중량%의 말레인산 또는 그의 무수물을 그래프트 공중합시켜 얻은 0.3이상의 고유점도를 갖는 변성 중합체에 의한 초벌코팅과, 이 초벌코팅 위에 코팅되는 도료 또는 기타수지의 코팅을 포함하는 것이 특징인 폴리올레핀 경화고무 성형품.Modified polyolefin-cured rubber molded article having an intrinsic viscosity of 0.3 or more obtained by graft copolymerization of a propylene / ethylene copolymer having a propylene content of 10-90 mol% and 0.5-15 wt% maleic acid or anhydride thereof coated on the surface of the molded article A polyolefin cured rubber molded article characterized by comprising a primary coating by a polymer and a coating of a paint or other resin coated on the primary coating. 제13항에서, 상기 폴리올레핀 경화고무가 에틸렌, α-올레핀 및 디올레핀의 공중합 반응에 의해 생성된 고무인 것이 특징인 폴리올레핀 경화고무 성형품.The polyolefin cured rubber molded article according to claim 13, wherein the polyolefin cured rubber is a rubber produced by a copolymerization reaction of ethylene, α-olefin and diolefin. 제14항에서, 상기 폴리올레핀 경화고무의 상기 에틸렌 함량이 55-73몰%, 상기 α-올레핀 함량이 17-45몰% 및 상기 디올레핀 함량이 0.5-10몰%인 것이 특징인 폴리올레핀 경화고무 성형품.The polyolefin cured rubber molded article according to claim 14, wherein the ethylene content of the polyolefin cured rubber is 55-73 mol%, the α-olefin content is 17-45 mol%, and the diolefin content is 0.5-10 mol%. . 제13항에서, 상기 도료 또는 기타수지의 코팅은 용매형 열가소성 아크릴수지 도료, 용매형 열경화수지 도료, 아크릴변성 알키드수지 및 에폭시수지 도료 또는 폴리우레탄계수지로부터 제조되는 것이 특징인 폴리올레핀 경화고무 성형품.The polyolefin cured rubber molded article according to claim 13, wherein the coating of the paint or other resin is made from a solvent type thermoplastic acrylic resin paint, a solvent type thermosetting resin paint, an acrylic modified alkyd resin, and an epoxy resin paint or a polyurethane resin. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019890010645A 1989-07-27 1989-07-27 Method for surface treatment of rubber molded article surface-treating agent used for this surface treatment process for preparation of this surface treating agent and cured rubber molded article formed by using surface-treating agent KR910007306B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100334073B1 (en) * 1999-10-19 2002-04-26 김순택 Electron gun for cathode ray tube

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100848278B1 (en) * 2006-09-29 2008-07-25 주식회사 동성엔에스씨 Water base composition for surface treatment for rubber

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100334073B1 (en) * 1999-10-19 2002-04-26 김순택 Electron gun for cathode ray tube

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