KR900013848A - Insect repellent composition - Google Patents

Abstract

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Description

Insect repellent composition

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Claims (30)

Compound of formula (I) as active ingredient, and 2,2'-methylenebis (4-ethyl-6-tert-butylphenol), 2-3 tert-butyl-6- (tert-butyl-2) -Hydroxy-5-methylbenzyl) -4-methylphenyl acrylate, 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate, bis (2,2 , 6,6-tetramethyl-4-piperidine) sebacate, tetrakis [methylene-3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate] methane, 4, 4'-butylidenebis (3-methyl-6-tert-butylphenol), alkylated diphenylamine, trisnonylphenyl phosphite and tris (2,4-di-tert-butylphenyl) phosphite Insect repellent composition containing one or more compounds selected from the group consisting of (II). Compound of formula (I) as active ingredient, and 2,2'-methylenebis (4-ethyl-6-tert-butylphenol), 2-3 tert-butyl-6- (tert-butyl-2) -Hydroxy-5-methylbenzyl) -4-methylphenyl acrylate, 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate, bis (2,2 , 6,6-tetramethyl-4-piperidine) sebacate, tetrakis [methylene-3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate] methane, 4, 4'-butylidenebis (3-methyl-6-tert-butylphenol), alkylated diphenylamine, trisnonylphenyl phosphite and tris (2,4-di-tert-butylphenyl) phosphite At least one compound selected from group (II), and benzotriazole, 1H-tetrazole, 1H-1,2,4-triazole, 3-mercapto-4-methyl-5-trifluoromethyl-4H Insect repellent composition containing at least one compound selected from the group (III) consisting of -1,2,4-triazole and 5-chlorobenzo triazole. A compound according to claim 1, wherein the compound (s) selected from group (II) are 2,2'-methylenebis (4-ethyl-6-tert-butylphenol) and / or 2,4-di-tert-butyl Insect repellent composition which is phenyl 3,5-di- tert- butyl- 4-hydroxybenzoate. The insect repellent composition according to claim 1, wherein the compound selected from group (II) is 2,2'-methylenebis (4-ethyl-6-tert-butylphenol). The insect repellent composition according to claim 1, wherein the compound selected from group (II) is 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate. The compound (s) of claim 2 wherein the compound (s) selected from group (II) is 2,2'-methylenebis (4-ethyl-6-tert-butylphenol) and / or 2,4-di-tert-butyl Insect repellent composition which is phenyl-3,5-di-tert-butyl-4-hydroxy benzoate. The insect repellent composition according to claim 2, wherein the compound selected from group (II) is 2,2'-methylenebis (4-ethyl-6-tert-butylphenyl). The insect repellent composition according to claim 2, wherein the compound selected from group (II) is 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate. The insect repellent composition according to claim 2, wherein the compound (s) selected from group (III) is benzotriazole and / or 1H-tetrazole. The insect repellent composition according to claim 2, wherein the compound selected from group (III) is benzotriazole. The insect repellent composition according to claim 2, wherein the compound selected from group (III) is 1H-tetrazole. The compound (s) of claim 2 wherein the compound (s) selected from group (II) is 2,2'-methylenebis (4-ethyl-6-tert-butylphenol) and / or 2,4-di-tert-butyl Insect repellent composition wherein phenyl 3,5-di-tert-butyl-4-hydroxy benzoate and the compound (s) selected from group (III) are benzotriazole and / or 1H-tetrazole. The compound (s) of claim 2 wherein the compound (s) selected from group (II) is 2,2'-methylenebis (4-ethyl-6-tert-butylphenol) and / or 2,4-di-tert-butyl The insect repellent composition wherein phenyl is 3,5-di-tert-butyl-4-hydroxybenzoate and the compound selected from group (III) is benzotriazole. The compound (s) of claim 2 wherein the compound (s) selected from group (II) is 2,2'-methylenebis (4-ethyl-6-tert-butylphenol) and / or 2,4-di-tert-butyl The insect repellent composition wherein phenyl is 3,5-di-tert-butyl-4-hydroxybenzoate and the compound selected from group (III) is 1H-tetrazole. The compound of claim 2 wherein the compound selected from group (II) is 2,2'-methylenebis (4-ethyl-6-tert-butylphenol) and the compound (s) selected from group (III) is benzotriazole. And / or 1H-tetrazole. The compound of claim 2 wherein the compound selected from group (II) is 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate and is selected from group (III) Insect repellent composition wherein the compound (s) are benzotriazole and / or 1H-tetrazole. The insect repellent composition according to claim 2, wherein the compound selected from group (II) is 2,2'-methylenebis (4-ethyl-6-tert-butylphenol) and the compound selected from group (III) is benzotriazole. The insect repellent composition according to claim 2, wherein the compound selected from group (II) is 2,2'-methylenebis (4-ethyl-6-tert-butylphenol), and the compound selected from group (III) is 1H-tetrazole. . The compound of claim 2 wherein the compound selected from group (II) is 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate and is selected from group (III) The insect repellent composition whose compound is benzotriazole. The compound of claim 2 wherein the compound selected from group (II) is 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate and is selected from group (III) The insect repellent composition whose compound is 1H- tetrazole. Compound of formula (I) as active ingredient, and 2,2'-methylenebis (4-ethyl-6-tert-butylphenol), 2-3 tert-butyl-6- (tert-butyl-2) -Hydroxy-5-methylbenzyl) -4-methylphenyl acrylate, 2,4-di-tert-butylphenyl-3,5-di-tert-butyl-4-hydroxybenzoate, bis (2, 2,6,6-tetramethyl-4-piperidine) sebacate, tetrakis [methylene-3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate] methane, 4 , 4'-butylidenebis (3-methyl-6-tert-butylphenol), alkylated diphenylamine, trisnonylphenylphosphite and tris (2,4-di-tert-butylphenyl) force A pest control composition comprising at least one compound selected from the group (II) consisting of pits. Compound of formula (I) as active ingredient, and 2,2'-methylenebis (4-ethyl-6-tert-butylphenol), 2-3 tert-butyl-6- (tert-butyl-2) -Hydroxy-5-methylbenzyl) -4-methylphenyl acrylate, 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate, bis (2,2 , 6,6-tetramethyl-4-piperidine) sebacate, tetrakis [methylene-3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate] methane, 4, 4'-butylidenebis (3-methyl-6-tert-butylphenol), alkylated diphenylamine, trisnonylphenyl phosphite and tris (2,4-di-tert-butylphenyl) phosphite At least one compound selected from group (II), and benzotriazole, 1H-tetrazole, 1H-1,2,4-triazole, 3-mercapto-4-methyl-5-trifluoromethyl-4H Using an insect repellent composition containing at least one compound selected from the group (III) consisting of -1,2,4-triazole and 5-chlorobenzotriazole The method for controlling pests by. 22. The compound of claim 21, wherein the compound (s) selected from group (II) are 2,2'-methylenebis (4-ethyl-6-tert-butylphenol) and / or 2,4-di-tert-butyl Phenyl 3,5-di-tert-butyl-4-hydroxybenzoate. The compound of claim 22, wherein the compound (s) selected from group (II) are 2,2′-methylenebis (4-ethyl-6-tert-butylphenol) and / or 2,4-di-tert-butyl Phenyl 3,5-di-tert-butyl-4-hydroxybenzoate. The method of claim 22, wherein the compound (s) selected from group (III) are benzotriazole and / or 1H-tetrazole. Compound of formula (I) as active ingredient, and 2,2'-methylenebis (4-ethyl-6-tert-butylphenol), 2-3 tert-butyl-6- (tert-butyl-2) -Hydroxy-5-methylbenzyl) -4-methylphenyl acrylate, 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate, bis (2,2 , 6,6-tetramethyl-4-piperidine) sebacate, tetrakis [methylene-3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate] methane, 4, 4'-butylidenebis (3-methyl-6-tert-butylphenol), alkylated diphenylamine, trisnonylphenyl phosphite and tris (2,4-di-tert-butylphenyl) phosphite A method for preventing the release of malodor in the insect repellent compound of formula (I), characterized by using an insect repellent composition containing at least one compound selected from the group (II). Compound of formula (I) as active ingredient, and 2,2'-methylenebis (4-ethyl-6-tert-butylphenol), 2-3 tert-butyl-6- (tert-butyl-2) -Hydroxy-5-methylbenzyl) -4-methylphenyl acrylate, 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate, bis (2,2 , 6,6-tetramethyl-4-piperidine) sebacate, tetrakis [methylene-3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate] methane, 4, 4'-butylidenebis (3-methyl-6-tert-butylphenol), alkylated diphenylamine, trisnonylphenyl phosphite and tris (2,4-di-tert-butylphenyl) phosphite At least one compound selected from group (II), and benzotriazole, 1H-tetrazole, 1H-1,2,4-triazole, 3-mercapto-4-methyl-5-trifluoromethyl-4H Using an insect repellent composition containing at least one compound selected from the group (III) consisting of -1,2,4-triazole and 5-chlorobenzo triazole As to a method of preventing color fading due to the odor-emitting and / or copper in the insect repellent compound of formula (I). 27. The compound of claim 26, wherein the compound (s) selected from group (II) is 2,2'-methylenebis (4-ethyl-6-tert-butylphenol) and / or 2,4-di-tert-butyl Phenyl 3,5-di-tert-butyl-4-hydroxybenzoate. 28. The compound of claim 27, wherein the compound (s) selected from group (II) are 2,2'-methylenebis (4-ethyl-6-tert-butylphenol) and / or 2,4-di-tert-butyl Phenyl 3,5-di-tert-butyl-4-hydroxybenzoate. The method of claim 27, wherein the compound selected from group (III) is benzotriazole and / or 1H-tetrazole. ※ Note: The disclosure is based on the initial application.