KR900003009B1 - Process for preservation of kimchi by adding chinese peper extracts and monoglyceride - Google Patents

Process for preservation of kimchi by adding chinese peper extracts and monoglyceride Download PDF

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KR900003009B1
KR900003009B1 KR1019870013713A KR870013713A KR900003009B1 KR 900003009 B1 KR900003009 B1 KR 900003009B1 KR 1019870013713 A KR1019870013713 A KR 1019870013713A KR 870013713 A KR870013713 A KR 870013713A KR 900003009 B1 KR900003009 B1 KR 900003009B1
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kimchi
peper
extract
monoglycerine
monoglyceride
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KR890009279A (en
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윤석인
박길동
김영찬
임영희
이철
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사단법인 한국식품공업협회
홍성철
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/10Preserving with acids; Acid fermentation

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  • Chemical & Material Sciences (AREA)
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  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
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  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
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Abstract

The method of prolonging the preserration period of KIMCHI by adding chinese peper and monoglyceride comprises (a) extracting available imgredinents from chinese peper by using ethanol and rotary evaporator, (b) preparing the seasoned KIMCHI, (c) adding chineses peper extract and monoglycerine caprate and or monoglycerine laurate and mixing.

Description

산초추출물과 모노글리세라이드를 첨가한 김치류의 보존 연장방법Preservation Method of Kimchi Added with Acid Extract and Monoglyceride

본 발명은 절임식품 특히, 김치에 산초추출물과 모노글리세라이드를 적량 첨가하여 관여 미생물의 생육을 억제하고, 그 가식 기간을 연장하는 방법에 관한 것이다.The present invention relates to a method of inhibiting the growth of related microorganisms by adding an appropriate amount of anchovy extract and monoglycerides to pickled foods, in particular, kimchi, and extending the eating period.

일반적으로 한국의 전통 발효식품중의 하나인 김치는 김치 원료 즉, 배추, 무우 등 각종 양념류의 당을 기질로 하여 유산균이 생육을 하여 젖산으로 내포되는 유기산을 생성, 산이를 부여하며, 최적 가식부위(PH4.0-4.5 총산 0.5-1.0%)에 이르게 되나 계속 발효가 진행되어 산패현상과 연부현상이 일어나 제품의 가치를 유지할 수 있는 기간이 매우 짧다.In general, Kimchi, one of the traditional fermented foods in Korea, uses lactic acid bacteria as raw materials of kimchi, that is, cabbage and radish, to grow lactic acid bacteria to produce organic acids contained in lactic acid and give acid value. (PH4.0-4.5 total acidity 0.5-1.0%), but the fermentation proceeds, causing rancidity and softening, so that the product's value is very short.

따라서, 김치류의 제품가치를 유지시키기 위해 많은 연구가 진행되어 왔으며, 이에 적용된 방법은 냉장, 냉동법, 가열살균을 이용한 보존법(통조림), 합성보존료 첨가법, 방사선 조사법 등이 시도 되었다.Therefore, many researches have been conducted to maintain the product value of kimchi, and the applied method has been attempted for preservation method (canning), synthetic preservative addition method, irradiation method, etc. using refrigeration, freezing method, heat sterilization.

그러나 위 방법들은 아래와 같은 단점이 있다.However, the above methods have the following disadvantages.

냉장법은 가장 바람직한 방법이나 시설비, 유통시의 원가상승요인이 클뿐더러 특히 하절기에 유통과정중 김치제품이 상온에 방치되는 경우 급격히 발효가 진행하여 산패되는 운영상의 문제점이 대두되고 있으며, 가열살균(저온살균)의 경우는 김치의 조직손상과 신선미 저하, 영양성분의 손실을 유발시킨다.The refrigerating method is the most desirable method, facility cost, and cost increase factor in distribution, and especially when kimchi products are left at room temperature during the distribution process in summer, fermentation proceeds rapidly, causing rancidity. Pasteurization) causes kimchi tissue damage, freshness and loss of nutrients.

또한, 합성보존료(예 Potassium sorbate)의 첨가는 보존연장 기간이 단기간일 뿐더러 이의 첨가 김치의 다량 섭취시 안전성에 무리가 있다는 문제가 크게 대두되고 있는 실정이며, 방사선 조사법 역시 그의 안전성에서 일반 소비자에게 불안감을 조성하며, 그의 실용화가 상당히 어려울 것 같다.In addition, the addition of synthetic preservatives (for example, Potassium sorbate) is not only a short period of extended storage period, but also a problem that the safety of the large amount of added kimchi intake of the situation is increasing, the irradiation method is also anxious to the general consumer in its safety. It is likely that his practical use will be quite difficult.

따라서, 본 발명자들은 상기의 문제점을 해결하기 위하여 인체에 무해한 천연재료중 산초를 대상으로 그 추출물과 식품첨가물인 유화제(모노글리세라이드)를 김치류에 적용, 보존기간을 연장하는 방법을 연구하였다.Accordingly, the present inventors have studied a method of extending the shelf life by applying an extract and a food additive emulsifier (monoglyceride) to kimchi in order to solve the above problems, the extracts and food additives of the natural herbs harmless to the human body.

예로부터 산초를 김치에 첨가하였다는 기록이 임원십육지(林園十六志 1764년 -1845년)에 명시되어 있으며, 근년에도 일부 지방에는 김치에 산초를 첨가 그의 독특한 향미를 김치에 부여하고 있다.Records of the addition of sancho to kimchi have been stated in the Office of the Sixteen Offices (林 園 十 六 志 1764-1845), and in recent years, some provinces have added kimchi to kimchi to give Kimchi its unique flavor. .

산초의 유효성분을 주로 정유(精油)로서 과피에 많이 함유되어 있다.The active ingredient of the vinegar is mainly contained in the skin as essential oils (精油).

정유성분은 시트로넬란(Citronellal), 리모넨(limonene), 제라니올(Geraniol)등이고, 신미(辛味)성분으로서는 샨슐(Shan shool)이 보고되어 있다. (일본약국방 해설서)The essential oil components are Citronellal, Limonene, Geraniol and the like, and Shan shool has been reported as a Shinmi ingredient. (Japanese Pharmacy Commentary)

그리고, 산초의 항균작용에 대하여는 장내 병원성 미생물인 Streptococcus속, Shigelia속, Shlmonella속, Yersinia속 등에 강력한 생육억제작용이 있음이 보고되어 있다. (생약학 회지 17.4.1986)In addition, the antimicrobial activity of Sancho has been reported to have a potent growth inhibitory effect on the intestinal pathogenic microorganisms Streptococcus, Shigelia, Shlmonella, Yersinia. (Journal of Pharmacognosy 17.4.1986)

그러나, 한방에서 일수에 의한 생약성분의 추출방법으로서는 수용성추출물이 대종을 이루므로 정유등 지용성 유효성분은 추출되기가 어렵다.However, as a method of extracting herbal ingredients by one day in water, water-soluble extracts are large, so fat-soluble effective ingredients such as essential oils are difficult to extract.

향신료의 수용성성분과 정유등 지용성추출물이 김치 주발효균인 유산균에 대해 항균효과를 연구한 보고를 보면 (Laural Zaika and John C.Kissinger, Journal of Food Sceience, 49,5,1984)향신료의 수용성 추출물은 유산균의 증식을 억제하지 못하고 오히려 촉진시키거나 유기용매에 의한 지용성 추출물은 유산균의 증식을 효과적으로 억제, 사멸시킨다고 하였다.A study on the antimicrobial effect of lactic acid bacteria such as essential oils and oil-soluble extracts of spices on lactic acid bacteria, Kimchi (Laural Zaika and John C.Kissinger, Journal of Food Sceience, 49,5,1984) Rather than inhibiting the proliferation of lactic acid bacteria, rather promoting or soluble extract by organic solvents effectively inhibited and killed the growth of lactic acid bacteria.

이는 김치 향신료로 사용되는 고추가루, 마늘, 생강이 수용성상태인 김치에서 유산균의 발효를 촉진하여 김치의 숙성기간을 단축시킨다는 연구 결과와 일치하고 있다. (한국 식품과학 회지 10.2.1978)This is consistent with the findings that the fermentation of lactic acid bacteria in kimchi, which has red pepper powder, garlic and ginger used as kimchi spice, accelerates fermentation of kimchi. (Korean Food Science Society 10.2.1978)

지방산에 의하여 미생균들이 발육을 억제당하며 살균이 되는 것은 긴사슬의 지방산으로부터 생성된 프리래디칼(Free radical)이 균세포나 포자의 세포벽을 용해시켜 세포막을 결합하고 있는 효소의 활성을 저하시키고 염기성 단백질에 의한 균의 저항력을 저하시켜 지방산의 세포막안으로 용이하게 침투되어 세포막의 구조를 변화시키고, 그 결과 인산화저해 곧 ATP(Adenosinetriphosphate)생성저해를 가져오며, 세포내 아미노슈가(Aminosugar)의 노출, 글리신(Glycin), 글루타민산(Glutamic-Acid), 페닐알라닌(Pheny lalanine)등 아미노산과 알파메틸글리코시드(Methylglycoside), 프락토스(Fructose)등 당류의 출입기능을 저하시켜 세균세포의 발육이 장애를 받아 결국에는 사멸하는 것으로 보여지며, 지방산 에스테르인 모노글리 세라이드 역시 그 작용 메카니즘이 같으며 다음은 산초추출물과 일반김치, 유화제 첨가김치와 일반김치를 20℃에서 숙성, 측정한 결과이다.The growth of microorganisms by microorganisms is suppressed and sterilized by free radicals generated from long-chain fatty acids, which dissolve the cell wall of mycelium cells or spores, thereby degrading the activity of enzymes that bind cell membranes and basic proteins. It lowers the resistance of bacteria and easily penetrates into the cell membrane of fatty acids, changing the structure of the cell membrane. As a result, phosphorylation inhibits ATP (Adenosinetriphosphate) production, and the exposure of intracellular aminosugar (Aminosugar), glycine ( Amino acids such as Glycin, Glutamic Acid, Phenylalanine, Glycin, Methylglycoside, Fructose, etc. decrease the accessibility of sugars, which impairs the development of bacterial cells and eventually kills them. The fatty acid ester, monoglyceride, also has the same mechanism of action. It is the result of ripening and measuring Kimchi and general kimchi with extract, general kimchi and emulsifier at 20 ℃.

[표 1] 일반김치 및 산초추출물 첨가김치와의 비교(20℃)[Table 1] Comparison of kimchi and kimchi added kimchi (20 ℃)

Figure kpo00001
Figure kpo00001

* 담금 직후의 김치 : PH 5.80, 총산 0.10, 염분 3%* Kimchi immediately after soaking: PH 5.80, Total 0.10, Salinity 3%

김치의 가식범위를 PH 4.0, 총산 1.0%로 볼때 20℃에서 일반김치는 약 3일정도, 산초추출물 첨가 김치의 경우는 6일-8일정도로 가식기간이 연장되었고, 산초추출물 첨가 농도별 영향은 0.05%-0.05%에서는 가식기간이 연장되었고, 산초추출물 첨가 농도별 영향은 0.05%-0.05%에서는 가식기간이 6일정도로 큰차이가 있었다.When the kimchi's decorative range was PH 4.0 and 1.0% of total acid, the general kimchi was extended to about 3 days at 20 ℃ and the kimchi extract added 6 days to 8 days. In 0.05% -0.05%, the duration of planting was prolonged, and the effect of the concentration of acid extract was significantly different from that in 0.05% -0.05%.

다만, 0.05%이상에서는 산초 취미가 강하게 느껴졌으며, 0.01% 이하에서는 보존효과가 저하되었다.However, at 0.05% or more, the taste of sancho was strongly felt, and at 0.01% or less, the preservation effect was lowered.

[표 2] 일반김치 및 유화제 첨가 김치와의 비교(20℃)[Table 2] Comparison with general kimchi and emulsifier added kimchi (20 ℃)

Figure kpo00002
Figure kpo00002

즉, 20℃에서 일반김치는 3-4일 경과후 가식범위를 벗어났으나 모노글리세린라우레미트와 모노글리세린 카프레이트를 병용첨가한 김치는 10일 경과후에도 가식범위를 유지하였다.In other words, Kimchi out of the range of 3-4 days after the general kimchi at 20 ℃, the kimchi combined with monoglycerin lauremite and monoglycerin caprate maintained the range of decoration even after 10 days.

[실시예]EXAMPLE

1) 산초유효성분의 추출1) Extraction of Active Herbal Ingredients

성숙하여 말린 산초(과피, 종차) 10g에 에탄올(99.8%)을 20ml첨가하여 수욕조에서 80℃로 환류냉각시키면서 3시간 추출한 후 여지로 여과한 여액에 증류수 100ml를 가하고 회전감압증발 농축기 (Rotary evaporator)를 사용하여 에탄올은 증발시키고 잔량이 50ml 될때까지 농축한다.20 ml of ethanol (99.8%) was added to 10 g of mature and dried acid (fermented vinegar) and extracted with refrigeration at 80 ° C in a water bath for 3 hours. 100 ml of distilled water was added to the filtrate, which was filtered through a rotary evaporator. Ethanol is evaporated and concentrated to 50 ml.

2) 배추김치 제조 및 첨가2) Preparation and Addition of Chinese Cabbage Kimchi

일반적인 방법으로 제조한 김치 즉, 배추의 겉잎등 손상부를 제거하고 크기에 따라 1/2-1/4포기로 절단한 배추를 10-12%의 식염용액에 15시간 전후로 침지시키고 수세한후 물기를 제거하고 준비해둔 고추가루, 마늘, 생강, 젖갈, 파등의 양념을 첨가하여 배합한다.Remove the damaged parts such as the outer leaves of kimchi, that is, cabbage prepared by the general method, and immerse the cabbage cut into 1 / 2-1 / 4 aeration according to the size in about 15 hours in 10-12% saline solution, and wash with water. Remove and mix with red pepper powder, garlic, ginger, milk brown and green onion.

여기에 산초추출물을 김치무게에 대해 0.05%(산초총량으로 환산)에 모노글리세란 카프레이트 0.05%, 모노글리세린 라우레이트 0.01%를 각각 첨가, 병용하여 잘 혼합한후 병입하여 15℃에 저장한 결과는 표 3과 같이 25일까지 식용이 가능하였다.Here, the extract was added 0.05% monoglycerol caprate and 0.01% monoglycerine laurate to 0.05% of kimchi (converted in the total amount of kimchi). The edible was available until 25 days as shown in Table 3.

[표 3] 일반김치와 유화제 첨가김치와의 비교 (15℃)[Table 3] Comparison of Kimchi with Emulsifiers (15 ℃)

Figure kpo00003
Figure kpo00003

Claims (3)

김치류의 가식기간을 연장시키기 위하여 상법으로 제조한 김치에 산초(과피, 종자)추출물과 모노글리세린라우레이트 및 모노글리세린 카프레이트를 첨가한 방법.To add kimchi prepared by the conventional method in order to prolong the period of kimchi kimchi and the addition of the acid extract (bark, seed), monoglycerin laurate and monoglycerine caprate. 제 1 항에 있어서, 산초추출물은 에틸알콜 등 유기용매로 추출하여 농축하는 방법.The method of claim 1, wherein the extract is concentrated with an organic solvent, such as ethyl alcohol extract. 제 1 항에 있어서, 산초추출물 첨가농도는 김치무게에 대해 산초총량이 0.01% -0.5%, 모노글리세린 라우레이트로 0.01%-0.1% 모노글리세린 카프레이트를 0.01 %-0.2%되게 첨가하는 방법.The method according to claim 1, wherein the concentration of acetic acid extract is added with 0.01% -0.5% total amount of acetic acid and 0.01% -0.1% monoglycerine caprate as monoglycerine laurate with respect to kimchi weight.
KR1019870013713A 1987-12-01 1987-12-01 Process for preservation of kimchi by adding chinese peper extracts and monoglyceride KR900003009B1 (en)

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