KR900002396B1 - Process for preservation of kimchi - Google Patents
Process for preservation of kimchi Download PDFInfo
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- KR900002396B1 KR900002396B1 KR1019870008379A KR870008379A KR900002396B1 KR 900002396 B1 KR900002396 B1 KR 900002396B1 KR 1019870008379 A KR1019870008379 A KR 1019870008379A KR 870008379 A KR870008379 A KR 870008379A KR 900002396 B1 KR900002396 B1 KR 900002396B1
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B7/00—Preservation or chemical ripening of fruit or vegetables
- A23B7/10—Preserving with acids; Acid fermentation
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Abstract
Description
본 발명은 김치류의 저장성을 연장시키는 방법에 관한 것으로, 양념 혼합시 글리신을 첨가하여 부패 미생물의 생육을 억제시키고 알칼리 물질을 사용하여 김치의 pH를 일정하게 유지시켜 김치 발효에 유익한 균주만이 지속적으로 생육 가능하도록 하면서 원료속의 당을 전부 소비 할 때까지 숙성시키고, 이후 유산균 및 기타 산패 미생물의 증식을 불가능하게 하여, 김치류의 저장성을 연장시키는 김치류 제조법에 관한 것을 특징으로 한다.The present invention relates to a method of extending the shelf life of kimchi, and when seasonings are mixed, glycine is added to inhibit the growth of decaying microorganisms, and the pH of the kimchi is kept constant by using an alkaline substance so that only the beneficial strain for kimchi ferment is continuously. It is characterized by a method of producing kimchi to allow the growth of the kimchi to be matured to allow the growth of lactic acid bacteria and other rancid microorganisms after aging until all the sugar in the raw material is consumed to be able to grow.
김치의 숙성에 관하여는 균주는 약 200여 종이 알려져 있으며, 김치의 숙성은 각 단계에서 각기 다른 일련의 균주들이 연속적으로 나타나서 이루어진다.About 200 kinds of strains are known about the ripening of kimchi, and the ripening of kimchi is achieved by successive series of different strains at each stage.
즉, 숙성 초기에는 아크로모 박터(Achromobacter), 슈도모나스(Pseudomonas), 프라보박테리륨(Flavobacterium), 바실러스 마서란스(Bacillus macerans)등의 호기성 세균이 생육하고, 중기에는 로이크 노스톡 메센테로이데스(Leuconostoc mesenteroides), 페디오코커스 세레비제(Pediococcus cerevisiae), 스트렙토코커스 헤커리스(Streptococcus faecalis), 락토바실러스 브레비스(Lactobacillus brevis), 락토바실러스 프란타룸(Lactobacillus plantarum)이 생육함으로써 김치가 숙성되며, 말기에는 디바리오마이세스(Debaryomyces), 지고사카로마이세스(Zygosaccharomyces)등의 미생물이 번식하므로써 신맛이 강하며 군내가 나고 조직이 물르는 연부현상이 일어나 최종적으로는 식용할 수 없는 상태로 부패하게 된다. 이러한 미생물의 증식을 억제하고, 사멸시켜 김치의 저장성(Shelf-life)을 연장할 수 있도록 여러 방법들이 고안되어 왔다.In other words, aerobic bacteria such as Achromobacter, Pseudomonas, Prabobacterium, and Bacillus macerans grow in the early stage of ripening, and in the middle stage, aerobic bacterium Leuconostoc mesenteroides, Pediococcus cerevisiae, Streptococcus faecalis, Lactobacillus brevis, Lactobacillus plantarum, Lactobacillus plantarum are grown, and the kimchi is matured By breeding microorganisms such as Debaryomyces and Zygosaccharomyces, the sour taste is strong, and the softening of the inside of the group and the bite of the tissue bites, resulting in decay in the last edible state. Various methods have been devised to extend the shelf life of kimchi by inhibiting and killing the growth of these microorganisms.
이러한 방법중에는 가열에 의한 살균 방법, 솔빈산등의 방부제를 사용하여 저장성을 부여하는 방법등이 있고, 최근에는 전리방사선을 조사하여 미생물을 사멸시키는 방법등이 개발되었다.Among these methods, there is a method of disinfecting by heating, a method of imparting shelf life by using an antiseptic such as sorbic acid, etc., and recently, a method of killing microorganisms by irradiating ionizing radiation has been developed.
그러나 가열에 의한 방법은 식품의 향기, 색깔, 조직의 변화와 영양소 파괴등의 단점이 있고, 방부제를 사용하는 방법은 방부제의 잔류 독성이 있으며, 그 사용량이 법적으로 제한되어 있어 미생물 억제효과가 확실하지 않다. 그리고 방사선을 이용하는 방법은 조작과 기술상의 문제점과 인체에 돌연변이를 유발할 수 있다는 우려가 있어 일부 국가에서 극히 제한된 식품에만 사용이 허용되고 있는 등의 문제점이 있다. 본 발명자는 이러한 문제점을 해결하고 김치의 저장성을 연장함과 동시에 기호성을 향상시킨 김치 제조 방법을 오랜 연구 결과 본 발명을 완성하였다.However, the method of heating has disadvantages such as the change of aroma, color, texture of the food and destruction of nutrients, and the method of using preservatives has residual toxicity of preservatives, and its usage is legally restricted, so the microbial inhibitory effect is certain. Not. In addition, the method of using radiation has problems such as manipulation and technology problems and the possibility of causing mutations in the human body, so that some countries are allowed to use only very limited food. The present inventors have completed the present invention as a result of a long study of the kimchi production method to solve this problem and to extend the storage of kimchi and at the same time improve the palatability.
본 발명은 아미노산중 항균작용이 인정되는 것으로 글리신, 시스테인, 트립토판, 페닐알라닌등이 있지만, 이중 글리신이 세균에 대해서 특이적으로 광범위한 항균작용이 있으므로 글리신을 0.5-2.0% 첨가하여 부패성 미생물의 생육을 억제시키고, 김치 숙성과정중 유산균의 최저 생육가능 pH이하로 김치의 pH가 저하되지 않도록 알칼리물질 일정량씩 첨가하여 pH4.2-4.8로 유지시켜 유기산에 의해 생성된 젖산과 초산을 젖산염(Lactate)과 초산염(Acetate)으로 중화시키면서, 내부의 당을 전부 소모할때까지 숙성을 하여 저장중 유산균 및 기타 산패 미생물의 증식을 불가능하게 하므로써 김치류의 저장성을 연장할 수 있게 하는 방법이다. 본 발명에 사용된 알칼리물질은 가성소다(NaOH), 수산화 칼슘(Ca(OH)2), 중조(NaHCO3), 탄산나트륨(Na2CO3), 탄산칼슘(CaCO3)등으로 김치 1kg을 제조하는데 사용된 알칼리물질의 사용량은 표 1과 같다.In the present invention, the antimicrobial activity is recognized among amino acids, but there are glycine, cysteine, tryptophan, phenylalanine, etc. Of these, since glycine has a wide range of antimicrobial activity specifically against bacteria, the growth of decaying microorganisms is suppressed by adding 0.5-2.0% of glycine. Lactic acid and acetic acid produced by lactic acid and acetic acid produced by organic acid were added by adding a certain amount of alkaline substances so that the pH of kimchi was not lowered below the minimum growth possible pH of lactic acid bacteria during the kimchi ripening process. It is a method to extend the shelf life of kimchi by neutralizing with (Acetate), making it impossible to proliferate lactic acid bacteria and other rancid microorganisms during storage by aging until all the sugars are consumed. The alkali material used in the present invention is caustic soda (NaOH), calcium hydroxide (Ca (OH) 2), sodium bicarbonate (NaHCO3), sodium carbonate (Na2CO3), calcium carbonate (CaCO3), etc. The usage of is shown in Table 1.
[표 1] 김치 1kg 생산에 필요한 알칼리물질의 양 (단위 : 그램)[Table 1] Amount of alkaline substances required to produce 1kg of kimchi (unit: grams)
본 발명의 공정을 보다 상세히 설명하면 배추, 무등을 적당한 크기로 썰어 12-15%의 염용액에 2-5시간 절인후 수도수로 씻고 탈수한 후 여기에 마늘, 파, 젖갈등의 부재료와 글리신을 첨가, 혼합하여 만든 김치류(배추김치, 무김치, 나박김치, 동치미등)를 온도 15℃-37℃로 숙성시킨다. 김치가 숙성되어 산도 0.4-0.7, pH4.2-4.8에 이르면 알칼리 물질을 일정량씩 첨가한다.When explaining the process of the present invention in more detail cut the cabbage, radish to a suitable size, marinated in 12-15% saline solution for 2-5 hours, washed with tap water and then dehydrated, and the ingredients and glycine such as garlic, green onions, lactose, etc. Add kimchi and mix kimchi (cabbage kimchi, radish kimchi, nabak kimchi, Dongchimi, etc.) to aged temperature 15 ℃ -37 ℃. When kimchi matures and reaches an acidity of 0.4-0.7 and pH 4.2-4.8, an alkaline substance is added in portions.
알칼리 용액을 일정량씩 첨가하여 pH가 4.2-4.8되게 유지하면서 김치를 숙성시킨다. pH가 일정하게 유지되면 PET/PE, NYLON/PE, OPP/PE, PP/PET 필름에 진공도 600-650mmHg로 진공포장하여 제품으로 한다. 본 발명의 공정을 간략하게 도시하면 다음과 같다.Add the alkaline solution in portions to mature the kimchi while keeping the pH at 4.2-4.8. If the pH is kept constant, the product is vacuum packed in PET / PE, NYLON / PE, OPP / PE, PP / PET film with a vacuum degree of 600-650mmHg. Briefly, the process of the present invention is as follows.
한편, 배추김치 및 나박김치에 0.5-2.0%의 글리신을 사용하여 나타난 pH 및 산도는 표 2 내지 표 3과 같다.On the other hand, the pH and acidity shown using 0.5-2.0% glycine in cabbage kimchi and nabak kimchi are shown in Tables 2 to 3.
[표 2] 배추김치의 글리신 함량에 따른 pH 및 산도의 변화[Table 2] Changes of pH and Acidity According to Glycine Content in Chinese Cabbage Kimchi
[표 3] 나박김치의 글리신 함량에 따른 pH 및 산도의 변화[Table 3] Changes of pH and Acidity According to Glycine Content in Nabak Kimchi
[실시예 1]Example 1
배추김치를 담가 용기에 담고 상온(20℃)에서 2-3일간 숙성시키고 산도(젖산함량)가 0.45-0.60, pH 4.2-4.8에 도달했을 때 1N-가성소다(NaOH)를 일정량씩 가해 김치의 pH를 4.2-4.8로 7-10일간 유지시키면서 김치액의 pH가 변화하지 않았을 때, 또는 소모기(Somogy)법으로 당분석 결과 0.2%이하 되었을 때, OPP/PE 필름에 진공도 600mmHg에서 진공포장하여 상온 방치한 결과 저장기간이 2개월 이상 되었다.Put the cabbage kimchi in a container and ripen for 2-3 days at room temperature (20 ℃). When acidity (lactic acid content) reaches 0.45-0.60 and pH 4.2-4.8, add 1N-caustic soda (NaOH) by a certain amount. When the pH of Kimchi solution did not change while keeping the pH at 4.2-4.8 for 7-10 days, or when the sugar analysis showed less than 0.2% by the Somogy method, vacuum packing the OPP / PE film at 600mmHg. After storage at room temperature, the shelf life was more than two months.
[실시예 2]Example 2
절임배추에 100℃에서 3-5분간 습식 살균한 고춧가루와 마늘, 젓갈, 파등의 부재료를 혼합하고 글리신(Glycine) 1%를 첨가하여 37℃에서 12시간-24시간 숙성시켜 산도가 0.4-0.5, pH 4.2-4.6에 이르렀을 때 2N-수산화칼슘(Ca(OH)2) 용액을 일정량씩 가하면서 3-5일후 pH.변화가 없거나, 또는 김치내의 당 존재를 확인하여 그 함량이 0.2%가 됐을 때 Nyoln/PE 필름에 진공도 550mmHg-650mmHg로 진공포장하여 20℃에 방치한 결과 제품의 저장기간(Shelf-life)이 3개월 이상 되었다.The pickled cabbage was mixed with red pepper powder wet and sterilized at 100 ° C. for 3-5 minutes and garlic, salted fish, and other ingredients, and 1% of glycine was added and aged at 37 ° C. for 12 hours to 24 hours. When the pH reaches 4.2-4.6, the pH is not changed after 3-5 days by adding a certain amount of 2N-calcium hydroxide (Ca (OH) 2) solution, or when the content of sugar reaches 0.2% by checking the presence of sugar in kimchi. The Nyoln / PE film was vacuum packed at a vacuum degree of 550mmHg-650mmHg and left at 20 ° C. The shelf life of the product was longer than 3 months.
[실시예 3]Example 3
무를 각변이 1-2cm의 정육면체가 되도록 썰어 15%염용액에 2시간 절이고 수도수로 씻고 여기에 파, 마늘, 고춧가루, 젓갈 등의 부재료를 혼합하고 15℃에서 숙성시키면서 2일-4일후 김치가 숙성되어 산도 0.4-0.7, pH 4.2-4.8로 된후 1N-가성소다용액을 시간당 일정량씩 주입하여 깍두기의 pH가 더 이상 변화하지 않게 됐을 때 PET/PE 필름에 진공 600mmHg에서 진공포장한 결과 저장기간이 2개월 이상 되었다.Slice radish into 1-2cm cubes, marinated in 15% saline solution for 2 hours, wash with tap water, and mix ingredients such as green onion, garlic, red pepper powder, and salted fish and ferment at 15 ℃ for 2-4 days. After aging, the pH was 0.4-0.7 and pH 4.2-4.8, and 1N-caustic soda solution was injected in a fixed amount per hour. When the pH of Kakadugi was no longer changed, vacuum packing was carried out at 600mmHg in vacuum in PET / PE film. This has been more than two months.
[실시예 4]Example 4
무 약 500g과 배추 약 200g을 썰어 놓고 3.5% 소금물 2리터와 아스파탐 0.001%와 글리신(Glycine) 1%을 혼합하여 동치미를 만들고 37℃에서 12시간-24시간 숙성후 산도가 0.4-0.8, pH 4.2-4.8로 되었을 때 2N-중조(NaHCO3)를 주입하여 5일후 일정한 산도를 나타내어 PP/PET 필름에 탈기 포장한 결과 3개월 이상 관능 변화가 없었다.Slice 500 g of radish and about 200 g of Chinese cabbage, mix 2 liters of 3.5% brine, 0.001% aspartame, and 1% glycine to make Dongchimi, and ferment at 37 ℃ for 12-24 hours. When it became -4.8, 2N-NaOH (NaHCO3) was injected and showed a constant acidity after 5 days, and when degassed and packaged in a PP / PET film, there was no sensory change for more than 3 months.
[실시예 5]Example 5
무 500g과 배추 약 300g을 썰어 넣고, 고춧가루 30g과 아스파탐 0.001%, 글리신(Glycine) 0.5%을 혼합하고 여기에 3% 소금물 2리터를 부어 나박김치를 담그고 20℃에서 숙성시키면서 pH가 4.4에 이르면 1N-수산화칼슘(Ca(OH)2)용액을 첨가하여 pH를 4.2-4.8로 유지시키면서 10일간 숙성 시킨후 pH변화가 없을 때 Nylon/PE 필름에 탈기 포장한 결과 제품의 관능 변화 없이 저장기간이 3개월 이상 되었다.500 g of radish and cabbage about 300 g are cut into pieces, and 30 g of red pepper powder, 0.001% aspartame, 0.5% glycine (Glycine) are mixed, and 2 liters of 3% brine is poured, soaked nabak kimchi and aged at 20 ° C. When the pH reaches 4.4, 1N After adding the calcium hydroxide (Ca (OH) 2) solution and aging for 10 days while maintaining the pH at 4.2-4.8, when the pH was not changed, it was degassed and packaged in nylon / PE film. It was over.
[실시예 6]Example 6
절임배추 6kg에 3% 식염수 2리터를 붓고 절임배추를 단독으로 숙성시키면서 pH를 4.2-4.8로 일정하게 유지되도록 가성소오다 용액을 일정량씩 첨가한후 가성소오다 용액 첨가없이 pH가 일정하게 되면 예비 숙성 배추를 분리 탈수하고 여기에 고춧가루, 마늘, 생강, 멸치, 젖갈등의 양념을 혼합하고 글리신 2%, 아스파탐 0.2%를 첨가해서 김치를 제조한 후 Nylon/PE 필름에 포장한 결과 저장기간이 3개월 이상이 되었다.Pour 2 liters of 3% saline into 6 kg of pickled cabbage, add caustic soda solution in a constant amount to keep the pH constant at 4.2-4.8 while aging the pickled cabbage alone. Dehydrated Chinese cabbage was separated and dehydrated, and seasoned with red pepper powder, garlic, ginger, anchovy, and lactose, kimchi was prepared by adding 2% glycine and 0.2% aspartame, and then packed in Nylon / PE film. It has been more than a month.
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1987
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