KR890002374B1 - Method of water-soluble doublesided adhesive-type - Google Patents

Method of water-soluble doublesided adhesive-type Download PDF

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Publication number
KR890002374B1
KR890002374B1 KR1019850008223A KR850008223A KR890002374B1 KR 890002374 B1 KR890002374 B1 KR 890002374B1 KR 1019850008223 A KR1019850008223 A KR 1019850008223A KR 850008223 A KR850008223 A KR 850008223A KR 890002374 B1 KR890002374 B1 KR 890002374B1
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KR
South Korea
Prior art keywords
water
soluble
film
adhesive
release paper
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KR1019850008223A
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Korean (ko)
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KR870005055A (en
Inventor
김병만
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김병만
김종영
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Application filed by 김병만, 김종영 filed Critical 김병만
Priority to KR1019850008223A priority Critical patent/KR890002374B1/en
Publication of KR870005055A publication Critical patent/KR870005055A/en
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Publication of KR890002374B1 publication Critical patent/KR890002374B1/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils

Abstract

The method comprises (i) coating water-soluble adhesive onto one side of a dualsided release paper and drying, (ii) sticking a water- soluble film selected from a gp. of gellatin, glue, cellulose and PVA on the coated paper, and (iii) coating adhesive dissolved in org. solvent onto the film, or joining over the film another release paper obtd. from coating water-soluble adhesive onto it and drying.

Description

수용성 양면 접착 테이프의 제조방법Manufacturing method of water-soluble double-sided adhesive tape

본 발명은 제지 공장에서 사용하는 수용성 양면 접착 테이프에 관한 것이다.The present invention relates to a water-soluble double-sided adhesive tape for use in a paper mill.

종래의 접착 테이프는 100% 수용성이 아니고, 용해속도가 느리고 온도나 pH의 범위에 따라서 사용범위가 한정되는 등의 결점이 있다.Conventional adhesive tapes are not 100% water soluble and have drawbacks such as a slow dissolution rate and limited use range depending on the temperature and pH range.

본 발명은 이와 같은 문제점을 해결코져 안출한 것으로서 이를 상술하면 다음과 같다.The present invention has been made to solve such a problem as described in detail as follows.

수용성 고분자 물질을 필름화시키는 것으로서, 환언하면 젤라틴, 아교, 셀루로즈(카복시메틸셀루로즈, 하이드록시에틸셀루로즈, 메틸셀루로즈, 녹말등)폴리비닐알코올, 폴리비닐피롤라돈 등의 천연 또는 합성의 수용성 고분자 물질을 물에 녹여서 적당한 점도로 만든 다음 이를 이형지에 도포하여 90 내지 150℃의 열풍으로 건조시킨 후 수용성 필름과 이형지를 분리하여 필름을 만든다. 그리고 접착제로서는 수용성 필름의 양면에 도포하며는 종이에 대하여 강한 접착력을 나타내면서 물속에서는 필름과 함께 녹아서 100% 용해되어 버리는 것으로서 그 주요성분은 접착성분, 가소제, 용매등으로 이루어지며 접착성분으로서는 폴리비닐피롤리돈, 폴리비닐알코올, 카복시메틸셀루로즈, 하이드록시에틸셀루로즈, 메틸셀루로즈, 젤라틴, 아교, 아크릴산, 메타이크릴산 등을 사용하며, 가소제로서는 수용성 폴리올로서 즉 폴리에틸렌글리콜, 글리세린, 에틸렌글리콜, 콜리프로필렌글리콜, 폴리프로필렌글리콜과 폴리에틸렌글리콜의 블록 공중합체, 폴리에틸렌글리콜의 알킬에스테르 등이다. 그리고, 용제로서는 물, 에탄올, 메탄올, 부탄올, 아세톤등을 사용한다. 그리고 용제로서 물을 사용한 접착제를 수용성 필름의 위에 직접 도포하며는 필름이 녹아서 형태가 변형되므로, 이경우에는 별도의 이형지에 물을 용매로 사용하여 만든 접착제를 도포하여 건조시킨 것을 수용성 필름위에 접착시키는 것이 좋다.In order to film a water-soluble high molecular substance, in other words, gelatin, glue, cellulose (carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose, starch, etc.) of natural or synthetic polyvinyl alcohol, polyvinylpyrrolidone, etc. After dissolving the water-soluble polymer material in water to make a suitable viscosity, it is applied to a release paper and dried with hot air of 90 to 150 ℃ and then separated from the water-soluble film and the release paper to make a film. As adhesive, it is applied to both sides of water-soluble film and shows strong adhesion to paper, and melts with water in film and is dissolved 100% in water. The main component is composed of adhesive component, plasticizer, solvent, etc. Lollidon, polyvinyl alcohol, carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose, gelatin, glue, acrylic acid, methacrylic acid, etc. are used as plasticizers, as water-soluble polyols, that is, polyethylene glycol, glycerin, ethylene glycol, Copolypropylene glycol, block copolymers of polypropylene glycol and polyethylene glycol, alkyl esters of polyethylene glycol, and the like. And as a solvent, water, ethanol, methanol, butanol, acetone, etc. are used. In addition, since the film is melted and the shape is deformed by directly applying an adhesive using water as a solvent on the water-soluble film, in this case, it is necessary to apply an adhesive made by using water as a solvent on a separate release paper and to dry the adhesive on the water-soluble film. good.

이하 본 발명을 실시예에 의거 설명하면 다음과 같다.Hereinafter, the present invention will be described based on Examples.

[실시예 1]Example 1

물 60부에 젤라틴 40부를 용해시킨 후 이형지 위에 필름 아플리케이터(Film applicater)로 적당한 두께로 균일하게 도포한 다음 80°내지120°에서 건조시키고 필름과 이형지를 분리시켜서 수용성 필름을 만들었다.After dissolving 40 parts of gelatin in 60 parts of water, the film was uniformly applied to a suitable thickness with a film applicater on a release paper, dried at 80 ° to 120 °, and the film and the release paper were separated to form a water-soluble film.

[실시예 2]Example 2

아크릴산 27부, 과황산암모늄 1부, 글리세틴 22부, 정제수 50부를 각각 반응조에 넣고, 일반적인 모노머의 중합방법에 의하여 60°내지80°에서 4시간 교반시켜 중합하여 접착제를 만들었다.27 parts of acrylic acid, 1 part of ammonium persulfate, 22 parts of glycerine, and 50 parts of purified water were put into a reactor, and the mixture was stirred at 60 ° to 80 ° for 4 hours by polymerization of a common monomer to prepare an adhesive.

[실시예 3]Example 3

실시예 2에서 만든 접착제를 양면 이형지의 일면에 도포하여 건조시킨 후, 실시예1에서 제조한 필름을 상기 접착제를 도포하고 건조시킨 면에 합지시킨 다음 그 필름위에 다시 별도의 이형지 위에 실시예2의 접착제를 도포하여 건조시킨 것을 접착시키고 두개의 이형지 중 한개를 박리베거하여 수용성 양면 접착 테이프를 만들었다.After applying the adhesive made in Example 2 to one side of the double-sided release paper and dried, the film prepared in Example 1 was applied to the adhesive coated and dried side and then on the film again on a separate release paper of Example 2 An adhesive was applied to dry the adhesive, and one of the two release papers was peeled off to form a water-soluble double-sided adhesive tape.

[실시예 4]Example 4

실시예2에서 만든 접착제를 양면 이형지의 일면에 도포하여 건조시킨 후, 실시예1에서 제조한 필름을 상기 접착제를 도포하고 건조시킨 면에 합지시킨 다음 그 필름위에 다시 폴리비닐 피롤리돈을 유기용매에 용해시켜서 얻은 접착제를 도포하여 건조시켜서 수용성 양면 접착 테이프를 만들었다.After applying the adhesive prepared in Example 2 to one side of the double-sided release paper and dried, the film prepared in Example 1 was laminated on the coated and dried surface of the adhesive, and then polyvinyl pyrrolidone was added to the organic solvent again. The adhesive obtained by dissolving in was applied and dried to make a water-soluble double-sided adhesive tape.

이상과 같이하여 제조된 수용성 양면 접착 테이프는 제지공장에서 사용할 경우 펄프 제품의 현미경 검사에서도 이물질을 발견할 수 없을 정도로 100%수용성이어서 제품의 품질에 전혀 나쁜 영향을 주지 않을 뿐만 아니라 용해속도 빠르므로 작업 능율이 좋고 온도나 pH의 범위에 구애받지 않고도 사용할 수 있는등 아주 우수한 효과가 있다.The water-soluble double-sided adhesive tape manufactured as described above is 100% water-soluble so that foreign substances can not be found even under the microscopic examination of the pulp product because it does not adversely affect the quality of the product at all, and it has a fast dissolution rate. It has very good effects such as good yield and can be used regardless of temperature or pH range.

Claims (2)

수용성 접착제를 양면 이형지의 일면에 도포하여 건조시키는 제 1 공정, 제 1 공정의 접착제 도포면에 수용성 필름을 합지시키는 제 2 공정, 및 제 2 공정의 필름위에 유기용매로 용해시킨 접착제를 도포하여 건조시키거나 제 2 공정의 필름위에 별도의 이형지에 수용성 접착제를 도포하여 건조시킨 것을 접착시키는 제 3 공정을 결합하여서 됨을 특징으로 하는 수용성 양면 접착 테이프의 제조방법.1st process of apply | coating a water-soluble adhesive to one surface of double-sided release paper, and drying it, the 2nd process of laminating | stacking a water-soluble film on the adhesive application surface of a 1st process, and apply | coating and drying the adhesive which melt | dissolved with the organic solvent on the film of a 2nd process Or a third step of adhering the dried product by applying a water-soluble adhesive to a separate release paper on the film of the second step and bonding the dried product. 제 1 항에 있어서, 수용성 필름으로서는 젤라틴, 아교, 셀루로즈, 폴리비닐알코올, 폴리비닐피롤리돈 중에서 어느 하나임을 특징으로 하는 수용성 양면 접착 테이프의 제조방법.The method for producing a water-soluble double-sided adhesive tape according to claim 1, wherein the water-soluble film is any one of gelatin, glue, cellulose, polyvinyl alcohol, and polyvinylpyrrolidone.
KR1019850008223A 1985-11-04 1985-11-04 Method of water-soluble doublesided adhesive-type KR890002374B1 (en)

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KR1019850008223A KR890002374B1 (en) 1985-11-04 1985-11-04 Method of water-soluble doublesided adhesive-type

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KR1019850008223A KR890002374B1 (en) 1985-11-04 1985-11-04 Method of water-soluble doublesided adhesive-type

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KR890002374B1 true KR890002374B1 (en) 1989-07-02

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101442479B1 (en) * 2013-04-16 2014-09-24 연세대학교 산학협력단 Collagen based biological gelatin glue

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101442479B1 (en) * 2013-04-16 2014-09-24 연세대학교 산학협력단 Collagen based biological gelatin glue

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