KR880013451A - Fungicides based on substituted cyanamides - Google Patents

Fungicides based on substituted cyanamides Download PDF

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KR880013451A
KR880013451A KR1019880006231A KR880006231A KR880013451A KR 880013451 A KR880013451 A KR 880013451A KR 1019880006231 A KR1019880006231 A KR 1019880006231A KR 880006231 A KR880006231 A KR 880006231A KR 880013451 A KR880013451 A KR 880013451A
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alkyl
group
alkoxy
same
optionally substituted
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리이벨 한스-조헴
아끼노리 히라시마
핀다이젠 쿠르트
파우스 루돌프
브란데스 빌헬름
핸슬러 게르트
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클라우스 대너, 귄터 슈마허
바이엘 아크티엔게젤샤프트
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A01N41/06—Sulfonic acid amides
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    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/22—Amides of acids of phosphorus
    • C07F9/24—Esteramides
    • C07F9/2454—Esteramides the amide moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/2479—Compounds containing the structure P(=X)n-N-acyl, P(=X)n-N-heteroatom, P(=X)n-N-CN (X = O, S, Se; n = 0, 1)
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals

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Abstract

내용 없음No content

Description

치환된 시안아미드를 기본으로 하는 살진균제Fungicides based on substituted cyanamides

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (10)

다음 일반식(Ⅰ)의 치환된 시안아미드를 하나 이상 함유함을 특징으로 하는 살진균제.A fungicide characterized in that it contains at least one substituted cyanamide of formula (I). 상기식에서 R1은 임의 치환된 알킬 또는 아릴을 나타내고, R2는 그룹 -CO-R3, -SO2-R4또는Wherein R 1 represents optionally substituted alkyl or aryl, and R 2 represents a group -CO-R 3 , -SO 2 -R 4 or (여기에서 R3는 알킬, 사이클로알킬, 알케닐, 알키닐, 아르알킬, 아르알케닐, 아릴, 헤테로아릴, 알콕시, 아르알콕시, 아릴옥시, 알킬티오, 아르알킬티오, 아릴티오, 알킬아미노, 사이클로알킬아미노, 디알킬아미노, 아르알킬아미노 및 아릴아미노로 이루어진 계열 중에서 선택된 임의 치환된 기를 나타내며, R4는 알킬, 아르알킬, 아릴 및 헤테로아릴로 이루어진 계열 중에서 선택된 임의 치환된 기를 나타내고, R5는 알킬, 아릴, 알콕시, 알킬티오, 알킬아미노 및 디알킬아미노로 이루어진 계열중에서 선택된 임의 치환된 기를 나타내며, R6는 알킬, 알콕시, 알킬티오, 알킬아미노 및 디알킬아미노로 이루어진 계열 중에서 선택된 임의 치환된 기를 나타내고, Q는 산소 또는 황을 나타낸다)을 나타낸다.Wherein R 3 is alkyl, cycloalkyl, alkenyl, alkynyl, aralkyl, aralkenyl, aryl, heteroaryl, alkoxy, aralkoxy, aryloxy, alkylthio, aralkylthio, arylthio, alkylamino, Represents an optionally substituted group selected from the group consisting of cycloalkylamino, dialkylamino, aralkylamino and arylamino, R 4 represents an optionally substituted group selected from the group consisting of alkyl, aralkyl, aryl and heteroaryl, R 5 Represents an optionally substituted group selected from the group consisting of alkyl, aryl, alkoxy, alkylthio, alkylamino and dialkylamino, and R 6 is optionally substituted from the group consisting of alkyl, alkoxy, alkylthio, alkylamino and dialkylamino And Q represents oxygen or sulfur. 제1항에 있어서, R1이 C1-C4-알킬, 또는 할로겐, 시아노, 니트로, C1-C6-알킬, C1-C2-할로겐노알킬, C1-C4-알콕시, C1-C2-할로게노알콕시, C1-C4-알킬티오, C1-C2- 할로게노알킬티오, C1-C4-알킬설피닐, C1-C4-알킬설포닐, C1-C2-할로게노알킬설포닐, C1-C4-알킬아미노, 디-(C1-C3-알킬)-아미노, C1-C|4-알킬-카보닐-아미노 및 C1-C4-알콕시 카보닐로 이루어진 그룹 중에서 선택된 동일 또는 상이한 치환제에 의해 임의로 일치환 내지 디치환된 페닐 또는 나프틸을 나타내고, R2가 그룹 -CO-R3, -SO2-R4또는The compound of claim 1 wherein ROneThis COne-C4Alkyl, or halogen, cyano, nitro, COne-C6Alkyl, COne-C2Halogenoalkyl, COne-C4Alkoxy, COne-C2Halogenoalkoxy, COne-C4-Alkylthio, COne-C2Halogenoalkylthio, COne-C4Alkylsulfinyl, COne-C4Alkylsulfonyl, COne-C2Halogenoalkylsulfonyl, COne-C4-Alkylamino, di- (COne-C3-Alkyl) -amino, COne-C |4-Alkyl-carbonyl-amino and COne-C4Phenyl or naphthyl, optionally mono-di-substituted by the same or different substituents selected from the group consisting of alkoxycarbonyl, R2Autumn group -CO-R3, -SO2-R4or 를 나타내며, 여기에서 R3가 할로겐 및 C1-C4-알콕시 중에서 선택된 동일 또는 상이한 치환체에 의해 임의로 일치환 내지 다치환된 C1-C10-알킬 ; 할로겐 및 C1-C|2-알킬 중에서 선택된 동일 또는 상이한 치환체에 의해 임의로 일치환 내지 다치환된 C3-C6-사이클로알킬 ; 동일 또는 상이한 할로겐 치환체에 의해 임의로 일치환 내지 다치환된 C2-C10-알케닐 ; C2-C10-알키닐 ; 동일 또는 상이한 할로겐 치환체에 의해 그 환이 임의로 일치환 내지 다치환된 벤질 ; 페닐에테닐 ; 할로겐, 시아노, 니트로, C1-C4-알킬, C1-C2-할로게노알킬, C1-C4-알콕시 및 C1-C2-할로게노알콕시로 이루어진 그룹중에서 선택된 동일 또는 상이한 치환체에 의해 임의로 일치환 내지 다치환된 페닐 ; 나프틸 ; 푸릴 ; 티에닐 ; 피리딜 ; C1-C5-알콕시 ; 벤질옥시 ; 페녹시 ; C1-C5-알킬티오 ; 벤질티오 ; 페닐티오 ; C1-C5-알킬아미노 ; C3-C6-사이클로알킬아미노 ; 디-(C1-C3-알킬)-아미노 ; 벤질아미노 ; 또는 할로겐 시아노, 니트로, C1-C4-알킬, C1-C2-할로게노알킬, C1-C4-알콕시, C1-C2-할로게노알콕시, C1-C4-알킬티오, C1-C2-할로게노알킬티오, C1-C4-알킬설피닐, C1-C4-알킬설포닐, C1-C2- 할로게노알킬설포닐 및 C1-C4-알콕시카보닐로 이루어진 그룹 중에서 선택된 동일 또는 상이한 치환체에 의해 임의로 일치환 내지 다치환된 페닐아미노를 나타내고,C 1 -C 10 -alkyl wherein R 3 is optionally mono- or polysubstituted by the same or different substituents selected from halogen and C 1 -C 4 -alkoxy; Halogen and C 1 -C | C 3 -C 6 -cycloalkyl optionally mono- or polysubstituted by the same or different substituents selected from 2 -alkyl; C 2 -C 10 -alkenyl optionally substituted with mono or polysubstitution with the same or different halogen substituents; C 2 -C 10 -alkynyl; Benzyl in which the ring is optionally mono- or polysubstituted by the same or different halogen substituents; Phenylethenyl; Same or different selected from the group consisting of halogen, cyano, nitro, C 1 -C 4 -alkyl, C 1 -C 2 -halogenoalkyl, C 1 -C 4 -alkoxy and C 1 -C 2 -halogenoalkoxy Phenyl optionally substituted with mono- or polysubstituted substituents; Naphthyl; Furyl; Thienyl; Pyridyl; C 1 -C 5 -alkoxy; Benzyloxy; Phenoxy; C 1 -C 5 -alkylthio; Benzylthio; Phenylthio; C 1 -C 5 -alkylamino; C 3 -C 6 -cycloalkylamino; Di - (C 1 -C 3 - alkyl) -amino; Benzylamino; Or halogen cyano, nitro, C 1 -C 4 -alkyl, C 1 -C 2 -halogenoalkyl, C 1 -C 4 -alkoxy, C 1 -C 2 -halogenoalkoxy, C 1 -C 4 -alkyl Thio, C 1 -C 2 -halogenoalkylthio, C 1 -C 4 -alkylsulfinyl, C 1 -C 4 -alkylsulfonyl, C 1 -C 2 -halogenoalkylsulfonyl and C 1 -C 4 Phenylamino optionally substituted with the same or different substituents selected from the group consisting of alkoxycarbonyl, R4가 동일 도는 상이한 할로겐 치환체에 의해 임의로 일치환 내지 다치환된 C1-C10-알킬 ; 할로겐, 시아노, 니트로, C1-C4-알킬, C1-C2-할로게노알킬, C1-C4-알콕시, C1-C2-할로게노알콕시 및 C1-C4-알콕시카보닐로 이루어진 그룹 중에서 선택된 동일 또는 상이한 치환체에 의해 임의로 일치환 내지 다치환된 벤질 ; 할로겐, 시아노, 니트로, 페닐, C1-C4-알킬, C1-C2-할로게노알킬, C1-C4-알콕시, C1-C2-할로게노알콕시,C1-C4-알킬티오, C1-C2-할로게노알킬티오, C1-C|4-알킬설피닐, C1-C4-할로게노알킬설포닐, 디-(C1-C2-알킬)-아미노설포닐 및 C1-C4-알콕시카보닐로 이루어진 그룹 중에서 선택된 동일 또는 상이한 치환체에 의해 임의로 일치환 내지 다치환된 페닐 ; 할로겐, 시아노, 니트로, C1-C4-알킬 및 C1-C4-알콕시로 이루어진 그룹 중에서 선택된 동일 또는 상이한 치환체에 의해 임의로 일치환 내지 다치환된 나프틸 ; 할로겐, C1-C4-알킬 및 C1-C4-알콕시-카보닐로 이루어진 그룹중에서 선택된 동일 또는 상이한 치환체에 의해 임의로 일치환 내지 다치환된 티에닐 ; 할로겐 C1-C4-알킬 및 C1-C4-알콕시-카보닐에 의해 임의 치환된 피라졸릴 ; 또는 할로겐, C1-C|4-알킬 및 C1-C4-알콕시-카보닐로 이루어진 그룹 중에서 선택된 동일 또는 상이한 치환체에 의해 임의로 일치환 내지 다치환된 피리딜을 나타내며,C 1 -C 10 -alkyl optionally substituted mono- or polysubstituted by different halogen substituents having the same R 4 ; Halogen, cyano, nitro, C 1 -C 4 -alkyl, C 1 -C 2 -halogenoalkyl, C 1 -C 4 -alkoxy, C 1 -C 2 -halogenoalkoxy and C 1 -C 4 -alkoxy Benzyl optionally mono- or polysubstituted by the same or different substituents selected from the group consisting of carbonyl; Halogen, cyano, nitro, phenyl, C 1 -C 4 -alkyl, C 1 -C 2 -halogenoalkyl, C 1 -C 4 -alkoxy, C 1 -C 2 -halogenoalkoxy, C 1 -C 4 -Alkylthio, C 1 -C 2 -halogenoalkylthio, C 1 -C | 4-alkyl-sulfinyl, C 1 -C 4 - halogenoalkyl sulfonyl, di - (C 1 -C 2 - alkyl) aminosulfonyl and C 1 -C 4 - the same selected from the group consisting of alkoxycarbonyl, or Phenyl optionally mono- or polysubstituted by different substituents; Naphthyl optionally mono- or polysubstituted by the same or different substituents selected from the group consisting of halogen, cyano, nitro, C 1 -C 4 -alkyl and C 1 -C 4 -alkoxy; Thienyl optionally mono- or polysubstituted by the same or different substituents selected from the group consisting of halogen, C 1 -C 4 -alkyl and C 1 -C 4 -alkoxy-carbonyl; Pyrazolyl optionally substituted by halogen C 1 -C 4 -alkyl and C 1 -C 4 -alkoxy-carbonyl; Or halogen, C 1 -C | 4 -alkyl and C 1 -C 4 - alkoxy - optionally substituted by identical or different substituents selected from the group consisting of a carbonyl group represents a mono- to multi-substituted pyridyl, R5가 동일 또는 상이한 할로겐 치환체에 의해 임의로 일치환 내지 다치환된 C1-C4-알킬, 페닐 ; 동일 또는 상이한 할로겐 치환체에 임의로 일치환 내지 다치환된 C1-C4-알콕시 ; C1-C4-알킬티오 ; C1-C4-알킬아미노 ; 또는 디-(C1-C3-알킬)-아미노를 나타내고, R6가 동일 또는 상이한 할로겐 치환체에 의해 임의로 일치환 내지 다치환된 C1-C4-알킬 ; 동일 또는 상이한 할로겐 치환체에 의해 임의로 일치환 내지 다치환된 C1-C5-알콕시 ; C1-C4-알킬티오, C1-C4-알킬아미노 ; 또는 디-(C1-C3-알킬)-아미노를 나타내며, Q가 산소 또는 황인 살진균제.C 1 -C 4 -alkyl, phenyl wherein R 5 is optionally mono- or polysubstituted by the same or different halogen substituents; C 1 -C 4 -alkoxy optionally substituted with mono or polysubstitutions with the same or different halogen substituents; C 1 -C 4 -alkylthio; C 1 -C 4 -alkylamino; Or di - (C 1 -C 3 - alkyl) amino represents a, R 6 are the same or optionally substituted with one substituent by a different halogen to the substituted C 1 -C 4 - alkyl; C 1 -C 5 -alkoxy optionally substituted with mono or polysubstitution with the same or different halogen substituents; C 1 -C 4 -alkylthio, C 1 -C 4 -alkylamino; Or di - (C 1 -C 3 - alkyl) - represents an amino, Q is oxygen or sulfur fungicide. 제1항에 있어서, R1이 불소, 염소, 브롬, 메틸, 에틸, 시아노, 니트로, 트리플루오로메틸, 트리클로로메틸, 메톡시, 에톡시, 디플루오로메톡시, 트리플루오로메톡시, 메틸티오, 에틸티오, 메틸아미노, 에틸아미노, 디메틸아미노, 디에틸아미노, 트리풀루오로메틸티오, 아세틸아미노, 프로피오닐아미노; 메톡시카보닐, 에톡시카보닐, 프로폭시카보닐 및 이소프로폭시카보닐로 이루어진 그룹 중에서 선택된 동일 또는 상이한 치환체에 의해 임의로 일치환 내지 삼치환된 페닐을 나타내고, R2가 그룹 -CO-R3, -SO2-R4또는The compound of claim 1, wherein R 1 is fluorine, chlorine, bromine, methyl, ethyl, cyano, nitro, trifluoromethyl, trichloromethyl, methoxy, ethoxy, difluoromethoxy, trifluoromethoxy, methyl Thio, ethylthio, methylamino, ethylamino, dimethylamino, diethylamino, trifuluromethylthio, acetylamino, propionylamino; Phenyl optionally mono- to trisubstituted by the same or different substituents selected from the group consisting of methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl and isopropoxycarbonyl, R 2 is a group -CO-R 3 , -SO 2 -R 4 or 를 나타내며, 여기에서 R3가 불소, 염소, 브롬, 시아노, 니트로, 메틸, 에틸, 트리플루오로메틸, 트리클로로메틸, 메톡시, 에톡시, 디플루오로메톡시, 트리플루오로메톡시 및 클로로디플루오로메톡시로 이루어진 그룹중에서 선택된 동일 또는 상이한 치환체에 의해 임의로 일치환 내지 삼치환된 페닐을 나타내고, R4가 불소,염소, 브롬, 시아노, 니트로, 메틸, 페닐, 플로로메틸, 트리플루오로메틸, 메톡시, 에톡시, 디플루오로메톡시, 트리플루오로메톡시, 메틸티오, 에틸티오, 트리플루오로메틸티오, 디메틸아미노설포닐, 메톡시카보닐, 에톡시카보닐, 프로폭시카보닐 및 이소프로폭시카보닐로 이루어진 그룹중에서 선택된 동일 또는 상이한 치환체에 의해 임의로 일치환 내지 삼치환된 페닐을 나타내며, R5가 메틸, 에틸, 페닐, 메톡시, 에톡시, 메틸티오, 에틸티오, 메틸아미노, 에틸아미노 또는 디메틸아미노를 나타내고, R6가 메틸, 에틸, 메톡시, 에톡시, 프로폭시, 부톡시, 펜틸옥시, 헥실옥시, 메틸티오, 에틸티오, 프로필티오, 부틸티오, 메틸아미노, 에틸아미노 또는 디메틸아미노를 나타내며, Q가 산소 또는 황을 나타내는 살진균제.Wherein R 3 is fluorine, chlorine, bromine, cyano, nitro, methyl, ethyl, trifluoromethyl, trichloromethyl, methoxy, ethoxy, difluoromethoxy, trifluoromethoxy and chlorodi Phenyl optionally substituted with the same or different substituents selected from the group consisting of fluoromethoxy, R 4 represents fluorine, chlorine, bromine, cyano, nitro, methyl, phenyl, fluoromethyl, trifluoro Methyl, methoxy, ethoxy, difluoromethoxy, trifluoromethoxy, methylthio, ethylthio, trifluoromethylthio, dimethylaminosulfonyl, methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl and isopropoxy-carbonyl denotes a carbonyl same or monosubstituted to trisubstituted by phenyl, optionally different substituents selected from the group consisting of, R 5 is methyl, ethyl, phenyl, methoxy, ethoxy, methylthioninium , Ethylthio, methylamino, represents an ethylamino or dimethylamino, R 6 is methyl, ethyl, methoxy, ethoxy, propoxy, butoxy, pentyloxy, hexyloxy, methylthio, ethylthio, propyl thio, A fungicide which represents butylthio, methylamino, ethylamino or dimethylamino, wherein Q represents oxygen or sulfur. 진균을 박멸하기 위한 제1항에 따르는 일반식(Ⅰ)의 치환된 시안아미드의 사용.Use of substituted cyanamides of general formula (I) according to claim 1 to eradicate fungi. 제1항에 따르는 일반식(Ⅰ)의 치환된 시안아미드를 진균 및/또는 이들의 서식지에 작용시킴을 특징으로 하여 진균을 박멸시키는 방법.A method for eradicating fungi, characterized in that the substituted cyanamide of formula (I) according to claim 1 acts on the fungi and / or their habitat. 제1항에 따르는 일반식(Ⅰ)의 치환된 시안아미드를 중량제 및/또는 계면활성제와 혼합시킴을 특징으로 하여 살진균제를 제조하는 방법.A process for the preparation of fungicides, characterized in that the substituted cyanamide of formula (I) according to claim 1 is mixed with a weighting agent and / or a surfactant. 일반식(Ⅰa)의 치환된 시안아미드Substituted Cyanamides of Formula (Ia) 상기식에서, A1은 임의 치환된 아릴을 나타내고, A2는 그룹Wherein A 1 represents optionally substituted aryl and A 2 is a group 를 나타내며, 여기에서 A3는 알킬, 아릴, 알콕시, 알킬티오, 알킬아미노 및 디알킬아미노로 이루어진 계열 중에서 선택된 임의 치환된 기를 나타내고 A4는 알킬, 알콕시, 알킬티오, 알킬아미노 및 디알킬아미노로 이루어진 계열중에서 선택된 임의 치환된 기를 나타내며, Q는 산소 또는 황을 나타낸다.Wherein A 3 represents an optionally substituted group selected from the group consisting of alkyl, aryl, alkoxy, alkylthio, alkylamino and dialkylamino and A 4 represents alkyl, alkoxy, alkylthio, alkylamino and dialkylamino An optionally substituted group selected from the group consisting of, Q represents oxygen or sulfur. 제7항에 있어서, A1이 할로겐, 시아노, 니트로, C1-C4-알킬, C1-C|2-할로게노알킬, C1-C4-알콕시, C1-C2-할로게노알콕시, C1-C4-알킬티오, C1-C2-할로게노알킬티오, C1-C4-알킬설피닐, C1-C4-알킬설포닐, C1-C2-할로게노알킬설포닐, C1-C4-알킬아미노, 디-(C1-C3-알킬)-아미노, C1-C4-알킬카보닐-아미노 및 C1-C4-알콕시-카보닐로 이루어진 그룹 중에서 선택된 동일 또는 상이한 치환체에 의해 임의로 일치환 내지 다치환된 페닐 또는 나프틸을 나타내고, A2가 그룹8. A compound according to claim 7, wherein A 1 is halogen, cyano, nitro, C 1 -C 4 -alkyl, C 1 -C | 2 -halogenoalkyl, C 1 -C 4 -alkoxy, C 1 -C 2 -halogenoalkoxy, C 1 -C 4 -alkylthio, C 1 -C 2 -halogenoalkylthio, C 1 -C 4- Alkylsulfinyl, C 1 -C 4 -alkylsulfonyl, C 1 -C 2 -halogenoalkylsulfonyl, C 1 -C 4 -alkylamino, di- (C 1 -C 3 -alkyl) -amino, C 1 -C 4 - alkylcarbonyl-amino and C 1 -C 4 - alkoxy-carbonyl denotes a same or monosubstituted to polysubstituted by a phenyl or naphthyl optionally different substituents selected from the group consisting of, a 2 is a group 를 나타내며, 여기에서 A3가 동일 또는 상이한 할로겐 치환체에 의해 일치환 내지 다치환된 C1-C4-알킬;페닐;동일 또는 상이한 할로겐 치환제에 의해 임의로 일치환 내지 다치환된 C1-C4-알콕시 ; C1-C4-알킬티오 ; C1-C4-알킬아미노 ; 또는 디-(C1-C3-알킬)-아미노를 나타내고, A4가 동일 또는 상이한 할로겐 치환체에 의해 임의로 일치환 내지 다치환된 C1-C4-알킬 ; 동일 또는 상이한 할로겐 치환체에 의해 임의로 일치환 내지 다치환된 C1-C4-알콕시 ; C1-C4-알킬티오 ; C1-C4-알킬아미노 ; 또는 디-(C1-C3-알킬)-아미노를 나타내며, Q가 산소 또는 황을 나타내는 일반식(Ⅰa)의 치환된 시안아미드.Represents the a, where A 3 is the same or is substituted by a different one to halogen substituents substituted on the C 1 -C 4 - alkyl, phenyl, a by identical or different halogen substituent optionally monosubstituted to polysubstituted C 1 -C 4 -alkoxy; C 1 -C 4 -alkylthio; C 1 -C 4 -alkylamino; Or di - (C 1 -C 3 - alkyl) amino represents a, A 4 are identical or optionally substituted with one substituent by a different halogen to the substituted C 1 -C 4 - alkyl; C 1 -C 4 -alkoxy optionally substituted with mono or polysubstitution with the same or different halogen substituents; C 1 -C 4 -alkylthio; C 1 -C 4 -alkylamino; Or di - (C 1 -C 3 - alkyl) - represents an amino, a substituted cyanamide of the general formula (Ⅰa), Q represents an oxygen or sulfur. 제8항에 있어서, A1이 불소, 염소, 브롬, 메틸, 에틸, 시아노, 니트로, 트리플루오로메틸, 트리플로로메틸, 메톡시, 에톡시, 디플루오로메톡시, 트리플루오로메톡시, 메틸티오, 에틸티오, 메틸아미노, 에틸아미노, 디메틸아미노, 디에틸아미노, 트리플루오로메틸티오, 아세틸아미노, 프로피오닐아미노, 메톡시카보닐, 에톡시카보닐, 프로폭시카보닐 및 이소프로폭시카보닐로 이루어진 그룹중에서 선택된 동일 또는 상이한 치환체에 의해 임의로 일치환 내지 삼치환된 페닐을 나타내고 A2가 그룹The compound of claim 8, wherein A 1 is fluorine, chlorine, bromine, methyl, ethyl, cyano, nitro, trifluoromethyl, trifluoromethyl, methoxy, ethoxy, difluoromethoxy, trifluoromethoxy, Methylthio, ethylthio, methylamino, ethylamino, dimethylamino, diethylamino, trifluoromethylthio, acetylamino, propionylamino, methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl and isopropoxy Phenyl optionally mono- to trisubstituted by the same or different substituents selected from the group consisting of carbonyl and A 2 is a group 를 나타내며, 여기에서 A3가 메틸, 에틸, 메톡시, 에톡시, 메틸티오, 에틸티오, 메틸아미노, 에틸아미노 또는 디메틸아미노를 나타내고, A4가 메틸, 에틸, 메톡시, 에톡시, 프로폭시, 부톡시, 펜틸옥시, 헥실옥시, 메틸티오, 에틸티오, 프로필티오, 부틸티오, 메틸아미노, 에틸아미노 또는 디메틸아미노를 나타내며, Q가 산소 또는 황을 나타내는 일반식(Ⅰa)의 치환된 시안아미드.Wherein A 3 represents methyl, ethyl, methoxy, ethoxy, methylthio, ethylthio, methylamino, ethylamino or dimethylamino, and A 4 represents methyl, ethyl, methoxy, ethoxy, propoxy Substituted cyanide of formula (Ia) wherein butoxy, pentyloxy, hexyloxy, methylthio, ethylthio, propylthio, butylthio, methylamino, ethylamino or dimethylamino and Q represents oxygen or sulfur amides. 일반식(Ⅱa)의 시안아미드를 필요한 경우 산수용체의 존재하 및 필요한 경우희석제의 존재하에서 일반식(Ⅲa)의 화합물과 반응시킴을 특징으로 하여, 일반식(Ⅰa)의 치환된 시안아미드를 제조하는 방법.A cyanamide of formula (IIa) is reacted with a compound of formula (IIIa) in the presence of an acid acceptor if necessary and in the presence of a diluent if necessary, to produce a substituted cyanamide of formula (Ia). How to. 상기식에서, A1은 임의 치환된 아릴을 나타내고 A2는 그룹Wherein A 1 represents optionally substituted aryl and A 2 is a group 를 나타내며, 여기에서 A3는 알킬, 아릴, 알콕시, 알킬티오, 알킬아미노 및 디알킬아미노로 이루어진 계열중에서 선택된 임의 치환된 기를 나타내고, A4는 알킬, 알콕시, 알킬티오, 알킬아미노 및 디알킬아미노로 이루어진 계열중에서 선택된 임의 치환된 기를 나타내며, Q는 산소 또는 황을 나타낸다.Wherein A 3 represents an optionally substituted group selected from the group consisting of alkyl, aryl, alkoxy, alkylthio, alkylamino and dialkylamino, and A 4 represents alkyl, alkoxy, alkylthio, alkylamino and dialkylamino An optionally substituted group selected from the group consisting of, Q represents oxygen or sulfur. ※ 참고사항 : 최초출원내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019880006231A 1987-05-27 1988-05-27 Fungicides based on substituted cyanamides KR880013451A (en)

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