KR870009257A - Transparent and slippery biaxially oriented polyester film - Google Patents

Transparent and slippery biaxially oriented polyester film Download PDF

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KR870009257A
KR870009257A KR870002802A KR870002802A KR870009257A KR 870009257 A KR870009257 A KR 870009257A KR 870002802 A KR870002802 A KR 870002802A KR 870002802 A KR870002802 A KR 870002802A KR 870009257 A KR870009257 A KR 870009257A
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South Korea
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acid
film
recording material
material according
organic lubricant
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KR870002802A
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Korean (ko)
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유지로 후꾸다
시게오 우쓰미
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다까미야 다다시
다이아호일 가부시끼 가이샤
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Publication of KR870009257A publication Critical patent/KR870009257A/en

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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/76Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/775Photosensitive materials characterised by the base or auxiliary layers the base being of paper
    • G03C1/785Photosensitive materials characterised by the base or auxiliary layers the base being of paper translucent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/20Carboxylic acid amides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02Polyesters derived from dicarboxylic acids and dihydroxy compounds

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음No content

Description

투명하고 미끄럼성이 좋은 2축연신 폴리에스테르 필름Transparent and slippery biaxially oriented polyester film

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (22)

0.005 내지 1중량% 의 유기 윤활제를 함유하고 하기와 같은 특성을 갑는 2축연신 폴리에스테르필름과 또 폴리에스테르 필름상에 적층된 적어도 하나의 감광층, 유액층, 광전도체층 및 감광층을 갑는 투명한 도체층으로 이루어진 기록재료,A biaxially stretched polyester film containing 0.005 to 1% by weight of an organic lubricant and having at least one photosensitive layer, an emulsion layer, a photoconductor layer and a photosensitive layer laminated on the polyester film. A recording material consisting of a conductor layer, 여기서, △H는 2축역신 필름의 표면 헤이즈이고, H0 100은 100㎛ 필름 두께를 기준으로 하여 계산한 필름의 내부 헤이즈이며, ㎲는 2축연신필름의 정비 마찰계수임.ΔH is the surface haze of the biaxially stretched film, H 0 100 is the internal haze of the film calculated on the basis of the 100 μm film thickness, and ㎲ is the maintenance friction coefficient of the biaxially stretched film. 제1항에 있어서, 2축연신 및 열경화처리후 필름의 평균 굴절률(n)이 1.640 내지 1.670인 기록재료A recording material according to claim 1, wherein the average refractive index (n) of the film after biaxial stretching and heat curing is 1.640 to 1.670. 제2항에 있어서, 2축연신 및 열경화처리후 필름의 평균 굴절률(n)이 1.650 내지 1.670인 기록재료A recording material according to claim 2, wherein the average refractive index n of the film after biaxial stretching and heat curing is 1.650 to 1.670. 제1항에 있어서, 유기 윤활제의 함량이 0.05 내지 0.5중량%인 기록재료.A recording material according to claim 1, wherein the content of the organic lubricant is 0.05 to 0.5% by weight. 제1항에 있어서, 2축연신 및 열결화처리후 필름의 표면 배향도가 0.155 내지 0.175인 기록재료.A recording material according to claim 1, wherein the degree of surface orientation of the film after biaxial stretching and thermal curing treatment is 0.155 to 0.175. 제1항에 있어서, 필름의 두께가 3내지 500㎛인 기록재료.A recording material according to claim 1, wherein the film has a thickness of 3 to 500 mu m. 제1항에 있어서, 유리 윤활제가 하기 일반식 (4) 또는 (5)로 표시되는 화합물인 기록재료A recording material according to claim 1, wherein the glass lubricant is a compound represented by the following general formula (4) or (5). 여기서, R'은 1 내지 12개의 탄소원자를 갑는 알킬렌기이고, R2및 R3은 각각 8 내지 30개의 탄소원자를 갖는 알킬기이며, R4는 수소원자 또는 메틸기이고, R5는 1 내지 12개의 탄소원자를 갑는 알킬렌기이거나, 또는 방향족 고리 또는 지방족 고리를 갑는 2가 탄화수소 잔기임.Here, R 'is an alkylene group having 1 to 12 carbon atoms, R 2 and R 3 are each an alkyl group having 8 to 30 carbon atoms, R 4 is a hydrogen atom or a methyl group, and R 5 is 1 to 12 carbon atoms It is an alkylene group for cutting, or a divalent hydrocarbon residue for an aromatic ring or an aliphatic ring. 제7항에 있어서, 일반식(4)의 유기 윤활제가, 예를들어 에틸렌디아민, 프로필렌디아민, 부틸렌디아민, 핵사메틸렌디아민, 옥타메틸렌디아민, 데카메티리렌디아민, 및 도데카메틸렌디아민과 같은 알킬렌디아민민을, 예를들어 스테아르산, 카프르산, 데칸산, 라우르산, 미리스트산, 팔미트산, 아라키딘산, 벤헨산, 올레산, 엘라이드산, 몬탄산 및 카르나우보산과 같은 지방산 반응시켜 수득할 수 있는 비스아미드 화학물인 기록재료.8. The organic lubricant according to claim 7, wherein the organic lubricant of general formula (4) is, for example, alkyl such as ethylenediamine, propylenediamine, butylenediamine, nucleamethylenediamine, octamethylenediamine, decamethyrylenediamine, and dodecamethylenediamine. Rendiamines such as, for example, stearic acid, capric acid, decanoic acid, lauric acid, myristic acid, palmitic acid, arachidic acid, benhenic acid, oleic acid, elideic acid, montanic acid and carnavoic acid A recording material which is a bisamide chemical obtainable by fatty acid reaction. 제7항에 있어서, 일반식(5)의 유기윤활제가, 예를들어, 옥틸아민, 데실아민, 펜타데실아민, 햅타데실아민 및 도데실아민과 같은 알킬모노아민을 예를들어 시클로헥산디카르복시산, 숙신산, 아디프산, 세바스산테레프탈산, 이소프탈산, 페틸에틸디카르복시산, 페틸에탄디카르복시산, 나프탈렌디카르복시산, 및 비페닐디카르복시산과 반응시켜 수득할 수 있는 비스아미드 화합물인 기록재료.8. The organic lubricant according to claim 7, wherein the organic lubricating agent of general formula (5) is, for example, cyclohexadicarboxylic acid, for example alkylmonamines such as octylamine, decylamine, pentadecylamine, heptadecylamine and dodecylamine. And a bisamide compound obtained by reacting with succinic acid, adipic acid, terephthalic acid sebacic acid, isophthalic acid, petylethyldicarboxylic acid, petylethanedicarboxylic acid, naphthalenedicarboxylic acid, and biphenyldicarboxylic acid. 제1항에 있어서, 100㎛ 필름 두께를 기준으로 하여 계산한 필름의 전체 헤이즈(H1 100)가 1.2% 이하인 기록재료.The recording material according to claim 1, wherein the total haze (H 1 100 ) of the film calculated on the basis of the film thickness of 100 µm is 1.2% or less. 제1항에 있어서, 필름의 동마찰계수(μd)가 1.2이상이고 필름의 정지마찰계수(㎲)보다 작은 기록재료.A recording material according to claim 1, wherein the coefficient of kinetic friction (mu d) of the film is 1.2 or more and smaller than the static friction coefficient of the film. 0.005 내지 1중량% 의 유기 윤활제를 함유하고 하기와 같은 특성을 갖는 2축연신 폴리에스테르필름 및 필름상에 적층된 투명한 도체층으로 이루어진 투명 전극,A transparent electrode comprising 0.005 to 1% by weight of an organic lubricant and having a biaxially stretched polyester film having the following characteristics and a transparent conductor layer laminated on the film, 여기서, △H는 2축연신 필름의 표면 헤이즈이고, H0 100은 100㎛ 필름 두께를 기준으로 하여 계산한 필름의 내부 헤이즈이며, ㎲는 2축연신필름의 정비 마찰계수임.ΔH is the surface haze of the biaxially stretched film, H 0 100 is the internal haze of the film calculated on the basis of the 100 μm film thickness, and ㎲ is the maintenance friction coefficient of the biaxially stretched film. 제12항에 있어서, 2축연신 및 열경화처리후 필름의 평균 굴절률(n)이 1.640 내지 1.670인 기록재료13. The recording material according to claim 12, wherein the average refractive index n of the film after biaxial stretching and heat curing is 1.640 to 1.670. 제13항에 있어서, 2축연신 및 열경화처리후 필름의 평균 굴절률(n)이 1.650 내지 1.670인 기록재료The recording material according to claim 13, wherein the average refractive index n of the film after biaxial stretching and heat curing is 1.650 to 1.670. 제12항에 있어서, 유기 윤활제의 함량이 0.05 내지 0.5중량%인 기록재료.13. The recording material according to claim 12, wherein the content of the organic lubricant is 0.05 to 0.5% by weight. 제12항에 있어서, 2축연신 및 열결화처리후 필름의 표면 배향도가 0.155 내지 0.175인 기록재료.13. The recording material according to claim 12, wherein the film has a surface orientation of 0.155 to 0.175 after biaxial stretching and thermal curing. 제12항에 있어서, 필름의 두께가 3내지 500㎛인 투명전극.The transparent electrode of claim 12, wherein the film has a thickness of 3 to 500 μm. 제12항에 있어서, 유기 윤활제가 하기 일반식 (4) 또는 (5)로 표시되는 화합물인 투명전극The transparent electrode according to claim 12, wherein the organic lubricant is a compound represented by the following general formula (4) or (5). 여기서, R'은 1 내지 12개의 탄소원자를 갑는 알킬렌기이고, R2및 R3은 각각 8 내지 30개의 탄소원자를 갖는 알킬기이며, R4는 수소원자 또는 메틸기이고, R5는 1 내지 12개의 탄소원자를 갖는 알킬렌기이거나, 또는 방향족 고리 또는 지방족 고리를 갖는 2가 탄화수소 잔기임.Here, R 'is an alkylene group having 1 to 12 carbon atoms, R 2 and R 3 are each an alkyl group having 8 to 30 carbon atoms, R 4 is a hydrogen atom or a methyl group, and R 5 is 1 to 12 carbon atoms An alkylene group having a group or a divalent hydrocarbon residue having an aromatic ring or an aliphatic ring. 제18항에 있어서, 일반식(4)의 유기 윤활제가, 예를들어 에틸렌디아민, 프로필렌디아민, 부틸렌디아민, 핵사메틸렌디아민, 옥타메틸렌디아민, 데카메틸렌디아민, 및 도데카메틸렌디아민과 같은 알킬렌디아민을 예를들어 스테아르산, 카프르산, 데칸산, 라우르산, 미리스트산, 팔미트산, 아라키딘산, 벤헨산, 올레산, 엘라이드산, 몬탄산 및 카르나우보산과 같은 지방산 반응시켜 수득할 수 있는 비스아미드 화학물인 투명전극.19. The alkyl lubricant of claim 18 wherein the organic lubricant of formula (4) is, for example, alkylene such as ethylenediamine, propylenediamine, butylenediamine, nucleamethylenediamine, octamethylenediamine, decamethylenediamine, and dodecamethylenediamine. Diamines are reacted with fatty acids such as, for example, stearic acid, capric acid, decanoic acid, lauric acid, myristic acid, palmitic acid, arachidic acid, behenic acid, oleic acid, ellide acid, montanic acid and carnavoic acid. Transparent electrode which is a bisamide chemical obtainable. 제18항에 있어서, 일반식(5)의 유기윤활제가, 예를들어, 옥틸아민, 데실아민, 펜타데실아민, 햅타데실아민, 옥타데실아민 및 도데실아민과 같은 알킬모노아민을 예를들어 시클로헥산디카르복시산, 숙신산, 아디프산, 세바스산, 테레프탈산, 이소프탈산, 페틸에틸디카르복시산, 페틸에탄디카르복시산, 나프탈렌디카르복시산, 및 비페닐디카르복시산과 같은 카르복시산과 반응시켜 수득할 수 있는 비스아미드 화합물인 투명전극.The organic lubricant of formula (5) according to claim 18, for example, alkyl monoamines such as octylamine, decylamine, pentadecylamine, heptadecylamine, octadecylamine and dodecylamine. Bisamides obtainable by reaction with carboxylic acids such as cyclohexanedicarboxylic acid, succinic acid, adipic acid, sebacic acid, terephthalic acid, isophthalic acid, petylethyldicarboxylic acid, petylethanedicarboxylic acid, naphthalenedicarboxylic acid, and biphenyldicarboxylic acid Transparent electrode that is a compound. 제1항에 있어서, 100㎛ 필름 두께를 기준으로 하여 계산한 필름의 전체 헤이즈(H1 100)가 1.2% 이하인 투명전극.The transparent electrode according to claim 1, wherein the total haze (H 1 100 ) of the film calculated on the basis of the film thickness of 100 µm is 1.2% or less. 제12항에 있어서, 필름의 동마찰계수(μd)가 1.2이사이고 필름의 정지마찰계수(㎲)보다 작은 투명전극.The transparent electrode according to claim 12, wherein the coefficient of kinetic friction (mu d) of the film is 1.2 or less and smaller than the static friction coefficient of the film. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR870002802A 1986-03-25 1987-03-25 Transparent and slippery biaxially oriented polyester film KR870009257A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP66861 1986-03-25
JP61066861A JPS62222829A (en) 1986-03-25 1986-03-25 Transparent easy-slip biaxially oriented polyester film

Publications (1)

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KR870009257A true KR870009257A (en) 1987-10-24

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US4894404A (en) * 1988-09-19 1990-01-16 Eastman Kodak Company Molding compositions based on poly(1,4-cyclohexylene dimethylene terephthalate) containing an amide crystallization aid
US6344310B1 (en) 1998-11-20 2002-02-05 Eastman Kodak Company Thin durable photographic element
WO2001072886A2 (en) * 2000-03-27 2001-10-04 E.I. Du Pont De Nemours And Company Reduction of friction effect between poly(ethylene terephthalate) preforms and bottles
US20120211150A1 (en) * 2011-02-18 2012-08-23 Cryovac, Inc. Method of Orienting A Polyester Film

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EP0061769B1 (en) * 1981-03-30 1987-04-01 Teijin Limited Magnetic recording medium

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GB8707094D0 (en) 1987-04-29
JPS62222829A (en) 1987-09-30
GB2188586A (en) 1987-10-07
GB2188586B (en) 1989-11-29
JPH0518692B2 (en) 1993-03-12

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