KR870008015A - Reinforced non-aqueous liquid laundry detergent composition and fabric washing method - Google Patents

Reinforced non-aqueous liquid laundry detergent composition and fabric washing method Download PDF

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KR870008015A
KR870008015A KR870001530A KR870001530A KR870008015A KR 870008015 A KR870008015 A KR 870008015A KR 870001530 A KR870001530 A KR 870001530A KR 870001530 A KR870001530 A KR 870001530A KR 870008015 A KR870008015 A KR 870008015A
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detergent
composition
detergent composition
quaternary ammonium
nonionic surfactant
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KR870001530A
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Korean (ko)
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기브로즈
바스뗑 다니엘르
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에이치 에스 실베스터
콜게이트-파아므올리브 캄파니
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Publication of KR870008015A publication Critical patent/KR870008015A/en

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/65Mixtures of anionic with cationic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0004Non aqueous liquid compositions comprising insoluble particles
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/001Softening compositions
    • C11D3/0015Softening compositions liquid
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • C11D1/06Ether- or thioether carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds

Abstract

내용 없음No content

Description

증강된 비수성 액체 세탁용 세제 조성물과 직물의 세탁 및 유연성 부여방법Reinforced non-aqueous liquid laundry detergent composition and fabric washing method

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (22)

수성 세탁욕에 첨가했을 때 서서히 가수분해하고 세탁되는 직물 위에 부착되어 연화시키기 위한 4차 암모늄 연화제를 방출하는, 산 말단 비이온 계면활성제와 양이온 4차 암모늄 염 연화제의 거대염 복합체로 구성되는 직물의 세탁 및 유연성 부여를 위한 세제 조성물.When added to an aqueous laundry bath, the fabric is composed of a macrosatellite complex of an acid-terminated nonionic surfactant and a cationic quaternary ammonium salt softener that slowly hydrolyzes and releases a quaternary ammonium softener for attaching and softening onto the fabric being washed. Detergent composition for washing and imparting flexibility. 제 1 항에 있어서, 비수성 액체이고 액체 비이온 계면활성제 세제로 구성되는 세제 조성물.The detergent composition of claim 1, which is a non-aqueous liquid and consists of a liquid nonionic surfactant detergent. 제 1 항에 있어서, 산 말단 비이온 계면활성제가 말단 OH기를 갖는 폴리 C2-C3알콕실화 지방알코올인 비이온 계면활성제와 폴리카르복실산 또는 폴리카르복실산 무수물의 반응 생성물로 구성되는 세제 조성물.The detergent according to claim 1, wherein the acid-terminated nonionic surfactant is a reaction product of a nonionic surfactant and a polycarboxylic acid or a polycarboxylic anhydride which is a poly C 2 -C 3 alkoxylated fatty alcohol having a terminal OH group. Composition. 제 1 항에 있어서, 거대염 복합체가 약 등몰량의 산 말단 비이온계 면활성제와 양이온 4차암모늄 연화제염으로 구성되는 세제 조성물.2. The detergent composition of claim 1, wherein the macrosalt complex comprises about equimolar amounts of acid terminal nonionic surfactants and cationic quaternary ammonium emollient salts. 제 1 항에 있어서, 양이온 4차 아민염이 하기식으로 나타내어지는 조성물.The composition according to claim 1, wherein the cationic quaternary amine salt is represented by the following formula. (상기식에서, R1은 10-22 탄소원자를 갖는 장쇄지방족 라디칼이고 R2는 독립적으로 저급 알킬 또는 히드록시알킬 라디칼이고, X는 수용성염 형성 음이온임.)(Wherein R 1 is a long chain aliphatic radical having 10-22 carbon atoms and R 2 is independently a lower alkyl or hydroxyalkyl radical and X is a water soluble salt forming anion.) 제 1 항에 있어서, 양이온 4차 아민염이 하기식으로 나타내어지는 조성물.The composition according to claim 1, wherein the cationic quaternary amine salt is represented by the following formula. (상기식에서, R1은 10-22 탄소원자를 갖는 장쇄지방족 라디칼이고, R2는 독립적으로 저급 알킬 또는 히드록시알킬 라디칼이고, X는 수용성염 형성 음이온임.)(Wherein R 1 is a long chain aliphatic radical having 10-22 carbon atoms, R 2 is independently a lower alkyl or hydroxyalkyl radical, and X is a water soluble salt forming anion.) 제 1 항에 있어서, 양이온 4차 아민염이 하기식으로 나타내어지는 조성물.The composition according to claim 1, wherein the cationic quaternary amine salt is represented by the following formula. (상기식에서, R1은 10-22 탄소원자를 갖는 장쇄지방족 라디칼이고, R2는 저급 알킬 또는 히드록시알킬 라디칼이고, x와 y는 각각 적어도 1의 양수이며, x와 y의 합은 2-15이고, X는 수용성 염 형성 음이온임.)Wherein R 1 is a long chain aliphatic radical having 10-22 carbon atoms, R 2 is a lower alkyl or hydroxyalkyl radical, x and y are each a positive integer of at least 1, and the sum of x and y is 2-15 X is a water soluble salt forming anion.) 제 1 항에 있어서, 양이온 4차 아민염이 하기식으로 나타내어지는 조성물.The composition according to claim 1, wherein the cationic quaternary amine salt is represented by the following formula. (상기식에서, R1은 10-22 탄소원자를 갖는 장쇄지방족 라디칼이며, R는 x와 y는 각각 적어도 1의 양수이며, x+y의 합은 2-15이며, X는 수용성 염 형성 음이온임.)(Wherein R 1 is a long chain aliphatic radical having 10-22 carbon atoms, R is x and y are each a positive number of at least 1, the sum of x + y is 2-15, and X is a water-soluble salt-forming anion). ) 제 1 항에 있어서, 조성물이 액체 비이온 계면활성제 세제로 구성되는 세제조성물.The detergent composition of claim 1, wherein the composition consists of a liquid nonionic surfactant detergent. 제 1 항에 있어서, 30-50%의 액체 비이온 계면활성제 세제로 구성되는 세제조성물.2. The detergent composition of claim 1, wherein the detergent composition consists of 30-50% liquid nonionic surfactant detergent. 제 1 항에 있어서, 무기세제 증강제 염, 물때 방지제, 알칼리금속규산염, 표백제, 표백활성제, 금속이온봉쇄제, 재부착방지제, 형광증백제, 효소, 향료 및 염료로 구성되는 군에서 선택되는 하나 또는 그 이상의 세제 보조제를 포함하는 세제 조성물.According to claim 1, Inorganic detergent enhancer salt, scale inhibitor, alkali metal silicate, bleach, bleach activator, metal ion sequestrant, anti-adhesion agent, fluorescent brightener, enzymes, fragrances and dyes or one selected from A detergent composition comprising more detergent aids. 제 11 항에 있어서, 무기증강제 염이 알칼리금속 폴리인산염으로 구성되는 조성물.12. The composition of claim 11, wherein the inorganic enhancer salt consists of an alkali metal polyphosphate. 제 1 항에 있어서, 복합체내의 산 말단 비이온 계면활성제가 조성물의 중량에 기준하여 중량 1-15%를 구성하는 조성물.The composition of claim 1, wherein the acid terminal nonionic surfactant in the composite constitutes 1-15% by weight, based on the weight of the composition. 제 1 항에 있어서, 모노고급알킬트리저급알킬 4차 아민염(Ⅰ), 디-고급알킬 디-저급알킬 4차 아민염(Ⅱ), 모노-고급알킬 모노-저급알킬 디에톡실화 4차 암모늄염(Ⅲ) 및 디-고급알킬 디에톡실화 4차 암모늄염(Ⅳ)으로 구성되는 군에서 선택되는 일원인 4차 암모늄염 연화제를 복합체내에 함유하는 조성물.A mono-alkylalkyltriloweralkyl quaternary ammonium salt according to claim 1, wherein the mono-higher alkyltrilower alkyl quaternary amine salt (I), the di-higher alkyl di-loweralkyl quaternary amine salt (II) A composition containing in a complex a quaternary ammonium salt softener, which is a member selected from the group consisting of (III) and di-higher alkyl diethoxylated quaternary ammonium salts (IV). 약 10-70중량%인 양의 적어도 하나의 액체 비이온 계면활성제;At least one liquid nonionic surfactant in an amount of about 10-70% by weight; 약 0-약 60중량%인 양의, 비이온 계면활성제내에 현탁된 적어도 하나의 무기세제 증강제 염; 모노-고급알킬 트리-저급알킬 4차 암모늄염(Ⅰ), 디-고급알킬 디-저급알킬 4차 암모늄염(Ⅱ), 모노-고급알킬 모노-저급알킬 디에톡실화 4차 암모늄염(Ⅲ) 및 디-고급알킬 디에톡실화 4차 암모늄염(Ⅳ)으로 구성되는 군에서 선택되는 일원인 약 1.5-20.0중량%의 4차 암모늄염 연화제와의 거대염 복합체내의 약 1-15중량%의 산 말단 비이온 계면활성제At least one inorganic detergent enhancer salt suspended in a nonionic surfactant in an amount of about 0-about 60% by weight; Mono-higher alkyl tri-lower alkyl quaternary ammonium salts (I), di-higher alkyl di-lower alkyl quaternary ammonium salts (II), mono-higher alkyl mono-lower alkyl diethoxylated quaternary ammonium salts (III) and di- About 1-15% by weight of acid terminated nonionic surfactant in a macrosalt complex with about 1.5-20.0% by weight of a quaternary ammonium salt softener, which is a member selected from the group consisting of higher alkyl diethoxylated quaternary ammonium salts (IV) 로 구성되는, 고온 및 저온에서 유동성이고 찬 물과 혼합되었을 때 겔화하지 않는 비수성 강력 증강 세탁용 세제 조성물.A non-aqueous, strongly fortified laundry detergent composition, comprising: a fluid that is fluid at high and low temperatures and does not gel when mixed with cold water. 제 15 항에 있어서, 약 5-30중량%의 알킬렌글리콜알킬 모노-에테르 점도 조절 및 겔 방지 첨가제로 구성되는 세제 조성물.16. The detergent composition of claim 15, comprising about 5-30% by weight of alkylene glycolalkyl mono-ether viscosity control and anti-gel additives. 제 15 항에 있어서, 효소, 부식방지제, 거품방지제, 비누거품억제제, 오물 현탁 또는 재부착 방지제, 황변 방지제, 착색제, 향료, 형광증백제, 청색화제, pH 조절제, pH완충제, 표백제, 표백안정제, 표백활성제, 효소억제제 및 금속이온봉쇄제로 구성되는 군에서 선택되는 하나 또는 그 이상의 세제보조제를 임의적으로 함유하는 세제 조성물.16. The method according to claim 15, wherein the enzyme, preservative, antifoam, antifoam, antifouling or reattachment agent, anti-yellowing agent, colorant, flavoring agent, optical brightener, blue colorant, pH adjuster, pH buffer, bleach, bleach stabilizer, A detergent composition optionally containing one or more detergent adjuvants selected from the group consisting of bleach activators, enzyme inhibitors and metal ion sequestrants. 제 15 항에 있어서, 다음으로 구성되는 비수성 액체 강력 세탁용 세제 조성물.The detergent composition for non-aqueous liquid strong laundry according to claim 15, which is composed of: 산 말단 비이온 계면활성제와 양이온 4차 암모늄염 연화제의 거대염 복합체로 구성되는 세제 조성물로 세탁주기와 헹굼주기를 갖는 자동세탁기내에서 직물을 세탁하는 것에 의해, 세탁주기 동안에 거대염 복합체가 세탁액내에서 서서히 가수분해되어 직물 위에 부착되기 위한 4차 암모늄 연화제염을 서서히 방출하는 것으로 구성되는, 직물의 세탁 및 유연성 부여를 위한 방법.The detergent composition consists of a macrosulfate complex of an acid-terminated nonionic surfactant and a cationic quaternary ammonium salt softener, by washing the fabric in an automatic washing machine having a washing cycle and a rinsing cycle, so that the macrosatellite complex in the washing liquid during the washing cycle. A method for laundering and providing flexibility of a fabric, comprising slowly releasing quaternary ammonium softener salts for slow hydrolysis to adhere onto the fabric. 제 19 항에 있어서, 제 4 항의 세제 조성물로 직물을 세탁하는 것으로 구성되는, 직물의 세탁 및 유연성 부여를 위한 방법.20. The method of claim 19, consisting of washing the fabric with the detergent composition of claim 4. 제 19 항에 있어서, 제 15 항의 세제 조성물로 직물을 세탁하는 것으로 구성되는, 직물의 세탁 및 유연성 부여를 위한 방법The method of claim 19, comprising washing the fabric with the detergent composition of claim 15. 제 19 항에 있어서, 제 18 항의 세제 조성물로 직물을 세탁하는 것으로 구성되는, 직물의 세탁 및 유연성 부여를 위한 방법.The method of claim 19 consisting in washing the fabric with the detergent composition of claim 18. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR870001530A 1986-02-21 1987-02-20 Reinforced non-aqueous liquid laundry detergent composition and fabric washing method KR870008015A (en)

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US06/831,752 US4806260A (en) 1986-02-21 1986-02-21 Built nonaqueous liquid nonionic laundry detergent composition containing acid terminated nonionic surfactant and quarternary ammonium softener and method of use
US831752 1986-02-21

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AU6905587A (en) 1987-08-27
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ZA871112B (en) 1988-09-28
GR870280B (en) 1987-06-16
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IT8747666A0 (en) 1987-02-20
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ATA34987A (en) 1993-05-15
CA1275756C (en) 1990-11-06
IL81583A0 (en) 1987-09-16
DE3704903A1 (en) 1987-08-27
DK88587A (en) 1987-08-22
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EG18392A (en) 1993-07-30
DK88587D0 (en) 1987-02-20
IN167997B (en) 1991-01-19
JPS62270699A (en) 1987-11-25
NO870696L (en) 1987-08-24
IT1206806B (en) 1989-05-03
BR8700810A (en) 1987-12-15
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AU605136B2 (en) 1991-01-10
CH672498A5 (en) 1989-11-30
US4806260A (en) 1989-02-21
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SE8700644D0 (en) 1987-02-17

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