KR870006168A - Catalytic dewaxing method of at least one oil-induced lubricant base oil precursor and a lubricant base oil produced thereby - Google Patents

Catalytic dewaxing method of at least one oil-induced lubricant base oil precursor and a lubricant base oil produced thereby Download PDF

Info

Publication number
KR870006168A
KR870006168A KR860010844A KR860010844A KR870006168A KR 870006168 A KR870006168 A KR 870006168A KR 860010844 A KR860010844 A KR 860010844A KR 860010844 A KR860010844 A KR 860010844A KR 870006168 A KR870006168 A KR 870006168A
Authority
KR
South Korea
Prior art keywords
hydrogen
dewaxing
lubricant base
base oil
wax
Prior art date
Application number
KR860010844A
Other languages
Korean (ko)
Other versions
KR940008389B1 (en
Inventor
차알즈 스템 스티븐
허어만 차알즈 윈퀴스트 브루스
램지 보우엔 제임즈
Original Assignee
오노 알버어스
셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25211785&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR870006168(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 오노 알버어스, 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 filed Critical 오노 알버어스
Publication of KR870006168A publication Critical patent/KR870006168A/en
Application granted granted Critical
Publication of KR940008389B1 publication Critical patent/KR940008389B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
    • C10G73/02—Recovery of petroleum waxes from hydrocarbon oils; Dewaxing of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/14—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural parallel stages only
    • C10G65/16—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural parallel stages only including only refining steps

Abstract

내용 없음No content

Description

하나 이상의 정유-유도 윤활기제유 선구물질의 촉매적 탈랍방법 및 그에 의해 제조된 윤활기제유Catalytic dewaxing method of at least one oil-induced lubricant base oil precursor and a lubricant base oil produced thereby

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

첨부 도면은 원유 공급물질에서부터 출발하여 4개의 다른 탈랍 윤활기제유를 제조하는 예를 도시한 도면이다.The accompanying drawings show examples of producing four different dewaxed lubricant base oils starting from the crude oil feedstock.

Claims (12)

수소탈랍 조건에서 수소-함유 기체존재시에 첫번째 반응지역 내에서 직쇄파라핀으로 구성되는 첫번째 왁스를 함유하는 첫번째 정유-유도라피네이트 윤활기제유 선구물질로 구성되는 첫번째 공급스트림을 상기 첫번째 왁스의 전환에 대해 선택성인 첫번째 수소탈랍 촉매와 접촉시키고 수소탈랍 조건에서 수소-함유기체 존재시에 평행-위치한 두번째 반응지역 내에서 분지쇄 및/또는 환족탄화 수소를 함유하는 두번째 왁스를 함유하는 두번째 정유-유도 라피네이트 윤활기제유 선구물질을 상기 두번째 왁스의 전환에 대해 선택성인 두번째 수소탈랍 촉매와 접촉시키고, 하나 또는 그 이상의 또 다른 반응지역 내에서 수소탈랍 조건에서 수소-함유 기체 존재시에 또 다른 정유-유도 왁스라피네이트 윤활기제유 선구물질 공급스트림을 수소탈랍 촉매와 임의적으로 접촉시키고, 상기 반응지역들로부터 정유탈랍윤활기제유의 적어도 두 평행유출 스트림을 제거하는 것으로 구성되는, 하나 이상의 정유-유도 윤활기제유 선구물질의 촉매적 탈랍방법.In a hydrogen dewaxing condition, in the presence of hydrogen-containing gas, the first feedstream consisting of the first oil-derivated raffinate lubricant base oil precursor containing the first wax consisting of linear paraffins in the first reaction zone is subjected to the conversion of the first wax. A second refinery containing a second wax containing branched chain and / or cycloaliphatic hydrocarbons in a second reaction zone which is contacted with the first hydrogen dewaxing catalyst which is selective for the hydrogen dewaxing condition and is parallel-positioned in the presence of hydrogen-containing gas under hydrogen dewaxing conditions. Inducing raffinate lubricant base oil precursor is contacted with a second hydrogen dewaxing catalyst that is selective for the conversion of the second wax and another in the presence of a hydrogen-containing gas under hydrogen dewaxing conditions in one or more other reaction zones. The refinery-induced wax raffinate lubricant base oil feedstream is fed with a hydrogen dewaxing catalyst. And catalytically dewaxing the at least one refinery-derived lubricant base oil precursor, comprising contacting with the solely and removing at least two parallel outflow streams of the refinery dewaxing lube base oil from the reaction zones. 제1항에 있어서, 윤활기제유 선구물질 공급 스트림이 탄화수소유 공급 스트림의 대기압중류의 하부 스트림을 분액화 하는 것에 의해 얻어지는 방법.The process of claim 1, wherein the lubricant base oil feed stream is obtained by separating the bottoms stream of atmospheric midstream of the hydrocarbon oil feed stream. 제1항 또는 제2항에 있어서, 수소탈랍 조건이 150℃∼500℃의 온도, 2∼200 바아 abs.의 압력 및 350∼2670 1(S.T.P)H2/오일공급 1의 수소/오일공급비로 구성되는 방법.The hydrogen / oil supply of claim 1 or 2, wherein the hydrogen dewaxing conditions are at a temperature of 150 ° C. to 500 ° C., a pressure of 2 to 200 bar abs. And a 350 to 2670 1 (STP) H 2 / oil supply 1 The method consists of rain. 제1항 내지 제3항 중 어느 한 항에 있어서, 첫번째 왁스가 중량55% 이하의 분지쇄 및 환족탄화수소를 함유하고 두번째 왁스는 중량 55% 이상의 분지쇄 및 환족 탄화수소를 함유하는 방법.The process of claim 1, wherein the first wax contains up to 55% by weight of branched and cyclic hydrocarbons and the second wax contains at least 55% by weight of branched and cyclic hydrocarbons. 제1항 내지 제4항 중 어느 한 항에 있어서, 첫번째 수소탈랍 촉매가 주기율표의 ⅥB족, ⅦB족 및 Ⅷ족 금속으로 구성되는 군에서 선택되는 적어도 하나의 금속이 그 속에 혼입된 합성페리어라이트로 구성되는 방법.The synthetic ferrier according to any one of claims 1 to 4, wherein the first hydrogen dewaxing catalyst is at least one metal selected from the group consisting of Group VIB, Group B, and Group VIII metals of the periodic table. How light is composed. 제5항에 있어서, HVI 80~150 또는 80∼100 왁스윤활유 선구물질로 구성되는 첫번째 공급스트림이 후속 수소처리가 없이 윤활기 제유가 얻어지는 첫번째 반응지역 내에서 수소탈랍되는 방법.6. The process according to claim 5, wherein the first feedstream consisting of HVI 80-150 or 80-100 wax lubricating oil precursors is hydrodesorbed in the first reaction zone from which lubricant lubrication is obtained without subsequent hydrotreating. 제1항 내지 제6항중 어느 한 항에 있어서, 두번째 수소탈랍 촉매가 0.5∼0.9㎚의 공극크기와 하기와 같은 몰비조성을 갖는 결정질 알루미노실리케이트로 구성되는 방법:The process according to claim 1, wherein the second hydrogen dewaxing catalyst consists of crystalline aluminosilicate having a pore size of 0.5 to 0.9 nm and a molar ratio composition as follows: 0.9±0.2M2/nO:AL2O3:5∼100SiO2:C-40H2O0.9 ± 0.2M 2 / n O: AL 2 O 3 : 5-100SiO 2 : C-40H 2 O 여기에서 M은 양이온이고, n은 상기 양이온의 원자가임.Where M is a cation and n is the valence of the cation. 제1항 내지 제7항중 어느 한 항에 있어서, 적어도 셋, 바람직하게는 넷 또는 그 이상의 평행-위치한 촉매적 수소탈랍 지역으로 구성되는 방법.8. Process according to any one of the preceding claims, which consists of at least three, preferably four or more parallel-located catalytic hydrogen dewaxing zones. 제1항 내지 제8항중 어느 한 항에 있어서, 각 수소탈랍촉매는 371℃∼566℃ 온도에서 산소-함유기체 존재시에 다른 탈랍반응지역(들) 내에서 탈랍조작(들)에 무관하게 재생되는 방법.9. The hydrogen dewaxing catalyst according to any one of claims 1 to 8, wherein each hydrogen dewaxing catalyst is independent of the dewaxing operation (s) in other dewaxing reaction zone (s) in the presence of oxygen-containing gas at a temperature of 371 ° C to 566 ° C. How to play. 제9항에 있어서, 상기 재생에 이어서 재생된 촉매의 불활성기체정화와 343℃∼538℃ 온도에서 수소-함유기체 존재시의 후속재활성화가 따르는 방법.10. The process according to claim 9, wherein said regeneration is followed by inert gas purification of the regenerated catalyst and subsequent reactivation in the presence of hydrogen-containing gas at temperatures between 343 ° C and 538 ° C. 제1항 내지 제10항 중 어느 한 항에 있어서, 적어도 둘의 탈랍윤활기제유가 혼합되어 적어도 하나의 윤활유 생성물을 배합하는 방법.The method of claim 1, wherein at least two dewaxing lubricant base oils are mixed to blend the at least one lubricant product. 제1항 내지 제11항 중 어느 한 항에 따르는 방법으로 제조된 촉매적으로 탈랍된 윤활기제유.A catalytically dewaxed lubricant base oil prepared by the process according to any one of claims 1 to 11. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019860010844A 1985-12-24 1986-12-17 Process for catalytic dewaxing of more than one refinery-derived lubricating base oil precursor KR940008389B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US81321485A 1985-12-24 1985-12-24
US813,214 1985-12-24

Publications (2)

Publication Number Publication Date
KR870006168A true KR870006168A (en) 1987-07-09
KR940008389B1 KR940008389B1 (en) 1994-09-14

Family

ID=25211785

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019860010844A KR940008389B1 (en) 1985-12-24 1986-12-17 Process for catalytic dewaxing of more than one refinery-derived lubricating base oil precursor

Country Status (11)

Country Link
EP (1) EP0237655B1 (en)
JP (1) JPS62190286A (en)
KR (1) KR940008389B1 (en)
CN (1) CN1016249B (en)
AU (1) AU592137B2 (en)
BR (1) BR8606234A (en)
CA (1) CA1282363C (en)
DE (1) DE3685578T2 (en)
ES (1) ES2031820T3 (en)
IN (1) IN168775B (en)
SG (1) SG44393G (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR970074901A (en) * 1996-05-14 1997-12-10 조규향 How to manufacture fuel oil and lubricating oil using untreated oil

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0161833B1 (en) * 1984-05-03 1994-08-03 Mobil Oil Corporation Catalytic dewaxing of light and heavy oils in dual parallel reactors
US5378348A (en) * 1993-07-22 1995-01-03 Exxon Research And Engineering Company Distillate fuel production from Fischer-Tropsch wax
US5833837A (en) * 1995-09-29 1998-11-10 Chevron U.S.A. Inc. Process for dewaxing heavy and light fractions of lube base oil with zeolite and sapo containing catalysts
WO2002064711A1 (en) 2001-02-13 2002-08-22 Shell Internationale Research Maatschappij B.V. Lubricant composition
MY139353A (en) 2001-03-05 2009-09-30 Shell Int Research Process to prepare a lubricating base oil and a gas oil
MY137259A (en) 2001-03-05 2009-01-30 Shell Int Research Process to prepare a lubricating base oil and a gas oil.
AR032941A1 (en) * 2001-03-05 2003-12-03 Shell Int Research A PROCEDURE TO PREPARE A LUBRICATING BASE OIL AND BASE OIL OBTAINED, WITH ITS VARIOUS USES
WO2004007647A1 (en) 2002-07-12 2004-01-22 Shell Internationale Research Maatschappij B.V. Process to prepare a heavy and a light lubricating base oil
JP4629435B2 (en) 2002-07-18 2011-02-09 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ Process for producing microcrystalline wax and middle distillate fuel
JP5221999B2 (en) * 2008-03-31 2013-06-26 Ｊｘ日鉱日石エネルギー株式会社 Method for producing lubricating base oil
US20160168490A1 (en) * 2013-07-15 2016-06-16 Shell Oil Company Process to prepare two or more base oils
WO2015007691A1 (en) * 2013-07-15 2015-01-22 Shell Internationale Research Maatschappij B.V. Process to prepare two or more base oils
US9796936B2 (en) 2015-09-09 2017-10-24 Chevron U.S.A. Inc. Production of heavy API group II base oil

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4211635A (en) * 1979-04-23 1980-07-08 Mobil Oil Corporation Catalytic conversion of hydrocarbons
JPS57100190A (en) * 1980-12-09 1982-06-22 Mobil Oil Corp Lube base stock and manufacture of slate thereof
CA1188247A (en) * 1981-04-02 1985-06-04 Nai Y. Chen Process for making naphthenic lubestocks from raw distillate by combination hydrodewaxing/hydrogenation
US4400265A (en) * 1982-04-01 1983-08-23 Mobil Oil Corporation Cascade catalytic dewaxing/hydrodewaxing process
EP0161833B1 (en) * 1984-05-03 1994-08-03 Mobil Oil Corporation Catalytic dewaxing of light and heavy oils in dual parallel reactors

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR970074901A (en) * 1996-05-14 1997-12-10 조규향 How to manufacture fuel oil and lubricating oil using untreated oil

Also Published As

Publication number Publication date
SG44393G (en) 1993-06-25
AU592137B2 (en) 1990-01-04
DE3685578D1 (en) 1992-07-09
IN168775B (en) 1991-06-01
CA1282363C (en) 1991-04-02
EP0237655A1 (en) 1987-09-23
AU6663986A (en) 1987-06-25
EP0237655B1 (en) 1992-06-03
BR8606234A (en) 1987-09-29
CN1016249B (en) 1992-04-15
DE3685578T2 (en) 1993-01-21
ES2031820T3 (en) 1993-01-01
CN86108258A (en) 1987-10-28
JPS62190286A (en) 1987-08-20
KR940008389B1 (en) 1994-09-14

Similar Documents

Publication Publication Date Title
KR870006168A (en) Catalytic dewaxing method of at least one oil-induced lubricant base oil precursor and a lubricant base oil produced thereby
US6179994B1 (en) Isoparaffinic base stocks by dewaxing fischer-tropsch wax hydroisomerate over Pt/H-mordenite
US4579986A (en) Process for the preparation of hydrocarbons
US6420618B1 (en) Premium synthetic lubricant base stock (Law734) having at least 95% noncyclic isoparaffins
US4423265A (en) Process for snygas conversions to liquid hydrocarbon products
BR9910219A (en) Process for selective production of c2 to c4 olefins
KR920703763A (en) Reforming Method of Petroleum Hydrocarbon Raw Materials
US4471145A (en) Process for syngas conversions to liquid hydrocarbon products utilizing zeolite Beta
WO2002004575A3 (en) Process and apparatus for the production of diesel fuels by oligomerisation of olefinic feed streams
BR9910216A (en) Process for selectively producing olefins c3 a naphtha feed stream in a process unit
JP2534036B2 (en) Hydrocarbon manufacturing method
CN1688674A (en) Heavy lube oil from fischer-tropsch wax
CA1241667A (en) Process for the preparation of hydrocarbons
JPH06510556A (en) Contact dewaxing method
JPH01258629A (en) Production of hydrocarbonaceous product liquid in normal state from hydrocarbon supply raw material containing linear olefin and branched olefin
US2573726A (en) Catalytic desulphurisation of naphthas
US2858348A (en) Process for making naphthalene
US3788972A (en) Process for the manufacture of lubricating oils by hydrocracking
US2697682A (en) Catalytic desulfurization of petroleum hydrocarbons
JP3469625B2 (en) Method for producing high octane gasoline
US4240900A (en) Process for the hydrogenation of olefins and aromatic compounds
US9162943B2 (en) Method of converting a coal to chemicals
EP0152652A1 (en) Catalyst activation
US3600298A (en) Process for producing hydrogenated alkyl tars
GB1469345A (en) Catalytic dewaxing gas oils and other selective cracking

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
NORF Unpaid initial registration fee