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C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F8/00—Chemical modification by after-treatment
Abstract
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Description
제거공정에 의한 중합체의 제조방법Manufacturing method of polymer by removal process
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.
Claims (10)
중합체 줄기의 5,6환 위치에 탄산염 그룹을 함유하는 사이클로헥스-2-에닐렌 환을 가지는 중합체를 포함하는 중합조성물을 적당한 유기아민으로 처리하여 탄산염이 상기의 모든 사이클로헥센일렌 환으로부터 제거되는 것으로 구성된 중합체 줄기에 방향쪽 환을 가지는 중합체의 제조방법.The polymerization composition comprising a polymer having a cyclohex-2-enylene ring containing a carbonate group at the 5,6 ring position of the polymer stem was treated with a suitable organic amine to remove the carbonate from all of the cyclohexenylene rings. A process for producing a polymer having an aromatic ring in a constructed polymer stem.제 1항에 있어서, 중합체 줄기에 사이클로헥스-2-에닐렌을 가지는 중합체는 다음 일반식으로 표현되는 구조를 가지는 것으로된 중합체 제조방법 :The method according to claim 1, wherein the polymer having cyclohex-2-enylene in the polymer stem has a structure represented by the following general formula:제 2항에 있어 그 줄기에 사이클로헥스-2-에닐렌 환을 가지는 중합체는 다음 일반식의 구조를 가진다는 중합체의 제조방법.The method for producing a polymer according to claim 2, wherein the polymer having a cyclohex-2-enylene ring in its stem has a structure of the following general formula.제 3항에 있어 R2는 4개 까지의 탄소원자를 가지는 알킬그룹인 제조방법.The process according to claim 3, wherein R 2 is an alkyl group having up to 4 carbon atoms.제 1항에 있어 유기아민은 3차 아민인 제조방법.The method of claim 1 wherein the organic amine is a tertiary amine.제 1항에 있어 아민은 대기압에서 200℃-600℃ 범위의 끓는 점을 갖는 제조방법.The process of claim 1 wherein the amine has a boiling point in the range of 200 ° C.-600 ° C. at atmospheric pressure.제 1항에 있어 제조공정은 100℃-300℃의 범위에서 시행되는 제조방법.The method of claim 1 wherein the manufacturing process is carried out in the range of 100 ℃ -300 ℃.제 1항에 있어 반응 혼합물 내의 아민 농도는 0.1-5몰%사이인 제조방법.The process of claim 1 wherein the amine concentration in the reaction mixture is between 0.1-5 mole percent.제 1항에 있어 중합 조성물은 필름, 코팅 또는 섬유형태인 제조방법.The method of claim 1 wherein the polymeric composition is in the form of a film, coating or fiber.제 1항에 있어 중합조성물은 중합혼합물을 포함하는 제조방법.The method of claim 1 wherein the polymerization composition comprises a polymerization mixture.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019830004660A1982-10-041983-09-30Process for the preparation of polymer having aromatic ring in main chain
KR910008289B1
(en)