KR840004703A - Method for producing aromatic alkanes derivatives - Google Patents

Method for producing aromatic alkanes derivatives Download PDF

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KR840004703A
KR840004703A KR1019830002180A KR830002180A KR840004703A KR 840004703 A KR840004703 A KR 840004703A KR 1019830002180 A KR1019830002180 A KR 1019830002180A KR 830002180 A KR830002180 A KR 830002180A KR 840004703 A KR840004703 A KR 840004703A
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general formula
following general
group
represented
methyl
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KR870001463B1 (en
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기요시(외 5) 나까따니
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시로 요시오까
미쓰이도오아쓰가가꾸 가부시기 가이샤
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Abstract

내용 없음No content

Description

방향족 알칸 유도체의 제조방법Method for producing aromatic alkanes derivatives

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (3)

하기 일반식(Ⅶ)로 표시되는 케톤과Ketone represented by the following general formula (Ⅶ) and (상기 식에서. Ar,R1및 R2는 하기 일반식(Ⅰ)에서 정의하였다.)(Wherein Ar, R 1 and R 2 are defined in the following general formula (I).) 하기 일반식(Ⅷ)로 표시되는 알데히드와의 반응으로By reaction with an aldehyde represented by the following general formula R12CHO (Ⅷ)R 12 CHO (Ⅷ) (상기 식에서, R12는 하기 일반식(Ⅰ)에서 정의하였다.)(In the above formula, R 12 is defined in the following general formula (I).) 하기 일반식(Ⅸ)로 표시되는 α,β-불포화된 카르보닐 화합물의 제조 및Preparation of α, β-unsaturated carbonyl compound represented by the following general formula (VII), and (상기 식에서, Ar,R1,R2및 R12는 하기 일반식(Ⅰ)에서 정의하였다.)(In the above formula, Ar, R 1 , R 2 and R 12 are defined by the following general formula (I).) 제조된 케톤(Ⅸ)를 환원하는 것을 특징으로 하는 하기 일반식(Ⅰ)로 표시되는 방향족 알칸 유도체의 제조방법.A method for producing an aromatic alkane derivative represented by the following general formula (I), wherein the produced ketone is reduced. (상기 식에서, Ar은 치환되거나 미치환된 페닐 또는 나프틸기, R1은 메틸, 에틸 또는 이소프로필기, R2는 수소원자 또는 메틸기, 또는 R1및 R2는 그들이 붙어 있는 탄소원자와 더불어 치환된 또는 미치환된 시클로알킬기, R3는 R12CH2-기를 나타내고, R12는 피레쓰로이드계의 합성에 R12CH2OH의 형태로 보통 사용되는 알콜의 기본적인 기를 나타낸다.Wherein Ar is a substituted or unsubstituted phenyl or naphthyl group, R 1 is methyl, ethyl or isopropyl group, R 2 is a hydrogen atom or a methyl group, or R 1 and R 2 are substituted together with the carbon atom to which they are attached An unsubstituted or unsubstituted cycloalkyl group, R 3 represents a R 12 CH 2 -group, and R 12 represents a basic group of an alcohol normally used in the form of R 12 CH 2 OH for synthesis of pyrethroid systems. 하기 일반식(Ⅹ)로 표시되는 알데히드와Aldehyde represented by the following general formula (Ⅹ) and (상기 식에서, Ar,R1및 R2는 하기 일반식(Ⅰ)에서 정의하였다.)(In the above formula, Ar, R 1 and R 2 are defined in the following general formula (I).) 하기 일반식(ⅩⅠ)로 표시되는 케톤과의 반응으로By reaction with ketone represented by the following general formula (XI) (상기 식에서, R12는 하기 일반식(Ⅰ)에서 정의하였다.)(In the above formula, R 12 is defined in the following general formula (I).) 하기 일반식(ⅩⅡ)로 표시되는 α,β-불포화된 카르보닐 화합물의 제조 및Preparation of α, β-unsaturated carbonyl compound represented by the following general formula (XII), and (상기 식에서, Ar,R1,R2및 R12는 하기 일반식(Ⅰ)에서 정의하였다.(In the above formula, Ar, R 1 , R 2 and R 12 are defined by the following general formula (I). 제조된 α,β-불포화된 카르보닐 화합물(ⅩⅡ)를 환원하는 것을 특징으로 하는 일반식(Ⅰ)로 표시되는 방향족 알칸 유도체의 제조방법.A method for producing an aromatic alkane derivative represented by the general formula (I), wherein the produced α, β-unsaturated carbonyl compound (XII) is reduced. (상기 식에서, Ar은 치환되거나 미치환된 페닐 또는 나프틸기, R1은 메틸, 에틸 또는 이소프로필기, R2는 수소원자 또는 메틸기, 또는 R1및 R2는 그들이 붙어 있는 탄소원자와 더불어 치환된 또는 미치환된 시클로알킬기, R3는 R12CH2-기를 나타내고, R12는 피레쓰로이드계의 합성에 R12CH2OH의 형태로 보통 사용되는 알콜의 기본적인 기를 나타낸다.)Wherein Ar is a substituted or unsubstituted phenyl or naphthyl group, R 1 is methyl, ethyl or isopropyl group, R 2 is a hydrogen atom or a methyl group, or R 1 and R 2 are substituted together with the carbon atom to which they are attached An unsubstituted or unsubstituted cycloalkyl group, R 3 represents a R 12 CH 2 -group, and R 12 represents a basic group of an alcohol normally used in the form of R 12 CH 2 OH for synthesis of pyrethroids.) 하기 일반식(ⅩⅢ)로 표시되는 알데히드와An aldehyde represented by the following general formula (XIII) (상기 식에서, Ar,R1및 R2, R12및 R3는 하기 일반식(Ⅰ)에서 정의하였다.(In the above formula, Ar, R 1 and R 2 , R 12 and R 3 are defined in the following general formula (I). 하기 일반식(ⅩⅣ) 또는 (ⅩⅤ)로 표시되는 화합물과의 반응으로By reaction with a compound represented by the following general formula (VII) or (VIIV) (상기 식에서, R3는 하기 일반식(Ⅰ)에서 정의하였고, R12은 피레쓰로이드계의 합성에 R12CH2OH의 형태로 보통 사용되는 알콜의 기본적인 기이고, R13은 알킬 또는 페닐기이고, R14는 알킬기를 나타낸다.)Wherein R 3 is defined in the following general formula (I), R 12 is a basic group of alcohol commonly used in the form of R 12 CH 2 OH for synthesis of pyrethroids, and R 13 is an alkyl or phenyl group And R 14 represents an alkyl group.) 하기 일반식(ⅩⅥ) 또는 (ⅩⅦ)로 표시되는 올레핀의 제조 및Preparation of an olefin represented by the following general formula (VII) or (iii) (상기 식에서, Ar,R1,R2,R12및 R3는 하기 일반식(Ⅰ)에서 정의하였다.(In the above formula, Ar, R 1 , R 2 , R 12 and R 3 are defined in the following general formula (I). 제조된 올레핀(ⅩⅥ) 또는 (ⅩⅦ)을 환원하는 것을 특징으로 하는 하기 일반식(Ⅰ)로 표시되는 방향족 알칸 유도체의 제조방법.A method for producing an aromatic alkane derivative represented by the following general formula (I), wherein the produced olefin (VI) or (iii) is reduced. (상기 식에서, Ar은 치환되거나 미치환된 페닐 또는 나프틸기, R1은 메틸, 에틸 또는 이소프로필기,R2는 수소원자 또는 메틸기, 또는 R1및 R2는 그들이 붙어 있는 탄소원자와 더불어 치환된 또는 미치환된 시클로알킬기, R3는 R12CH2-기를 나타내고, R12는 피레쓰로이드계의 합성에 R12CH2OH의 형태로 보통사용되는 알콜의 기본적인 기를 나타낸다.)Wherein Ar is a substituted or unsubstituted phenyl or naphthyl group, R 1 is methyl, ethyl or isopropyl group, R 2 is a hydrogen atom or a methyl group, or R 1 and R 2 are substituted together with the carbon atom to which they are attached Or an unsubstituted cycloalkyl group, R 3 represents a R 12 CH 2 -group, and R 12 represents a basic group of an alcohol commonly used in the form of R 12 CH 2 OH for synthesis of pyrethroids.) ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
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