KR840002825A - Method for preparing aminosulfonyl urea derivative - Google Patents

Method for preparing aminosulfonyl urea derivative Download PDF

Info

Publication number
KR840002825A
KR840002825A KR1019820005396A KR820005396A KR840002825A KR 840002825 A KR840002825 A KR 840002825A KR 1019820005396 A KR1019820005396 A KR 1019820005396A KR 820005396 A KR820005396 A KR 820005396A KR 840002825 A KR840002825 A KR 840002825A
Authority
KR
South Korea
Prior art keywords
carbon atoms
formula
compound
alkyl
urea
Prior art date
Application number
KR1019820005396A
Other languages
Korean (ko)
Inventor
트루에브 베르너
Original Assignee
진크라머, 한스 루돌프 하우스
산도즈 리미티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 진크라머, 한스 루돌프 하우스, 산도즈 리미티드 filed Critical 진크라머, 한스 루돌프 하우스
Publication of KR840002825A publication Critical patent/KR840002825A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/06—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/32—One oxygen, sulfur or nitrogen atom
    • C07D239/42—One nitrogen atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/14—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
    • C07D251/16—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to only one ring carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C07D251/48—Two nitrogen atoms
    • C07D251/50—Two nitrogen atoms with a halogen atom attached to the third ring carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/22—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with hetero atoms directly attached to ring nitrogen atoms
    • C07D295/26—Sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

내용 없음No content

Description

아미노설포닐 우레아 유도체의 제조방법Method for preparing aminosulfonyl urea derivative

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (2)

a) 적절한 이소시아네트 또는 카바메이트, 또는 이의 반응성 유도체를 상응하는 아민과 우레아 축합함으로써 1-디아지닐- 및 1-트리아지닐-3-아미노-설포닐 우레아를 수득하고,a) 1-diazinyl- and 1-triazinyl-3-amino-sulfonyl urea are obtained by urea-condensing the appropriate isocyanates or carbamates or reactive derivatives thereof with the corresponding amines, b) 적절한 클로로설포닐 우레아를 상응하는 아민과 반응시킴으로써 1-디아지닐-및 1-트리아지닐-3-아미노설포닐 우레아를 수득하고b) 1-diazinyl- and 1-triazinyl-3-aminosulfonyl urea are obtained by reacting the appropriate chlorosulfonyl urea with the corresponding amine and c) 적절한 N-아미노설포닐 카본이미드산 또는 디티오산 또는 이와 같은 산의 에스테르를 상응하는 아민과 반응시킴으로써 1-디아지닐-및 1-트리아지닐-2-알킬-3-아미노설포닐 이소우레아 및 이소티오우레아를 수득하고,c) 1-diazinyl- and 1-triazinyl-2-alkyl-3-aminosulfonyl isourea by reacting an appropriate N-aminosulfonyl carbonimide acid or dithio acid or ester of such acid with the corresponding amine And isothiourea, d) 상응하는 이소티오우레아를 산화시킴으로써 1-미아지닐-및 1-트리아지닐-3-아미노설포닐 우레아를 수득함을 특징으로 하는, 1-디아지닐-또는 1-트리아지닐-3-아미노설포닐 우레아, 1-디아지닐-또는 1-트리아지닐-2-알킬-3-아미노설포닐 이소우레아 및 이의 상응하는 이소티오우레아의 그룹에 속하는 신규 아미노설포닐 우레아 유도체의 제조방법.d) 1-diazinyl- or 1-triazinyl-3-aminosul, characterized in that 1-miazinyl- and 1-triazinyl-3-aminosulfonyl urea are obtained by oxidizing the corresponding isothiourea. A process for the preparation of novel aminosulfonyl urea derivatives belonging to the group of phonyl urea, 1-diazinyl- or 1-triazinyl-2-alkyl-3-aminosulfonyl isourea and their corresponding isothioureas. 제1항에 있어서, a) 우레아 축합반응 조건하에서 다음 일반식(Ⅱ)의 화합물을 다음 일반식(Ⅱ)의 화합물과 반응시킴으로써 다음 일반식(Ⅰa)의 화합물을 수득하거나(단, 일반식(Ⅱ)의 화합물 또는 일반식(Ⅱ)의 화합물은 반응성 카밤산 또는 이소시아네이트이다), 또는The compound according to claim 1, wherein a) a compound of the following general formula (II) is reacted with a compound of the following general formula (II) under urea condensation reaction conditions to obtain a compound of the general formula (Ia) The compound of formula (II) or a compound of formula (II) is a reactive carbamic acid or isocyanate), or b) 다음 일반식(Ⅳ)의 화합물을 다음 일반식(Ⅴ)의 아민과 반응시킴으로써 다음 일반식(Ⅰb)의 화합물을 수득하거나, 또는b) reacting a compound of formula (IV) with a amine of formula (V) to obtain a compound of formula (Ib) c) 다음 일반식(Ⅵ)의 화합물을 다음 일반식(Ⅶ)의 화합물과 반응시킴으로써 다음 일반식(Ⅰc)의 화합물을 수득하고,c) reacting a compound of formula (VI) with a compound of formula (VII) to obtain a compound of formula (Ic) d) 다음 일반식(Ⅰd)의 화합물을 산화시키으로써 다음 일반식(Ⅰb)의 화합물을 수득함을 특징으로 하는 다음 일반식(Ⅰ)화합물의 제조방법.d) A process for the preparation of the following compound of formula (I), wherein the compound of formula (Ib) is obtained by oxidizing the compound of formula (Id). 상기식에서In the above formula R1및 R2는 독립적으로 H, CN, 탄소수 1 내지 6의 알콕시-CO 또는 탄소수 1 내지 6의 알킬, 탄소수 2 내지 6의 알케닐, 탄소수 2 내지 6의 알키닐, 탄소수 3 내지 7의 사이클로알킬 또는 페닐로 이루어진 그룹으로 부터 선택한 비치환된 또는 치환된 하이드로-카빌이거나, 또는R 1 and R 2 are independently H, CN, alkoxy-CO of 1 to 6 carbon atoms or alkyl of 1 to 6 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkynyl of 2 to 6 carbon atoms, cyclo of 3 to 7 carbon atoms Unsubstituted or substituted hydro-carbyl selected from the group consisting of alkyl or phenyl, or R1및 R2는 결합된 질소와 함께 포화된 5-내지 7-원 복소환을 형성하고,R 1 and R 2 together with the bound nitrogen form a saturated 5- to 7-membered heterocycle, X는 일반식 NR3-CO-NR4R5의 그룹 G1또는 일반식 N=C(AR6)-NR4R5의 그룹 G2이며,X is a group of general formula NR 3 or G 1 of the formula -CO-NR 4 R 5 N = C (AR 6) in the group G 2 -NR 4 R 5, R3는 H 또는 탄소수 1 내지 5의 알킬이고,R 3 is H or alkyl of 1 to 5 carbon atoms, R4는 4-R7-6-R8-피리미딘-2-일, 2-R7-6-R8-리리미딘|4-일, 4-R7-6-R8-1,3,5-트리아진-2-일 또는 5-R7-6-R8-1,3,4-트리아진-2-일이며,R 4 is 4-R 7 -6-R 8 -pyrimidin-2-yl, 2-R 7 -6-R 8 -ririmidin | 4-yl, 4-R 7 -6-R 8 -1, 3,5-triazin-2-yl or 5-R 7 -6-R 8 -1,3,4-triazin-2-yl, R5는 H 또는 탄소수 1 내지 5의 알킬이고,R 5 is H or alkyl of 1 to 5 carbon atoms, R6는 H 또는 탄소수 1 내지 5의 알킬이며,R 6 is H or alkyl of 1 to 5 carbon atoms, R7및 R8는 독립적으로 H, 할로겐, 탄소수 1 내지 5의 알킬, 탄소수 1 내지 5의 할로알킬, 탄소수 1 내지 5의 알콕시, 탄소수 1 내지 5의 알킬티오, 탄소수 1 내지 5의 알콕시-탄소수 1 내지 5의 알킬, NH2, 탄소수 1 내지 5의 알킬-NH 또는 디(탄소수 1 내지 5의 알킬) N이고,R 7 and R 8 are independently H, halogen, alkyl of 1 to 5 carbon atoms, haloalkyl of 1 to 5 carbon atoms, alkoxy of 1 to 5 carbon atoms, alkylthio of 1 to 5 carbon atoms, alkoxy-carbon number of 1 to 5 carbon atoms Alkyl of 1 to 5, NH 2 , alkyl-NH of 1 to 5 carbon atoms or di (alkyl of 1 to 5 carbon atoms) N, A는 0 또는 S이며,A is 0 or S, R9가 H 또는 탄소수 1 내지 5의 알킬이고,R 9 is H or alkyl of 1 to 5 carbon atoms, X1이 H 또는 COOH의 기능적 반응성 유도체를 함유하는 카보닐이거나, 또는X 1 is carbonyl containing a functional reactive derivative of H or COOH, or R9및 X1은 함께 C=O 이며,R 9 and X 1 together are C═O, R9' 및 X1'은 각각 R9및 X1과 같다.R 9 ′ and X 1 ′ are the same as R 9 and X 1 , respectively. ※참고사항:최초출원 내용에 의하여 공개하는 것임.※ Note: This is to be disclosed based on the first application.
KR1019820005396A 1981-12-03 1982-12-01 Method for preparing aminosulfonyl urea derivative KR840002825A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH8136459 1981-12-03
GB8136459 1981-12-03

Publications (1)

Publication Number Publication Date
KR840002825A true KR840002825A (en) 1984-07-21

Family

ID=10526349

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019820005396A KR840002825A (en) 1981-12-03 1982-12-01 Method for preparing aminosulfonyl urea derivative

Country Status (12)

Country Link
JP (1) JPS58103371A (en)
KR (1) KR840002825A (en)
AU (1) AU9105582A (en)
BE (1) BE895168A (en)
BR (1) BR8207015A (en)
DE (1) DE3243533A1 (en)
DK (1) DK536182A (en)
ES (1) ES517857A1 (en)
FR (1) FR2517675A1 (en)
IL (1) IL67391A0 (en)
IT (1) IT1189428B (en)
NL (1) NL8204635A (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4448959A (en) * 1981-10-19 1984-05-15 Ciba-Geigy Corporation Chlorosulfonyl urea triazines
CH649081A5 (en) * 1982-01-12 1985-04-30 Ciba Geigy Ag TRIAZA CONNECTIONS.
US4521597A (en) * 1982-10-25 1985-06-04 Ciba Geigy Corporation Process for producing sulfonylureas having a herbicidal action
DE3517821A1 (en) * 1984-08-30 1986-03-13 Bayer Ag, 5090 Leverkusen SULFONYLGUANIDINOTRIAZINE DERIVATIVES
DE3517842A1 (en) * 1984-08-30 1986-03-13 Bayer Ag, 5090 Leverkusen SULFONYLGUANIDINOPYRIMIDINE DERIVATIVES
DE3324802A1 (en) * 1983-07-09 1985-01-17 Hoechst Ag, 6230 Frankfurt NEW N-ALKOXY AND N-ALKYLSULFONYLAMINOSULFONYL UREAS, AND NEW (PYRIMIDO) TRIAZINO-THIADIAZINOXIDES AS PRE-PRODUCTS
DE3519091A1 (en) * 1984-08-30 1986-03-13 Bayer Ag, 5090 Leverkusen UNBALANCED SULFONYL GUANIDINE
DE3517844A1 (en) * 1984-08-30 1986-03-13 Bayer Ag, 5090 Leverkusen SULFONYLISO (THIO) UREA DERIVATIVES
DE59007677D1 (en) * 1989-07-19 1994-12-15 Hoechst Schering Agrevo Gmbh Heterocyclically substituted sulfonylureas, processes for their preparation and their use as herbicides or plant growth regulators.
EP0507093B1 (en) * 1991-03-07 1996-06-19 Hoechst Schering AgrEvo GmbH Process for the preparation of sulfonylureas
EP0592676B1 (en) * 1991-06-28 1998-09-30 Nissan Chemical Industries, Limited Iminosulfonylurea derivative and herbicide
DE4302701A1 (en) * 1993-02-01 1994-08-04 Bayer Ag Arylaminosulfonylureas
DE4302702A1 (en) * 1993-02-01 1994-08-04 Bayer Ag Arylaminosulfonylureas
DE4337847A1 (en) * 1993-11-05 1995-05-11 Bayer Ag Substituted phenylaminosulphonylureas
DE4414840A1 (en) * 1994-04-28 1995-11-02 Bayer Ag Substituted phenylaminosulfonylureas
DE19707580A1 (en) * 1997-02-26 1998-08-27 Bayer Ag Phenylaminosulfonylurea derivatives

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2806M (en) * 1961-02-09 1964-09-28 Pfizer & Co C N, n-disubstituted sulfamylureas.
US4191553A (en) * 1978-03-02 1980-03-04 E. I. Du Pont De Nemours And Company Herbicidal sulfamates
BR8102529A (en) * 1980-04-29 1982-01-05 Du Pont COMPOUNDS AND COMPOSITIONS HERBICIDES OR SUITABLE FOR THE CONTROL OF THE UNDESIRABLE VEGETATION GROWTH AND ITS PREPARATION PROCESSES; PROCESS FOR THE CONTROL OF THE UNDESIRABLE VEGETATION GROWTH
CH649081A5 (en) * 1982-01-12 1985-04-30 Ciba Geigy Ag TRIAZA CONNECTIONS.

Also Published As

Publication number Publication date
AU9105582A (en) 1983-06-09
ES517857A1 (en) 1984-01-16
BR8207015A (en) 1983-10-11
IL67391A0 (en) 1983-05-15
FR2517675A1 (en) 1983-06-10
DE3243533A1 (en) 1983-06-09
NL8204635A (en) 1983-07-01
JPS58103371A (en) 1983-06-20
DK536182A (en) 1983-06-04
BE895168A (en) 1983-05-30
IT8249592A0 (en) 1982-11-30
IT1189428B (en) 1988-02-04

Similar Documents

Publication Publication Date Title
KR840002825A (en) Method for preparing aminosulfonyl urea derivative
KR840006638A (en) Method for preparing amine derivative
KR860003243A (en) Process for preparing tazolidinedione derivatives
KR860008129A (en) Method for preparing benzoyl urea compound
KR840003242A (en) Method for preparing N-arylsulfonyl-N&#39;-pyrimidinyl urea
GB1290729A (en)
KR890005111A (en) Amidino tricycle derivative
KR860000243A (en) Method for preparing amine derivative
KR840007882A (en) Dihydropyridine derivatives and their preparation
KR860000248A (en) Method for preparing N-acyl acidic amino acid diamide derivative
KR850001907A (en) Insecticidal compounds and methods of making the compositions
HUT48882A (en) Process for producing sulfonyl urea derivatives
KR860008993A (en) Method for preparing -O-carbomethoxysulfonylurea
KR840004089A (en) Method for preparing guanidino heterocyclic phenylamidine
KR870007142A (en) Method for preparing bicyclic compound
KR840000481A (en) Method for preparing herbicidal compound derived from phenoxybenzoic acid
KR870011103A (en) Manufacturing method of cyclic rain lea
KR830010073A (en) Method for preparing 1,4-dihydropyridine derivative
KR870000290A (en) Process for preparing substituted urea
KR830010057A (en) Process for preparing NN- (arylthioalkyl) -N &#39;-(aminoalkyl) urea
AU2069892A (en) Process for the preparation of pure n,n&#39;-asymmetrically substituted phenylureas
KR920002577A (en) Insecticidal heterocyclic compounds, methods for preparing the same, pesticide compositions composed thereof, intermediate compounds for preparing the same, and methods for preparing the same
EP0249136A3 (en) Process for producing cyclic ureas
KR860000295A (en) Method for preparing oxycam derivative
KR880001672A (en) Method for preparing cefem derivatives