KR830010134A - Process for preparing electroactive polymer - Google Patents

Process for preparing electroactive polymer Download PDF

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KR830010134A
KR830010134A KR1019820002136A KR820002136A KR830010134A KR 830010134 A KR830010134 A KR 830010134A KR 1019820002136 A KR1019820002136 A KR 1019820002136A KR 820002136 A KR820002136 A KR 820002136A KR 830010134 A KR830010134 A KR 830010134A
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electroactive polymer
substituted
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quinoline
producing
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에스. 파필 요람
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제이. 에이. 부캐넌, 쥬니어
셰브런 리써취 캄파니
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Priority claimed from US06/370,231 external-priority patent/US4519937A/en
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Publication of KR830010134A publication Critical patent/KR830010134A/en

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Abstract

내용 없음No content

Description

전기활성 중합체의 제조방법Process for preparing electroactive polymer

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (56)

융합되고 질소원자를 함유한 불포화 헤테로사이클의 반복단위를 갖는 중합체를 불활성대기나 불활성 용매내에서 알카리금속 나프타리드와 알카리금속 안트라시니드로 구성된 그룹에서 선택된 전도성 병형제인 도판트와 반응시켜 충전된 중합체 골격과 충전보상 이온성 도판트가 이 중합체 골격에 결합된 전기활성 중합체를 제조하는 방법.The polymer is charged by reacting a polymer having repeating units of unsaturated heterocycle containing nitrogen atoms with a dopant which is a conductive bottle selected from the group consisting of alkali metal naphthalide and alkali metal anthraceneide in an inert atmosphere or in an inert solvent. A process for producing an electroactive polymer wherein a polymer backbone and a charge compensated ionic dopant are bonded to this polymer backbone. 융합되고 질소원자를 함유한 불포화 헤테로사이클의 반복단위를 갖는 중합체를 충전을 보상하는 이온성 도판트를 제공해줄 수 있는 전해질 용액에서 전기 화학적으로 도핑시켜 충전된 중합체 골격과 충전 보상이온성 도판트가 이 중합체 골격에 결합된 전기 활성 중합체를 제조하는 방법.The polymer backbone and the charge compensation ionic dopant are fused and electrochemically doped in an electrolyte solution that can provide an ionic dopant that compensates for the charge having a repeating unit of unsaturated heterocycle containing nitrogen atoms. A method of producing an electroactive polymer bonded to this polymer backbone. (이때 충전보상이온성 도판트는 알카리금속 양이온,알카리토금속 양이온, 주기율 그룹 Ⅲ 금속 양이온 이거나 다음 구조식을 갖는 유기양이온이다.)(The charged compensating ionic dopant is an alkali metal cation, an alkali earth metal cation, a periodic group III metal cation or an organic cation having the following structural formula.) (Rxi는C1-C6의 직쇄 또는 측쇄의 알킬기임) 또는 이 양이온의 혼합이거나 할로겐 음이온, 무기음이온, 유기음이온 또는 음이온의 혼합이다.(Rxi is a C 1 -C 6 straight or branched alkyl group) or a mixture of these cations or a mixture of halogen anions, inorganic anions, organic anions or anions. 제1항 또는 제2항에 있어서 중합체 골격의 반복단위가 융합되고 6-원의 질소원자 환 디라디칼인 전기활성 중합체를 제조하는 방법.The process for producing an electroactive polymer according to claim 1 or 2, wherein the repeating unit of the polymer backbone is fused and is a 6-membered nitrogen atom ring diradical. 제3항에 있어서 디리디칼들은 1내지 6개의 질소원자를 융합된 6-원환 전반에 걸쳐 분포되고 각 환은 3 이하의 질소원자가 서로 연속하여 결합된 전기 활성 중합체의 제조방법.4. The method according to claim 3, wherein the di-radicals are distributed throughout the 6-membered ring in which 1 to 6 nitrogen atoms are fused and each ring has 3 or less nitrogen atoms continuously bonded to each other. 제4항에 있어서 융합환이 1개의 질소를 함유하고 퀴노린, 이소퀴노린, 9aH-퀴노린 또는 퀴노리지니움의 위치 디라디칼인 전기활성 중합체의 제조방법.The method for producing an electroactive polymer according to claim 4, wherein the fused ring contains one nitrogen and is positional radical of quinoline, isoquinoline, 9aH-quinoline, or quinorizinium. 제4항에 있어서 융합환이 2개의 질소원자를 함유하고 시노린, 퀴나졸린, 퀴녹사린, 2-페닐-퀴녹사린, 프탈라진, 1,5-나프타리딘, 1,6-나프타리딘, 1,7-나프타리딘,1,8-나프타리딘, 2,6-나프타라딘 또는 코피린의 위치 디라디칼인 전기 활성 중합체의 제조방법.5. The fused ring of claim 4, wherein the fused ring contains two nitrogen atoms and comprises cynoline, quinazoline, quinoxaline, 2-phenyl-quinoxaline, phthalazine, 1,5-naphtharidine, 1,6-naphtharidine, A process for preparing an electroactive polymer which is a positional diradical of 1,7-naphthridine, 1,8-naphthridine, 2,6-naphtharadine or kophyrin. 제4항에 있어서 융합환이 3개의 질소를 함유하고 1,2,3-벤조트리아진, 1,2,4-벤조트리아진,피리도〔3,2-d〕피리미딘, 피리도〔3,4-d〕피리미딘, 피리도〔4,3-d〕피리미딘, 피리도〔2,3-d〕피리미딘, 피리도〔2,3-b〕피리다진 피리도〔3,4-b〕피리다진,피리도〔2,3-d〕피리다진 또는 피리도〔3,4-d〕피리다진의 위의 디라디칼의 전기활성 중합체의 제조방법.5. A fused ring according to claim 4, wherein the fused ring contains three nitrogens: 1,2,3-benzotriazine, 1,2,4-benzotriazine, pyrido [3,2-d] pyrimidine, pyrido [3, 4-d] pyrimidine, pyrido [4,3-d] pyrimidine, pyrido [2,3-d] pyrimidine, pyrido [2,3-b] pyridazine pyrido [3,4-b A method for producing an electroactive polymer of diradical on pyridazine, pyrido [2,3-d] pyridazine or pyrido [3,4-d] pyridazine. 제4항에 있어서 융합환이 4개의 질소원자를 함유하고 피리다지노〔4,5-c〕피리다진, 피리미도〔5,4-d〕피리미딘, 프터리딘, 피리미도〔4,5-d〕피리다진, 피리미도〔4,5-d〕피리미딘, 피리지노〔2,3-b〕피라진, 피라지노〔2,3-d〕피리다진, 피라지조〔2,3-c〕피라다진, 피리다지노〔4,5-d〕피리다진, 피리미도〔4,5-c〕피리다진,피리도〔2,3-d〕-v-트리아진 또는 피리도 〔2,3-e〕-as-트리아진의 위치 디라디칼의 전기활성 중합체의 제조방법.5. A fused ring according to claim 4, wherein the fused ring contains four nitrogen atoms, and pyridazino [4,5-c] pyridazine, pyrimido [5,4-d] pyrimidine, pyrididine, pyrimido [4,5- d] pyridazine, pyrimido [4,5-d] pyrimidine, pyridino [2,3-b] pyrazine, pyrazino [2,3-d] pyridazine, pyrazygi [2,3-c] pyra Chopped, pyridazino [4,5-d] pyridazine, pyrimido [4,5-c] pyridazine, pyrido [2,3-d] -v-triazine or pyrido [2,3-e A process for producing an electroactive polymer of positional radicals of -as-triazine. 제4항에 있어서 융합환이 5개의 질소원자를 함유하고 피리미도〔4,5-e〕-as-트리아진 또는 피리미도〔5,4-d〕-v-트리아진의 위치 디라디칼인 전기활성 중합체의 제조방법.Electroactivity according to claim 4, wherein the fused ring contains five nitrogen atoms and is the positional radical of pyrimido [4,5-e] -as-triazine or pyrimido [5,4-d] -v-triazine. Method of Making Polymers. 제4항에 있어서 융합환이 6개의 질소원자를 함유하고 as-트리아지노〔6,5-d〕-v-트리아진 또는 s-테트라지노〔1,2-a〕-s-테트라진의 위치 디라디칼인 전기활성 중합체의 제조방법5. The positional radical of claim 4, wherein the fused ring contains six nitrogen atoms and contains as-triazino [6,5-d] -v-triazine or s-tetrazino [1,2-a] -s-tetazine. Process for preparing phosphorus electroactive polymer 제4항에 있어서 반복단위가 퀴노리지니움, 9aH-퀴노린, 피리다지노〔1,2-a〕피리다진, 2H-피리도〔1,2-a〕-피라진, 피리도〔1,2-a〕피리미딘-5-윰, 피리미도〔1,2-a〕피리미딘-5-윰 및 피라지노〔1,2-a〕피라진으로 구성된 그룹에서 선택된 디라디칼인 전기활성 중합체의 제조방법.5. The repeating unit according to claim 4, wherein the repeating unit is quinorizinium, 9aH-quinoline, pyridazino [1,2-a] pyridazine, 2H-pyrido [1,2-a] -pyrazine, pyrido [1, 2-a] Preparation of an electroactive polymer which is a diradical selected from the group consisting of pyrimidine-5-VII, pyrimido [1,2-a] pyrimidine-5-VII and pyrazino [1,2-a] pyrazine Way. 제3항에 있어서 반복단위는 치환 또는 비치환된 퀴노린 또는 이소퀴노린 및 이의 혼합인 전기활성 중합체의 제조방법.The method of claim 3, wherein the repeating unit is substituted or unsubstituted quinoline or isoquinoline and a mixture thereof. 제12항에 있어서 퀴노린과 치환된 퀴노린 반복단위가 2,6 위치나 3,6위치에서 서로 연결된 디라디칼이거나 이의 혼합인 전기활성 중합체의 제조방법.The method for preparing an electroactive polymer according to claim 12, wherein the quinoline and the substituted quinoline repeating units are diradicals or mixtures thereof linked to each other at the 2,6 or 3,6 positions. 제12항에 있어서 이소퀴노린과 치환된 이소퀴노린 반복단위가 2,6위치나 3,6위치에 서로 연결된 디라디칼이거나 이의 혼합물인 전기활성 중합체의 제조방법.The method for producing an electroactive polymer according to claim 12, wherein the isoquinoline and the substituted isoquinoline repeating units are diradicals or mixtures thereof linked to the 2,6 or 3,6 positions. 제12항에 있어서 반복단위가 비치환 퀴노린이거나 4위치에 치환체를 갖고 있는 퀴노린의 그룹으로 부터 선택된 전기활성 중합체의 제조방법.The method for producing an electroactive polymer according to claim 12, wherein the repeating unit is an unsubstituted quinoline or is selected from the group of quinoline having a substituent at the 4 position. 제15항에서 퀴노린과 치환된 퀴노린 단위는 2,6 위치나 3,6 위치에서 서로 연결된 디라디칼이거나 이들의 혼합인 전기활성 중합체의 제조방법.The method for preparing an electroactive polymer according to claim 15, wherein the quinoline and the substituted quinoline unit are diradicals or mixtures thereof connected to each other at the 2,6 or 3,6 positions. 제3항에 있어서 반복단위는 비치환 퀴노린이나 4 위치에 치환체를 갖는 퀴노린 디라디칼로 구성된 그룹에서 선택된 전기활성 중합체의 제조방법.The method for preparing an electroactive polymer according to claim 3, wherein the repeating unit is selected from the group consisting of unsubstituted quinoline or quinoline diradical having a substituent at the 4 position. 제17항에 있어서 디라디칼 단위는 2,6 위치나 3,6 위치에 서로 연결되며 이들의 혼합인 전기 활성중합체의 제조방법.The method of claim 17, wherein the diradical units are linked to each other at the 2,6 or 3,6 position and are a mixture thereof. 제3항에 있어서 반복단위는 퀴노린 디라디칼 및 치환된 퀴노린 디라디칼이며 이 디라디칼은 연결단위를 통하여 2,6 위치나 3,6 위치에 서로 연결되거나 또는 이들의 혼합인 전기활성 중합체의 제조방법.The method of claim 3, wherein the repeating units are quinoline diradicals and substituted quinoline diradicals, the diradicals being linked to each other at the 2,6 or 3,6 position via a linking unit, or a mixture thereof. Manufacturing method. 제3항에 있어서 반복단위는 이소퀴노린 디라디칼 및 치환 이소퀴노린 디라디칼이며 이 디라디칼은 2,6 위치나 3,6위치에 결합 연결되거나 이들의 혼합인 전기활성 중합체의 제조방법.The method for producing an electroactive polymer according to claim 3, wherein the repeating units are isoquinolin diradicals and substituted isoquinolin diradicals, which diradicals are bonded to, or mixed with, 2,6 or 3,6 positions. 제3항에 있어서 반복단위는 퀴노린, 치환퀴노린, 이소퀴노린, 치환이소퀴노린 및 이의 혼합물로 구성된 그룹으로 부터 선택된 디라디칼로서 디라디칼은 2,6위치나 3,6 위치에 연결되거나 이의 혼합인 전기중합체의 제조방법.The repeating unit according to claim 3, wherein the repeating unit is a diradical selected from the group consisting of quinoline, substituted quinoline, isoquinoline, substituted isoquinoline and mixtures thereof, wherein the diradical is linked to the 2,6 or 3,6 position or Method for producing an electropolymer is a mixture thereof. 제21항에 있어서 반복단위는 비치환 퀴노린과 비치환 이소퀴노린의 디라디칼인 전기활성 중합체의 제조방법.The method for producing an electroactive polymer according to claim 21, wherein the repeating unit is a diradical of unsubstituted quinoline and unsubstituted isoquinoline. 제21항에 있어서 반복단위는 치환된 퀴노린과 비치환 이소퀴노린의 디라디칼인 전기 활성 중합체의 제조방법.The method of claim 21, wherein the repeating unit is a diradical of substituted quinoline and unsubstituted isoquinoline. 제21항에 있어서 반복단위는 비히환 퀴노린과 치환 이소퀴노린의 디라디칼인 전기 활성 중합체의 제조방법.The method for producing an electroactive polymer according to claim 21, wherein the repeating unit is a diradical of unsubstituted quinoline and substituted isoquinoline. 제21항에 있어서 반복단위는 치환 퀴노린과 치환 이소퀴노린 디라디칼인 전기활성 중합체의 제조 방법.The method for producing an electroactive polymer according to claim 21, wherein the repeating unit is substituted quinoline and substituted isoquinoline diradical. 제4항에 있어서 반복단위가 다음 구조식을 갖는 전기활성 중합체의 제조방법.The method for producing an electroactive polymer according to claim 4, wherein the repeating unit has the following structural formula. 융합되고 질소원자를 함유한 불포화 헤테로사이클의 반복단위를 갖는 중합체를 불활성 대기나 불활성 용매내에서 알카리금속 나프타리드와 알카리금속 안트라시니드로 구성된 그룹에서 선택된 전도성 병형제인 도판트와 반융시켜 중합체 골격이 충전되고 충전 보상이온성 도판트가 이 중합체 골격과 결합된 다음 구조식의 전기활성 중합체를 조제하는 방법.Polymers having fused and nitrogen-containing unsaturated heterocycle repeating units are semi-fused with a dopant, a conductive bottling agent selected from the group consisting of alkali metal naphtharids and alkali metal anthraceneides in an inert atmosphere or in an inert solvent. A method for preparing an electroactive polymer of the following structural formula wherein said filled and charged compensating ionizable dopant is combined with this polymer backbone. 여기서 a는 0이나 1이고; b 및 c는 0이나 1이고; n은 2내지 20,000의 정수이고; d는 1내지 40,000의 정수이고; S는 1,2 또는 3의 정수이고; R은 융합 질소 함유 불포화 디라디칼 헤테로사이클린 환 시스템이고, R′은 R과 같거나 다른 융합 불포화 헤테로사이클환 시스템이며;X는 연결단위이고;Y는 X와 같거나 다른 연결단위이고;M은 중합체 골격에 지니고 있는 충전에 상극되는 전기 충전을 갖는 충전보상 이온성 도판트이다.Where a is 0 or 1; b and c are 0 or 1; n is an integer from 2 to 20,000; d is an integer from 1 to 40,000; S is an integer of 1,2 or 3; R is a fused nitrogen containing unsaturated diradical heterocycline ring system, R 'is a fused unsaturated heterocycle ring system, which is the same as or different from R; X is a linking unit; Y is a linking unit equal to or different from X; M is a polymer It is a charge-compensating ionic dopant having an electrical charge that is opposite to the charge in the skeleton. 융합되고 질소원자를 함유한 불포화 헤테로사이클의 반복단위를 갖는 중합체는 충전을 보상하는 이온성 도판트를 제공해 줄 수 있는 전해질 용액에서 전기 화학적으로 도핑시켜 충전된 중합체 골격과 충전보상이온성 도판트가 이 중합체 골격에 결합된 다음 구조식의 전기활성 중합체의 제조방법.Polymers with repeating units of unsaturated heterocycles containing nitrogen atoms, which are fused and nitrogen atom, are electrochemically doped in an electrolyte solution that can provide an ionic dopant to compensate for the charge. Process for producing an electroactive polymer of the following structural formula bonded to this polymer backbone. 위에서 a는 0이나 1이고;b는 0이나 1이고; c는 0이나 1이고 n은 2내지 20,000의 정수이고;d는 1내지 40,000 정수이고; S는 1,2 또는 3의 정수이고; R은 융합되고 질소 함유 불포화 디리디칼 헤테로사이클 환 시스템이고; R′은 R과 같거나 다른 융합 불포화헤테로사이클환 시스템이며;X는 연결단위이고;Y는 X와 같거나 다른 연결단위이고;M은 중합체 골격에 지니고 있는 충전에 상극되는 전기 충전을 갖는 충전보상 이온성 도판트이며, 충전보상 이온성 도판트는 알카리 금속이온, 알카리토금속 양이온, 주기율 그룹Ⅲ 금속양이온이거나 다음 구조식을 갖는 유기양이온A is 0 or 1; b is 0 or 1; c is 0 or 1 and n is an integer from 2 to 20,000; d is an integer from 1 to 40,000; S is an integer of 1,2 or 3; R is fused and nitrogen-containing unsaturated dicyclic heterocycle ring system; R ′ is a fused unsaturated heterocycle ring system that is the same as or different from R; X is a linking unit; Y is a linking unit equal to or different from X; M is a charge compensation with an electrical charge opposite to the charge in the polymer backbone. It is an ionic dopant, and the charge-compensating ionic dopant is an alkali metal ion, an alkali earth metal cation, a periodic group III metal cation or an organic cation having the structure (이때 Rxi는 C1-C6직쇄 또는 측쇄의 알킬기임)또는 이 양이온의 혼합이거나 또는 할로겐 음이온, 무기음이온, 유기음이온 또는 이 음이온이 혼합이다.Where R xi is a C 1 -C 6 straight or branched alkyl group or a mixture of these cations or a halogen anion, an inorganic anion, an organic anion or a mixture of these anions. 제27항 및 제28항에 있어서 R 및 R′은 융합된 6-원 질소함유 단위의 디라디칼인 전기활성 중합체의 제조방법.29. The method of claim 27 and 28 wherein R and R 'are diradical of fused 6-membered nitrogen containing units. 제29항에 있어서 R 및 R′은 1내지 6개의 질소원자를 융합된 6-원환 전반에 걸쳐 분포되고 각 환은 3 이하의 질소원자가 서로 연속하여 결합된 전기 활성 중합체의 제조방법.30. The method of claim 29, wherein R and R 'are distributed throughout the fused 6-membered ring of 1 to 6 nitrogen atoms, each ring having up to 3 nitrogen atoms continuously bonded to each other. 제30항에 있어서 R 및 R′이 치환된 전기활성 중합체의 제조방법.31. The method of claim 30 wherein R and R 'are substituted. 제31항에 있어서 R 및 R′은 퀴녹사린이거나 치환된 퀴녹사린인 전기활성 중합체의 제조방법.32. The method of claim 31, wherein R and R 'are quinoxarin or substituted quinoxarin. 제31항에 있어서 R 및 R′은 퀴노린, 이소퀴노린 이의 치환된 유도체이고, X와 Y는 R 과 R′의 2,6위치 또는 3,6 위치에 연결된 전기활성 중합체의 제조방법.32. The method of claim 31, wherein R and R 'are quinoline, isoquinoline substituted derivatives thereof, and X and Y are linked to the 2,6 or 3,6 position of R and R'. 제33항에 있어서 R 및 R′는 다음 구조식을 갖는 2,6-퀴노린인 전기활성 중합체의 제조방법.34. The method of claim 33, wherein R and R 'are 2,6-quinolines having the structure: 여기서Rⅱ,Rⅲ및 Riv은 수소, 하이드록시, 카복시, 아미노, C1-C|4알킬, C1-C4알콕시, C1-C4알킬티오, C5또는C6사이클로 알리파틱 그룹, C|2-C4알케닐 그룹, C6-C10아릴 그룹, 1내지 3의 C1-C4알킬그룹, C2-C4알케닐 그룹, C2-C4알키닐 그룹, C1-C4알콕시 그룹으로 치환되거나, 1내지 3의 시아노그룹으로 치환되거나, 1내지 3의 할로겐 원자로 치환되거나, C1-C4디알킬아미노 그룹으로 치환되거나,C1-C4알킬티오로 치환된 C6-C10아릴이거나, 5-원 또는 6-원이며 질소 함유 불포화헤테로사이클 그룹에서 선택된 기인 전기활성 중합체의 제조방법.Wherein R ii , R ⅲ and R iv are hydrogen, hydroxy, carboxy, amino, C 1 -C | 4 alkyl, C 1 -C 4 alkoxy, C 1 -C 4 alkylthio, C 5 or C 6 cyclo aliphatic group, C | 2 -C 4 alkenyl group, C 6 -C 10 aryl group, 1 to 3 C 1 -C 4 alkyl group, C 2 -C 4 alkenyl group, C 2 -C 4 alkynyl group, C 1 -C Substituted with 4 alkoxy groups, substituted with 1 to 3 cyano groups, substituted with 1 to 3 halogen atoms, substituted with C 1 -C 4 dialkylamino groups, or substituted with C 1 -C 4 alkylthio A process for preparing an electroactive polymer which is C 6 -C 10 aryl, 5- or 6-membered and is a group selected from the group containing nitrogen containing unsaturated heterocycles. 제34항에 있어서 Rⅱ및Riv는 수소인 전기 활성 중합체의 제조방법.35. The method of claim 34, wherein R ii and R iv are hydrogen. 재35항에 있어서 Rⅱ및Riv는 수소이고, a는 1이고, b는 0이며, c는 0이고, X는 -CRvii=CRvii-인 다음 구조식의 반복단위를 갖는 전기활성 중합체의 제조방법.In the material 35, wherein R ⅱ and R iv is hydrogen, a is 1, b is 0, c is 0, X is -CR = CR vii vii - the electroactive polymer has a repeating unit of the following structural formula Manufacturing method. 제35항에 있어서 Riii는 -COOH이며, a는 0이고 b와 c는 1이고,Y는인 다음 구조식을 갖는 반복단위로 된 전기 활성 중합체의 제조방법.The compound of claim 35, wherein R iii is —COOH, a is 0, b and c are 1, and Y is A process for producing an electroactive polymer of repeating units having the following structural formula: 제35항에 있어서 Riii은 수소이고 a는 0,b와 c는 1이고, Y는 비페닐 디라디칼인 다음 구조식의 반복단위를 갖는 전기활성 중합체의 제조방법.36. The method of claim 35 wherein R iii is hydrogen, a is 0, b and c is 1, and Y is biphenyl diradical. 제35항에 있어서 Riii가 -CH3이고, a는 0이며, b와 c는 1이고 y는인(Z는 연결그룹임) 다음 구조식의 반복단위를 갖는 전기활성 중합체를 제조하는 방법.The compound of claim 35, wherein R iii is —CH 3 , a is 0, b and c are 1 and y is Phosphorus (Z is a linking group) A process for preparing an electroactive polymer having a repeating unit of the structure 제35항에 있어서 Riii은-OH이고, b는 0,n및 c는 1이고, X는인 다음 구조식의 반복 단위를 갖는 전기활성 중합체를 제조하는 방법.The compound of claim 35, wherein R iii is —OH, b is 0, n and c is 1, and X is A process for preparing an electroactive polymer having repeating units of the structure 제35항에서 Riii은 페닐인 다음 구조식의 반복단위를 갖는 전기활성 중합체의 제조방법.36. The method of claim 35 wherein R iii is phenyl. 제41항에 있어서 Riii는 4-위치에 할로겐으로 치환된 페닐인 다음 구조식의 반복단위로 된 전기 활성 중합체의 제조방법.42. The method of claim 41 wherein R iii is phenyl substituted with halogen at the 4-position. 제41항에서 Riii은 4-위치에 -OCH3그룹으로 치환된 페닐인 다음 구조식의 반복단위를 갖는 전기 활성 중합체의 제조방법.42. The method of claim 41 wherein R iii is phenyl substituted at the 4-position with a -OCH 3 group. 제41항에서 X는 -0-이고, a,b 및 c는 1이고 Y는인 다음 구조식의 반복단위를 갖는 전기 활성 중합체의 제조방법.The compound of claim 41 wherein X is -0-, a, b and c are 1 and Y is A process for producing an electroactive polymer having a repeating unit of the formula 제41항에서 있어서 a는 1이고, X는 비페닐 라디칼이며, b는 0이고, c는 1인 다음 구조식의 반복단위로 된 전기활성 중합체의 제조방법.42. The method of claim 41 wherein a is 1, X is a biphenyl radical, b is 0 and c is 1. 제41항에 있어서 R 및 R′의 질소원자가 CH3 +이온으로 치환되고 a 및 b는 o인 다음 구조식의 반복단위를 갖는 전기 활성 중합체의 제조방법.42. The method of claim 41 wherein the nitrogen atoms of R and R 'are substituted with CH 3 + ions and a and b are o. 제41항에서 a는 0이고 b와 c는 1이며, R 및 R′는 같으며 페닐퀴녹사린이고, Y는인 다음 구조식의 반복단위를 갖는 전기활성 중합체의 제조방법.42. The compound of claim 41 wherein a is 0, b and c are 1, R and R 'are the same and are phenylquinoxarine, and Y is A process for producing an electroactive polymer having a repeating unit of the formula 제27항, 제28항, 제34항, 제35항,제41항, 제42항 또는 제43항에 있어서 연결단위 X와 Y는 다음 라디칼로 구성된 그룹으로 부터 선택되거나 이 연결단위의 혼합으로된 전기 활성 중합체의 제조방법.44. The linking unit X and Y according to claim 27, 28, 34, 35, 41, 42 or 43 is selected from the group consisting of the following radicals or by a mixture of these linking units. Of the prepared electroactive polymer. 여기서Rv;Rvi및Rvii은 수소 또는 메틸이다.Wherein R v ; R vi and R vii are hydrogen or methyl. 제48항에 있어서 c는 0이고 n은 10 내지 20,000인 전지 활성 중합체의 제조방법.49. The method of claim 48, wherein c is 0 and n is 10 to 20,000. 제49항에 있어서 n이고 50내지 5,000인 전지 활성 중합체의 제조방법.The method of claim 49, wherein n is 50 to 5,000. 제27항 또는 제28항에 있어서 R 및 R′은 다음 구조식의 이소퀴놀린인 전기활성 중합체의 제조방법.29. The method of claim 27 or 28, wherein R and R 'are isoquinoline of the following structural formula. 여기서Rviii, Rix및 Rx는 수소, 하이드록시, 카복시, 아미노, C1-C|4알킬, C1-C4알콕시, C1-C4알킬티오, C5또는 C6사이클로알리파틱그룹, C2-C4알케닐그룹, C6-C10아릴그룹, 1내지 3의 C1-C4알킬그룹, C2-C4알케닐 그룹, C2-C4알키닐그룹, C1-C4알콕시그룹으로 치환되거나, 1내지 3의 시아노그룹으로 치환되거나, 1내지 3의 할로겐 원자로 치환되거나, C1-C4디알킬아미노 그룹으로 치환되거나,C1-C4알킬티오로 치환된 C6-C10아릴이거나, 5-원 또는 6-원이며 질소함유 불포화 헤테로사이클그룹에서 선택된 전기활성 중합체의 제조방법.Wherein R viii , R ix and R x are hydrogen, hydroxy, carboxy, amino, C 1 -C | 4 alkyl, C 1 -C 4 alkoxy, C 1 -C 4 alkylthio, C 5 or C 6 cycloaliphatic group, C 2 -C 4 alkenyl group, C 6 -C 10 aryl group, 1 to 3 C Substituted with 1- C 4 alkyl group, C 2 -C 4 alkenyl group, C 2 -C 4 alkynyl group, C 1 -C 4 alkoxy group, substituted with 1 to 3 cyano group, 1 to 3 substituted with a halogen atom, or, C 1 -C 4 dialkylamino, or substituted with amino group, C 1 -C 4 alkyl or a C 6 -C 10 aryl substituted with a thio, a 5-membered or 6-membered nitrogen-containing unsaturated heterocycle Process for preparing an electroactive polymer selected from the group. 제51항에 있어서 연결단위X와 Y는 다음 라디칼로 구성된 그룹에서 선택되거나 이 라디칼의 혼합으로 된 전기 활성 중합체의 제조방법.52. The method of claim 51 wherein the linking units X and Y are selected from the group consisting of the following radicals or are mixtures of these radicals. (여기서 Rv;Rvi및Rvii은 수소 또는 메틸이다.)Wherein R v ; R vi and R vii are hydrogen or methyl. 제27항,제28항, 제31항, 제32항, 제33항,제51항 또는 제52항에 있어서, a는 1이고 b와 c는 0인 다음의 구조식을 갖는 전기활성 중합체의 제조방법.52. The preparation of an electroactive polymer according to claim 27, 28, 31, 32, 33, 51 or 52, wherein a is 1 and b and c are 0. Way. -〔-R-(X)a-〕-[-R- (X) a-]- 제27항,제28항, 제31항, 제32항, 제33항,제51항 또는 제52항에 있어서 a,b 및 c는 0인 다음 구조식의 반복단위를 갖는 전기활성 중합체의 제조방법.52. A process for preparing an electroactive polymer having repeat units of the following structural formulas in claims 27, 28, 31, 32, 33, 51, or 52 wherein a, b and c are zero. . -〔-R-〕--[-R-]- 제51항 또는 제53항에 있어서 c는 0이고 n은 10내지 20,000인 전기활성 중합체의 제조방법.54. The method of claim 51 or 53, wherein c is 0 and n is 10 to 20,000. 제54항에 있어서 n은 50내지 5,0000 인 전기 활성 중합체의 제조방법.55. The method of claim 54, wherein n is 50 to 5,0000. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019820002136A 1981-05-18 1982-05-17 Process for preparing electroactive polymer KR830010134A (en)

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