KR830006240A - Method for preparing substituted phenyltriazolyl-vinyl ketone - Google Patents

Method for preparing substituted phenyltriazolyl-vinyl ketone Download PDF

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Publication number
KR830006240A
KR830006240A KR1019810001730A KR810001730A KR830006240A KR 830006240 A KR830006240 A KR 830006240A KR 1019810001730 A KR1019810001730 A KR 1019810001730A KR 810001730 A KR810001730 A KR 810001730A KR 830006240 A KR830006240 A KR 830006240A
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KR
South Korea
Prior art keywords
optionally substituted
formula
alkyl
phenyltriazolyl
phenyl
Prior art date
Application number
KR1019810001730A
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Korean (ko)
Inventor
레이제르 볼프
엘베 한스-루드빅
뷰첼 칼헤인즈
프로흐베르게르 파울-에른스트
브란데스 빌헤름
Original Assignee
칼루드빅쉬미트, 게르하르트 뮬러
바이엘 아크티엔 게젤사프트
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Application filed by 칼루드빅쉬미트, 게르하르트 뮬러, 바이엘 아크티엔 게젤사프트 filed Critical 칼루드빅쉬미트, 게르하르트 뮬러
Priority to KR1019810001730A priority Critical patent/KR830006240A/en
Publication of KR830006240A publication Critical patent/KR830006240A/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Abstract

내용 없음No content

Description

치환된 페닐트리아졸일-비닐케톤의 제조방법Method for preparing substituted phenyltriazolyl-vinyl ketone

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (1)

일반식(Ⅱ)의 케토-에나민을 용매의 존재하에 필요시 촉매의 존재하에 일반식(Ⅲ)의 유기마그네슘화합물과 반응시키거나 일반식(Ⅳ)의 트리아졸일케톤을 용매의 존재하에서와 촉매의 존재하에서 일반식(Ⅴ)의 알데히드와 반응시키고, 필요시 상기에서 수득된 화합물에 산 또는 금속염을 첨가하여 일반식(Ⅰ)의 치환된 페닐트리아졸일-비닐케톤 및 그의 생리적으로 무독한 산부가염과 금속착화합물을 제조하는 방법.Keto-enamine of formula (II) is reacted with an organomagnesium compound of formula (III) in the presence of a catalyst if necessary in the presence of a solvent or triazolylketone of formula (IV) and in the presence of a solvent Substituted phenyltriazolyl-vinylketone of general formula (I) and its physiologically toxic acid addition salts by reacting with an aldehyde of general formula (V) in the presence of And a method for producing a metal complex. Hal-Mg-R (Ⅲ)Hal-Mg-R (III) O=CH-R (Ⅴ)O = CH-R (Ⅴ) 상기식에서In the above formula R은 메틸, 에틸, 이소프로필, 탄소수 3이상을 가진 알킬, 임으로 치환된 사이클로알킬, 임의로 치환된 사이클로알케닐 임의로 치환된 알케닐, 임의로 치환된 알키닐, 알킬 부위 및/또는 페닐 부위에서 임의로 치환된 펜옥시페닐 또는 페닐 알킬이고R is methyl, ethyl, isopropyl, alkyl having 3 or more carbon atoms, optionally substituted cycloalkyl, optionally substituted cycloalkenyl optionally substituted alkenyl, optionally substituted alkynyl, alkyl moiety and / or phenyl moiety Phenoxyphenyl or phenyl alkyl X는 할로겐, 임의 치환된 페닐 또는 임의 치환된 펜옥시이고X is halogen, optionally substituted phenyl or optionally substituted phenoxy n은 0,1,2 또는 3의 정수이고, n이 2 또는 3의 정수일 경우 X는 상술한 기들을 각각 선택하여 취할 수 있고n is an integer of 0,1,2 or 3, and when n is an integer of 2 or 3, X can be taken by selecting each of the groups mentioned above, R1및 R2는 같거나 서로 다른 알킬이고R 1 and R 2 are the same or different alkyl Hal을 할로겐이다.Hal is halogen. ※참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: It is to be disclosed based on the initial application.
KR1019810001730A 1981-05-19 1981-05-19 Method for preparing substituted phenyltriazolyl-vinyl ketone KR830006240A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019810001730A KR830006240A (en) 1981-05-19 1981-05-19 Method for preparing substituted phenyltriazolyl-vinyl ketone

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019810001730A KR830006240A (en) 1981-05-19 1981-05-19 Method for preparing substituted phenyltriazolyl-vinyl ketone

Publications (1)

Publication Number Publication Date
KR830006240A true KR830006240A (en) 1983-09-20

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019810001730A KR830006240A (en) 1981-05-19 1981-05-19 Method for preparing substituted phenyltriazolyl-vinyl ketone

Country Status (1)

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KR (1) KR830006240A (en)

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