KR830001912A - Method for preparing geometric isomer of 1-substituted-1-triazolylstyrenes - Google Patents

Method for preparing geometric isomer of 1-substituted-1-triazolylstyrenes Download PDF

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Publication number
KR830001912A
KR830001912A KR1019800001147A KR800001147A KR830001912A KR 830001912 A KR830001912 A KR 830001912A KR 1019800001147 A KR1019800001147 A KR 1019800001147A KR 800001147 A KR800001147 A KR 800001147A KR 830001912 A KR830001912 A KR 830001912A
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South Korea
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structural formula
cdcl
isomers
compound
geometric
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KR1019800001147A
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Korean (ko)
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KR860000517B1 (en
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유우지 후나끼
히로후미 오오시따
시즈야 다나까
도시로 가또
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니시끼다 노리스미
스미또모 가가꾸 고오교 가부시기 가이샤
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00—Drugs for dermatological disorders
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
    • A61P31/04—Antibacterial agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • General Chemical & Material Sciences (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Animal Behavior & Ethology (AREA)
  • Medicinal Chemistry (AREA)
  • Public Health (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Dentistry (AREA)
  • Oncology (AREA)
  • Dermatology (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Communicable Diseases (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음No content

Description

1-치환-1-트리아졸릴스티렌류의 기하이성체의 제조방법Method for preparing geometric isomer of 1-substituted-1-triazolylstyrenes

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this content is publicly disclosed, the full text is not included.

Claims (5)

다음구조식(Ⅱ)의 트리아졸화합물의 두 기하 이성체중 올레핀프로톤이, CDCl3중에서 NMR 스펙트럼상 낮은 자장에 나타나는 다른 기하 이성체에 광선을 조사시켜 이성화시켜서 올레핀프로톤이 CDCl3중에서 스펙트럼상 높은 자장에 나타나는 기하 이성체를 제조하는 방법.Of the two geometric isomers of the following structural formula (II), the olefin proton among the two isomers of CDCl 3 is isomerized by irradiating light to other geometric isomers appearing in the low magnetic field in the NMR spectrum in CDCl 3 , so that the olefin proton appears in the high magnetic field in the spectrum in CDCl 3 Method for preparing geometric isomers. 상기식에서 R2는 C1∼C6알킬, 사이클로프로필 또는 1-메틸사이클로프로필기이며, R3는 같거나 다르며, 각각 할로겐원자, C1∼C4알킬, 할로겐-치환-C1-C3알킬, C1∼C4알콕시, 페녹시, 페닐, 시아노 또는 니트로기이며, n은 0-3의 정수이다.In the above formula, R 2 is a C 1 to C 6 alkyl, cyclopropyl or 1-methylcyclopropyl group, R 3 is the same or different, and each is a halogen atom, C 1 to C 4 alkyl, halogen-substituted-C 1 -C 3 Alkyl, C 1 -C 4 alkoxy, phenoxy, phenyl, cyano or nitro group, n is an integer from 0-3. 상기 구조식(Ⅱ)의 트리아졸 화합물의 두 기하이성체 혼합물에 광선을 조사시켜서 이성화시켜서 올레핀 프로톤이 CDCl3중에서 NMR 스펙트럼상 높은 자장에 나타나는 하나의 기하이성체를 제조하는 방법.A method for preparing one geometric isomer in which the olefin proton appears in a high magnetic field in the NMR spectrum in CDCl 3 by isomerizing by irradiating the mixture of two geometric isomers of the triazole compound of the structural formula (II) with light. 상기 구조식(Ⅱ)의 트리아졸 화합물의 두 기하이성체 중 올레핀 프로톤이 CDCl3중에서 NMR 스펙트럼상 높은 자상에 나타나는 기하이성체를 환원시켜서 다음 구조식(Ⅰ)의 하나의 기하 이성체를 제조하는 방법.A method for preparing one geometric isomer of the following structural formula (I) by reducing the geometric isomer in which olefin proton among the two isomers of the triazole compound of the structural formula (II) appears in a high magnetic phase in the NMR spectrum in CDCl 3 . 상기 식에서, R2, R3및 n은 특허청구의 범위 1에서 정의한 바와 같다.In the above formula, R 2 , R 3 and n are as defined in claim 1. 상기 구조식(Ⅱ)의 트리아졸 화합물의 두 기하이성체 중 올레핀 프로톤이 CDCl3중에서 NMR 스펙트럼상 높은 자장에 나타나는 기하 이성체를 환원시켜서 얻어진 상기 구조식(Ⅰ')의 화합물을 염기 또는 그 염의 존재하에 반응성 C1-C4알킬, C3-C4알케닐 또는 2-프로피닐 유도체와 반응시켜서 다음 구조식(Ⅰ)의 화합물의 기하 이성체를 제조하는 방법.Of the two isomers of the triazole compound of the structural formula (II), the compound of the structural formula (I') obtained by reducing the geometric isomers in which olefin protons appear in a high magnetic field in the NMR spectrum in CDCl 3 is reactive C in the presence of a base or its salt. A method for preparing a geometric isomer of a compound of the following structural formula (I) by reacting with a 1 -C 4 alkyl, C 3 -C 4 alkenyl or 2-propynyl derivative. 상기 식에서, R1은 C1-C4알킬, C3-C4알케닐 또는 2-프로피닐기이며, R2, R3및 n은 특허청구의 범위 1에서 정의한 바와 같다.In the above formula, R 1 is a C 1 -C 4 alkyl, C 3 -C 4 alkenyl or 2-propynyl group, and R 2 , R 3 and n are as defined in claim 1. 상기 구조식(Ⅱ)의 트리아졸 화합물의 두 기하 이성체중 올레핀 프로톤이 CDCl3중에서 NMR 스펙트럼상 높은 자장에 나타나는 이성체를 환원시키거나, 또는 이 생성 화합물이나 그 염류를 더 에테르화 시켜서 얻어진 상기 구조식(Ⅰ) 화합물의 기하 이성체를 활성 성분으로 함유하는 농, 원예용 살균제, 제초제 및 또는 식물생장 조절제 조성물.Of the two geometric isomers of the triazole compound of the structural formula (II), the olefin proton is obtained by reducing an isomer that appears in a high magnetic field in the NMR spectrum in CDCl 3 or by further etherifying the product compound or its salt. ) Agrochemical, horticultural fungicides, herbicides and/or plant growth regulator compositions containing the geometrical isomer of the compound as an active ingredient. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: Disclosure is based on the original application.
KR1019800001147A 1979-03-20 1980-03-19 Process for preparing geometrical isomer of 1-substituted-1-triazoly styrenes KR860000517B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3287679A JPS55124771A (en) 1979-03-20 1979-03-20 Triazole-based geometrical isomerism compound or its salt, its preparation, and fungicide for agriculture and gardening comprising it as active ingredient

Publications (2)

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KR830001912A true KR830001912A (en) 1983-05-19
KR860000517B1 KR860000517B1 (en) 1986-05-02

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JP (1) JPS55124771A (en)
KR (1) KR860000517B1 (en)
BE (1) BE882335A (en)
RO (1) RO84686B (en)
ZA (1) ZA801597B (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS633036Y2 (en) * 1980-12-10 1988-01-25
JPS57106669A (en) * 1980-12-22 1982-07-02 Sumitomo Chem Co Ltd Optically active triazolyl alcohol derivative, its preparation, and plant growth regulator and herbicide containing said derivative as active component
JPS6113123Y2 (en) * 1980-12-17 1986-04-23
JPS58183602A (en) * 1982-04-20 1983-10-26 Sumitomo Chem Co Ltd Agricultural and gardening fungicide composition
PH18026A (en) * 1982-04-22 1985-03-03 Sumitomo Chemical Co A fungicidal composition
JPS5951204A (en) * 1982-05-27 1984-03-24 Sumitomo Chem Co Ltd Fungicidal composition for agriculture and horticulture
JPS58210002A (en) * 1982-05-31 1983-12-07 Sumitomo Chem Co Ltd Fungicidal composition for agricultural and horticultural purposes
JPS5951203A (en) * 1982-05-27 1984-03-24 Sumitomo Chem Co Ltd Fungicidal composition for agriculture and horticulture
JPS58208201A (en) * 1982-05-28 1983-12-03 Sumitomo Chem Co Ltd Agricultural and horticultural germicidal composition
JPS58208202A (en) * 1982-05-28 1983-12-03 Sumitomo Chem Co Ltd Agricultural and horticultural germicidal composition
JPH0657642B2 (en) * 1985-03-05 1994-08-03 住友化学工業株式会社 How to save cut flowers

Also Published As

Publication number Publication date
JPS55124771A (en) 1980-09-26
BE882335A (en) 1980-07-16
JPS6228789B2 (en) 1987-06-23
RO84686B (en) 1984-09-30
RO84686A (en) 1984-07-17
ZA801597B (en) 1981-03-25
KR860000517B1 (en) 1986-05-02

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