KR20240063635A - Manufacturing method of natural leather material having excellent washing property and easy cleaning property and natural leather material using the same - Google Patents
Manufacturing method of natural leather material having excellent washing property and easy cleaning property and natural leather material using the same Download PDFInfo
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- KR20240063635A KR20240063635A KR1020220145467A KR20220145467A KR20240063635A KR 20240063635 A KR20240063635 A KR 20240063635A KR 1020220145467 A KR1020220145467 A KR 1020220145467A KR 20220145467 A KR20220145467 A KR 20220145467A KR 20240063635 A KR20240063635 A KR 20240063635A
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- natural leather
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- 239000010985 leather Substances 0.000 title claims abstract description 92
- 239000000463 material Substances 0.000 title claims abstract description 34
- 238000004140 cleaning Methods 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 238000005406 washing Methods 0.000 title description 3
- 238000000034 method Methods 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 39
- 235000013372 meat Nutrition 0.000 claims description 34
- 239000011248 coating agent Substances 0.000 claims description 26
- 238000000576 coating method Methods 0.000 claims description 26
- 229920001296 polysiloxane Polymers 0.000 claims description 21
- 238000004078 waterproofing Methods 0.000 claims description 18
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 16
- 229910052731 fluorine Inorganic materials 0.000 claims description 16
- 239000011737 fluorine Substances 0.000 claims description 16
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 16
- 239000002519 antifouling agent Substances 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 11
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 8
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 8
- 235000019253 formic acid Nutrition 0.000 claims description 8
- 239000005871 repellent Substances 0.000 claims description 8
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 claims description 8
- 235000019254 sodium formate Nutrition 0.000 claims description 8
- 238000010422 painting Methods 0.000 claims description 7
- 244000061458 Solanum melongena Species 0.000 claims description 5
- 235000002597 Solanum melongena Nutrition 0.000 claims description 5
- 230000002940 repellent Effects 0.000 claims description 5
- 239000004280 Sodium formate Substances 0.000 claims description 4
- 239000004922 lacquer Substances 0.000 claims description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 4
- 238000009987 spinning Methods 0.000 claims 2
- 239000000356 contaminant Substances 0.000 abstract description 12
- 238000011109 contamination Methods 0.000 abstract description 5
- 230000000052 comparative effect Effects 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- 229920005822 acrylic binder Polymers 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 102000008186 Collagen Human genes 0.000 description 2
- 108010035532 Collagen Proteins 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 229920001436 collagen Polymers 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000002085 persistent effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 244000137852 Petrea volubilis Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- -1 acryl Chemical group 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14B—MECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
- C14B1/00—Manufacture of leather; Machines or devices therefor
- C14B1/44—Mechanical treatment of leather surfaces
- C14B1/46—Fluffing, buffing, or sanding
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/08—Chemical tanning by organic agents
- C14C3/22—Chemical tanning by organic agents using polymerisation products
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/08—Chemical tanning by organic agents
- C14C3/26—Chemical tanning by organic agents using other organic substances, containing halogen
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/30—Chemical tanning using physical means combined with chemical means
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
본 발명은 세탁성 및 이지 클리닝 특성이 우수한 천연가죽 소재의 제조방법 및 이 방법에 의해 제조된 천연가죽 소재에 관한 것으로, 보다 구체적으로는 기모를 가지고 있는 육면가죽에 물리적 및 화학적인 가공 처리를 통해, 표면 장력 33dyne/cm 이하, 오염물과의 접촉각 100°이상을 가질 수 있도록 하여 오염에 대한 저항성을 향상시킴으로써, 우수한 세탁성 및 오염물이 쉽게 제거되는 이지 클리닝 특성을 부여하고, 이로 인해 천연가죽은 세탁이 불가능하다는 고정관념에서 벗어나 신발, 소파, 가방 등에 범용적으로 적용할 수 있도록 하는, 세탁성 및 이지 클리닝 특성이 우수한 천연가죽 소재의 제조방법 및 이 방법에 의해 제조된 천연가죽 소재에 관한 것이다.The present invention relates to a method for manufacturing a natural leather material with excellent washability and easy cleaning properties, and to a natural leather material manufactured by this method. More specifically, it relates to a method of producing a natural leather material with excellent washability and easy cleaning properties. More specifically, it relates to a method of producing a natural leather material with excellent washability and easy cleaning properties. , by improving resistance to contamination by having a surface tension of 33 dyne/cm or less and a contact angle with contaminants of more than 100°, it provides excellent washability and easy cleaning characteristics in which contaminants are easily removed. This makes natural leather easy to wash. The present invention relates to a method of manufacturing a natural leather material with excellent washability and easy-cleaning characteristics that allows it to be universally applied to shoes, sofas, bags, etc., breaking away from the stereotype that this is impossible, and to a natural leather material manufactured by this method.
Description
본 발명은 표면 장력 33dyne/cm 이하, 오염물과의 접촉각 100°이상을 가짐으로써 오염에 대한 저항성을 향상시키고, 이로 인해 우수한 세탁성 및 이지 클리닝 특성을 부여할 수 있도록 하는 천연가죽 소재의 제조방법 및 이 방법에 의해 제조된 천연가죽 소재에 관한 것이다.The present invention provides a method for manufacturing a natural leather material that improves resistance to contamination by having a surface tension of 33 dyne/cm or less and a contact angle with contaminants of 100° or more, thereby providing excellent washability and easy cleaning characteristics; and It relates to natural leather materials manufactured by this method.
일반적으로 신발, 가방, 가구의 주요 소재로 사용되는 가죽은 은면가죽(Grain leather)과 육면가죽(Split leather, 스플릿 가죽)로 구분되며, 국내의 중·저가의 신발, 가방, 가구 등에는 기모성을 가지고 있는 저가 원자재인 육면가죽을 주로 사용하고 있다.In general, leather used as the main material for shoes, bags, and furniture is divided into grain leather and split leather, and brushed leather is used in domestic mid- to low-priced shoes, bags, and furniture. We mainly use meat leather, which is a low-cost raw material.
가죽에 대한 연구는 주로 은면가죽과 도장가죽(Finished leather)에 대한 연구가 대부분이고, 기모(Nap)를 가지는 저급의 육면가죽에 대한 연구는 대부분 유연성, 터치성, 항균성 등에 대한 연구가 대부분이었으며, 그 이유는 육면가죽은 기모를 가지고 있어 도장이 어렵고, 일반적으로 염색만 한 상태로 제품화가 진행되기 때문이다.Most research on leather has been on silver-faced leather and finished leather, and most research on low-quality flesh-side leather with naps has been on flexibility, touchability, and antibacterial properties. This is because flesh leather has brushing, making it difficult to paint, and is generally commercialized in a dyed state.
최근에는 은면가죽보다 상대적으로 저렴한 원자재인 육면가죽에 대한 활용도가 증대하여 신발, 가방, 가구(소파)등 그 사용범위가 확대되고 있는 추세이나, 조직적인 특성으로 도장이 어려운 문제로 인해서 표면 가공이 거의 불가능하여 소비자 및 바이어들이 요구하는 기능성 부여에 어려움을 가지고 있고, 특히 천연가죽에서는 시도한 바 없는 세탁에 의한 오염물의 세척, 인위적인 오염에 대한 이지 클리닝(easy cleaning), 외부의 오염물에 대한 저항성을 가지는 소재의 기능성 개선에 대한 연구가 지속적으로 요구되고 있다.Recently, the use of six-faced leather, which is a relatively cheaper raw material than silver-faced leather, has increased, and its range of use has expanded to include shoes, bags, and furniture (sofas). However, surface processing is difficult due to the difficulty of painting due to its organizational characteristics. It is almost impossible, making it difficult to provide the functionality demanded by consumers and buyers. In particular, it has the ability to clean contaminants by washing, which has never been attempted with natural leather, easy cleaning against artificial contamination, and resistance to external contaminants. Research into improving the functionality of materials is continuously required.
이를 해결하기 위하여 특허문헌 1에서는 하나 이상의 플루오르화 우레탄, 하나 이상의 플루오르화 에스테르, 또는 이것들의 혼합물을 포함하는 조성물과 세탁가능한 피혁을 접촉시킴을 포함하는, 세탁가능한 피혁에 지속적인 발유성, 지속적인 제오성 및 지속적인 발수성을 부여하는 방법을 제안하였다.To solve this problem, Patent Document 1 discloses a method for imparting persistent oil repellency and persistent stain resistance to washable leather, which involves contacting the washable leather with a composition containing one or more fluorinated urethanes, one or more fluorinated esters, or a mixture thereof. and a method for providing continuous water repellency was proposed.
하지만, 상기 특허문헌 1과 같은 종래기술은 표면 장력 및 오염물과의 접촉각이 커짐에 따라 실제 세탁성 및 이지 클리닝 특성이 부여되지 못하는 문제점이 있었다.However, the prior art, such as Patent Document 1, had a problem in that actual washability and easy cleaning characteristics were not provided as the surface tension and the contact angle with contaminants increased.
본 발명은 상기와 같은 문제점을 해결하기 위한 것으로, 기모를 가지고 있는 육면가죽에 물리적 및 화학적인 가공 처리를 통해, 표면 장력 33dyne/cm 이하, 오염물과의 접촉각 100°이상을 가질 수 있도록 하여 오염에 대한 저항성을 향상시킴으로써, 우수한 세탁성 및 오염물이 쉽게 제거되는 이지 클리닝 특성을 부여하고, 이로 인해 천연가죽은 세탁이 불가능하다는 고정관념에서 벗어나 신발, 소파, 가방 등에 범용적으로 적용할 수 있도록 함을 과제로 한다.The present invention is intended to solve the above problems, through physical and chemical processing on brushed flesh leather, so that it can have a surface tension of 33 dyne/cm or less and a contact angle with contaminants of 100° or more, thereby preventing contamination. By improving the resistance to heat, it provides excellent washability and easy-cleaning characteristics that allow contaminants to be easily removed, thereby breaking away from the stereotype that natural leather cannot be washed and allowing it to be universally applied to shoes, sofas, bags, etc. Make it an assignment.
본 발명은 천연가죽 소재의 제조방법에 있어서, 샌드페이퍼를 이용하여 육면 가죽을 버핑 처리하는 버핑 단계(S100); 상기 버핑 단계를 거친 육면가죽을 폴리머계 리탄닝제를 포함하는 리탄닝 용액을 이용하여 리탄닝 처리하는 리탄닝 단계(S200); 상기 리탄닝 단계를 거친 육면가죽을 실리콘계 방수 가지제 및 발수 보조제를 포함하는 가지 용액을 이용하여 가지 처리하는 가지 단계(S300); 상기 가지 단계를 거친 육면가죽을 불소계 방수제 또는 실리콘계 방수제와 캡핑제를 포함하는 캡핑 용액을 이용하여 캡핑 처리하는 캡핑 단계(S400); 및 상기 캡핑 단계를 거친 육면가죽에 불소계 방오제 또는 실리콘계 방오제를 포함하는 탑 코팅용 코팅 용액을 코팅하는 도장 단계(S500);을 포함하되, 상기 버핑 단계(S100)는 샌드페이퍼를 사용하고, 상기 상기 리탄닝 단계(S200)는 폴리머계 리탄닝제를 포함하는 리탄닝 용액을 사용하고, 상기 상기 가지 단계(S300)는 실리콘계 방수 가지제를 포함하는 가지 용액을 사용하며, 상기 캡핑 단계(S400)는 불소계 방수제를 포함하는 캡핑 용액을 사용하는 것을 특징으로 하는, 세탁성 및 이지 클리닝 특성이 우수한 천연가죽 소재의 제조방법을 과제의 해결 수단으로 한다.The present invention relates to a method for manufacturing a natural leather material, comprising: a buffing step (S100) of buffing the fleshy leather using sandpaper; A retanning step (S200) in which the meat leather that has undergone the buffing step is retanned using a retanning solution containing a polymer-based retanning agent; A fatliquuring step (S300) of fatliquuring the meat leather that has undergone the retanning step using a fatliquor solution containing a silicone-based waterproof fatliquor and a water-repellent auxiliary agent; A capping step (S400) of capping the meat leather that has gone through the above branching steps using a capping solution containing a fluorine-based waterproofing agent or a silicon-based waterproofing agent and a capping agent; and a painting step (S500) of coating the meat leather that has undergone the capping step with a top coating solution containing a fluorine-based antifouling agent or a silicone-based antifouling agent. However, the buffing step (S100) uses sandpaper, and the The retanning step (S200) uses a retanning solution containing a polymer-based retanning agent, the fatliquoring step (S300) uses a fatliquoring solution containing a silicone-based waterproof fatliquor, and the capping step (S400) uses a retanning solution containing a polymer-based retanning agent. A method for manufacturing a natural leather material with excellent washability and easy cleaning properties, characterized by using a capping solution containing a fluorine-based waterproofing agent, is used as a means of solving the problem.
본 발명은 표면 장력 33dyne/cm 이하, 오염물과의 접촉각 100°이상을 가질 수 있도록 하여 오염에 대한 저항성을 향상시킴으로써, 우수한 세탁성 및 오염물이 쉽게 제거되는 이지 클리닝 특성을 부여하고, 이로 인해 천연가죽은 세탁이 불가능하다는 고정관념에서 벗어나 신발, 소파, 가방 등에 범용적으로 적용할 수 있는 효과가 있다.The present invention improves resistance to contamination by enabling a surface tension of 33 dyne/cm or less and a contact angle with contaminants of 100° or more, thereby providing excellent washability and easy cleaning characteristics in which contaminants are easily removed, thereby providing natural leather It has the effect of being universally applicable to shoes, sofas, bags, etc., breaking away from the stereotype that it cannot be washed.
도 1은 본 발명에 따른 천연가죽 소재의 제조방법을 나타낸 공정 흐름도Figure 1 is a process flow chart showing the manufacturing method of natural leather material according to the present invention.
상기의 효과를 달성하기 위한 본 발명은 세탁성 및 이지 클리닝 특성이 우수한 천연가죽 소재의 제조방법 및 이 방법에 의해 제조된 천연가죽 소재에 관한 것으로서, 본 발명의 기술적 구성을 이해하는데 필요한 부분만이 설명되며 그 이외 부분의 설명은 본 발명의 요지를 흩트리지 않도록 생략될 것이라는 것을 유의하여야 한다.The present invention to achieve the above effects relates to a method for manufacturing a natural leather material with excellent washability and easy cleaning properties and a natural leather material manufactured by this method. Only the parts necessary to understand the technical configuration of the present invention are provided. It should be noted that the description of other parts will be omitted so as not to distract from the gist of the present invention.
이하, 본 발명에 따른 세탁성 및 이지 클리닝 특성이 우수한 천연가죽 소재의 제조방법 및 이 방법에 의해 제조된 천연가죽 소재를 상세히 설명하면 다음과 같다.Hereinafter, the method for manufacturing a natural leather material with excellent washability and easy cleaning characteristics according to the present invention and the natural leather material manufactured by this method will be described in detail as follows.
본 발명은 천연가죽 소재의 제조방법 및 이 방법에 의해 제조된 천연가죽 소재에 있어서, 도 1에 도시된 바와 같이, 버핑 단계(S100)와, 리탄닝 단계(S200)와, 가지 단계(S300)와, 캡핑 단계(S400) 및, 도장 단계(S500)를 포함하되, 상기 버핑 단계(S100)는 샌드페이퍼를 사용하고, 상기 상기 리탄닝 단계(S200)는 폴리머계 리탄닝제를 포함하는 리탄닝 용액을 사용하고, 상기 상기 가지 단계(S300)는 실리콘계 방수 가지제를 포함하는 가지 용액을 사용하며, 상기 캡핑 단계(S400)는 불소계 방수제를 포함하는 캡핑 용액을 사용한다.The present invention relates to a method for manufacturing a natural leather material and a natural leather material produced by the method, as shown in FIG. 1, a buffing step (S100), a retanning step (S200), and a branching step (S300). and a capping step (S400) and a painting step (S500), wherein the buffing step (S100) uses sandpaper, and the retanning step (S200) uses a retanning solution containing a polymer-based retanning agent. The fatliquoring step (S300) uses a fatliquoring solution containing a silicone-based waterproofing agent, and the capping step (S400) uses a capping solution containing a fluorine-based waterproofing agent.
보다 구체적으로 상기 버핑 단계(S100)는 천연가죽 표면의 기모(Nap)의 길이 등을 조절하기 위한 것으로, 육면가죽을 버핑(buffing) 처리하며, 보다 구체적으로 육면가죽의 표면을 샌드페이퍼(sandpapaer)를 이용하여 버핑처리한다. 여기서, 상기 샌드페이퍼는 셀(cell) 크기가 #120 ~ #240 등을 사용할 수 있으나 여기에 한정되는 것은 아니고 이미 공지된 다양한 샌드페이퍼의 사용이 가능하다.More specifically, the buffing step (S100) is for controlling the length of naps on the surface of natural leather, and the meat leather is buffed. More specifically, the surface of the meat leather is treated with sandpaper (sandpapaer). Buffing is done using. Here, the sandpaper may have a cell size of #120 to #240, but is not limited thereto, and various previously known sandpapers may be used.
상기 리탄닝 단계(S200)는, 육면가죽 내 콜라겐 성분의 메트릭스 내부에 리탄닝제를 침투시켜 처리함으로써 육면가죽의 방수성, 통기성 및 경량성 등을 향상시키기 위한 것으로, 상기 버핑 단계를 거친 육면가죽을 리탄닝 용액을 이용하여 리탄닝(retanning)처리하며, 보다 구체적으로 물 100 중량부에 대하여, 폴리머계 리탄닝제 10 ~ 13 중량부, 포름산나트륨(HCOONa) 1 ~ 3 중량부 및 탄산수소나트륨(NaHCO3) 0.1 ~ 0.3 중량부를 혼합한 리탄닝 용액 및 육면가죽을 드럼에 투입한 후, 40 ~ 50℃에서 120 ~ 130분간 회전시켜 리탄닝 처리한다.The retanning step (S200) is to improve the water resistance, breathability, and lightness of the meat leather by infiltrating and treating the inside of the matrix of the collagen component in the meat leather with a retanning agent. The meat leather that has gone through the buffing step is retanned. Retanning is performed using a tanning solution, and more specifically, based on 100 parts by weight of water, 10 to 13 parts by weight of a polymer-based retanning agent, 1 to 3 parts by weight of sodium formate (HCOONa), and sodium hydrogen carbonate (NaHCO 3) . ) 0.1 to 0.3 parts by weight of mixed retanning solution and meat leather are put into the drum and then rotated at 40 to 50°C for 120 to 130 minutes for retanning treatment.
그리고, 상기와 같이 리탄닝 처리가 완료되면 리탄닝 용액을 드럼으로부터 배출시킨 다음 리탄닝 처리한 육면가죽에 함침된 리탄닝 용액이 제거될 수 있도록 3 ~ 4회 수세처리하고 건조시킨다.When the retanning treatment is completed as described above, the retanning solution is discharged from the drum, then washed with water 3 to 4 times and dried to remove the retanning solution impregnated in the retanned meat leather.
여기서, 상기 폴리머계 리탄닝제는 Basyntan AN(BASF 사) 등을 사용할 수 있으나 반드시 여기에 한정되는 것은 아니고 이미 공지된 다양한 폴리머계 리탄닝제의 사용이 가능하다. Here, the polymer-based retanning agent may be used, such as Basyntan AN (BASF), but is not necessarily limited thereto, and various known polymer-based retanning agents can be used.
한편, 상기 리탄닝 용액의 조성비 및 처리 조건이 상기 범위를 벗어날 경우 리탄닝 처리 효과가 미비해질 우려가 있다.On the other hand, if the composition ratio and processing conditions of the retanning solution are outside the above range, there is a risk that the retanning treatment effect will be insufficient.
상기 가지 단계(S300)는, 육면가죽 내에 함유된 콜라겐과 같은 단백질 내부에 가지제를 침투시켜 육면가죽의 유연성을 부여하여 부드러운 특성을 향상시키는 작용을 하는 것으로, 상기 리탄닝 단계를 거친 육면가죽을 가지 용액을 이용하여 가지(Fatliquoring)처리하며, 보다 구체적으로 물 100 중량부에 대하여, 실리콘계 방수 가지제 5 ~ 6 중량부, 발수 보조제 5 ~ 6 중량부 및 포름산(formic acid) 2 ~ 2.5 중량부를 혼합한 가지 용액 및 육면가죽을 드럼에 투입한 후, 50 ~ 60℃에서 90 ~ 100분간 회전시켜 가치 처리한다.The fatliquoring step (S300) provides flexibility to the flesh leather by infiltrating the fatliquor into proteins such as collagen contained in the flesh leather, thereby improving soft characteristics. The flesh leather that has gone through the retanning step is Fatliquoring is performed using a fatliquoring solution, and more specifically, for 100 parts by weight of water, 5 to 6 parts by weight of a silicone-based waterproof fatliquor, 5 to 6 parts by weight of a water repellent auxiliary, and 2 to 2.5 parts by weight of formic acid. After putting the mixed eggplant solution and meat skin into the drum, it is processed by rotating it at 50 ~ 60℃ for 90 ~ 100 minutes.
그리고, 상기와 같이 가지 처리가 완료되면 가지 용액을 드럼으로부터 배출시킨 다음 가지 처리한 육면가죽에 함침된 가지 용액이 제거될 수 있도록 3 ~ 4회 수세처리하고 건조시킨다.Then, when the branching treatment is completed as described above, the branching solution is discharged from the drum, then washed with water 3 to 4 times and dried so that the branching solution impregnated in the branching-treated meat leather can be removed.
여기서, 상기 실리콘계 방수 가지제는 AZ-601(피엔에스사) 등을 사용할 수 있고, 발수 보조제는 PQX(피엔에스사) 등을 사용할 수 있으나 반드시 여기에 한정되는 것은 아니고 이미 공지된 다양한 실리콘계 방수 가지제 및 발수 보조제의 사용이 가능하다.Here, the silicone-based waterproofing fatliquor may be used such as AZ-601 (PNS), and the water-repellent auxiliary may be used as PQX (PNS), etc., but is not necessarily limited thereto and may include various already known silicone-based waterproofing fatliquors. It is possible to use chemicals and water repellent auxiliaries.
한편, 상기 가지 용액의 조성비 및 처리 조건이 상기 범위를 벗어날 경우 가지 처리 효과가 미비해질 우려가 있다.On the other hand, if the composition ratio and processing conditions of the eggplant solution are outside the above range, there is a risk that the eggplant treatment effect may be insufficient.
상기 캡핑 단계(S400)는, 방수 가지제를 섬유 사이에 고착시키기 위한 것으로, 상기 가지 단계를 거친 육면가죽을 캡핑 용액을 이용하여 캡핑(capping)처리하며, 보다 구체적으로 물 100 중량부에 대하여, 불소계 방수제 또는 실리콘계 방수제 3 ~ 3.5 중량부, 캡핑제 2 ~ 2.5 중량부 및 포름산(formic acid) 0.1 ~ 0.3 중량부를 혼합한 캡핑 용액 및 육면가죽을 드럼에 투입한 후, 50 ~ 60℃에서 90 ~ 100분간 회전시켜 캡핑 처리한다.The capping step (S400) is for fixing the waterproof fatliquor between the fibers, and the meat leather that has gone through the fatliquoring step is capped using a capping solution. More specifically, with respect to 100 parts by weight of water, After adding the capping solution and meat leather mixed with 3 to 3.5 parts by weight of fluorine-based or silicone-based waterproofing agent, 2 to 2.5 parts by weight of capping agent, and 0.1 to 0.3 parts by weight of formic acid into the drum, the mixture is heated at 50 to 60°C for 90 to 90 minutes. Rotate for 100 minutes and cap.
그리고, 상기와 같이 캡핑 처리가 완료되면 캡핑 용액을 드럼으로부터 배출시킨 다음 캡핑 처리한 육면가죽에 함침된 캡핑 용액이 제거될 수 있도록 3 ~ 4회 수세처리하고 건조시킨다.When the capping treatment is completed as described above, the capping solution is discharged from the drum, and then the capped meat leather is washed with water 3 to 4 times and dried to remove the capping solution impregnated.
여기서, 상기 불소계 방수제는 WR-5910(다락사) 등을 사용할 수 있으며, 실리콘계 방수제는 CK-104(다락사) 등을 사용할 수 있고, 캡핑제는 Tankrom-AB(Sisecam Chemicals 사) 등을 사용할 수 있으나 반드시 여기에 한정되는 것은 아니고 이미 공지된 다양한 불소계 방수제, 실리콘계 방수제 및 캡핑제의 사용이 가능하다.Here, the fluorine-based waterproofing agent may be used such as WR-5910 (Atticsa), the silicone-based waterproofing agent may be used such as CK-104 (Atticsa), and the capping agent may be used such as Tankrom-AB (Sisecam Chemicals). However, it is not necessarily limited to this, and various already known fluorine-based waterproofing agents, silicone-based waterproofing agents, and capping agents can be used.
한편, 상기 캡핑 용액의 조성비 및 처리 조건이 상기 범위를 벗어날 경우 캡핑 처리 효과가 미비해질 우려가 있다.Meanwhile, if the composition ratio and processing conditions of the capping solution are outside the above range, there is a risk that the capping treatment effect will be insufficient.
상기 도장 단계(S500)는, 스프릿 가죽을 외부 환경으로 부터 보호하기 위해 그 표면을 코팅처리하는 것으로 통상 베이스 코팅(Base coating), 미디움 코팅(Medium coating) 및 탑 코팅(Top coating)으로 이루어진다. 여기서 상기 베이스 코팅과 미디움 코팅은 특정 조성에 한정하지 않고 이미 공지된 일반적인 코팅액(예를 들면, 물 100 중량부, 안료 70 ~ 80 중량부, 아크릴(Acryl) 또는 우레탄 바인더(Urethane binder) 30 ~ 50 중량부, 왁스(Wax) 30 ~ 35 중량부, 레벨링제(Leveller), 가교제 5 ~ 10 중량부로 이루어진 코팅액)의 사용이 가능하며, 본 발명에서는 특징부로 탑 코팅 시 불소계 방오제 또는 실리콘계 방오제를 혼합하여 표면을 코팅처리한다.The painting step (S500) is to coat the surface of the split leather to protect it from the external environment and is usually comprised of base coating, medium coating, and top coating. Here, the base coating and medium coating are not limited to specific compositions, but are already known general coating solutions (e.g., 100 parts by weight of water, 70 to 80 parts by weight of pigment, 30 to 50 parts by weight of acryl or urethane binder) It is possible to use a coating solution consisting of 30 to 35 parts by weight of wax, 5 to 10 parts by weight of leveling agent, and 5 to 10 parts by weight of a crosslinking agent. In the present invention, a fluorine-based antifouling agent or a silicone-based antifouling agent is used as a feature during top coating. Mix and coat the surface.
보다 구체적으로 탑 코팅은 물 100 중량부에 대하여, 락카(Lacquer) 100 ~ 130 중량부 및 불소계 방오제 또는 실리콘계 방오제 20 ~ 25 중량부를 혼합한 코팅 용액을 이용하여 코팅한다.More specifically, the top coating is coated using a coating solution that mixes 100 to 130 parts by weight of lacquer and 20 to 25 parts by weight of a fluorine-based or silicone-based antifouling agent based on 100 parts by weight of water.
여기서, 상기 불소계 방오제는 Aquaderm X-shied L2(Lanxess사) 등을 사용할 수 있고, 실리콘계 방오제는 Melio 06-F-76(CLARIANT사) 등을 사용할 수 있으나 반드시 여기에 한정되는 것은 아니고 이미 공지된 다양한 불소계 방수제 및 실리콘계 방오제의 사용이 가능하다.Here, the fluorine-based antifouling agent may be used, such as Aquaderm It is possible to use various fluorine-based waterproofing agents and silicone-based antifouling agents.
한편, 상기 코팅 용액의 조성비가 상기 범위를 벗어날 경우 도장 처리 효과가 미비해질 우려가 있다.On the other hand, if the composition ratio of the coating solution is outside the above range, there is a risk that the painting treatment effect will be insufficient.
이하, 본 발명을 아래 실시예에 의거하여 더욱 상세히 설명하지만, 본 발명이 실시예에 의해 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail based on the examples below, but the present invention is not limited by the examples.
1. 천연 가죽 소재의 제조1. Manufacturing of natural leather material
(실시예 1)(Example 1)
육면가죽을 #240의 샌드페이퍼를 이용하여 버핑 처리하였다(S100). 그리고, 물 100 중량부에 대하여, 폴리머계 리탄닝제(Basyntan AN(BASF 사)) 10 중량부, 포름산나트륨(HCOONa) 1 중량부 및 탄산수소나트륨(NaHCO3) 0.1 중량부를 혼합한 리탄닝 용액 및 육면가죽을 드럼에 투입한 후, 40℃에서 120분간 회전시켜 리탄닝 처리한 후, 배수, 수세 및 건조 처리하였다(S200). 또한, 물 100 중량부에 대하여, 실리콘계 방수 가지제(AZ-601(피엔에스사)) 5 중량부, 발수 보조제(PQX(피엔에스사)) 5 중량부 및 포름산 2 중량부를 혼합한 가지 용액 및 육면가죽을 드럼에 투입한 후, 50℃에서 90분간 회전시켜 가지 처리하고, 배수, 수세 및 건조 처리하였다(S300). 아울러, 물 100 중량부에 대하여, 불소계 방수제(WR-5910(다락사)) 3 중량부, 캡핑제(Tankrom-AB(Sisecam Chemicals 사)) 2 중량부 및 포름산 0.1 중량부를 혼합한 캡핑 용액 및 육면가죽을 드럼에 투입한 후, 50℃에서 90분간 회전시켜 캡핑 처리하고, 배수, 수세 및 건조 처리하였다(S400). 그리고, 상기 공정을 거친 육면가죽에 베이스 코팅(물 100 중량부에 대하여, 안료 70 중량부, 아크릴 바인더 50 중량부, 우레탄 바인더 30 중량부, 왁스 30 중량부, 레벨링제(Leveller S(BASF 사)) 30 중량부) 및 미디움 코팅(물 100 중량부에 대하여, 안료 70 중량부, 아크릴 바인더 50 중량부, 우레탄 바인더 30 중량부, 왁스 30 중량부, 레벨링제(Leveller S(BASF 사)) 30 중량부, 가교제 5 중량부)을 수행한 후, 물 100 중량부에 대하여, 락카 100 중량부 및 불소계 방오제(Aquaderm X-shied L2(Lanxess사)) 20 중량부를 혼합한 코팅 용액을 이용하여 탑 코팅하여 제조하였다(S500).The meat leather was buffed using #240 sandpaper (S100). In addition, a retanning solution containing 10 parts by weight of a polymer-based retanning agent (Basyntan AN (BASF)), 1 part by weight of sodium formate (HCOONa), and 0.1 part by weight of sodium bicarbonate (NaHCO 3 ) based on 100 parts by weight of water, and After putting the meat leather into the drum, it was rotated at 40°C for 120 minutes and retanned, then drained, washed with water, and dried (S200). In addition, based on 100 parts by weight of water, a fatliquor solution containing 5 parts by weight of silicone-based waterproof fatliquor (AZ-601 (PNS)), 5 parts by weight of water repellent auxiliary (PQX (PNS)) and 2 parts by weight of formic acid, and After putting the meat leather into the drum, it was branched by rotating at 50°C for 90 minutes, and then drained, washed with water, and dried (S300). In addition, based on 100 parts by weight of water, 3 parts by weight of fluorine-based waterproofing agent (WR-5910 (Daraksa)), 2 parts by weight of capping agent (Tankrom-AB (Sisecam Chemicals)) and 0.1 part by weight of formic acid were mixed with the capping solution and meat. After putting the leather into the drum, it was rotated at 50°C for 90 minutes, capped, and drained, washed, and dried (S400). Then, a base coating was applied to the meat leather that had gone through the above process (based on 100 parts by weight of water, 70 parts by weight of pigment, 50 parts by weight of acrylic binder, 30 parts by weight of urethane binder, 30 parts by weight of wax, leveling agent (Leveller S (BASF)) ) 30 parts by weight) and medium coating (based on 100 parts by weight of water, 70 parts by weight of pigment, 50 parts by weight of acrylic binder, 30 parts by weight of urethane binder, 30 parts by weight of wax, 30 parts by weight of leveling agent (Leveller S (BASF)) After performing the cross-linking agent (5 parts by weight), top coating was performed using a coating solution mixed with 100 parts by weight of lacquer and 20 parts by weight of a fluorine-based antifouling agent (Aquaderm It was prepared (S500).
(실시예 2)(Example 2)
육면가죽을 #120의 샌드페이퍼를 이용하여 버핑 처리하였다(S100), 그리고, 물 100 중량부에 대하여, 폴리머계 리탄닝제(Basyntan AN(BASF 사)) 13 중량부, 포름산나트륨(HCOONa) 3 중량부 및 탄산수소나트륨(NaHCO3) 0.3 중량부를 혼합한 리탄닝 용액 및 육면가죽을 드럼에 투입한 후, 50℃에서 130분간 회전시켜 리탄닝 처리한 후, 배수, 수세 및 건조 처리하였다(S200). 또한, 물 100 중량부에 대하여, 실리콘계 방수 가지제(AZ-601(피엔에스사)) 6 중량부, 발수 보조제(PQX(피엔에스사)) 6 중량부 및 포름산 2.5 중량부를 혼합한 가지 용액 및 육면가죽을 드럼에 투입한 후, 60℃에서 100분간 회전시켜 가지 처리하고, 배수, 수세 및 건조 처리하였다(S300). 아울러, 물 100 중량부에 대하여, 실리콘계 방수제(CK-104(다락사)) 3.5 중량부, 캡핑제(Tankrom-AB(Sisecam Chemicals 사)) 2.5 중량부 및 포름산 0.3 중량부를 혼합한 캡핑 용액 및 육면가죽을 드럼에 투입한 후, 60℃에서 100분간 회전시켜 캡핑 처리하고, 배수, 수세 및 건조 처리하였다(S400). 그리고, 상기 공정을 거친 육면가죽에 베이스 코팅(물 100 중량부에 대하여, 안료 70 중량부, 아크릴 바인더 50 중량부, 우레탄 바인더 30 중량부, 왁스 30 중량부, 레벨링제(Leveller S(BASF 사)) 30 중량부) 및 미디움 코팅(물 100 중량부에 대하여, 안료 70 중량부, 아크릴 바인더 50 중량부, 우레탄 바인더 30 중량부, 왁스 30 중량부, 레벨링제(Leveller S(BASF 사)) 30 중량부, 가교제 5 중량부)을 수행한 후, 물 100 중량부에 대하여, 락카 130 중량부 및 실리콘계 방오제(Melio 06-F-76(CLARIANT사)) 25 중량부를 혼합한 코팅 용액을 이용하여 탑 코팅하여 제조하였다(S500).The meat leather was buffed using #120 sandpaper (S100), and based on 100 parts by weight of water, 13 parts by weight of a polymer-based retanning agent (Basyntan AN (BASF)) and 3 parts by weight of sodium formate (HCOONa) were added. A retanning solution mixed with 0.3 parts by weight of sodium bicarbonate (NaHCO 3 ) and meat leather were put into a drum, retanned by rotating at 50°C for 130 minutes, and then drained, washed with water, and dried (S200). In addition, based on 100 parts by weight of water, a solution of 6 parts by weight of silicone-based waterproof fatliquor (AZ-601 (PNS)), 6 parts by weight of water repellent auxiliary agent (PQX (PNS)) and 2.5 parts by weight of formic acid, and After putting the meat leather into the drum, it was branched by rotating at 60°C for 100 minutes, and then drained, washed with water, and dried (S300). In addition, based on 100 parts by weight of water, a capping solution mixed with 3.5 parts by weight of silicone-based waterproofing agent (CK-104 (Daraksa)), 2.5 parts by weight of capping agent (Tankrom-AB (Sisecam Chemicals)) and 0.3 parts by weight of formic acid and meat. After putting the leather into the drum, it was rotated at 60°C for 100 minutes, capped, and drained, washed, and dried (S400). Then, a base coating was applied to the meat leather that had gone through the above process (based on 100 parts by weight of water, 70 parts by weight of pigment, 50 parts by weight of acrylic binder, 30 parts by weight of urethane binder, 30 parts by weight of wax, leveling agent (Leveller S (BASF)) ) 30 parts by weight) and medium coating (based on 100 parts by weight of water, 70 parts by weight of pigment, 50 parts by weight of acrylic binder, 30 parts by weight of urethane binder, 30 parts by weight of wax, 30 parts by weight of leveling agent (Leveller S (BASF)) After performing the treatment (5 parts by weight of crosslinking agent), the top was coated using a coating solution of 130 parts by weight of lacquer and 25 parts by weight of silicone-based antifouling agent (Melio 06-F-76 (CLARIANT)) with respect to 100 parts by weight of water. It was manufactured by coating (S500).
(비교예 1)(Comparative Example 1)
실시예 1과 동일하게 제조하되, 버핑 처리를 하지 않았다.Manufactured in the same manner as Example 1, but without buffing.
(비교예 2)(Comparative Example 2)
실시예 2와 동일하게 제조하되, 리탄닝제로 크롬 신탄(Neosyn HL, H사)을 사용하였고, 방수 가지제로 탄화수소계 방수가지제(Perfectol QT, S사)를 사용하였으며, 발수 보조제는 사용하지 않았다.It was prepared in the same manner as in Example 2, except that chrome syntan (Neosyn HL, Company H) was used as a retanning agent, a hydrocarbon-based waterproof fatliquor (Perfectol QT, Company S) was used as a waterproofing agent, and no water-repellent auxiliary agent was used. .
(비교예 3)(Comparative Example 3)
실시예 1과 동일하게 제조하되, 가지 단계 이후 캡핑 처리를 하지 않았다.It was prepared in the same manner as in Example 1, but no capping treatment was performed after the eggplant step.
(비교예 4)(Comparative Example 4)
실시예 2와 동일하게 제조하되, 탑 코팅 시 방오제를 사용하지 않았다.It was prepared in the same manner as in Example 2, but no antifouling agent was used during top coating.
2. 천연 가죽 소재의 평가2. Evaluation of natural leather materials
상기 실시예 및 비교예에 대한 표면장력, 접촉각 등의 특성을 시험하였으며, 시험항목, 시험규격 및 결과는 아래 [표 1]과 같다.The above Examples and Comparative Examples were tested for properties such as surface tension and contact angle, and the test items, test specifications, and results are shown in [Table 1] below.
항목test
item
1Example
One
2Example
2
1Comparative example
One
2Comparative example
2
3Comparative example
3
4Comparative example
4
규격test
standard
(Grade
(dyne/cm))surface tension
(Grade
(dyne/cm))
(33dyne/cm 이하)level 4
(less than 33dyne/cm)
(33dyne/cm 이하)level 4
(less than 33dyne/cm)
(33dyne/cm 초과)level 3
(Exceeding 33dyne/cm)
(33dyne/cm 초과)level 3
(Exceeding 33dyne/cm)
(33dyne/cm 초과)level 3
(Exceeding 33dyne/cm)
(33dyne/cm 초과)level 3
(Exceeding 33dyne/cm)
(Grade)Staining resistance
(Grade)
(Grade)Fastness to rubbing
(Grade)
(Grade)Washing fastness
(Grade)
(Grade)Sunlight fastness
(Grade)
(cycle)
(1.2-1.4mm)Water resistance
(cycle)
(1.2-1.4mm)
이상10,000
more
이상10,000
more
미만10,000
under
미만10,000
under
미만10,000
under
미만10,000
under
(cycle)
(1.4-1.6mm)Water resistance
(cycle)
(1.4-1.6mm)
이상11,000
more
이상11,000
more
미만11,000
under
미만11,000
under
미만11,000
under
미만11,000
under
(cycle)
(1.6-1.8mm)Water resistance
(cycle)
(1.6-1.8mm)
이상13,000
more
이상13,000
more
미만13,000
under
미만13,000
under
미만13,000
under
미만13,000
under
(cycle)
(1.8-2.0mm)Water resistance
(cycle)
(1.8-2.0mm)
이상15,000
more
이상15,000
more
미만15,000
under
미만15,000
under
미만15,000
under
미만15,000
under
(mg.loss)Wear resistance
(mg.loss)
상기 [표 1]에서와 같이, 본 발명의 실시예에 따른 천연 가죽 소재는 비교예에 비하여 표면 장력 33dyne/cm 이하를 가질 뿐만 아니라, 오염물과의 접촉각이 100°이상을 가지는 등 우수한 세탁성 및 오염물이 쉽게 제거되는 이지 클리닝 특성이 부여됨을 알 수 있다.As shown in [Table 1], the natural leather material according to the example of the present invention not only has a surface tension of 33 dyne/cm or less compared to the comparative example, but also has a contact angle with contaminants of 100° or more, and excellent washability and It can be seen that easy cleaning properties are provided to easily remove contaminants.
상술한 바와 같은, 본 발명의 바람직한 실시예에 따른 세탁성 및 이지 클리닝 특성이 우수한 천연가죽 소재의 제조방법 및 이 방법에 의해 제조된 천연가죽 소재를 상기한 설명 및 도면에 따라 설명하였지만 이는 예를 들어 설명한 것에 불과하며 본 발명의 기술적 사상을 벗어나지 않는 범위 내에서 다양한 변화 및 변경이 가능하다는 것을 이 분야의 통상적인 기술자들은 잘 이해할 수 있을 것이다.As described above, the method for manufacturing a natural leather material with excellent washability and easy cleaning characteristics according to a preferred embodiment of the present invention and the natural leather material manufactured by this method have been described according to the above description and drawings, but this is an example. Those skilled in the art will be able to understand that this is merely an explanation and that various changes and modifications can be made without departing from the technical spirit of the present invention.
Claims (7)
육면 가죽을 버핑 처리하는 버핑 단계(S100);
상기 버핑 단계를 거친 육면가죽을 리탄닝 용액을 이용하여 리탄닝 처리하는 리탄닝 단계(S200);
상기 리탄닝 단계를 거친 육면가죽을 가지 용액을 이용하여 가지 처리하는 가지 단계(S300);
상기 가지 단계를 거친 육면가죽을 캡핑 용액을 이용하여 캡핑 처리하는 캡핑 단계(S400); 및
상기 캡핑 단계를 거친 육면가죽에 코팅 용액을 코팅하는 도장 단계(S500);을 포함하되,
상기 버핑 단계(S100)는 샌드페이퍼를 사용하고,
상기 상기 리탄닝 단계(S200)는 폴리머계 리탄닝제를 포함하는 리탄닝 용액을 사용하고,
상기 상기 가지 단계(S300)는 실리콘계 방수 가지제를 포함하는 가지 용액을 사용하며,
상기 캡핑 단계(S400)는 불소계 방수제를 포함하는 캡핑 용액을 사용하는 것을 특징으로 하는, 세탁성 및 이지 클리닝 특성이 우수한 천연가죽 소재의 제조방법.
In the manufacturing method of natural leather material,
Buffing step (S100) of buffing the flesh leather;
A retanning step (S200) in which the meat leather that has undergone the buffing step is retanned using a retanning solution;
A branching step (S300) of fatliquuring the meat leather that has undergone the retanning step using a fatliquoring solution;
A capping step (S400) of capping the meat leather that has gone through the branching step using a capping solution; and
It includes a painting step (S500) of coating the coating solution on the meat leather that has undergone the capping step,
The buffing step (S100) uses sandpaper,
The retanning step (S200) uses a retanning solution containing a polymer-based retanning agent,
The fatliquoring step (S300) uses a fatliquor solution containing a silicone-based waterproof fatliquor,
The capping step (S400) is a method of manufacturing a natural leather material with excellent washability and easy cleaning properties, characterized in that the capping solution containing a fluorine-based waterproofing agent is used.
상기 버핑 단계(S100)는,
육면가죽의 표면을 셀(cell) 크기가 #120 ~ #240인 샌드페이퍼를 이용하여 버핑처리하는 것을 특징으로 하는, 세탁성 및 이지 클리닝 특성이 우수한 천연가죽 소재의 제조방법.
According to clause 1,
The buffing step (S100) is,
A method of manufacturing a natural leather material with excellent washability and easy cleaning properties, characterized in that the surface of the flesh leather is buffed using sandpaper with a cell size of #120 to #240.
상기 리탄닝 단계(S200)는,
물 100 중량부에 대하여, 폴리머계 리탄닝제 10 ~ 13 중량부, 포름산나트륨(HCOONa) 1 ~ 3 중량부 및 탄산수소나트륨(NaHCO3) 0.1 ~ 0.3 중량부를 혼합한 리탄닝 용액 및 육면가죽을 드럼에 투입한 후, 40 ~ 50℃에서 120 ~ 130분간 회전시켜 리탄닝 처리하는 것을 특징으로 하는, 세탁성 및 이지 클리닝 특성이 우수한 천연가죽 소재의 제조방법.
According to clause 1,
In the retanning step (S200),
A retanning solution mixed with 10 to 13 parts by weight of a polymer-based retanning agent, 1 to 3 parts by weight of sodium formate (HCOONa), and 0.1 to 0.3 parts by weight of sodium bicarbonate (NaHCO 3 ) per 100 parts by weight of water and drummed into meat leather. A method of manufacturing a natural leather material with excellent washability and easy cleaning properties, characterized in that it is retanned by rotating it at 40 to 50°C for 120 to 130 minutes after putting it in.
상기 가지 단계(S300)는,
물 100 중량부에 대하여, 실리콘계 방수 가지제 5 ~ 6 중량부, 발수 보조제 5 ~ 6 중량부 및 포름산 2 ~ 2.5 중량부를 혼합한 가지 용액 및 육면가죽을 드럼에 투입한 후, 50 ~ 60℃에서 90 ~ 100분간 회전시켜 가치 처리하는 것을 특징으로 하는, 세탁성 및 이지 클리닝 특성이 우수한 천연가죽 소재의 제조방법.
According to clause 1,
The branching step (S300) is,
For 100 parts by weight of water, add 5 to 6 parts by weight of silicone-based waterproof fatliquor, 5 to 6 parts by weight of water repellent auxiliary, and 2 to 2.5 parts by weight of formic acid into the drum, then pour the eggplant solution and meat leather into the drum and heat at 50 to 60°C. A method of manufacturing natural leather material with excellent washability and easy cleaning properties, characterized by spinning for 90 to 100 minutes and treating it with value.
상기 캡핑 단계(S400)는,
물 100 중량부에 대하여, 불소계 방수제 또는 실리콘계 방수제 3 ~ 3.5 중량부, 캡핑제 2 ~ 2.5 중량부 및 포름산 0.1 ~ 0.3 중량부를 혼합한 캡핑 용액 및 육면가죽을 드럼에 투입한 후, 50 ~ 60℃에서 90 ~ 100분간 회전시켜 캡핑 처리하는 것을 특징으로 하는, 세탁성 및 이지 클리닝 특성이 우수한 천연가죽 소재의 제조방법.
According to clause 1,
The capping step (S400) is,
After adding the capping solution and meat leather mixed with 3 to 3.5 parts by weight of fluorine-based or silicone-based waterproofing agent, 2 to 2.5 parts by weight of capping agent and 0.1 to 0.3 parts by weight of formic acid for 100 parts by weight of water, into the drum, at 50 to 60°C. A method of manufacturing a natural leather material with excellent washability and easy cleaning properties, characterized by capping by spinning for 90 to 100 minutes.
상기 도장 단계(S500)는,
물 100 중량부에 대하여, 락카 100 ~ 130 중량부 및 불소계 방오제 또는 실리콘계 방오제 20 ~ 25 중량부를 혼합한 코팅 용액을 탑 코팅하는 공정을 포함하는 것을 특징으로 하는, 세탁성 및 이지 클리닝 특성이 우수한 천연가죽 소재의 제조방법.
According to clause 1,
In the painting step (S500),
Washability and easy cleaning properties, comprising a process of top coating a coating solution mixed with 100 to 130 parts by weight of lacquer and 20 to 25 parts by weight of a fluorine-based antifouling agent or a silicone-based antifouling agent based on 100 parts by weight of water. Manufacturing method of excellent natural leather material.
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20070114766A (en) | 2005-02-22 | 2007-12-04 | 이 아이 듀폰 디 네모아 앤드 캄파니 | Washable leather with oil- and water-repellency |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20070114766A (en) | 2005-02-22 | 2007-12-04 | 이 아이 듀폰 디 네모아 앤드 캄파니 | Washable leather with oil- and water-repellency |
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