KR20240049996A - paper for waterproof with barrier coating - Google Patents
paper for waterproof with barrier coating Download PDFInfo
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- KR20240049996A KR20240049996A KR1020220129602A KR20220129602A KR20240049996A KR 20240049996 A KR20240049996 A KR 20240049996A KR 1020220129602 A KR1020220129602 A KR 1020220129602A KR 20220129602 A KR20220129602 A KR 20220129602A KR 20240049996 A KR20240049996 A KR 20240049996A
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- South Korea
- Prior art keywords
- paper
- barrier coating
- resinous solution
- present
- particles
- Prior art date
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- 239000011248 coating agent Substances 0.000 title claims description 25
- 238000000576 coating method Methods 0.000 title claims description 25
- 230000004888 barrier function Effects 0.000 title claims description 23
- 239000002245 particle Substances 0.000 claims abstract description 21
- 238000005470 impregnation Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 150000004665 fatty acids Chemical class 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 239000011247 coating layer Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- -1 Polyethylene Polymers 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/22—Polyalkenes, e.g. polystyrene
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
Abstract
본 발명은, 종이 입자와 수지성 용액을 혼합하여 준비하는 단계; 및 종이 입자와 상기 수지성 용액이 혼합되어 종이 입자 사이에 수지성 용액이 믹싱되는 단계를 포함하는 기술적 사상을 개시한다. The present invention includes the steps of preparing paper particles and a resinous solution by mixing them; and mixing paper particles and the resinous solution to mix the resinous solution between the paper particles.
Description
본 발명은 종이 입자에 베리어 코팅을 제공하여 습기 또는 수분에 강한 종이를 형성하도록 하는 베리어 코팅을 구비한 강습 페이퍼지에 관한 기술분야이다.The present invention relates to the technical field of training paper with a barrier coating that provides a barrier coating to paper particles to form paper that is resistant to moisture or moisture.
"지방산을 압착 가열 기상 그라프팅 처리한 소수성 종이 및 그 제조방법(출원번호 제10-2020-0093949호, 특허문헌 1이라 한다.)"가 존재한다. “Hydrophobic paper obtained by compressing, heating, and vapor phase grafting of fatty acids and its manufacturing method (Application No. 10-2020-0093949, referred to as Patent Document 1)” exists.
특허문헌 1은, 압착 가열 가스 그라프팅 소수화 처리 설비를 이용한 소수성 종이 제조방법은 비통기성 드라이어 벨트가 구비된 압착 가열 가스 그라프팅 소수화 처리 설비를 이용하므로 염화지방산과 종이 수산기의 반응 시 발생하는 염산의 소산을 막아 지방산과 종이 수산기가 에스테르화 반응을 일으키도록 염산을 촉매로써 사용하는 특징이다. Patent Document 1 states that the method for producing hydrophobic paper using a press heating gas grafting hydrophobization treatment facility uses a press heating gas grafting hydrophobization treatment facility equipped with a non-breathable dryer belt, so that the hydrochloric acid generated during the reaction between chlorinated fatty acids and paper hydroxyl groups is removed. It is characterized by using hydrochloric acid as a catalyst to block dissipation and cause an esterification reaction between fatty acids and paper hydroxyl groups.
특허문헌1의 경우, 값비싼 염화지방산의 일부를 저렴한 일반 지방산으로 대체한 혼합 소수화제를 사용하므로 종래의 염화지방산만을 소수화제로 사용한 소수화 종이의 제조방법에 대비하여 동일한 품질의 소수화 종이를 더 저렴한 제조비용으로 제조할 수 있는 장점이 있다.In the case of Patent Document 1, a mixed hydrophobizer is used in which some of the expensive chlorinated fatty acids are replaced with inexpensive general fatty acids, so compared to the conventional method of manufacturing hydrophobized paper using only chlorinated fatty acids as the hydrophobizer, the same quality of hydrophobized paper is cheaper. It has the advantage of being able to be manufactured at low manufacturing costs.
또한 특허문헌 1에 따르면, 압착 가열 가스 그라프팅 소수화 처리 설비를 이용한 소수성 종이 제조방법은 종래의 염화지방산과 가스 그라프팅 소수화 처리 설비를 이용한 소수화 종이의 제조방법에 대비하여 반응시 발생하는 염산과 같은 강산을 재활용하므로 강산의 처리비용이 절감되는 효과가 있다In addition, according to Patent Document 1, the method of producing hydrophobic paper using a compressed heating gas grafting hydrophobization treatment facility is different from the method of producing hydrophobization paper using a conventional chlorinated fatty acid and gas grafting hydrophobization treatment facility, such as hydrochloric acid generated during reaction. By recycling strong acids, the cost of processing strong acids is reduced.
본 발명에 따른 베리어 코팅을 구비한 강습 페이퍼지는 상기한 바와 같은 종래 문제점을 해결하기 위해 안출된 것으로서, 다음과 같은 해결하고자 하는 과제를 제시한다.The instructional paper with a barrier coating according to the present invention was designed to solve the conventional problems described above, and presents the following problems to be solved.
본 발명은 베리어 코팅을 구비한 강습 페이퍼지에 관한 기술적 사상을 제시하고자 한다. The present invention seeks to present technical ideas regarding instructional paper with a barrier coating.
본 발명의 해결 과제는 이상에서 언급된 것들에 한정되지 않으며, 언급되지 아니한 다른 해결과제들은 아래의 기재로부터 당업자에게 명확하게 이해될 수 있을 것이다.The problems to be solved by the present invention are not limited to those mentioned above, and other problems not mentioned will be clearly understood by those skilled in the art from the description below.
본 발명에 따른 베리어 코팅을 구비한 강습 페이퍼지는 상기의 해결하고자 하는 과제를 위하여 다음과 같은 과제 해결 수단을 가진다.The instructional paper having a barrier coating according to the present invention has the following means for solving the problem.
본 발명에 따른 베리어 코팅을 구비한 강습 페이퍼지는 종이 입자와 수지성 용액을 혼합하여 준비하는 단계; 및 상기 종이 입자와 상기 수지성 용액이 혼합되어 상기 종이 입자 사이에 상기 수지성 용액이 믹싱되는 단계를 포함하는 것을 특징으로 한다. Preparing an instructional paper with a barrier coating according to the present invention by mixing paper particles and a resinous solution; and mixing the paper particles and the resinous solution, thereby mixing the resinous solution between the paper particles.
본 발명에 따른 베리어 코팅을 구비한 강습 페이퍼지는 종이 입자 상호 간에 미세 함침구간이 형성되는 단계; 복수 개의 상기 종이 입자 표면으로부터 수지성 용액을 선택적으로 함침하는 단계; 및 상기 수지성 용액이 함침된 상기 종이 표면의 일측면에 소정의 친수성 코팅을 제공하는 단계를 포함하는 것을 특징으로 한다. The step of forming a fine impregnation zone between paper particles in the instructional paper having a barrier coating according to the present invention; selectively impregnating the surfaces of the plurality of paper particles with a resinous solution; and providing a predetermined hydrophilic coating on one side of the paper surface impregnated with the resinous solution.
본 발명에 따른 베리어 코팅을 구비한 강습 페이퍼지의 상기 상기 수지성 용액은, 상기 미세 함침구간에 함침되어, 상기 종이 입자의 임의 분산을 방지하는 것을 특징으로 한다. The resinous solution of the steel paper with a barrier coating according to the present invention is impregnated in the fine impregnation zone to prevent random dispersion of the paper particles.
이상과 같은 구성의 본 발명에 따른 베리어 코팅을 구비한 강습 페이퍼지는 다음과 같은 효과를 제공한다.The instructional paper paper equipped with the barrier coating according to the present invention with the above configuration provides the following effects.
본 발명은 베리어 코팅을 구비한 강습 페이퍼지에 관한 기술적 사상을 제시하고자 한다. The present invention seeks to present technical ideas regarding instructional paper with a barrier coating.
본 발명의 효과는 이상에서 언급한 것들에 한정되지 않으며, 언급되지 아니한 다른 효과들은 아래의 기재로부터 당업자에게 명확하게 이해될 수 있을 것이다.The effects of the present invention are not limited to those mentioned above, and other effects not mentioned will be clearly understood by those skilled in the art from the description below.
도1은 종이에 베리어 코팅층이 형성된 것을 도시한 것이다.
도2는 종이에 베리어 코팅층이 형성된 후 친수성 코팅이 형성된 것을 도시한 것이다. Figure 1 shows a barrier coating layer formed on paper.
Figure 2 shows that a hydrophilic coating is formed after a barrier coating layer is formed on paper.
본 발명에 따른 베리어 코팅을 구비한 강습 페이퍼지는 다양한 변경을 가할 수 있고 여러 가지 실시예를 가질 수 있는바, 특정 실시예들을 도면에 예시하고 상세한 설명에 상세하게 설명하고자 한다. 그러나, 이는 본 발명을 특정한 실시 형태에 대해 한정하려는 것이 아니며, 본 발명의 기술적 사상 및 기술 범위에 포함되는 모든 변경, 균등물 내지 대체물을 포함하는 것으로 이해되어야 한다. The instructional paper with a barrier coating according to the present invention can be subjected to various changes and can have several embodiments, and specific embodiments will be illustrated in the drawings and described in detail in the detailed description. However, this is not intended to limit the present invention to specific embodiments, and should be understood to include all changes, equivalents, and substitutes included in the technical spirit and scope of the present invention.
본 발명에 따른 베리어 코팅을 구비한 강습 페이퍼지는 종이 입자와 수지성 용액을 혼합하여 준비하고, 종이 입자와 수지성 입자를 혼합한 후 믹싱되어 제공되는 방법과 종이 입자 상호 간에 미세 함침구간이 형성되어, 미세 함침구간으로 수지성 용액이 선택적으로 함침되는 방법을 통하여 베리어 코팅을 구비하는 것을 특징으로 한다. The lecture paper with a barrier coating according to the present invention is prepared by mixing paper particles and a resinous solution, and the paper particles and the resinous particles are mixed and then mixed, and a fine impregnation zone is formed between the paper particles. , characterized in that the barrier coating is provided through a method in which a resinous solution is selectively impregnated into a fine impregnation section.
수지성 용액은 물에도 강한 종이를 형성하며, 베리어 코팅을 구비한 종이는 내구성과 물에 젖지 않는 효과를 제공할 수 있다. The resinous solution forms paper that is resistant to water, and paper with a barrier coating can provide durability and a water-repellent effect.
종이 입자와 수지성 용액이 혼합되어 베리어 코팅이 형성되는 경우, 종이의 절단면으로부터 종이 입자의 비산이 방지되며, 절단면을 통한 수분의 유입이 이루어지지 않는 것이 바람직하다. When a barrier coating is formed by mixing paper particles and a resinous solution, it is desirable to prevent paper particles from scattering from the cut surface of the paper and to prevent moisture from entering through the cut surface.
반면, 상하 표면으로부터 베리어 코팅이 이루어지는 경우, 선택적 함침을 통하여 절단면에는 수지성 용액이 침투되지 않을 수 있어, 목적하는 바에 따라 선택적 함침이 이루어지도록 할 수 있는 것이다. On the other hand, when barrier coating is performed from the upper and lower surfaces, the resinous solution may not penetrate into the cut surface through selective impregnation, so that selective impregnation can be performed according to the purpose.
본 발명에 따른 베리어 코팅을 구비한 강습 페이퍼지의 수지성 용액은, 수지성 용액이 함침된 종이 표면의 일측면에 소정의 친수성 코팅을 제공하는 단계를 포함한다. The resinous solution of steel paper with a barrier coating according to the present invention includes the step of providing a predetermined hydrophilic coating on one side of the paper surface impregnated with the resinous solution.
친수성 코팅의 경우, PE(Polyethylene) 등에 해당할 수 있다. In the case of hydrophilic coating, it may correspond to PE (Polyethylene), etc.
본 발명의 권리 범위는 특허청구범위에 기재된 사항에 의해 결정되며, 특허 청구범위에 사용된 괄호는 선택적 한정을 위해 기재된 것이 아니라, 명확한 구성요소를 위해 사용되었으며, 괄호 내의 기재도 필수적 구성요소로 해석되어야 한다.The scope of rights of the present invention is determined by the matters stated in the patent claims, and parentheses used in the patent claims are not used for selective limitation, but are used for clear elements, and descriptions within parentheses are also interpreted as essential elements. It has to be.
1: 종이
2: 베리어 코팅층
3: 친수성 코팅층1: paper
2: Barrier coating layer
3: Hydrophilic coating layer
Claims (3)
상기 종이 입자와 상기 수지성 용액이 혼합되어 상기 종이 입자 사이에 상기 수지성 용액이 믹싱되는 단계를 포함하는 것을 특징으로 하는, 베리어 코팅을 구비한 강습 페이퍼지.
Preparing by mixing paper particles and a resinous solution; and
Instructional paper with a barrier coating, characterized in that it includes the step of mixing the paper particles and the resinous solution and mixing the resinous solution between the paper particles.
복수 개의 상기 종이 입자 표면으로부터 수지성 용액을 선택적으로 함침하는 단계를 포함하는 것을 특징으로 하는,
Forming a fine impregnation zone between paper particles;
characterized by selectively impregnating a plurality of the surfaces of the paper particles with a resinous solution,
상기 수지성 용액이 함침된 상기 종이 표면의 일측면에 소정의 친수성 코팅을 제공하는 단계를 포함하는 것을 특징으로 하는, 베리어 코팅을 구비한 강습 페이퍼지.
The method of claim 2, wherein the resinous solution is:
Instructional paper with a barrier coating, comprising the step of providing a predetermined hydrophilic coating on one side of the paper surface impregnated with the resinous solution.
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KR20200093949A (en) | 2019-01-29 | 2020-08-06 | 현대자동차주식회사 | Engine system |
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KR20200093949A (en) | 2019-01-29 | 2020-08-06 | 현대자동차주식회사 | Engine system |
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