KR20240047751A - Cosmetic composition of silicone-in-water-in-formulation for lips - Google Patents
Cosmetic composition of silicone-in-water-in-formulation for lips Download PDFInfo
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- cosmetic composition
- lips
- dimethicone
- silicone
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- 239000000203 mixture Substances 0.000 title claims abstract description 177
- 238000009472 formulation Methods 0.000 title claims abstract description 66
- 239000002537 cosmetic Substances 0.000 title claims abstract description 61
- 229920006037 cross link polymer Polymers 0.000 claims abstract description 34
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 33
- 239000004909 Moisturizer Substances 0.000 claims abstract description 25
- 230000001333 moisturizer Effects 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229920002545 silicone oil Polymers 0.000 claims abstract description 24
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 16
- 230000003020 moisturizing effect Effects 0.000 claims abstract description 6
- 229940008099 dimethicone Drugs 0.000 claims description 46
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 46
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 46
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 46
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- 238000000034 method Methods 0.000 claims description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 4
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 claims description 4
- SCRSFLUHMDMRFP-UHFFFAOYSA-N trimethyl-(methyl-octyl-trimethylsilyloxysilyl)oxysilane Chemical compound CCCCCCCC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C SCRSFLUHMDMRFP-UHFFFAOYSA-N 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims description 3
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 claims description 3
- 229940090934 diphenylsiloxy phenyl trimethicone Drugs 0.000 claims description 3
- 229940057874 phenyl trimethicone Drugs 0.000 claims description 3
- 230000002335 preservative effect Effects 0.000 claims description 3
- LINXHFKHZLOLEI-UHFFFAOYSA-N trimethyl-[phenyl-bis(trimethylsilyloxy)silyl]oxysilane Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)C1=CC=CC=C1 LINXHFKHZLOLEI-UHFFFAOYSA-N 0.000 claims description 3
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 claims description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 2
- 229940035437 1,3-propanediol Drugs 0.000 claims description 2
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 claims description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 2
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 claims description 2
- RGMZNZABJYWAEC-UHFFFAOYSA-N Methyltris(trimethylsiloxy)silane Chemical compound C[Si](C)(C)O[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C RGMZNZABJYWAEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000007983 Tris buffer Substances 0.000 claims description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 claims description 2
- 229940105990 diglycerin Drugs 0.000 claims description 2
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical group OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 claims description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 229940073663 methyl trimethicone Drugs 0.000 claims description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims description 2
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 229920002379 silicone rubber Polymers 0.000 abstract description 8
- 238000004040 coloring Methods 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 7
- 230000000052 comparative effect Effects 0.000 description 39
- 239000012071 phase Substances 0.000 description 21
- 239000002994 raw material Substances 0.000 description 16
- 239000003921 oil Substances 0.000 description 13
- 239000000049 pigment Substances 0.000 description 11
- 230000001131 transforming effect Effects 0.000 description 8
- 238000010586 diagram Methods 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 4
- 239000012860 organic pigment Substances 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000000346 nonvolatile oil Substances 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003213 antiperspirant Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- DBZJJPROPLPMSN-UHFFFAOYSA-N bromoeosin Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC(Br)=C(O)C(Br)=C1OC1=C(Br)C(O)=C(Br)C=C21 DBZJJPROPLPMSN-UHFFFAOYSA-N 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- LQJVOKWHGUAUHK-UHFFFAOYSA-L disodium 5-amino-4-hydroxy-3-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=C2C(N)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 LQJVOKWHGUAUHK-UHFFFAOYSA-L 0.000 description 1
- IVKWXPBUMQZFCW-UHFFFAOYSA-L disodium;2-(2,4,5,7-tetraiodo-3-oxido-6-oxoxanthen-9-yl)benzoate;hydrate Chemical compound O.[Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 IVKWXPBUMQZFCW-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- SEACYXSIPDVVMV-UHFFFAOYSA-L eosin Y Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 SEACYXSIPDVVMV-UHFFFAOYSA-L 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000013022 formulation composition Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229940091554 lauryl peg-9 polydimethylsiloxyethyl dimethicone Drugs 0.000 description 1
- 239000007934 lip balm Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- ZYIBVBKZZZDFOY-UHFFFAOYSA-N phloxine O Chemical compound O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(Br)=C(O)C(Br)=C1OC1=C(Br)C(O)=C(Br)C=C21 ZYIBVBKZZZDFOY-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
휘발성 실리콘 오일, 실리콘 크로스폴리머 및 보습제를 포함하는 수중 실리콘(silicone-in-water: S/W) 제형의 입술용 화장료 조성물에 관한 것이다. 일 양상에 따른 입술용 화장료 조성물은 수 중 실리콘 (S/W) 제형으로, 휘발성 실리콘 오일, 유화제, 실리콘 크로스폴리머 및 보습제를 포함하여, 촉촉하면서도 매트한 사용감을 가지며, 종전 W/S 제형에 비해 착색효과가 뛰어나기 때문에 메이크업 조성료로 우수하게 활용될 수 있다. 또한 일 양상에 따른 입술용 화장료 조성물은 기존 S/W 제형과 달리 겔 성상의 실리콘 엘라스토머가 없는 조성물로, 뭉침 현상과 보습력이 개선된 입술용 화장료 조성물로써 유용하게 활용될 수 있다. It relates to a cosmetic composition for lips in a silicone-in-water (S/W) formulation containing volatile silicone oil, silicone crosspolymer, and moisturizer. The cosmetic composition for lips according to one aspect is a water-based silicone (S/W) formulation, containing volatile silicone oil, emulsifier, silicone crosspolymer, and moisturizer, and has a moist and matte feeling when used, compared to the previous W/S formulation. Because it has an excellent coloring effect, it can be excellently used as a makeup composition. In addition, the cosmetic composition for lips according to one aspect, unlike existing S/W formulations, is a composition without gel-like silicone elastomer, and can be usefully used as a cosmetic composition for lips with improved clumping and moisturizing properties.
Description
휘발성 실리콘 오일, 실리콘 크로스폴리머 및 보습제를 포함하는 수중 실리콘(silicone-in-water: S/W) 제형의 입술용 화장료 조성물에 관한 것이다.It relates to a cosmetic composition for lips in a silicone-in-water (S/W) formulation containing volatile silicone oil, silicone crosspolymer, and moisturizer.
최근 입술용 화장품으로서 매트 타입의 제형은, 기존 실리콘 중 수형(W/S) 과는 달리 오일감이 드는 사용감 보다는 수분감이 느껴지는 워터매트 타입의 제형이 유행을 하고 있다. 답답하거나 건조할 수 있는 W/S 제형에 비해 S/W 제형은 수분함량 및 보습제 함량이 높아 촉촉하면서도 매트한 제형구현으로 소비자들에게 각광받고 있다. 더불어, W/S 제형에 비해 메이크업효과, 착색효과가 더 높다는 점도 소비자들에게 긍정적인 측면으로 작용한다. Recently, matte type formulations for lip cosmetics have become popular, unlike the existing water type (W/S) silicone type, which has a moisture-like feel rather than an oily feel. Compared to the W/S formulation, which can be stuffy or drying, the S/W formulation has a high moisture content and moisturizer content, and is gaining popularity among consumers for its moist yet matte formulation. In addition, the fact that the makeup effect and coloring effect are higher compared to the W/S formulation also acts as a positive aspect for consumers.
다만 아직은 해당 제형에 대한 연구가 많이 이루어지지 않아 사용감 다변화를 위한 처방 다양화가 많이 이루어지지 않아 새로운 립 조성물의 개발이 요구되고 있다. 이 외에도 기존 제형의 조성물과 이의 개발이 특정 원료에 대한 의존도가 높기 때문에 처방 자유도가 떨어진다는 단점과, 덧바를 때 뭉친다는 단점이 있어 처방자유도를 높이면서도 기존 제형의 단점을 보완한 제형 개발이 필요하다. However, as not much research has been done on the formulation yet, there has not been much diversification of prescriptions to diversify the feeling of use, so the development of new lip compositions is required. In addition, the existing formulation composition and its development are highly dependent on specific raw materials, which reduces the freedom of prescription, and has the disadvantage of clumping when reapplied. Therefore, it is necessary to develop a formulation that improves the freedom of prescription while complementing the shortcomings of the existing formulation. do.
이에, 상기 종래 기술들의 문제점들을 극복하기 위하여 종래 수 중 실리콘 입술용 화장료에 포함되어있던 실리콘 엘라스토머 원료중 겔 성상의 원료를 배제하면서도 실리콘 오일과, 실리콘 크로스폴리머를 활용한 고함량 수분의 제형을 개발하기 위한 필요성이 있다.Therefore, in order to overcome the problems of the prior technologies, a high-moisture formulation using silicone oil and silicone crosspolymer was developed while excluding gel-like raw materials among the silicone elastomer raw materials included in conventional underwater silicone lip cosmetics. There is a need to do this.
일 양상은 휘발성 실리콘 오일, 실리콘 크로스폴리머 및 보습제를 포함하는 수중 실리콘(silicone-in-water: S/W) 제형의 입술용 화장료 조성물을 제공하는 것이다.One aspect is to provide a cosmetic composition for the lips in a silicone-in-water (S/W) formulation comprising a volatile silicone oil, a silicone crosspolymer, and a moisturizer.
일 양상은 휘발성 실리콘 오일을 포함하는 A상; 실리콘 크로스폴리머를 포함하는 B상 및 보습제를 포함하는 수중 실리콘(silicone-in-water: S/W) 제형의 입술용 화장료 조성물을 제공한다.One aspect includes Phase A comprising a volatile silicone oil; Provided is a cosmetic composition for lips in a silicone-in-water (S/W) formulation containing phase B containing a silicone crosspolymer and a moisturizer.
상기 입술용 화장료 조성물은 수 중 실리콘 (S/W) 제형으로 제조될 수 있다. 상기 S/W 제형으로 제조된 입술용 화장료 조성물은 휘발성 실리콘 오일 및 실리콘 유화제, 실리콘 크로스 폴리머를 포함하며, 다량의 물과 보습제로 포함할 수 있어 촉촉하면서도 매트한 사용감을 갖는 제형을 제공할 수 있다. 일 양상의 S/W 제형의 입술용 조성물은 기존 실리콘 중수형 (W/S) 제형에 비해 수분함량이 높아 보습효과가 뛰어나며, 착색효과 또한 W/S 제형에 비해 뛰어나다. 외상이 오일로 구성되어있는 W/S 제형은 동일한 유기색소/착색색소가 들어가더라도 피부와의 친수성이 떨어지기 때문에 착색이 잘 되지 않는 반면, 일 양상의 S/W 제형은 착색효과가 뛰어나기 때문에 메이크업 조성료로써 유용하게 활용될 수 있다. 더불어, 기존 W/S 제형에서는 실리콘엘라스토머, 실리콘겔을 다량으로 활용한 반면, 일 양상의 입술용 조성물은 저점도 휘발성 실리콘 오일과, 실리콘 크로스폴리머를 사용하여 매트한 사용감을 냈기 때문에 W/S 제형 대비 더 얇고 고른 발림성을 가지며 종전 제형의 문제점인 뭉치거나 밀리는 현상을 개선할 수 있다. The cosmetic composition for lips may be prepared in a silicone-in-water (S/W) formulation. The cosmetic composition for lips manufactured using the above S/W formulation contains volatile silicone oil, a silicone emulsifier, and a silicone cross polymer, and can contain a large amount of water and a moisturizer to provide a formulation with a moist and matte feel. . In one aspect, the lip composition of the S/W formulation has a higher moisture content than the existing silicone heavy water type (W/S) formulation, so it has an excellent moisturizing effect, and the coloring effect is also superior to the W/S formulation. The W/S formulation, whose outer layer is composed of oil, does not color well even if the same organic pigment/coloring pigment is added because it has poor hydrophilicity with the skin, whereas the S/W formulation in one aspect has an excellent coloring effect. It can be useful as a makeup composition. In addition, while the existing W/S formulation used a large amount of silicone elastomer and silicone gel, one aspect of the lip composition used low-viscosity volatile silicone oil and silicone crosspolymer to create a matte feeling. It is thinner and more evenly applied compared to other formulations, and can improve the clumping or rolling phenomenon that was a problem with previous formulations.
아울러, 상기 입술용 화장료 조성물은 도포한 직후에는 물광이 돌면서 촉촉하게 도포될 수 있으나, 도포 후 마찰을 일으킨 후에는 매트한 마무리감을 가지는 외관이 변하는 트랜스포밍(transforming) 제형인 것에 특징이 있다. In addition, the cosmetic composition for the lips can be applied moistly with a watery sheen immediately after application, but is characterized by being a transforming formulation in which the appearance changes to a matte finish after friction occurs after application.
상기 실리콘 크로스폴리머는 입술용 화장료 조성물 내에 포함됨으로써 입술에 도포되는 경우 매트한 사용감을 가능하게 한다. 상기 실리콘 크로스폴리머는 겔, 페이스트 또는 파우더, 또는 물에 분산된 액상의 형태일 수 있다. 상기 실리콘 엘라스토머는 해당 분야에서 공지된 모든 실리콘 엘라스토머가 사용될 수 있으나, 예를 들면 다이메티콘 크로스폴리머, 비닐 다이메티콘 크로스폴리머, 다이메티콘/비닐 다이메티콘 크로스폴리머, 다이메티콘크로스폴리머-3, 또는 이들의 조합으로부터 선택된 것일 수 있다.The silicone crosspolymer is included in the lip cosmetic composition to enable a matte feeling when applied to the lips. The silicone crosspolymer may be in the form of a gel, paste, powder, or liquid dispersed in water. The silicone elastomer may be any silicone elastomer known in the relevant field, for example, dimethicone crosspolymer, vinyl dimethicone crosspolymer, dimethicone/vinyl dimethicone crosspolymer, dimethicone crosspolymer- 3, or a combination thereof.
일 양상의 입술용 화장료 조성물은 휘발성 실리콘 오일이 포함될 수 있으며, 상기 휘발성 실리콘 오일은 예를 들면 사이클로펜타실록산, 사이클로헥사실록산, 트라이실록산, 카프릴릴메티콘, 메틸트리메티콘, 페닐 트리메티콘, 다이페닐실록시페닐트라이메티콘, 및 다이메티콘, 다이메티콘올로 이루어진 군으로부터 선택된 1종 이상을 포함하는 것일 수 있다. One aspect of the cosmetic composition for lips may include volatile silicone oil, and the volatile silicone oil may include, for example, cyclopentasiloxane, cyclohexasiloxane, trisiloxane, caprylylmethicone, methyltrimethicone, phenyl trimethicone, It may include one or more types selected from the group consisting of diphenylsiloxyphenyltrimethicone, dimethicone, and dimethiconol.
일 양상의 입술용 화장료 조성물의 A상은 유화제가 추가적으로 포함될 수 있다. 상기 A상에 휘발성 실리콘 오일 이외에 추가되는 유화제는 통상적으로 활용되는 유화제가 사용될 수 있다. 일 양상의 화장료 조성물에 활용되는 유화제는 실리콘 유화제를 포함할 수 있다. 또한 상기 유화제는 예를 들면 세틸피이지/피피지-10/1다이메티콘, 라우릴피이지-10트리스(트라이메틸실록시)실릴에틸다이메티콘, 라우릴피이지-9폴리다이메틸실록시에틸다이메티콘, 피이지-10다이메티콘, 폴리글리세릴-3폴리다이메틸실록시에틸다이메티콘, 라우릴폴리글리세릴-3폴리다이메틸실록시에틸다이메티콘, 피이지/피피지-19/19다이메티콘, 및 피이지-11메틸에터다이메티콘으로 이루어진 군으로부터 선택된 1종 이상을 포함하는 것일 수 있다.Phase A of the lip cosmetic composition may additionally contain an emulsifier. The emulsifier added to phase A in addition to the volatile silicone oil may be a commonly used emulsifier. Emulsifiers used in one aspect of the cosmetic composition may include silicone emulsifiers. In addition, the emulsifiers include, for example, cetyl PEG/PPG-10/1 dimethicone, lauryl PEG-10 tris(trimethylsiloxy)silylethyldimethicone, and lauryl PEG-9 polydimethylsilone. Siethyl Dimethicone, PEG-10 Dimethicone, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, PEG/P It may include one or more types selected from the group consisting of sebum-19/19 dimethicone, and sebum-11 methyl ether dimethicone.
상기 입술용 조성물에 포함되는 보습제는 폴리올이 포함될 수 있으며, 이러한 보습제는 입술 피부에 대한 밀착감과 보습감을 부여해줄 수 있다. 예를 들면 상기 보습제는 다이글리세린, 1,3-프로판다이올, 1,3-부틸렌 글라이콜, 2,3-부탄다이올, 프로필렌글라이콜, 다이프로필렌글라이콜, 글리세레스-26, 또는 이들의 혼합물로부터 선택된 것일 수 있다. The moisturizer included in the lip composition may include polyol, and this moisturizer can provide a feeling of adhesion and moisturization to the lip skin. For example, the moisturizer includes diglycerin, 1,3-propanediol, 1,3-butylene glycol, 2,3-butanediol, propylene glycol, dipropylene glycol, and glycerol-26. , or a mixture thereof.
종래 수 중 실리콘 입술 화장료 조성물에는 30~50 중량%의 실리콘 크로스폴리머가 포함된 혼합 원료가 사용됨으로써, 입술용 조성물에 추가적으로 포함될 수 있는 오일 및 보습제 함량에 제한이 있었으나, 일 양상의 입술용 화장료 조성물은, 실리콘 크로스폴리머가 포함된 혼합원료가 화장료 조성물 총 중량을 기준으로 1~20 중량% 포함되어있어 기존 입술 화장료 조성물에 비해 약 20~40 중량% 가량의 오일 및 보습제를 더 추가할 수 있다는 처방자유도의 이점이 있다. 이로써 종전 수 중 실리콘 입술 화장료 조성물에 비해 훨씬 덜 건조하고 사용감 다변화가 가능한 입술용 화장료 조성물을 제공할 수 있다.Conventional underwater silicone lip cosmetic compositions used mixed raw materials containing 30 to 50% by weight of silicone crosspolymer, which limited the amount of oil and moisturizer that could be additionally included in the lip composition. However, one aspect of the lip cosmetic composition Since mixed raw materials containing silver and silicone crosspolymer are contained 1 to 20% by weight based on the total weight of the cosmetic composition, the prescription states that approximately 20 to 40% by weight of oil and moisturizer can be added compared to existing lip cosmetic compositions. There is the advantage of freedom. As a result, it is possible to provide a cosmetic composition for the lips that is much less dry than the existing underwater silicone lip cosmetic composition and allows for a variety of uses.
일 양상의 입술용 조성물은 유상으로 일컬어지는 A상 및 수상으로 일컬어지는 B상 및 보습제를 포함하는 C상을 포함할 수 있다. 일 양상에 있어서, 상기 A상은 화장료 조성물 총 중량을 기준으로 예를 들면 10 내지 65중량%, 10 내지 60중량%, 10 내지 55중량%, 10 내지 50중량%, 10 내지 45중량%, 10 내지 40중량%, 10 내지 35중량%, 10 내지 32중량%, 15 내지 65중량%, 15 내지 60중량%, 15 내지 55중량%, 15 내지 50중량%, 15 내지 45중량%, 15 내지 40중량%, 15 내지 35중량%, 15 내지 32중량%, 20 내지 65중량%, 20 내지 60중량%, 20 내지 55중량%, 20 내지 50중량%, 20 내지 45중량%, 20 내지 40중량%, 20 내지 35중량%, 또는 20 내지 32중량%로 포함될 수 있다.One aspect of the lip composition may include a phase A, referred to as an oil phase, a phase B, referred to as an aqueous phase, and a C phase including a moisturizer. In one aspect, the A phase is, for example, 10 to 65% by weight, 10 to 60% by weight, 10 to 55% by weight, 10 to 50% by weight, 10 to 45% by weight, 10 to 10% by weight, based on the total weight of the cosmetic composition. 40% by weight, 10 to 35% by weight, 10 to 32% by weight, 15 to 65% by weight, 15 to 60% by weight, 15 to 55% by weight, 15 to 50% by weight, 15 to 45% by weight, 15 to 40% by weight %, 15 to 35% by weight, 15 to 32% by weight, 20 to 65% by weight, 20 to 60% by weight, 20 to 55% by weight, 20 to 50% by weight, 20 to 45% by weight, 20 to 40% by weight, It may be included in 20 to 35% by weight, or 20 to 32% by weight.
상기 B상은 화장료 조성물 총 중량을 기준으로 예를 들면 1 내지 35중량%, 1 내지 30중량%, 1 내지 25중량%, 1 내지 20중량%, 1 내지 15중량%, 1 내지 12중량%, 1 내지 10중량%, 3 내지 12중량%, 또는 5 내지 12중량%로 포함될 수 있다.The B phase is, for example, 1 to 35% by weight, 1 to 30% by weight, 1 to 25% by weight, 1 to 20% by weight, 1 to 15% by weight, 1 to 12% by weight, 1 based on the total weight of the cosmetic composition. It may be included in an amount of from 10% by weight, 3 to 12% by weight, or 5 to 12% by weight.
상기 보습제는 1 내지 20중량%, 1 내지 15중량%, 1 내지 10중량%, 1 내지 8중량%, 또는 1 내지 6중량%로 포함될 수 있다. The humectant may be included at 1 to 20% by weight, 1 to 15% by weight, 1 to 10% by weight, 1 to 8% by weight, or 1 to 6% by weight.
또한 일 양상의 입술용 화장료 조성물은 화장료 조성물 총 중량을 기준으로 상기 휘발성 실리콘 오일을 예를 들면 10 내지 30중량%, 10 내지 25중량%, 15 내지 30중량%, 또는 15 내지 25중량%로 포함하는 것일 수 있다.In addition, the cosmetic composition for lips in one aspect includes, for example, 10 to 30% by weight, 10 to 25% by weight, 15 to 30% by weight, or 15 to 25% by weight of the volatile silicone oil based on the total weight of the cosmetic composition. It may be.
일 양상의 입술용 화장료 조성물은 화장료 조성물 총 중량을 기준으로 상기 실리콘 크로스폴리머를 예를 들면 1 내지 20중량%, 1 내지 15중량%, 1 내지 10중량%, 또는 5 내지 10중량%로 포함할 수 있다. 상기 실리콘 크로스폴리머 함량이 상기 범위를 벗어나 높아지면 입술이 지나치게 건조해지고, 원료가 때처럼 밀리는 현상이 발생할 수 있다.In one aspect, the cosmetic composition for lips may include, for example, 1 to 20% by weight, 1 to 15% by weight, 1 to 10% by weight, or 5 to 10% by weight of the silicone crosspolymer based on the total weight of the cosmetic composition. You can. If the silicone crosspolymer content exceeds the above range, the lips may become excessively dry and the raw material may become dirty.
일 양상의 입술용 화장료 조성물은 상기 실리콘 오일, 추가 보습제, 방부제, 정제수 및 색소로 이루어진 군으로부터 선택된 1종 이상을 더 포함하는 것일 수 있다. In one aspect, the cosmetic composition for lips may further include one or more selected from the group consisting of silicone oil, additional moisturizer, preservative, purified water, and colorant.
상기 추가 보습제는 B상에 포함된 보습제 이외에 더 포함될 수 있는 보습제를 의미하며, 예를 들어 폴리올일 수 있으나, 구체적으로 글리세린일 수 있다. The additional moisturizer refers to a moisturizer that may be included in addition to the moisturizer included in phase B. For example, it may be polyol, but may specifically be glycerin.
상기 화장료 조성물은 오일을 더 포함할 수 있으며, 상기 오일은 비휘발성 실리콘 오일 또는 휘발성 실리콘 오일을 포함할 수 있다. 또한 본 명세서에서 용어 "비휘발성 오일"은 실온 및 대기압에서, 적어도 수시간 동안 남아있는 오일을 지칭할 수 있다. 구체적으로, 상기 비휘발성 오일은 비휘발성 실리콘오일, 비휘발성 탄화수소계오일, 또는 이들의 혼합물을 포함할 수 있다.The cosmetic composition may further include oil, and the oil may include non-volatile silicone oil or volatile silicone oil. Also, as used herein, the term “non-volatile oil” may refer to oil that remains at room temperature and atmospheric pressure for at least several hours. Specifically, the non-volatile oil may include non-volatile silicone oil, non-volatile hydrocarbon-based oil, or a mixture thereof.
상기 입술용 화장료 조성물은 수상 색소 및/또는 안료를 더 포함할 수 있으며, 화장료 조성물의 총 중량 대비 예를 들면0.01 내지 1중량%, 또는 0.1 내지 1중량%로 포함하는 것일 수 있다. 상기 색소 또는 안료는 당해 분야에서 공지된 것이라면 임의의 것을 사용할 수 있으며, 염료 또는 안료의 함량은 사용되는 성분 및 목적하는 색상의 강도에 따라 당해 분야의 통상의 기술자가 임의로 변형 가능하다. 상기 색소는 유기색소, 수상색소 또는 이들의 조합을 더 포함할 수 있다. 구체적으로, 상기 안료는 황색 203호, 황색 4호, 황색 5호, 황색 201호, 황색 204호, 적색 103호, 적색 201호, 적색 202호, 적색 218호, 적색 220호, 적색 223호, 적색 226호, 적색 227호, 청색 1호, 청색 2호 등의 바륨 또는 알루미늄 레이크의 유기 안료 및 진주 안료 등의 착색용 안료를 포함할 수 있다.The cosmetic composition for lips may further include an aqueous colorant and/or pigment, and may be included in, for example, 0.01 to 1% by weight, or 0.1 to 1% by weight, based on the total weight of the cosmetic composition. The dye or pigment can be used as long as it is known in the art, and the content of the dye or pigment can be arbitrarily modified by a person skilled in the art depending on the ingredients used and the intensity of the desired color. The pigment may further include an organic pigment, an aqueous pigment, or a combination thereof. Specifically, the pigments are Yellow No. 203, Yellow No. 4, Yellow No. 5, Yellow No. 201, Yellow No. 204, Red No. 103, Red No. 201, Red No. 202, Red No. 218, Red No. 220, Red No. 223, It may include organic pigments of barium or aluminum lake, such as Red No. 226, Red No. 227, Blue No. 1, and Blue No. 2, and coloring pigments such as pearl pigments.
상기 입술용 화장료 조성물은 예를 들면 립스틱, 립글로스, 립밤, 립틴트, 립파렛트 및 립라이너로 이용될 수 있다.The cosmetic composition for lips can be used, for example, as lipstick, lip gloss, lip balm, lip tint, lip palette, and lip liner.
상기 화장료 조성물은 보존제, 안정화제, 계면활성제, 점증제, 용해제, 보습제, 에몰리언트제, 자외선 흡수제, 방부제, 살균제, 유화제, 산화 방지제, pH 조정제, 유기 및 무기 안료, 향료, 냉감제 또는 제한제 등 당해 분야에서 통상적으로 이용되는 첨가물을 더 포함할 수 있다. 상기 보존제 등의 추가 성분의 배합량은 본 발명의 목적 및 효과를 손상시키지 않는 범위 내에서 당업자가 용이하게 선정 가능하며, 그 배합량은 조성물 전체 중량을 기준으로 0.001 내지 40 중량%일 수 있다.The cosmetic composition includes preservatives, stabilizers, surfactants, thickeners, solubilizers, moisturizers, emollients, ultraviolet absorbers, preservatives, disinfectants, emulsifiers, antioxidants, pH adjusters, organic and inorganic pigments, fragrances, coolants or antiperspirants, etc. It may further include additives commonly used in the field. The mixing amount of additional ingredients such as the preservative can be easily selected by a person skilled in the art within a range that does not impair the purpose and effect of the present invention, and the mixing amount may be 0.001 to 40% by weight based on the total weight of the composition.
일 양상에 따른 입술용 화장료 조성물은 수 중 실리콘 (S/W) 제형으로, 휘발성 실리콘 오일, 실리콘 크로스폴리머 및 보습제를 포함하여, 촉촉하면서도 매트한 사용감을 가지며, 종전 W/S 제형에 비해 착색효과가 뛰어나기 때문에 메이크업 조성료로 우수하게 활용될 수 있다. 또한 일 양상에 따른 입술용 화장료 조성물은 기존 S/W 제형과 달리 겔 성상의 실리콘 엘라스토머가 없는 조성물로, 뭉침 현상과 보습력이 개선된 입술용 화장료 조성물로써 유용하게 활용될 수 있다.The cosmetic composition for lips according to one aspect is a water-based silicone (S/W) formulation, contains volatile silicone oil, silicone crosspolymer, and moisturizer, has a moist and matte feel, and has a coloring effect compared to the previous W/S formulation. Because it is excellent, it can be excellently used as a makeup composition. In addition, the cosmetic composition for lips according to one aspect, unlike existing S/W formulations, is a composition without gel-like silicone elastomer, and can be usefully used as a cosmetic composition for lips with improved clumping and moisturizing properties.
도 1은 실시예 1 조성물을 입술에 도포한 직후(왼쪽)과 도포 후 입술을 위아래로 포개어 마찰을 일으킨 후(오른쪽)을 나타낸 도이다.
도 2는 실시예 1 조성물을 손등에 도포한 직후의 상태를 확인한 도이다.
도 3은 실시예 1 조성물을 손등에 도포한 후 손가락을 이용해 3~5회 문지른 후의 외관을 확인한 도이다.
도 4는 실시예 1 조성물을 손등에 도포 후 손가락으로 3~5회 문지른 후의 상태를 확인한 도이다.
도 5는 비교예 1 조성물을 손등에 도포 후 손가락으로 3~5회 문지른 후의 상태를 확인한 도이다.Figure 1 is a diagram showing the composition of Example 1 immediately after applying it to the lips (left) and after applying the composition by overlapping the lips up and down to cause friction (right).
Figure 2 is a diagram confirming the state immediately after applying the composition of Example 1 to the back of the hand.
Figure 3 is a diagram confirming the appearance after applying the composition of Example 1 to the back of the hand and rubbing it 3 to 5 times with a finger.
Figure 4 is a diagram confirming the state after applying the composition of Example 1 to the back of the hand and rubbing it 3 to 5 times with a finger.
Figure 5 is a diagram confirming the state after applying the composition of Comparative Example 1 to the back of the hand and rubbing it 3 to 5 times with a finger.
이하 본 발명을 실시예 및 실험예를 통하여 보다 상세하게 설명한다. 그러나, 이들 실시예 및 실험예는 본 발명을 예시적으로 설명하기 위한 것으로 본 발명의 범위가 이들 실시예 및 실험예에 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail through examples and experimental examples. However, these examples and experimental examples are for illustrative purposes only and the scope of the present invention is not limited to these examples and experimental examples.
실시예 및 비교예 1 내지 2 조성물의 제조Examples and Comparative Examples 1 to 2 Preparation of compositions
아래 표 1과 같은 조성으로 실시예 및 비교예 1 내지 2의 매트 타입의 입술 화장료 조성물을 제조하였다.Matte type lip cosmetic compositions of Examples and Comparative Examples 1 to 2 were prepared with the compositions shown in Table 1 below.
(저점도 휘발성 실리콘오일)Caprylylmethicone
(Low viscosity volatile silicone oil)
(페닐트라이메티콘)5.0
(phenyltrimethicone)
(다이페닐실록시페닐트라이메티콘, 트라이메틸실록시페닐다이메티콘)18.0
(Diphenylsiloxyphenyltrimethicone, trimethylsiloxyphenyldimethicone)
(다이메티콘/비닐다이메티콘크로스폴리머; 수상)B prize
(Dimethicone/Vinyl Dimethicone Crosspolymer; Award)
6.36
(보습제, 정제수)C prize
(Moisturizer, purified water)
실시예 1 및 비교예 1, 2는 상기 표 1의 성분과 함량에 따라 각 원료를 비이커에 계량한 후 고형상인 원료가 녹을 때까지 대략 70~80℃의 온도로 가온한 후, 아지믹서, 디스퍼를 이용하여 약 100rpm으로 15분간 균일하게 혼합하였다. 실시예 1과 비교예 1의 경우, 다이메티콘/비닐다이메이콘크로스폴리머가 포함된 혼합원료를 수상에 투입후 10분간 분산하였고, 상기 원료가 포함되지 않는 비교예 2의 경우는 해당 과정이 생략되었다. 이후 상기 조성을 가진 수상과 유상을 혼합 후 호모 믹서(Homo Mixer)를 사용하여 7000rpm 으로 15분간 균일하게 혼합한 후, 냉각 후 점증제를 투입 후 7분간 추가 혼합 후, 35℃로 냉각한 후, 기포를 제거하여 화장료 조성물을 제조하였다.In Example 1 and Comparative Examples 1 and 2, each raw material was weighed in a beaker according to the ingredients and contents in Table 1, heated to a temperature of approximately 70 to 80 ° C. until the solid raw material was melted, and then mixed with an azimixer and diss. The mixture was uniformly mixed using a whisk at about 100 rpm for 15 minutes. In the case of Example 1 and Comparative Example 1, mixed raw materials containing dimethicone/vinyl dimacone crosspolymer were added to the water phase and dispersed for 10 minutes, and in the case of Comparative Example 2, which did not contain the above raw materials, the process was omitted. After mixing the water phase and the oil phase with the above composition, mix uniformly at 7000 rpm for 15 minutes using a homo mixer, cool, add the thickener, mix for an additional 7 minutes, cool to 35°C, and add bubbles. was removed to prepare a cosmetic composition.
실험예 1. 실시예 및 비교예 1 내지 2 조성물에 따른 제형 비교Experimental Example 1. Examples and Comparative Examples 1 to 2 Comparison of formulations according to composition
1.1 실시예 1 조성물의 제형의 비교1.1 Comparison of formulations of Example 1 compositions
상기 제조된 실시예 1과 비교예 1 내지 2의 제형을 비교하였다. 상기 실시예 1과 비교예 1의 유상은 다르게 구성되어 있다. 또한 실시예 1의 경우 끈적이지 않고 보습제를 유동성이 높은 2,3-부탄다이올을 포함하였으며, 비교예 1,2의 경우에는 통상의 보습제로 사용하는 글리세린을 포함시켰다.The formulations of Example 1 prepared above and Comparative Examples 1 to 2 were compared. The oil phases of Example 1 and Comparative Example 1 were composed differently. In addition, in Example 1, 2,3-butanediol, which is not sticky and has high fluidity as a moisturizer, was included, and in Comparative Examples 1 and 2, glycerin, which is used as a conventional moisturizer, was included.
실시예 1의 경우, 라우릴피이지-9폴리다이메틸실록시에틸다이메티콘 및 피이지-10다이메티콘을 포함하는 실리콘 유화제를 포함한 유화제와 저점도의 휘발성 실리콘 오일인 카프릴릴메티콘이 20중량%로 포함되어 있어 계면장력이 매우 낮으며, 비교예 1의 경우 유화제를 포함한, 겔 성상의 실리콘 엘라스토머가 포함되어 유동성을 거의 갖지 않음을 확인하였다. 비교예 2의 경우 일반적인 글로스 제형의 수 중 유 (O/W) 제형으로, 문지름에 따라 사용감 변화가 없는 제형으로, 트랜스포밍 제형에 해당되지 않음을 확인하였다. In Example 1, an emulsifier containing a silicone emulsifier containing lauryl PEG-9 polydimethylsiloxyethyldimethicone and PEG-10 dimethicone and caprylylmethicone, a low viscosity volatile silicone oil, were used. Since it was contained at 20% by weight, the interfacial tension was very low, and in the case of Comparative Example 1, it was confirmed that it had almost no fluidity because it contained a gel-like silicone elastomer including an emulsifier. In the case of Comparative Example 2, it was an oil-in-water (O/W) formulation of a general gloss formulation, and it was confirmed that it was a formulation that did not change the feeling of use depending on rubbing, and did not correspond to a transforming formulation.
아울러, 실시예 1에서 사용한 B상을 기준으로 다이메티콘/비닐다이메티콘크로스폴리머가 63.6%, 정제수 35.5%, 이외에 유화안정제와 방부제로 구성되어 있는 혼합원료를 화장료 조성물 총 중량을 기준으로 10.0%로 포함하였다, 비교예 1에서 사용한 B상을 기준으로 다이메티콘/비닐다이메티콘크로스폴리머 가 11.5%, 정제수가 27.9%, 다이메티콘 55%, 이외 유화안정제와 점증제로 구성되어 있는 원료를 화장료 조성물 총 중량을 기준으로 45.0% 로 포함하였다.In addition, based on phase B used in Example 1, the mixed raw materials consisting of 63.6% dimethicone/vinyl dimethicone crosspolymer, 35.5% purified water, and emulsion stabilizers and preservatives were mixed at 10.0% based on the total weight of the cosmetic composition. Included in percentage, based on phase B used in Comparative Example 1, the raw materials consist of 11.5% dimethicone/vinyl dimethicone crosspolymer, 27.9% purified water, 55% dimethicone, and other emulsion stabilizers and thickeners. It was included at 45.0% based on the total weight of the cosmetic composition.
즉, 트랜스포밍 제형에서 핵심 원료로 사용되는 B상의 다이메티콘/비닐다이메티콘크로스폴리머를 실시예 1 과 비교예 1에서 각기 다른 원료로 적용하였다. 다만, 비교예 1의 경우, 약 6%의 다이메티콘/비닐다이메티콘크로스폴리머를 포함하기 위해 이외 혼합원료를 약 40%로 포함하여 처방자유도가 떨어지는 반면, 실시예 1의 경우, 비교예 1보다 높은 다이메티콘/비닐다이메티콘크로스폴리머로 구성되어있음에도 불구하고 B상에 포함되는 혼합원료를 약 5%로 포함하므로, 화장료 조성물의 처방자유도가 높아 보다 다양한 오일조합으로 유상(A상)을 구성할 수 있음을 확인하였다.That is, phase B dimethicone/vinyl dimethicone crosspolymer, which is used as a key raw material in transforming formulations, was applied as a different raw material in Example 1 and Comparative Example 1. However, in the case of Comparative Example 1, the freedom of prescription is low because it contains about 40% of other mixed raw materials in order to contain about 6% of dimethicone/vinyl dimethicone crosspolymer, whereas in the case of Example 1, Comparative Example Even though it is composed of dimethicone/vinyl dimethicone crosspolymer higher than 1, it contains about 5% of the mixed raw materials included in phase B, so the degree of freedom in prescribing the cosmetic composition is high, allowing oil phase (phase A) to be used in more diverse oil combinations. ) was confirmed to be configurable.
상기 트랜스포밍(transforming) 제형임을 확인한 실시예 1 조성물을 실제 입술에 도포한 직후를 도 1의 왼쪽에 도포 이후 입술을 위아래로 포개어 마찰을 일으킨 이후를 도 1의 오른쪽에 나타내었다.The Example 1 composition, which was confirmed to be the transforming formulation, is shown on the left side of Figure 1 immediately after the composition was actually applied to the lips, and the right side of Figure 1 shows after the composition was applied and the lips were overlapped up and down to cause friction.
상기 도 1에서 확인한 바와 같이, 도포 직후에는 물광이 돌면서 촉촉한 외관을 보이는 반면, 입술을 문지른 후에는 매트한 외관을 나타나는 것을 확인하였다. 이처럼 실시예 1 조성물은 도포한 이후 그 외관이 변하는 트랜스포밍(transforming) 제형의 특징이 나타나는 것을 확인하였다. As confirmed in Figure 1, it was confirmed that immediately after application, it had a moist appearance with a watery sheen, while after rubbing the lips, it had a matte appearance. In this way, it was confirmed that the composition of Example 1 exhibited the characteristics of a transforming formulation in which its appearance changed after application.
아울러, 상기와 같은 실시예 1 조성물의 제형의 변화를 손등에서 재확인하였으며, 손등에 어플리케이터(팁)을 이용하여 도포한 후를 도 2에 나타내었고, 상기 실시예 1 조성물을 도포한 이후 손가락을 이용해 3~5회 문지른 후의 외관을 확인하고 이를 도 3에 나타내었다.In addition, the change in formulation of the composition of Example 1 as described above was confirmed again on the back of the hand, and is shown in Figure 2 after application to the back of the hand using an applicator (tip). After applying the composition of Example 1, it was applied using a finger. The appearance after rubbing 3 to 5 times was confirmed and shown in Figure 3.
상기 도 2에서 확인한 바와 같이, 실시예 1 조성물을 손등에 어플리케이터(팁)을 이용하여 도포한 직후는 물광에 의해 빛이 반사되는 것을 확인할 수 있었다. 도 3에서 확인한 바와 같이, 실시예 1 조성물을 손가락을 이용해 3~5회 문지른 경우, 도 2에서의 물광과 두께감이 확연하게 줄어들어 색만 남은 듯한 매트한 외관을 확인할 수 있었다. 이에, 다시 한번 손등에서도 마찰력에 의해 실시예 1 조성물을 도포한 곳의 외관이 바뀌는 트랜스포밍(transforming) 제형의 특징이 나타나는 것을 확인하였다. As confirmed in FIG. 2, it was confirmed that light was reflected by water shine immediately after the composition of Example 1 was applied to the back of the hand using an applicator (tip). As confirmed in Figure 3, when the composition of Example 1 was rubbed 3 to 5 times with a finger, the water shine and thickness in Figure 2 were significantly reduced, resulting in a matte appearance as if only color remained. Accordingly, it was confirmed once again that the characteristics of a transforming formulation, in which the appearance of the area where the composition of Example 1 was applied changed due to frictional force, were also observed on the back of the hand.
1.2 실시예 1 조성물 및 비교예 1 조성물에 대한 제형의 비교1.2 Comparison of formulations for the composition of Example 1 and Comparative Example 1
상기 실험예에서 트랜스포밍 제형임을 확인한 실시예 1 조성물과 기존 수 중 실리콘 (S/W) 제형인 비교예 1 조성물을 손등에 도포한 이후의 제형을 비교하는 실험을 수행하였다. 실시예 1 조성물을 손등에 도포 후 손가락으로 3~5회 문지른 후를 확인한 결과를 도 4에, 비교예 1 조성물을 손등에 도포 후 손가락으로 3~5회 문지른 후를 확인한 결과를 도 5에 나타내었다.An experiment was conducted to compare the composition of Example 1, which was confirmed to be a transforming formulation in the above experimental example, and the formulation of Comparative Example 1, which was an existing silicone-in-water (S/W) formulation, after applying it to the back of the hand. Figure 4 shows the results obtained after applying the composition of Example 1 to the back of the hand and rubbing it 3 to 5 times with the finger, and Figure 5 shows the results obtained after applying the composition of Comparative Example 1 to the back of the hand and rubbing it 3 to 5 times with the finger. It was.
상기 도 4에서 확인한 바와 같이 실시예 1 조성물은 도포 후 손가락으로 3~5회 문지른 경우에도 제형 밀림이나 뭉침 현상이 없는 것을 확인하였으나, 도 5에서 확인할 수 있는 바와 같이, 비교예 1 조성물은 제형 밀림이나 뭉침 현상이 나타나는 것을 확인하였다. As confirmed in FIG. 4, it was confirmed that the composition of Example 1 did not cause the formulation to slip or clump even when rubbed 3 to 5 times with a finger after application. However, as can be seen in FIG. 5, the composition of Comparative Example 1 did not cause the formulation to slip. It was confirmed that agglomeration phenomenon occurred.
실험예 2. 입술용 화장료 화장료 조성물의 관능 평가Experimental Example 2. Sensory evaluation of lip cosmetic composition
상기 기재한 제조방법에 따라 제조된 입술용 화장료 조성물인 실시예 1 및 비교예 1 내지 2의 관능평가를 수행하였다. 상기 실시예 1, 비교예 1 및 2에 따른 화장료 조성물을 20 ~ 35 세 사이의 전문 여성 패널 10명을 대상으로 사전정보에 대한 고지없이 블라인드 테스트로 진행하였다. 이후 바를 때 느끼는 사용감에 관한 수분감, 매트함, 묻어나옴, 광택 등의 전반적인 사용감을 평가하여 그 결과를 하기 표 2에 나타내었다.Sensory evaluation of Example 1 and Comparative Examples 1 to 2, which were cosmetic compositions for lips prepared according to the manufacturing method described above, was performed. The cosmetic compositions according to Example 1 and Comparative Examples 1 and 2 were blind tested on 10 professional female panels between the ages of 20 and 35 without prior information. Afterwards, the overall feeling of use, such as moisture, matteness, staining, and gloss, was evaluated when applied, and the results are shown in Table 2 below.
각각의 지표는 5점 만점으로 확인하였으며, 이후 10명의 평가점수의 평균을 아래와 같이 확인하였다. Each indicator was confirmed with a score out of 5, and the average of the evaluation scores of 10 people was confirmed as follows.
상기 표 2에 나타난 결과, 기존 수 중 실리콘 (S/W) 제형인 비교예 1의 경우 수분감이 떨어지며, 무광에 가까운 매트로 건조한 것을 확인하였으며, 비교예 1 조성물의 최대 단점인 제형 뭉침이 나타나는 것을 확인하였다. 이러한 제형 뭉침으로 인해 비교예 1 조성물은 수정 화장이나 덧바르기가 용이하지 않음을 확인할 수 있었다.As a result of the results shown in Table 2, it was confirmed that Comparative Example 1, which is an existing underwater silicone (S/W) formulation, had poor moisture content and dried to a matte color close to matte, and that the formulation clumping appeared, which was the biggest disadvantage of the composition of Comparative Example 1. Confirmed. It was confirmed that the composition of Comparative Example 1 was not easy to correct makeup or reapply due to this formulation agglomeration.
가장 보편적인 수 중 유 (O/W) 제형인 글로시 타입의 비교예 2의 경우, 다이메티콘/비닐다이메이콘크로스폴리머가 전혀 포함되지 않은 조성물로, 문지름에 따른 제형 변화 없이 도포 직후와 문지른 후의 외관이 모두 광택이 도는 글로시 제형이며, 수분감과 광택이 많은 것을 확인하였다. 다만, 묻어남이 심하여 실제 사용 시 편리하지 않음을 확인하였고, 더욱이 비교예 2 조성물은 매트타입의 입술용 화장료 제품으로는 적합하지 않은 조성물임을 확인하였다. In the case of Comparative Example 2 of the glossy type, which is the most common oil-in-water (O/W) formulation, it is a composition that does not contain dimethicone/vinyl dimacone crosspolymer at all, and is effective immediately after application and after rubbing without changing the formulation due to rubbing. It was confirmed that the overall appearance was a glossy formulation with a lot of moisture and gloss. However, it was confirmed that it was not convenient for actual use due to severe staining, and furthermore, it was confirmed that the composition of Comparative Example 2 was not suitable as a matte type lip cosmetic product.
반면, 기존 수 중 실리콘 (W/S) 제형인 비교예 1의 묻어나지 않는 장점과, 비교예 2의 수분감을 살리면서도 비교예 1의 가장 큰 단점인 제형 밀림 현상을 개선한 실시예 1은 수분감이 가장 많이 느껴지면서도, 트랜스포밍 제형으로 문지른 후에 매트해지는 사용감 변화로 인해 패널들이 신선하다고 평가하였다. 또한 실시예 1 조성물은 매트하면서도 건조하지 않고, 밀림 현상이 없어 여러 번 덧바르기에 용이하여 수정화장이 쉬워 사용감의 편리성을 확인할 수 있었다. On the other hand, Example 1, which took advantage of the non-smearing advantage of Comparative Example 1, which is an existing underwater silicone (W/S) formulation, and the moisturizing feeling of Comparative Example 2, while improving the formulation slipping phenomenon, which was the biggest disadvantage of Comparative Example 1, had a moisturizing feeling. Although this was felt the most, the panels were evaluated as fresh due to the change in feeling of use that became matte after rubbing with the transforming formulation. In addition, the composition of Example 1 was matte but not dry, and did not cause any shedding, so it was easy to reapply several times and touch-up makeup was confirmed, making it convenient to use.
실험예 3. 입술용 화장료 화장료 조성물의 제형 안정도 확인Experimental Example 3. Confirmation of formulation stability of lip cosmetic composition
상기 표 1의 구성에 따라 제조된 실시예 1 및 비교예 1 조성물의 제형 안정도를 온도를 달리한 조건에서 확인하였다. 구체적으로 20ml 유리 바이알에 상기 실시예 1 및 비교예 1 조성물 10g을 충전시킨 후, 25℃, 37℃, 45℃, 및 -10℃~-40℃사이클 조건의 항온조에 4주 방치하여 안정도를 확인하고, 이를 표 3에 나타내었다.The formulation stability of the compositions of Example 1 and Comparative Example 1 prepared according to the composition in Table 1 was confirmed under different temperature conditions. Specifically, 10 g of the compositions of Example 1 and Comparative Example 1 were filled into a 20 ml glass vial, and then left in a constant temperature bath under cycle conditions of 25°C, 37°C, 45°C, and -10°C to -40°C for 4 weeks to check stability. And this is shown in Table 3.
(-10℃~ 40℃)Cycle
(-10℃~40℃)
상기 표 3에서 확인한 바와 같이, 실시예 1 조성물은 모든 조건에서 4주 간 제형분리가 나타나지 않은 것을 확인하였으나, 고형상의 실리콘 엘라스토머 포함된 비교예 1의 경우 고온에서 약한 분리현상을 보였으며, 특히나 온도가 변하는 cycle 조건에서 가장 취약한 것을 확인하였다. 따라서, 비교예 1의 경우 온도에 따른 제형의 성상차이가 심한 반면, 실시예 1의 경우 온도에 따른 제형 성상 차이가 거의 없기 때문에 안정도 면에서 우수한 것을 확인하였다.As confirmed in Table 3, it was confirmed that the composition of Example 1 did not exhibit formulation separation for 4 weeks under all conditions. However, in the case of Comparative Example 1 containing solid silicone elastomer, a weak separation phenomenon was observed at high temperatures, especially It was confirmed that it was most vulnerable under cycle conditions where temperature changed. Therefore, in the case of Comparative Example 1, there was a significant difference in the properties of the formulation depending on the temperature, whereas in the case of Example 1, there was almost no difference in the properties of the formulation depending on the temperature, so it was confirmed that it was excellent in terms of stability.
Claims (10)
실리콘 크로스폴리머를 포함하는 B상 및 보습제를 포함하는 수중 실리콘(silicone-in-water: S/W) 제형의 입술용 화장료 조성물.Phase A comprising volatile silicone oil;
A cosmetic composition for lips in a silicone-in-water (S/W) formulation containing phase B containing a silicone crosspolymer and a moisturizer.
The cosmetic composition for lips according to claim 1, wherein the silicone crosspolymer is contained in an amount of 1 to 20% by weight based on the total weight of the cosmetic composition.
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