KR20240047699A - Method for manufacturing bipolar membrane and bipolar membrane - Google Patents
Method for manufacturing bipolar membrane and bipolar membrane Download PDFInfo
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- KR20240047699A KR20240047699A KR1020220127037A KR20220127037A KR20240047699A KR 20240047699 A KR20240047699 A KR 20240047699A KR 1020220127037 A KR1020220127037 A KR 1020220127037A KR 20220127037 A KR20220127037 A KR 20220127037A KR 20240047699 A KR20240047699 A KR 20240047699A
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- South Korea
- Prior art keywords
- bipolar membrane
- manufacturing
- sheet
- present
- sheet layer
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- 239000012528 membrane Substances 0.000 title claims abstract description 69
- 238000004519 manufacturing process Methods 0.000 title claims description 55
- 238000000034 method Methods 0.000 title claims description 42
- 239000003054 catalyst Substances 0.000 claims abstract description 57
- 229920000554 ionomer Polymers 0.000 claims abstract description 24
- 239000000243 solution Substances 0.000 claims description 21
- 238000002347 injection Methods 0.000 claims description 6
- 239000007924 injection Substances 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 6
- 150000001450 anions Chemical class 0.000 abstract description 9
- 150000001768 cations Chemical class 0.000 abstract description 9
- 239000010410 layer Substances 0.000 description 72
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- WZFUQSJFWNHZHM-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC(=O)N1CC2=C(CC1)NN=N2 WZFUQSJFWNHZHM-UHFFFAOYSA-N 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 4
- 239000003014 ion exchange membrane Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 3
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 2
- CONKBQPVFMXDOV-QHCPKHFHSA-N 6-[(5S)-5-[[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]methyl]-2-oxo-1,3-oxazolidin-3-yl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C[C@H]1CN(C(O1)=O)C1=CC2=C(NC(O2)=O)C=C1 CONKBQPVFMXDOV-QHCPKHFHSA-N 0.000 description 2
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 2
- 239000004696 Poly ether ether ketone Substances 0.000 description 2
- 239000004695 Polyether sulfone Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 238000005349 anion exchange Methods 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000005341 cation exchange Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- UPWOEMHINGJHOB-UHFFFAOYSA-N oxo(oxocobaltiooxy)cobalt Chemical compound O=[Co]O[Co]=O UPWOEMHINGJHOB-UHFFFAOYSA-N 0.000 description 2
- 229920006393 polyether sulfone Polymers 0.000 description 2
- 229920002530 polyetherether ketone Polymers 0.000 description 2
- 229920006380 polyphenylene oxide Polymers 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 229910021642 ultra pure water Inorganic materials 0.000 description 2
- 239000012498 ultrapure water Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- OHVLMTFVQDZYHP-UHFFFAOYSA-N 1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-2-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]ethanone Chemical compound N1N=NC=2CN(CCC=21)C(CN1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)=O OHVLMTFVQDZYHP-UHFFFAOYSA-N 0.000 description 1
- YIWGJFPJRAEKMK-UHFFFAOYSA-N 1-(2H-benzotriazol-5-yl)-3-methyl-8-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carbonyl]-1,3,8-triazaspiro[4.5]decane-2,4-dione Chemical compound CN1C(=O)N(c2ccc3n[nH]nc3c2)C2(CCN(CC2)C(=O)c2cnc(NCc3cccc(OC(F)(F)F)c3)nc2)C1=O YIWGJFPJRAEKMK-UHFFFAOYSA-N 0.000 description 1
- LDXJRKWFNNFDSA-UHFFFAOYSA-N 2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]ethanone Chemical compound C1CN(CC2=NNN=C21)CC(=O)N3CCN(CC3)C4=CN=C(N=C4)NCC5=CC(=CC=C5)OC(F)(F)F LDXJRKWFNNFDSA-UHFFFAOYSA-N 0.000 description 1
- IHCCLXNEEPMSIO-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)CC(=O)N1CC2=C(CC1)NN=N2 IHCCLXNEEPMSIO-UHFFFAOYSA-N 0.000 description 1
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 1
- 229910002588 FeOOH Inorganic materials 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- -1 SnClxOHy Chemical compound 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- FHKPLLOSJHHKNU-INIZCTEOSA-N [(3S)-3-[8-(1-ethyl-5-methylpyrazol-4-yl)-9-methylpurin-6-yl]oxypyrrolidin-1-yl]-(oxan-4-yl)methanone Chemical compound C(C)N1N=CC(=C1C)C=1N(C2=NC=NC(=C2N=1)O[C@@H]1CN(CC1)C(=O)C1CCOCC1)C FHKPLLOSJHHKNU-INIZCTEOSA-N 0.000 description 1
- JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229910001679 gibbsite Inorganic materials 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- DKAGJZJALZXOOV-UHFFFAOYSA-N hydrate;hydrochloride Chemical compound O.Cl DKAGJZJALZXOOV-UHFFFAOYSA-N 0.000 description 1
- 238000007603 infrared drying Methods 0.000 description 1
- HTXDPTMKBJXEOW-UHFFFAOYSA-N iridium(IV) oxide Inorganic materials O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 description 1
- FLTRNWIFKITPIO-UHFFFAOYSA-N iron;trihydrate Chemical group O.O.O.[Fe] FLTRNWIFKITPIO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N nickel(II) oxide Inorganic materials [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J47/00—Ion-exchange processes in general; Apparatus therefor
- B01J47/12—Ion-exchange processes in general; Apparatus therefor characterised by the use of ion-exchange material in the form of ribbons, filaments, fibres or sheets, e.g. membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
- B01D61/445—Ion-selective electrodialysis with bipolar membranes; Water splitting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0088—Physical treatment with compounds, e.g. swelling, coating or impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1213—Laminated layers
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
- C02F1/4693—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2287—After-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Water Supply & Treatment (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Urology & Nephrology (AREA)
- Molecular Biology (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Fuel Cell (AREA)
Abstract
본 발명은 바이폴라 멤브레인에 대한 것이며, 양이온시트 및 음이온 시트 사이에 촉매를 형성하며, 음이온 시트 표면에 형성된 돌기에 의해 양이온시트와의 결합성을 향상시키는 것을 목적으로 한다. 구체적으로 제1이오노머로 제1시트(110)를 형성하는 제1시트층형성단계(S100); 상기 제1시트층 형성단계 후, 제1시트층의 일면에 촉매층(130)을 형성하는 촉매층형성단계(S300); 상기 촉매층형성단계 후, 촉매층 일면에 제2이오노머로 제2시트층(120)을 형성하는 제2시트층형성단계(S500);를 시계열적 단계로 형성된다. The present invention relates to a bipolar membrane, and its purpose is to form a catalyst between a cation sheet and an anion sheet and improve bonding with the cation sheet by protrusions formed on the surface of the anion sheet. Specifically, a first sheet layer forming step (S100) of forming a first sheet 110 with a first ionomer; After the first sheet layer forming step, a catalyst layer forming step (S300) of forming a catalyst layer 130 on one surface of the first sheet layer; After the catalyst layer forming step, a second sheet layer forming step (S500) of forming a second sheet layer 120 with a second ionomer on one side of the catalyst layer is formed in time series.
Description
본 발명은 바이폴라 멤브레인에 대한 것이며, 양이온시트 및 음이온 시트 사이에 촉매를 형성하며, 음이온 시트 표면에 형성된 돌기에 의해 양이온시트와의 결합성을 향상시키는 기술에 대한 것이다. The present invention relates to a bipolar membrane, to a technology for forming a catalyst between a cation sheet and an anion sheet, and to improving bonding with the cation sheet by protrusions formed on the surface of the anion sheet.
본 발명의 특허발명 001 내지 004는 본 발명과 기술적으로 관련이 있는 선행기술문헌이며, 특히 바이폴라 이온교환막을 제조하는 방법을 특징으로 한다. Patent inventions 001 to 004 of the present invention are prior art documents technically related to the present invention, and particularly feature a method of manufacturing a bipolar ion exchange membrane.
특허발명 001 내지 004는 바이폴라멤브레인을 공통으로 포함하고 있으나, 본 발명의 촉매층 형성에 대하여 동일 또는 유사한 기술을 직접 기재 및 내재하고 있지 않다. Patent inventions 001 to 004 commonly include a bipolar membrane, but do not directly describe or contain the same or similar technology for forming the catalyst layer of the present invention.
특허문헌 001은 이온교환막, 이온교환막의 제조방법 및 이온교환 장치이며, 특허문헌 002는 유가자원회수용 바이폴라 이온교환시트, 이의 제조방법 및 이를 이용한 유가자원 회수 장치이며, 특허문헌 003은 불균질 이온교환막을 지지체로 이용한 바이폴라 이온교환막 및 그 제조방법이며, 특허문헌 004는 바이폴라 이온교환시트 및 그 제조방법을 제시하고 있다. Patent Document 001 is an ion exchange membrane, a manufacturing method of an ion exchange membrane, and an ion exchange device, Patent Document 002 is a bipolar ion exchange sheet for valuable resource recovery, a manufacturing method thereof, and a valuable resource recovery device using the same, and Patent Document 003 is a heterogeneous ion It is a bipolar ion exchange membrane using an exchange membrane as a support and its manufacturing method, and patent document 004 proposes a bipolar ion exchange sheet and its manufacturing method.
본 발명은 바이폴라멤브레인에 대한 것이며, 양이온시트 및 음이온 시트 사이에 촉매를 형성하며, 음이온 시트 표면에 형성된 돌기에 의해 양이온시트와의 결합성을 향상시키는 것을 목적으로 한다. The present invention relates to a bipolar membrane, and its purpose is to form a catalyst between a cation sheet and an anion sheet and improve bonding with the cation sheet by protrusions formed on the surface of the anion sheet.
본 발명은 바이폴라멤브레인(100) 제조방법에 대한 것이며, 구체적으로 제1이오노머로 제1시트(110)를 형성하는 제1시트층형성단계(S100); 상기 제1시트층 형성단계 후, 제1시트층의 일면에 촉매층(130)을 형성하는 촉매층형성단계(S300); 상기 촉매층형성단계 후, 촉매층 일면에 제2이오노머로 제2시트층(120)을 형성하는 제2시트층형성단계(S500);를 포함하는 시계열적 단계로 이루어진다. The present invention relates to a method for manufacturing a bipolar membrane 100, and specifically, a first sheet layer forming step (S100) of forming a first sheet 110 with a first ionomer; After the first sheet layer forming step, a catalyst layer forming step (S300) of forming a catalyst layer 130 on one surface of the first sheet layer; After the catalyst layer forming step, it consists of time-series steps including a second sheet layer forming step (S500) of forming a second sheet layer 120 with a second ionomer on one side of the catalyst layer.
본 발명은 바이폴라멤브레인(100) 제조방법에 대한 것이며, 앞에서 제시한 발명에 있어서, 상기 제1시트층 형성단계 후, 제1시트층 일면에 복수의 돌기(111)를 형성하는 돌기층형성단계(S200);를 포함하는 단계로 이루어진다. The present invention relates to a method of manufacturing a bipolar membrane 100, and in the invention presented above, after the first sheet layer forming step, a protrusion layer forming step of forming a plurality of protrusions 111 on one surface of the first sheet layer ( It consists of steps including S200);
본 발명은 바이폴라멤브레인(100) 제조방법에 대한 것이며, 앞에서 제시한 발명에 있어서, 상기 촉매층 형성단계는 촉매용액(310)을 스프레이로 분사하는 촉매용액분사단계(S330);를 포함하는 단계로 이루어진다. The present invention relates to a method for manufacturing a bipolar membrane (100), and in the invention presented above, the catalyst layer forming step includes a catalyst solution injection step (S330) of spraying the catalyst solution (310). .
본 발명은 바이폴라멤브레인(100) 제조방법에 대한 것이며, 앞에서 제시한 발명에 있어서, 상기 제1시트층 형성단계 중, 지지체(510)를 고정하는 지지체형성단계(S130);를 포함하는 단계로 이루어진다. The present invention relates to a method of manufacturing a bipolar membrane 100, and in the invention presented above, the first sheet layer forming step includes a support forming step (S130) for fixing the support 510. .
본 발명은 바이폴라멤브레인에 대한 것이며, 앞에서 제시한 방법으로 제조된 바이폴라멤브레인을 제시한다. The present invention relates to a bipolar membrane, and presents a bipolar membrane manufactured by the method presented above.
본 발명의 바이폴라 멤브레인은 제1시트층 및 제2시트층의 결합성을 높이기 위해 제1시트층의 일면에는 복수의 돌기를 형성한 후, 돌기가 형성된 면에 제2시트층을 형성한다. 따라서, 상호 높은 결합력을 가지며, 층간분리 발생을 방지할 수 있다. In the bipolar membrane of the present invention, a plurality of protrusions are formed on one side of the first sheet layer to increase bonding between the first sheet layer and the second sheet layer, and then a second sheet layer is formed on the surface where the protrusions are formed. Therefore, they have high bonding strength and can prevent interlayer separation.
본 발명은 복수의 돌기에 의해 시트층의 면적이 넓어지며, 이는 물 분해 효과를 향상시킨다.In the present invention, the area of the sheet layer is expanded by the plurality of protrusions, which improves the water decomposition effect.
본 발명의 돌기는 돌기는 3성분(제1이오노머, 제2이오노머, 촉매)의 계면면적을 증대하므로, 전류밀도가 높아지며, 이는 물분해시 전압의 증가를 방지할 수 있다. The protrusions of the present invention increase the interfacial area of the three components (the first ionomer, the second ionomer, and the catalyst), thereby increasing the current density, which can prevent an increase in voltage during water decomposition.
도 1은 본 발명의 바이폴라 멤브레인 사시도 및 단면도.
도 2는 본 발명의 바이폴라 멤브레인 제조단계.
도 3 및 도 4는 본 발명의 바이폴라 멤브레인 제조방법 순서도.1 is a perspective view and cross-sectional view of a bipolar membrane of the present invention.
Figure 2 shows the bipolar membrane manufacturing steps of the present invention.
Figures 3 and 4 are flowcharts of the bipolar membrane manufacturing method of the present invention.
이하, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 본 발명을 용이하게 실시할 수 있을 정도로 상세히 설명하기 위하여, 본 발명의 가장 바람직한 실시 예를 상세하게 설명한다. 실시예의 인용번호는 지정번호에 한정하지 않으며, 모든 번호를 인정할 수 있다. 실시예에 제시된 구성은 동일한 목적 및 효과를 발휘하는 대상으로 확대될 수 있다. 실시예에 제시된 구성의 하위개념은 직접기재 하지 않아도 내제된 것으로 볼 수 있다. Hereinafter, the most preferred embodiments of the present invention will be described in detail in order to enable those skilled in the art to easily practice the present invention. The reference number in the example is not limited to the designated number, and any number can be accepted. The configuration presented in the examples can be expanded to objects that have the same purpose and effect. The sub-concepts of the configuration presented in the examples can be viewed as inherent even if they are not directly described.
(실시예 1-1) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 구체적으로 제1이오노머로 제1시트(110)를 형성하는 제1시트층형성단계(S100); 상기 제1시트층 형성단계 후, 제1시트층의 일면에 촉매층(130)을 형성하는 촉매층형성단계(S300); 상기 촉매층형성단계 후, 촉매층 일면에 제2이오노머로 제2시트층(120)을 형성하는 제2시트층형성단계(S500);를 포함하는 시계열적 단계로 구성된다. (Example 1-1) The present invention relates to a method for manufacturing a bipolar membrane, and specifically, a first sheet layer forming step (S100) of forming a first sheet 110 with a first ionomer; After the first sheet layer forming step, a catalyst layer forming step (S300) of forming a catalyst layer 130 on one surface of the first sheet layer; After the catalyst layer forming step, it consists of time-series steps including a second sheet layer forming step (S500) of forming a second sheet layer 120 with a second ionomer on one side of the catalyst layer.
(실시예 1-2) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 1-1에 있어서, 상기 제2이오노머는 제1이오노머와 반대이온으로 형성되는 것;을 포함한다.(Example 1-2) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 1-1, the second ionomer is formed from a counter ion to the first ionomer.
(실시예 1-3) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 1-1에 있어서, 상기 제1시트층 및 제2시트층은 고분자이오노머로 형성되는 것;을 포함한다.(Example 1-3) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 1-1, the first sheet layer and the second sheet layer are formed of a polymer ionomer.
(실시예 1-4) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 1-3에 있어서, 상기 제1시트층 및 제2시트층의 고분자이오노머는 PPO(polyphenylene oxide)계, PFSA(perfluorosulfonic acid)계, PES(polyethersulfone)계, PEEK(polyetheretherketone)계 중 선택된 어느 하나로 형성되는 것;을 포함한다.(Example 1-4) The present invention relates to a method for manufacturing a bipolar membrane. In Example 1-3, the polymer ionomer of the first sheet layer and the second sheet layer is PPO (polyphenylene oxide) based, PFSA (perfluorosulfonic). It includes those formed from any one selected from acid)-based, PES (polyethersulfone)-based, and PEEK (polyetheretherketone)-based.
(실시예 1-5) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 1-4에 있어서, 상기 고분자이오노머에 각각의 제1시트층 및 제2스트층에 음이온교환기 또는 양이온교환작용기를 첨가하는 것;을 포함한다.(Example 1-5) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 1-4, an anion exchange group or a cation exchange functional group is added to each of the first sheet layer and the second sheet layer of the polymer ionomer. includes; doing.
(실시예 1-6) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 1-5에 있어서, 상기 음이온교환기는 1급 아민 내지 4급 아민 중 선택된 어느 하나로 형성되는 것;을 포함한다. (Example 1-6) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 1-5, the anion exchange group is formed of any one selected from primary amines to quaternary amines.
(실시예 1-7) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 1-5에 있어서, 상기 양이온교환기는 슬폰산기 또는 카르복실기로 형성되는 것;을 포함한다.(Example 1-7) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 1-5, the cation exchange group is formed of a sulfonic acid group or a carboxyl group.
(실시예 1-8) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 1-1에 있어서, 상기 제1시트층 형성단계 전, 고분자이오노머를 슬러리 형태로 형성하는 슬러리형성단계(S110); 상기 슬러리형성단계 후, 상기 슬러리를 캐스팅하는 케스팅단계(S120);를 포함한다. (Example 1-8) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 1-1, before the first sheet layer forming step, a slurry forming step (S110) of forming a polymer ionomer in the form of a slurry; After the slurry forming step, a casting step (S120) of casting the slurry is included.
(실시예 1-9) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 1-1에 있어서, 상기 제1시트층의 두께는 10 μm 내지 300 μm로 형성되는 것;을 포함한다.(Example 1-9) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 1-1, the first sheet layer has a thickness of 10 μm to 300 μm.
(실시예 1-10) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 1-1에 있어서, 상기 제2시트층의 두께는 제1시트층 두께보다 얇게 형성하는 것;을 포함한다.(Example 1-10) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 1-1, the thickness of the second sheet layer is formed to be thinner than the thickness of the first sheet layer.
본 발명(실시예 1-1 내지 1-10)은 바이폴라멤브레인 제조방법에 대한 발명이다. 바이폴라멤브레인은 물의 이온은 전기에 의해 양이온 및 음이온으로 분리되며, 분리된 양이온 및 음이온은 바이폴라멤브레인에 의해 산성 및 염기성 영역으로 구분된다. The present invention (Examples 1-1 to 1-10) relates to a method for manufacturing a bipolar membrane. The bipolar membrane separates water ions into cations and anions by electricity, and the separated cations and anions are divided into acidic and basic regions by the bipolar membrane.
이를 구현하기위해, 바이폴라멤브레인은 촉매층을 중심으로 양단에 각각 음이온 시트층(제1시트층) 및 양이온 시트층(제2시트층)을 형성해야 된다. 상기 제1시트층 및 제2시트층은 고분자이오노머로 이루어지며, 이는 이온전도도가 높으며, 크로스오버(crossover)가 작으며, 함수율이 높은 특징을 가진다. To implement this, the bipolar membrane must form an anion sheet layer (first sheet layer) and a cation sheet layer (second sheet layer) at both ends of the catalyst layer, respectively. The first sheet layer and the second sheet layer are made of polymer ionomer, which has the characteristics of high ionic conductivity, small crossover, and high moisture content.
상기 촉매층은 이온분리 효과를 향상시킨다. 본 발명의 바이폴라멤브레인은 이온분리 필터에 활용되며, 수처리장치 등에 활용될 수 있다. 상기 제1시트층 또는 제2시트층의 두께는 10 내지 300마이크로미터로 형성된다. The catalyst layer improves the ion separation effect. The bipolar membrane of the present invention is used in ion separation filters and can be used in water treatment devices, etc. The first sheet layer or the second sheet layer has a thickness of 10 to 300 micrometers.
(실시예 2-1) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 1-1에 있어서, 상기 제1시트층 형성단계 후, 제1시트층 일면에 복수의 돌기(111)를 형성하는 돌기층형성단계(S200);를 포함한다. (Example 2-1) The present invention relates to a method for manufacturing a bipolar membrane. In Example 1-1, after the first sheet layer forming step, a plurality of protrusions 111 are formed on one surface of the first sheet layer. It includes a protrusion layer forming step (S200).
(실시예 2-2) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 2-1에 있어서, 상기 돌기층 형성단계는 응집체가 수용된 용액을 제1시트층에 분사하는 분사단계(S220);를 포함한다. (Example 2-2) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 2-1, the protrusion layer forming step includes a spraying step (S220) of spraying a solution containing aggregates onto the first sheet layer; Includes.
(실시예 2-3) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 2-2에 있어서, 상기 응집체는 제1이오노머와 동종으로 형성되는 것;을 포함한다.(Example 2-3) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 2-2, the aggregate is formed homogeneously with the first ionomer.
(실시예 2-4) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 2-1에 있어서, 상기 분사단계 전, 용매와 제1이오노머를 혼합하는 혼합단계(S210);를 포함한다. (Example 2-4) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 2-1, includes a mixing step (S210) of mixing the solvent and the first ionomer before the spraying step.
(실시예 2-5) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 2-4에 있어서, 상기 혼합단계 후, 응집체의 량을 제어하기 위해 용매의 량을 제어하는 응집체량 제어단계(S230);를 포함한다. (Example 2-5) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 2-4, after the mixing step, an aggregate amount control step (S230) of controlling the amount of solvent to control the amount of aggregates. ); includes.
(실시예 2-6) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 2-1에 있어서, 상기 용매는 알코을 및/또는 초순수로 형성되는 것;을 포함한다.(Example 2-6) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 2-1, the solvent includes alcohol and/or ultrapure water.
(실시예 2-7) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 2-1에 있어서, 상기 알코올은 에탄올, 메탄올, 프로탄올 중 선택된 어느 하나로 형성되는 것;을 포함한다.(Example 2-7) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 2-1, the alcohol is formed from any one selected from ethanol, methanol, and propanol.
(실시예 2-8) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 1-1에 있어서, 상기 응집체 크기는 균일 및/또는 불균일하게 형성하는 것;을 포함한다.(Example 2-8) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 1-1, the size of the aggregate is formed uniformly and/or non-uniformly.
(실시예 2-9) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 1-1에 있어서, 상기 응집체의 입경은 0.1 μm 내지 10 μm로 형성되는 것;을 포함한다.(Example 2-9) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 1-1, the particle size of the aggregate is formed from 0.1 μm to 10 μm.
(실시예 2-10) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 1-1에 있어서, 상기 응집체 형상은 균일 및/또는 불균일하게 형성하는 것;을 포함한다.(Example 2-10) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 1-1, the shape of the aggregate is formed uniformly and/or non-uniformly.
본 발명(실시예 2-1 내지 2-10)은 돌기층 형성단계를 구체화한다. 각각의 시트층 및 촉매층의 결합성을 높이기 위해 제1시트층의 일면에는 복수의 돌기를 형성한다. The present invention (Examples 2-1 to 2-10) embodies the protrusion layer forming step. In order to increase the bonding properties of each sheet layer and the catalyst layer, a plurality of protrusions are formed on one surface of the first sheet layer.
상기 돌기에 의해 상호 끼워 맞춤 효과를 발휘하며, 이는 제1시트 및 제2시트의층간분리 방지효과를 가진다. 또한 상기 복수의 돌기에 의해 시트층의 면적이 넓어지며, 이는 물 분해 효과를 향상시킨다. 상기 돌기는 3성분(제1이오노머, 제2이오노머, 촉매)의 계면면적을 증대하므로, 전류밀도가 높아지며, 이는 물분해 시 전압의 증가를 방지할 수 있다. The protrusions provide a mutual fit effect, which has the effect of preventing interlayer separation between the first sheet and the second sheet. Additionally, the area of the sheet layer is expanded by the plurality of protrusions, which improves the water decomposition effect. The protrusions increase the interfacial area of the three components (the first ionomer, the second ionomer, and the catalyst), thereby increasing the current density, which can prevent an increase in voltage during water decomposition.
돌기층을 형성하기 위한 방법으로 응집체가 수용된 용액을 제1시트층에 분사하며, 건조되어 응집체가 제1시트층에 부착되어 진다. 상기 응집체는 용매와 제1이오노머의 혼합으로 이루어진다. 적정량의 응집체를 형성하기 위해 용매의 량을 제어해야 된다. 상기 용액은 알코올 또는 물을 사용하며, 물은 초순수를 사용하며, 상기 물은 에탄올, 메탄올, 프로탄올을 사용한다. As a method of forming a protrusion layer, a solution containing aggregates is sprayed onto the first sheet layer, and after drying, the aggregates are attached to the first sheet layer. The aggregate is composed of a mixture of a solvent and a first ionomer. The amount of solvent must be controlled to form an appropriate amount of aggregate. The solution uses alcohol or water, the water uses ultrapure water, and the water uses ethanol, methanol, or propanol.
응집체의 크기는 0.1 내지 10 마이크로미터의 입경크기를 가지며, 응집체의 크기는 다양한 크기로 형성될 수 있으나 동일한 크기로 형성되며, 그 배치는 균일한배치로 형성됨이 바람직하다. The size of the aggregate has a particle size of 0.1 to 10 micrometers. The size of the aggregate may be formed in various sizes, but it is preferably formed of the same size and the arrangement is uniform.
(실시예 3-1) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 1-1에 있어서, 상기 촉매층 형성단계는 촉매용액(310)을 스프레이로 분사하는 촉매용액분사단계(S330);를 포함한다. (Example 3-1) The present invention relates to a method for manufacturing a bipolar membrane. In Example 1-1, the catalyst layer forming step includes a catalyst solution injection step (S330) of spraying the catalyst solution 310. Includes.
(실시예 3-2) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 3-1에 있어서, 상기 촉매는 금속산화물, 금속수산화물, 금속염화수산화물 중 선택된 어느 하나로 형성되는 것;을 포한다.(Example 3-2) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 3-1, the catalyst is formed of any one selected from metal oxide, metal hydroxide, and metal chloride hydroxide.
(실시예 3-3) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 3-1에 있어서, 상기 촉매는 Fe(OH)3, Fe3O4, FeOOH, TiO2, NiO, MnO2, SnO2, SnCl2, SnClxOHy, Al(OH)3, Al2O3, SiO2, ZrO2, Co2O3, IrO2, RuO2 로 형성되는 것;을 포한다.(Example 3-3) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 3-1, the catalyst is Fe(OH)3, Fe3O4, FeOOH, TiO2, NiO, MnO2, SnO2, SnCl2, SnClxOHy , Al(OH)3, Al2O3, SiO2, ZrO2, Co2O3, IrO2, RuO2.
(실시예 3-4) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 3-1에 있어서, 촉매의 입경은 1nm 내지 2000 nm로 형성되는 것;을 포한다.(Example 3-4) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 3-1, the particle size of the catalyst is 1 nm to 2000 nm.
(실시예 3-5) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 3-1에 있어서, 상기 촉매용액분사단계 전, 촉매입자(312)와 분산액(311)을 혼합하여 촉매용액를 형성하는 촉매용액형성단계(S310);를 포함한다. (Example 3-5) The present invention relates to a method for manufacturing a bipolar membrane. In Example 3-1, before the catalyst solution injection step, catalyst particles 312 and dispersion liquid 311 are mixed to form a catalyst solution. Includes a catalyst solution forming step (S310).
(실시예 3-6) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 3-5에 있어서, 상기 촉매용액형성단계 중, 촉매용액 내부에 제1이오노머를 혼합하는 첨가단계(S320);를 포함한다.(Example 3-6) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 3-5, during the catalyst solution forming step, an addition step of mixing the first ionomer into the catalyst solution (S320); Includes.
(실시예 3-7) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 3-1에 있어서, 상기 촉매용액분사단계 후, 촉매용액을 건조하는 촉매건조단계(S340);를 포함한다.(Example 3-7) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 3-1, it includes a catalyst drying step (S340) of drying the catalyst solution after the catalyst solution injection step.
본 발명(실시예 3-1 내지 실시예 3-7)은 촉매용액 분사단계를 구체화한다. The present invention (Examples 3-1 to 3-7) embodies the catalyst solution injection step.
촉매용액은 제1시트층과 돌기의 표면에 분사되어진다. 상기 촉매용액은 분산액과 촉매입자로 이루어진다. 상기 촉매용액의 내부에는 제1이오너머를 미소량 혼합하며, 이는 촉매의 바인더 역할을 한다. 상기 촉매의 입경은 1nm 내지 2000 nm로 형성됨이 바람직하다. The catalyst solution is sprayed on the surface of the first sheet layer and the protrusions. The catalyst solution consists of a dispersion liquid and catalyst particles. A small amount of the first ionomer is mixed inside the catalyst solution, which serves as a binder for the catalyst. The particle size of the catalyst is preferably 1 nm to 2000 nm.
촉매층이 형성된 이후에는 건조에 의해 촉매층을 돌기와 제1시트층에 고형화 된다. 상기 건조단계는 급속건조가 바람직하며, 열풍건조, 적외선 건조, 등을 취할 수 있다. After the catalyst layer is formed, the catalyst layer is solidified on the protrusions and the first sheet layer by drying. The drying step is preferably rapid drying, and hot air drying, infrared drying, etc. may be used.
(실시예 4-1) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 1-1에 있어서, 상기 제1시트층 형성단계 중, 지지체(510)를 고정하는 지지체형성단계(S130);를 포함한다. (Example 4-1) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 1-1, among the first sheet layer forming steps, a support forming step (S130) of fixing the support 510; Includes.
(실시예 4-2) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 4-1에 있어서, 상기 지지체는 PTFE, PP, PE, PA, PAT 중 선택된 어느 하나의 재질로 형성되는 것;을 포한다.(Example 4-2) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 4-1, the support is formed of any one material selected from PTFE, PP, PE, PA, and PAT; Includes
(실시예 4-3) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 4-1에 있어서, 상기 지지체는 직포 또는 부직포의 형태로 형성되는 것;을 포한다.(Example 4-3) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 4-1, the support is formed in the form of a woven fabric or non-woven fabric.
(실시예 4-4) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 4-1에 있어서, 상기 지지체는 메쉬형태로 형성되는 것;을 포한다.(Example 4-4) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 4-1, the support is formed in a mesh shape.
(실시예 4-5) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 4-1에 있어서, 상기 메쉬는 실의 두께가 50 μm이며, 지지체 두께는 100 μm로 형성되는 것;을 포한다.(Example 4-5) The present invention relates to a method of manufacturing a bipolar membrane, and in Example 4-1, the mesh is formed with a thread thickness of 50 μm and a support thickness of 100 μm. .
(실시예 4-6) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 4-1에 있어서, 상기 지지체는 다공성 필름으로 형성되는 것;을 포한다.(Example 4-6) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 4-1, the support is formed of a porous film.
(실시예 4-7) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 4-1에 있어서, 상기 지지체는 균일한 두께로 형성되는 것;을 포한다.(Example 4-7) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 4-1, the support is formed to have a uniform thickness.
(실시예 4-8) 본 발명은 바이폴라멤브레인 제조방법에 대한 것이며, 실시예 4-1에 있어서, 상기 제1시트층 및 지지체 두께 비율은 1: 0.5 내지 0.7로 형성되는 것;을 포한다.(Example 4-8) The present invention relates to a method for manufacturing a bipolar membrane, and in Example 4-1, the thickness ratio of the first sheet layer and the support is 1:0.5 to 0.7.
본 발명(실시예 4-1 내지 4-8)은 지지체 형성단계를 구체화한다. 바이폴라멤브레인에 일정한 강도를 높이는 목적으로 지지체를 형성한다. The present invention (Examples 4-1 to 4-8) specifies the support forming step. A support is formed for the purpose of increasing a certain strength of the bipolar membrane.
상기 지지체는 제1시트층에 형성됨이 바람직하다. 상기 지지체는 다공성이 형성되어야 하며, 직포, 부직포, 메시망 등이 사용될 수 있다. 상기 지지체는 필름형태로 형성되며, 균일한 두께와 강도를 가져야 된다. The support is preferably formed on the first sheet layer. The support must be porous, and woven fabric, non-woven fabric, mesh net, etc. may be used. The support is formed in the form of a film and must have uniform thickness and strength.
(실시예 5-1) 본 발명은 바이폴라멤브레인에 대한 것이며, 앞에서 제시한 모든 실시예 중 선택된 어느 하나의 방법으로 제조된 바이폴라멤브레인을 나타낸다. (Example 5-1) The present invention relates to a bipolar membrane, and represents a bipolar membrane manufactured by any one method selected from all the examples presented above.
본 발명(실시예 5-1)은 물건발명인 바이폴라멤브레인을 특정하고 있으나, 이는 제조방법에 의해 물건의 영향을 미치게 된다. 즉, 제조방법에 의해 생산된 물건을 대상으로 한다. The present invention (Example 5-1) specifies a bipolar membrane, which is a product invention, but this has an effect on the product depending on the manufacturing method. In other words, it covers products produced using manufacturing methods.
100 : 바이폴라멤브레인
110 : 제1시트
111 : 돌기
120 : 제2시트층
130 : 촉매층
310 : 촉매용액
510 : 지지체100: Bipolar membrane
110: 1st sheet
111: protrusion
120: second sheet layer
130: catalyst layer
310: Catalyst solution
510: support
Claims (5)
제1이오노머로 제1시트(110)를 형성하는 제1시트층형성단계(S100);
상기 제1시트층 형성단계 후, 제1시트층의 일면에 촉매층(130)을 형성하는 촉매층형성단계(S300);
상기 촉매층형성단계 후, 촉매층 일면에 제2이오노머로 제2시트층(120)을 형성하는 제2시트층형성단계(S500) ;
를 포함하는 바이폴라멤브레인 제조방법.
In the method of manufacturing the bipolar membrane (100),
A first sheet layer forming step (S100) of forming a first sheet 110 with a first ionomer;
After the first sheet layer forming step, a catalyst layer forming step (S300) of forming a catalyst layer 130 on one surface of the first sheet layer;
After the catalyst layer forming step, a second sheet layer forming step (S500) of forming a second sheet layer 120 with a second ionomer on one side of the catalyst layer;
A bipolar membrane manufacturing method comprising.
상기 제1시트층 형성단계 후, 제1시트층 일면에 복수의 돌기(111)를 형성하는 돌기층형성단계(S200);
를 포함하는 바이폴라멤브레인 제조방법.
In claim 1,
After the first sheet layer forming step, a protrusion layer forming step (S200) of forming a plurality of protrusions 111 on one surface of the first sheet layer;
A bipolar membrane manufacturing method comprising.
상기 촉매층 형성단계는 촉매용액(310)을 스프레이로 분사하는 촉매용액분사단계(S330);
를 포함하는 바이폴라멤브레인 제조방법.
In claim 1,
The catalyst layer forming step includes a catalyst solution injection step (S330) of spraying the catalyst solution 310;
A bipolar membrane manufacturing method comprising.
상기 제1시트층 형성단계 중, 지지체(510)를 고정하는 지지체형성단계(S130);
를 포함하는 바이폴라멤브레인 제조방법.
In claim 1,
Among the first sheet layer forming steps, a support forming step (S130) of fixing the support 510;
A bipolar membrane manufacturing method comprising.
청구항 1 내지 청구항 4 중 선택된 어느 하나의 방법으로 제조된 바이폴라멤브레인.
In the bipolar membrane,
A bipolar membrane manufactured by any one method selected from claims 1 to 4.
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| KR20170035718A (en) | 2015-09-23 | 2017-03-31 | 코웨이 주식회사 | Bipolar ion exchange sheet and method of manufacturing the same |
| KR102064179B1 (en) | 2017-03-28 | 2020-01-09 | 웅진코웨이 주식회사 | Bipolar ion-exchange membrane having heterogeneous ion-exchange membrane and method for preparing the same |
| KR102126307B1 (en) | 2018-03-30 | 2020-06-24 | 주식회사 이노켐텍 | Ion exchange membrane, method for manufacturing ion exchange membrane, and Ion exchange device |
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