KR20240039907A - Antibacterial coating composition using inorganic minerals and manufacturing method thereof - Google Patents
Antibacterial coating composition using inorganic minerals and manufacturing method thereof Download PDFInfo
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 45
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 29
- 239000008199 coating composition Substances 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 239000012141 concentrate Substances 0.000 claims abstract description 28
- 239000004575 stone Substances 0.000 claims abstract description 24
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000292 calcium oxide Substances 0.000 claims abstract description 14
- 239000011812 mixed powder Substances 0.000 claims abstract description 13
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000008213 purified water Substances 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 239000006228 supernatant Substances 0.000 claims abstract description 8
- 238000001704 evaporation Methods 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 230000008020 evaporation Effects 0.000 claims abstract description 4
- 239000002244 precipitate Substances 0.000 claims abstract description 4
- 238000010298 pulverizing process Methods 0.000 claims abstract description 4
- 239000011248 coating agent Substances 0.000 claims description 29
- 239000000047 product Substances 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 5
- 239000011259 mixed solution Substances 0.000 claims description 4
- 239000011435 rock Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 description 20
- 238000000576 coating method Methods 0.000 description 17
- 239000011707 mineral Substances 0.000 description 13
- 235000010755 mineral Nutrition 0.000 description 12
- 235000012255 calcium oxide Nutrition 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- 241000588724 Escherichia coli Species 0.000 description 10
- 241000191967 Staphylococcus aureus Species 0.000 description 7
- 230000001877 deodorizing effect Effects 0.000 description 7
- 241000894006 Bacteria Species 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 241000588747 Klebsiella pneumoniae Species 0.000 description 5
- 239000002928 artificial marble Substances 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 230000009931 harmful effect Effects 0.000 description 4
- 239000000057 synthetic resin Substances 0.000 description 4
- 229920003002 synthetic resin Polymers 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000011550 stock solution Substances 0.000 description 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241001536352 Fraxinus americana Species 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical class C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
본 발명은 무기질 미네랄을 이용한 항균 코팅 조성물 및 이의 제조방법관한 것으로, 화산석과 산화칼슘을 혼합하고, 1300~1600메쉬로 분쇄하여 혼합분말을 형성하는 1공정; 상기 혼합분말을 정제수와 혼합한 혼합액을 가열교반기에 넣고 교반하면서 열을 가하여 증발시키는 2공정; 상기 2공정 후 증발시킨 후 수득된 증발농축액을 상온에서 방치시켜 침전물과 상등액으로 분리되도록 하는 3공정; 상기 3공정의 상등액을 추출시켜 항균농축액을 수득하는 4공정;을 포함한다. The present invention relates to an antibacterial coating composition using inorganic minerals and a method for manufacturing the same. Step 1 of mixing volcanic stone and calcium oxide and pulverizing them to 1300 to 1600 mesh to form a mixed powder; Step 2 of evaporating the mixed powder mixed with purified water by placing it in a heating stirrer and applying heat while stirring; Step 3, where the evaporated concentrate obtained after evaporation after step 2 is left at room temperature to separate into precipitate and supernatant; It includes a fourth step of extracting the supernatant of the above three steps to obtain an antibacterial concentrate.
Description
본 발명은 실내 내장재, 외장재에 사용될 수 있는 무기질 미네랄을 이용한 항균 코팅 조성물 및 이의 제조방법에 관한 것이다. The present invention relates to an antibacterial coating composition using inorganic minerals that can be used in interior and exterior materials and a method for manufacturing the same.
일반적으로 실내에 시공 또는 설치되는 각종 내장재는 주로 경제적인 이유로 인하여, 여러 장의 합성수지판이나 목재판을 접착제로 접착하여 다층 구조를 형성하고, 다층 구조로 형성된 내장재의 표면을 도료로 채색하거나 무늬목 등을 접착하여 제조되고 있다. In general, various interior materials constructed or installed indoors are mainly made for economic reasons by bonding several sheets of synthetic resin or wood with adhesive to form a multi-layer structure, and the surface of the interior materials formed in the multi-layer structure is painted with paint or decorated with wood veneer, etc. It is manufactured by gluing.
상기와 같은 방법으로 제조되는 내장재는 경량이고 가격이 저렴한데다 외관이 미려하여 광범위하게 사용되고 있다.Interior materials manufactured by the above method are widely used because they are lightweight, inexpensive, and have an attractive appearance.
그러나, 이러한 내장재를 제조하는 단계에서 합성수지판이나 목재판을 다층 구조로 접합하기 위하여 접착과 관련된 각종 물성이 우수한 합성수지 접착제가 사용되고, 내장재의 표면을 채색하기 위하여 도장과 관련된 각종 물성이 우수한 합성도료가 사용되므로, 상기 합성수지 접착제와 합성도료에 포함되는 각종 유기 화합물이나 휘발성 물질이 발산되어 건축물 내부에서 거주하거나 활동하는 사람들의 건강에 악영향을 미치게 된다.However, in the manufacturing stage of these interior materials, synthetic resin adhesives with excellent properties related to adhesion are used to join synthetic resin boards or wooden boards into a multi-layer structure, and synthetic paints with excellent properties related to painting are used to color the surface of interior materials. As they are used, various organic compounds or volatile substances contained in the synthetic resin adhesive and synthetic paint are emitted, which has a negative impact on the health of people living or working inside the building.
또한 화장실의 인조대리석, 변기, 수전, 타일 등의 내장재는 곰팡이가 생기고, 유해균이 서식하게 되어 인체에 해로운 단점이 있었다. In addition, interior materials such as artificial marble, toilets, faucets, and tiles in bathrooms have the disadvantage of causing mold and harmful bacteria to grow, which are harmful to the human body.
종래 기술은 아크릴계 공중합물 에멀전, 수성 우레탄계 수지, 왁스 에멀전, 알칼리 가용성 수지, 자외선 흡수제로 이루어지는 코팅제 조성물이 개시되어 있다.The prior art discloses a coating composition consisting of an acrylic copolymer emulsion, an aqueous urethane resin, a wax emulsion, an alkali-soluble resin, and an ultraviolet ray absorber.
그러나, 이러한 아크릴계 코팅제 조성물은 그 자체에서 인체에 유해한 물질을 발산하여 실제로 내장재에 적용하는 것이 곤란하다는 문제점이 있다.However, this acrylic coating composition has a problem in that it emits substances harmful to the human body, making it difficult to actually apply it to interior materials.
본 발명은 종래 기술의 문제점을 해소하기 위해 안출된 것으로, 인조대리석, 변기, 수전, 타일 등의 내장재에 코팅시키기 용이하고, 항균성, 탈취성능이 향상될 수 있는 무기질 미네랄을 이용한 항균 코팅 조성물 및 이의 제조방법을 제공하는데 그 목적이 있다. The present invention was made to solve the problems of the prior art, and is an antibacterial coating composition using an inorganic mineral that is easy to coat on interior materials such as artificial marble, toilets, faucets, and tiles, and has improved antibacterial and deodorizing properties, and the same. The purpose is to provide a manufacturing method.
상기한 본 발명의 목적은, 다공성의 화산석과 산화칼슘을 혼합하고, 1300~1600메쉬로 분쇄하여 혼합분말을 형성하는 1공정; 상기 혼합분말을 정제수와 혼합한 혼합액을 가열교반기에 넣고 교반하면서 열을 가하여 증발시키는 2공정; 상기 2공정 후 증발시킨 후 수득된 증발농축액을 상온에서 방치시켜 침전물과 상등액으로 분리되도록 하는 3공정; 상기 3공정의 상등액을 추출시켜 항균농축액을 수득하는 4공정;을 포함하는 무기질 미네랄을 이용한 항균 코팅 조성물의 제조방법에 의해 달성될 수 있다. The object of the present invention described above is the first step of mixing porous volcanic stone and calcium oxide and pulverizing them to 1300 to 1600 mesh to form a mixed powder; Step 2 of evaporating the mixed powder mixed with purified water by placing it in a heating stirrer and applying heat while stirring; Step 3, where the evaporated concentrate obtained after evaporation after step 2 is left at room temperature to separate into precipitate and supernatant; It can be achieved by a method of manufacturing an antibacterial coating composition using an inorganic mineral, which includes a fourth step of extracting the supernatant of the above three steps to obtain an antibacterial concentrate.
상기 4공정의 항균농축액을 코팅제에 혼합하여 제품화시키는 5공정;을 더 포함하는 것을 특징으로 한다. It is characterized in that it further includes a 5th step of mixing the antibacterial concentrate of the 4th step with a coating agent to commercialize the product.
상기 1공정은 산화칼슘 80~90중량%와 화산석 10~20중량%를 혼합하는 것을 특징으로 한다. The first step is characterized by mixing 80 to 90% by weight of calcium oxide and 10 to 20% by weight of volcanic stone.
상기 2공정은 정제수 80~90중량%와, 혼합분말 10~20중량%를 혼합하는 것을 특징으로 한다. The second process is characterized by mixing 80 to 90% by weight of purified water and 10 to 20% by weight of mixed powder.
상기 4공정은 혼합액 100중량부를 기준으로 하여 98~99중량부를 버리고, 1~2중량부만 추출하여 된 항균농축액을 수득하는 것을 특징으로 한다. The above 4 steps are characterized in that based on 100 parts by weight of the mixed solution, 98 to 99 parts by weight are discarded and only 1 to 2 parts by weight are extracted to obtain an antibacterial concentrate.
본 발명에 따르면, 시판되는 코팅제에 섞어 사용될 수 있고, 인조대리석, 변기, 수전, 타일 등의 내장재에 분사하여 코팅시킴으로써 코팅 작업이 용이하고, 코팅된 후 내장재에는 항균성, 탈취성능이 향상될 수 있는 효과가 있다. According to the present invention, it can be used by mixing with commercially available coating agents, and the coating operation is easy by spraying and coating interior materials such as artificial marble, toilets, faucets, and tiles, and the antibacterial and deodorizing performance of interior materials can be improved after coating. It works.
본 발명에 따라 제조된 마루용 항균코팅제와 대리석용 항균코팅제는 기존의 제품에 본 발명의 항균조성물을 더 넣어 기존의 방수, 방오염에 10분 항균 기능까지 첨가한 것이다. The antibacterial coating agent for flooring and the antibacterial coating agent for marble manufactured according to the present invention add the antibacterial composition of the present invention to the existing product to add a 10-minute antibacterial function to the existing water resistance and anti-pollution effect.
본 제품은 코팅후 휘발성이 날라간 후 무기질(실란 : 일명 실리카)이 나노유리막을 조성하는 것이다. 본 발명은 실란 유리막에 같은 무기질인(화산석+산화칼슘)을 더하는 것으로 실리카 나노 무기질+화산석 산화칼슘 무기질의 혼합물이다. In this product, after coating and the volatility has dissipated, inorganic substances (silane: aka silica) form a nano-glass film. The present invention is a mixture of silica nano-mineral + volcanic calcium oxide mineral by adding the same mineral (volcanic stone + calcium oxide) to the silane glass film.
다른 제품의 경우 화학물에 무기질을 혼합하는 것과 다르게 1. 같은 무기질로서 인체유해 영향이 현저히 낮고, 2. 같은 무기질의 혼합으로 그 융합성이 뛰어나며, 3. 방수, 방오염의 성능향상은 물론 실질적인 항균기능을 대폭 향상(시간)까지 시킨 제품을 제공하게 된다. In the case of other products, unlike mixing minerals with chemicals, 1. the same mineral has significantly less harmful effects on the human body, 2. the mixing of the same mineral has excellent compatibility, 3. it not only improves the performance of waterproofing and anti-pollution, but also provides practical We will provide a product with greatly improved antibacterial function (time).
도 1은 본 발명에 따른 무기질 미네랄을 이용한 항균 코팅 조성물의 제조방법에 대한 흐름도,
도 2는 본 발명에 따른 샘플(ABPM-stone coating)의 시험성적서,
도 3은 본 발명에 따른 샘플(ABPM-stone coating)에 이식된 escherichia coli(대장균)의 제거를 보여주는 사진,
도 4는 본 발명에 따른 샘플(ABPM-stone coating)에 이식된 폐렴막대균(klebsiella pneumoniae)의 제거를 보여주는 사진,
도 5는 본 발명에 따른 샘플(ABPM-stone coating)에 이식된 staphylococcus aureus(황색포도상구균)의 제거를 보여주는 사진. 1 is a flow chart of a method for producing an antibacterial coating composition using inorganic minerals according to the present invention;
Figure 2 is a test report of a sample (ABPM-stone coating) according to the present invention,
Figure 3 is a photograph showing the removal of escherichia coli (E. coli) implanted in a sample (ABPM-stone coating) according to the present invention;
Figure 4 is a photograph showing the removal of klebsiella pneumoniae implanted in a sample (ABPM-stone coating) according to the present invention;
Figure 5 is a photograph showing the removal of staphylococcus aureus (Staphylococcus aureus) implanted in a sample (ABPM-stone coating) according to the present invention.
이하 바람직한 실시예를 첨부된 도면을 토대로 상세하게 설명하면 다음과 같다.Hereinafter, the preferred embodiment will be described in detail based on the attached drawings.
하기에서 설명될 실시예는 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 발명을 용이하게 실시할 수 있을 정도로 상세하게 설명하기 위한 것이며, 이로 인해 본 발명의 기술적인 사상 및 범주가 한정되는 것을 의미하지는 않는다.The examples to be described below are intended to explain the invention in detail so that a person skilled in the art can easily carry out the invention, and this does not limit the technical idea and scope of the present invention. doesn't mean
또한, 도면에 도시된 구성요소의 크기나 형상 등은 설명의 명료성과 편의상 과장되게 도시될 수 있으며, 본 발명의 구성 및 작용을 고려하여 특별히 정의된 용어들은 사용자, 운용자의 의도 또는 관례에 따라 달라질 수 있고, 이러한 용어들에 대한 정의는 본 명세서 전반에 걸친 내용을 토대로 내려져야 함을 밝혀둔다. In addition, the size or shape of the components shown in the drawings may be exaggerated for clarity and convenience of explanation, and terms specifically defined in consideration of the configuration and operation of the present invention may vary depending on the intention or custom of the user or operator. It should be noted that definitions of these terms must be made based on the content throughout this specification.
첨부된 도 1은 본 발명에 따른 무기질 미네랄을 이용한 항균 코팅 조성물의 제조방법에 대한 흐름도, 도 1은 본 발명에 따른 무기질 미네랄을 이용한 항균 코팅 조성물의 제조방법에 대한 흐름도, 도 2는 본 발명에 따른 샘플(ABPM-stone coating)의 시험성적서, 도 3은 본 발명에 따른 샘플(ABPM-stone coating)에 이식된 escherichia coli(대장균)의 제거를 보여주는 사진, 도 4는 본 발명에 따른 샘플(ABPM-stone coating)에 이식된 폐렴막대균(klebsiella pneumoniae)의 제거를 보여주는 사진, 도 5는 본 발명에 따른 샘플(ABPM-stone coating)에 이식된 staphylococcus aureus(황색포도상구균)의 제거를 보여주는 사진이다. The attached Figure 1 is a flowchart of a method for manufacturing an antibacterial coating composition using an inorganic mineral according to the present invention, Figure 1 is a flowchart of a method of manufacturing an antibacterial coating composition using an inorganic mineral according to the present invention, and Figure 2 is a flowchart of the manufacturing method of an antibacterial coating composition using an inorganic mineral according to the present invention. The test report of the sample (ABPM-stone coating) according to the present invention, Figure 3 is a photograph showing the removal of escherichia coli (E. coli) implanted in the sample (ABPM-stone coating) according to the present invention, and Figure 4 is the sample (ABPM) according to the present invention. Figure 5 is a photograph showing the removal of klebsiella pneumoniae implanted in a sample (ABPM-stone coating) according to the present invention. .
도 1에 도시된 바와 같이, 본 발명에 따른 무기질 미네랄을 이용한 항균 코팅 조성물의 제조방법은, As shown in Figure 1, the method for producing an antibacterial coating composition using inorganic minerals according to the present invention is,
화산석과 산화칼슘을 혼합하고, 1300~1600메쉬로 분쇄하여 혼합분말을 형성하는 1공정(S1);Step 1 (S1) of mixing volcanic rock and calcium oxide and pulverizing them to 1300-1600 mesh to form a mixed powder;
상기 혼합분말을 정제수와 혼합한 혼합액을 가열교반기에 넣고 교반하면서 열을 가하여 증발시키는 2공정(S2);Step 2 (S2) of placing the mixed powder mixed with purified water in a heating stirrer and applying heat while stirring to evaporate;
상기 2공정(S2) 후 증발시킨 후 수득된 증발농축액을 상온에서 방치시켜 침전물과 상등액으로 분리되도록 하는 3공정(S3);Step 3 (S3) in which the evaporated concentrate obtained after evaporation after step 2 (S2) is left at room temperature to separate into precipitate and supernatant;
상기 3공정(S3)의 상등액을 추출시켜 항균농축액을 수득하는 4공정(S4);을 포함한다. It includes a 4th step (S4) of extracting the supernatant of the 3rd step (S3) to obtain an antibacterial concentrate.
상기 1공정(S1)은 산화칼슘 80~90중량%와 화산석 10~20중량%를 혼합한다. In the first step (S1), 80 to 90% by weight of calcium oxide and 10 to 20% by weight of volcanic stone are mixed.
산화칼슘 (Calcium oxide, CaO)은 칼슘의 산화물로 생석회, 생회(生灰), 강회(剛灰), 백회(白灰)라고도 불린다. 탄산 칼슘(CaCO3)을 공기가 차단된 상태에서 가열하면 이산화탄소(CO2)를 잃으며 생성된다. Calcium oxide (CaO) is an oxide of calcium and is also called quicklime, raw ash, steel ash, or white ash. When calcium carbonate (CaCO 3 ) is heated in an air-blocked state, carbon dioxide (CO 2 ) is lost and produced.
생석회가 물에 용해 되면 물과 반응하여 수산화 칼슘 (Ca(OH)2)이 생성되면서 이온화되어 용액이 염기성을 띠게 된다.When quicklime is dissolved in water, it reacts with water to produce calcium hydroxide (Ca(OH) 2 ), which is then ionized and the solution becomes basic.
따라서 상기 2공정(S2)은 정제수 80~90중량%와, 혼합분말 10~20중량%를 혼합하는 것으로, 혼합된 혼합액은 pH 8~9의 알칼리성이므로 살균성을 갖게 된다. Therefore, the second step (S2) is to mix 80 to 90% by weight of purified water and 10 to 20% by weight of mixed powder, and the mixed solution is alkaline with a pH of 8 to 9, so it has sterilizing properties.
일 예에 따르면, 정제수 98중량%에 혼합분말 2중량%를 혼합한다. According to one example, 2% by weight of mixed powder is mixed with 98% by weight of purified water.
상기 화산석은 칼슘 20~25 중량%, 망간 8~10중량%, 철 5~10중량%, 마그네슘 5~10중량%, 미네랄 50~60 중량%를 포함한다. The volcanic stone contains 20-25% by weight of calcium, 8-10% by weight of manganese, 5-10% by weight of iron, 5-10% by weight of magnesium, and 50-60% by weight of minerals.
칼슘(Ca)이 20 중량% 미만이면 효능이 저하되고, 25 중량% 이상이면 과다하여 비용 상승의 부담이 따른다. If calcium (Ca) is less than 20% by weight, the efficacy is reduced, and if it is more than 25% by weight, it is excessive and increases the cost.
망간(Mn)은 8 중량% 미만이면 효능이 저하되고, 10 중량% 이상이면 과다하여 비용 상승과 효능 저하의 우려가 있다. If the amount of manganese (Mn) is less than 8% by weight, the efficacy decreases, and if it is more than 10% by weight, the content is excessive, raising the risk of increased cost and decreased efficacy.
철(Fe)은 5 중량% 미만이면 효능이 저하되고, 10중량% 이상이면 과다하여 비용 상승과 효능 저하의 우려가 있다. If iron (Fe) is less than 5% by weight, the efficacy is reduced, and if it is more than 10% by weight, it is excessive and there is a risk of increased cost and reduced efficacy.
마그네슘(Mg)이 5중량% 미만이면 효능이 저하되고, 10중량% 이상이면 과다하여 비용 상승과 효능 저하의 우려가 있다. If magnesium (Mg) is less than 5% by weight, the efficacy is reduced, and if it is more than 10% by weight, it is excessive, raising the risk of increased costs and reduced efficacy.
미네랄은 50 중량% 미만이면 효능이 저하되고, 60중량% 이상이면 과다하여 비용 상승과 효능 저하의 우려가 있다. If the mineral content is less than 50% by weight, the efficacy decreases, and if it is more than 60% by weight, the mineral content is excessive, raising the risk of increased cost and reduced efficacy.
상기 미네랄은 철, 구리, 칼슘, 칼륨의 금속 미립자 혼합물과, 광물을 혼합한 혼합물이며, 입자 크기가 1300~1500메쉬이다. The mineral is a mixture of metal fine particles of iron, copper, calcium, and potassium and minerals, and has a particle size of 1300 to 1500 mesh.
이러한 미네랄은 살균성을 갖는 금속 미립자가 혼합되어 있으므로 항균성능이 발휘될 수 있다. These minerals can exhibit antibacterial properties because they are mixed with metal particles that have bactericidal properties.
상기 금속 미립자 혼합물 100 중량부를 기준하여 광물을 50~60중량부를 혼합한 것이다. 50 to 60 parts by weight of mineral is mixed based on 100 parts by weight of the metal fine particle mixture.
바람직하게는 화산석은 다공성 화산석이 적용된다. Preferably, the volcanic stone is a porous volcanic stone.
상기 4공정(S4)은 혼합액 100중량부를 기준으로 하여 98~99중량부를 버리고, 1~2중량부만 추출하여 된 항균농축액을 수득한다. In the fourth step (S4), based on 100 parts by weight of the mixed solution, 98 to 99 parts by weight are discarded and only 1 to 2 parts by weight are extracted to obtain an antibacterial concentrate.
예를 들어 정제수 98ℓ에 혼합분말 2kg을 혼합하고, 교반 및 가열하여 원액을 2ℓ 얻는다. For example, mix 2 kg of mixed powder with 98 liters of purified water, stir and heat to obtain 2 liters of stock solution.
상기 원액을 상온에서 10~20분 방치하여 200g만 추출하고, 나머지 원액과 가라앉은 침전물은 버린다. Leave the above stock solution at room temperature for 10 to 20 minutes to extract only 200g, and discard the remaining stock solution and settled sediment.
이렇게 최종 수득된 원액은 20만 ppm 이다. The final solution obtained in this way is 200,000 ppm.
이하 실시예를 통해 본 발명을 더욱 상세하게 설명한다. The present invention will be described in more detail through examples below.
[실시예 1][Example 1]
다공성 화산석 12kg과 산화칼슘 88kg을 혼합하고, 1500메쉬 분말로 만든다. Mix 12 kg of porous volcanic stone and 88 kg of calcium oxide and make it into 1500 mesh powder.
혼합된 혼합물 2kg을 정제수 98ℓ에 섞는다. Mix 2 kg of the mixed mixture with 98 liters of purified water.
이후 교반과 가열을 동시에 실시하여 농축되도록 한 증발농축액을 얻고, 증발농축액의 상층부의 항균농축액 200g을 추출한다. Afterwards, stirring and heating are carried out simultaneously to obtain a concentrated evaporated concentrate, and 200 g of the antibacterial concentrate is extracted from the upper layer of the evaporated concentrate.
추출된 항균농축액을 코팅제에 혼합하여 변기 커버에 분사한다. 코팅제 100중량부를 기준으로 하여 항균농축액은 5중량부를 혼합한다. Mix the extracted antibacterial concentrate with the coating agent and spray it on the toilet cover. Based on 100 parts by weight of coating agent, mix 5 parts by weight of antibacterial concentrate.
[실시예 2][Example 2]
다공성 화산석 10kg과 산화칼슘 90kg을 혼합하고, 1500메쉬 분말로 만든다. Mix 10 kg of porous volcanic stone and 90 kg of calcium oxide and make it into 1500 mesh powder.
혼합된 혼합물 1.5kg을 정제수 98ℓ에 섞는다. Mix 1.5 kg of the mixed mixture with 98 liters of purified water.
이후 교반과 가열을 동시에 실시하여 농축되도록 한 증발농축액을 얻고, 증발농축액의 상층부의 항균농축액 200g을 추출한다. Afterwards, stirring and heating are carried out simultaneously to obtain a concentrated evaporated concentrate, and 200 g of the antibacterial concentrate is extracted from the upper layer of the evaporated concentrate.
추출된 항균농축액을 코팅제에 혼합하여 변기 커버에 분사한다. 코팅제 100중량부를 기준으로 하여 항균농축액은 5중량부를 혼합한다. Mix the extracted antibacterial concentrate with the coating agent and spray it on the toilet cover. Based on 100 parts by weight of coating agent, mix 5 parts by weight of antibacterial concentrate.
[실시예 3][Example 3]
다공성 화산석 15kg과 산화칼슘 85kg을 혼합하고, 1500메쉬 분말로 만든다. Mix 15 kg of porous volcanic stone and 85 kg of calcium oxide and make it into 1500 mesh powder.
혼합된 혼합물 2.5kg을 정제수 98ℓ에 섞는다. Mix 2.5 kg of the mixed mixture with 98 liters of purified water.
이후 교반과 가열을 동시에 실시하여 농축되도록 한 증발농축액을 얻고, 증발농축액의 상층부의 항균농축액 200g을 추출한다. Afterwards, stirring and heating are carried out simultaneously to obtain a concentrated evaporated concentrate, and 200 g of the antibacterial concentrate is extracted from the upper layer of the evaporated concentrate.
추출된 항균농축액을 코팅제에 혼합하여 변기 커버에 분사한다. 코팅제 100중량부를 기준으로 하여 항균농축액은 5중량부를 혼합한다. Mix the extracted antibacterial concentrate with the coating agent and spray it on the toilet cover. Based on 100 parts by weight of coating agent, mix 5 parts by weight of antibacterial concentrate.
[비교예][Comparative example]
기존 시판되는 인조대리석 코팅제를 사용한다. 상품명 : nanopico 천연 인조대리석 코팅제 100mlUses existing commercially available artificial marble coating agents. Product name: nanopico natural artificial marble coating 100ml
[표 1]을 참조하면, 본 발명에 따른 실시예 1~3은 비교예 보다 생활 악취의 원인물질에 대한 탈취성능이 월등히 향성될 수 있었음을 알 수 있다. Referring to [Table 1], it can be seen that Examples 1 to 3 according to the present invention were able to significantly improve the deodorizing performance against substances causing household bad odors compared to the comparative examples.
첨부된 도 2는 본 발명에 따른 샘플(ABPM-stone coating)의 시험성적서이다. The attached Figure 2 is a test report of a sample (ABPM-stone coating) according to the present invention.
본 발명자의 업체명 : GLOBALWORKS COMPANY CO., LTDCompany name of the present inventor: GLOBALWORKS COMPANY CO., LTD
시험기관명 : SGS KOREATesting agency name: SGS KOREA
샘플 무게 : 1gSample weight: 1g
staphylococcus aureus(황색포도상구균) : 1.8*105 CFU/mLstaphylococcus aureus: 1.8*10 5 CFU/mL
escherichia coli(대장균) : 1.3*105 CFU/mLescherichia coli (E. coli): 1.3*10 5 CFU/mL
폐렴막대균(klebsiella pneumoniae) : 1.4*105 CFU/mLKlebsiella pneumoniae: 1.4*10 5 CFU/mL
완충용액(BUFFER SOLUTION) : 0.25M KH2PO4 BUFFER SOLUTION: 0.25M KH 2 PO 4
배양 조건 : 35℃, 24hrCulture conditions: 35℃, 24hr
도 2를 참조하면, 본 발명에 따른 샘플(ABPM-stone coating)에 균을 이식한 후 30분 동안 감소율을 측정한 것이다. Referring to Figure 2, the reduction rate was measured for 30 minutes after the bacteria were transplanted into the sample (ABPM-stone coating) according to the present invention.
staphylococcus aureus(황색포도상구균), escherichia coli(대장균), 폐렴막대균(klebsiella pneumoniae)에 대한 감소율을 나타낸다. It shows the reduction rate for staphylococcus aureus (Staphylococcus aureus), escherichia coli (E. coli), and klebsiella pneumoniae.
결과적으로 99.9% 이상의 감소율을 보여주어 항균, 제균 성능이 매우 우수함을 알 수 있었다. As a result, it showed a reduction rate of over 99.9%, showing that the antibacterial and bactericidal performance was very excellent.
도 3은 본 발명에 따른 샘플(ABPM-stone coating)에 이식된 escherichia coli(대장균)의 제거를 보여주는 사진이다. Figure 3 is a photograph showing the removal of escherichia coli (E. coli) implanted in a sample (ABPM-stone coating) according to the present invention.
좌측은 시작 단계이고, 우측은 30분 경과후 변화이다. 다수개의 점으로 보였던 균이 거의 사라졌음을 알 수 있다. The left side is the starting stage, and the right side is the change after 30 minutes. You can see that the bacteria that appeared as multiple dots have almost disappeared.
도 4는 본 발명에 따른 샘플(ABPM-stone coating)에 이식된 폐렴막대균(klebsiella pneumoniae)의 제거를 보여주는 사진이다. Figure 4 is a photograph showing the removal of klebsiella pneumoniae implanted in a sample (ABPM-stone coating) according to the present invention.
좌측은 시작 단계이고, 우측은 30분 경과후 변화이다. 다수개의 점으로 보였던 균이 거의 사라졌음을 알 수 있다. The left side is the starting stage, and the right side is the change after 30 minutes. You can see that the bacteria that appeared as multiple dots have almost disappeared.
도 5는 본 발명에 따른 샘플(ABPM-stone coating)에 이식된 staphylococcus aureus(황색포도상구균)의 제거를 보여주는 사진이다. Figure 5 is a photograph showing the removal of staphylococcus aureus (Staphylococcus aureus) implanted in a sample (ABPM-stone coating) according to the present invention.
좌측은 시작 단계이고, 우측은 30분 경과후 변화이다. 다수개의 점으로 보였던 균이 거의 사라졌음을 알 수 있다. The left side is the starting stage, and the right side is the change after 30 minutes. You can see that the bacteria that appeared as multiple dots have almost disappeared.
비록 바람직한 실시예와 관련하여 설명되어졌지만, 발명의 요지와 범위로부터 벗어남이 없이 다양한 수정 및 변형이 가능한 것은 당업자라면 용이하게 인식할 수 있을 것이며, 이러한 변경 및 수정은 모두 첨부된 청구의 범위에 속함은 자명하다.Although the description has been made in relation to preferred embodiments, it will be readily apparent to those skilled in the art that various modifications and variations can be made without departing from the gist and scope of the invention, and all such changes and modifications fall within the scope of the appended claims. is self-explanatory.
S1 : 1공정 S2 : 2공정
S3 : 3공정 S4 : 4공정 S1: Process 1 S2: Process 2
S3: Process 3 S4: Process 4
Claims (6)
상기 혼합분말을 정제수와 혼합한 혼합액을 가열교반기에 넣고 교반하면서 열을 가하여 증발시키는 2공정;
상기 2공정 후 증발시킨 후 수득된 증발농축액을 상온에서 방치시켜 침전물과 상등액으로 분리되도록 하는 3공정;
상기 3공정의 상등액을 추출시켜 항균농축액을 수득하는 4공정;
을 포함하는 것을 특징으로 하는 무기질 미네랄을 이용한 항균 코팅 조성물의 제조방법. Step 1: mixing volcanic rock and calcium oxide and pulverizing them to 1300-1600 mesh to form mixed powder;
Step 2 of evaporating the mixed powder mixed with purified water by placing it in a heating stirrer and applying heat while stirring;
Step 3, where the evaporated concentrate obtained after evaporation after step 2 is left at room temperature to separate into precipitate and supernatant;
Step 4 of extracting the supernatant of step 3 above to obtain an antibacterial concentrate;
A method for producing an antibacterial coating composition using an inorganic mineral, comprising:
상기 1공정은 산화칼슘 80~90중량%와 화산석 10~20중량%를 혼합하는 것을 특징으로 하는 무기질 미네랄을 이용한 항균 코팅 조성물의 제조방법. According to clause 1,
The first step is a method of producing an antibacterial coating composition using inorganic minerals, characterized in that 80 to 90% by weight of calcium oxide and 10 to 20% by weight of volcanic stone are mixed.
상기 2공정은 정제수 80~90중량%와, 혼합분말 10~20중량%를 혼합하는 것을 특징으로 하는 무기질 미네랄을 이용한 항균 코팅 조성물의 제조방법. According to clause 1,
The second process is a method of producing an antibacterial coating composition using inorganic minerals, characterized in that 80 to 90% by weight of purified water and 10 to 20% by weight of mixed powder are mixed.
상기 4공정은 혼합액 100중량부를 기준으로 하여 98~99중량부를 버리고, 1~2중량부만 추출하여 된 항균농축액을 수득하는 것을 특징으로 하는 무기질 미네랄을 이용한 항균 코팅 조성물의 제조방법. According to clause 1,
In the above 4 steps, based on 100 parts by weight of the mixed solution, 98 to 99 parts by weight are discarded and only 1 to 2 parts by weight are extracted to obtain an antibacterial concentrate. A method of producing an antibacterial coating composition using inorganic minerals.
상기 4공정의 항균농축액을 코팅제에 혼합하여 제품화시키는 5공정;을 더 포함하는 것을 특징으로 하는 무기질 미네랄을 이용한 항균 코팅 조성물의 제조방법. According to clause 1,
A method for producing an antibacterial coating composition using an inorganic mineral, further comprising a 5th step of mixing the antibacterial concentrate of the 4th step with a coating agent to commercialize the product.
An antibacterial coating composition using an inorganic mineral prepared by the production method according to any one of claims 1 to 4.
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