KR20240027907A - Thermal adhesive composite fiber having excellent antibacterial property and soft property and Manufacturing method thereof - Google Patents
Thermal adhesive composite fiber having excellent antibacterial property and soft property and Manufacturing method thereof Download PDFInfo
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- KR20240027907A KR20240027907A KR1020220105231A KR20220105231A KR20240027907A KR 20240027907 A KR20240027907 A KR 20240027907A KR 1020220105231 A KR1020220105231 A KR 1020220105231A KR 20220105231 A KR20220105231 A KR 20220105231A KR 20240027907 A KR20240027907 A KR 20240027907A
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- sheath
- composite fiber
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- fine particles
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- 239000000835 fiber Substances 0.000 title claims abstract description 85
- 239000002131 composite material Substances 0.000 title claims abstract description 70
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 22
- 239000000853 adhesive Substances 0.000 title description 8
- 230000001070 adhesive effect Effects 0.000 title description 2
- 239000004745 nonwoven fabric Substances 0.000 claims abstract description 22
- 229920005989 resin Polymers 0.000 claims description 33
- 239000011347 resin Substances 0.000 claims description 33
- 239000010419 fine particle Substances 0.000 claims description 29
- -1 polyethylene Polymers 0.000 claims description 22
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 20
- 239000004700 high-density polyethylene Substances 0.000 claims description 18
- 239000002952 polymeric resin Substances 0.000 claims description 16
- 229920003002 synthetic resin Polymers 0.000 claims description 16
- 239000000839 emulsion Substances 0.000 claims description 14
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 claims description 14
- PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 238000002788 crimping Methods 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 239000011787 zinc oxide Substances 0.000 claims description 10
- 238000009987 spinning Methods 0.000 claims description 9
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 7
- 239000010954 inorganic particle Substances 0.000 claims description 7
- 229920001155 polypropylene Polymers 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 238000005520 cutting process Methods 0.000 claims description 3
- 229920004889 linear high-density polyethylene Polymers 0.000 claims description 3
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 3
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 3
- 229920001684 low density polyethylene Polymers 0.000 claims description 3
- 239000004702 low-density polyethylene Substances 0.000 claims description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 3
- 229920001225 polyester resin Polymers 0.000 claims description 3
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004645 polyester resin Substances 0.000 claims description 2
- 230000000052 comparative effect Effects 0.000 description 33
- 238000002360 preparation method Methods 0.000 description 32
- 229920001903 high density polyethylene Polymers 0.000 description 15
- 239000000155 melt Substances 0.000 description 12
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 238000004332 deodorization Methods 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- 239000003242 anti bacterial agent Substances 0.000 description 3
- 230000003385 bacteriostatic effect Effects 0.000 description 3
- 230000001877 deodorizing effect Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000009998 heat setting Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 2
- WZFUQSJFWNHZHM-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC(=O)N1CC2=C(CC1)NN=N2 WZFUQSJFWNHZHM-UHFFFAOYSA-N 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- YJLUBHOZZTYQIP-UHFFFAOYSA-N 2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NN=C(O1)CC(=O)N1CC2=C(CC1)NN=N2 YJLUBHOZZTYQIP-UHFFFAOYSA-N 0.000 description 1
- 201000008225 Klebsiella pneumonia Diseases 0.000 description 1
- 241000588747 Klebsiella pneumoniae Species 0.000 description 1
- 206010035717 Pneumonia klebsiella Diseases 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
- D01D10/02—Heat treatment
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/096—Humidity control, or oiling, of filaments, threads or the like, leaving the spinnerettes
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/098—Melt spinning methods with simultaneous stretching
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/22—Formation of filaments, threads, or the like with a crimped or curled structure; with a special structure to simulate wool
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/42—Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
- D04H1/5412—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres sheath-core
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/542—Adhesive fibres
- D04H1/544—Olefin series
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/542—Adhesive fibres
- D04H1/55—Polyesters
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2505/00—Industrial
- D10B2505/04—Filters
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2509/00—Medical; Hygiene
- D10B2509/02—Bandages, dressings or absorbent pads
- D10B2509/026—Absorbent pads; Tampons; Laundry; Towels
Abstract
본 발명은 열접착성 복합섬유 및 이를 제조하는 방법에 관한 것으로서, 우수한 기계적 물성을 가지면서도, 항균성 및 소트프성이 우수한 열접착형 복합섬유, 이를 제조하는 방법 및 이를 포함하는 부직포를 제공할 수 있는 발명이다. The present invention relates to a heat-bonded composite fiber and a method of manufacturing the same, and provides a heat-bonded composite fiber with excellent mechanical properties and excellent antibacterial and soft properties, a method of manufacturing the same, and a nonwoven fabric containing the same. It's an invention.
Description
본 발명은 우수한 탄력성, 소프트한 터치감 등의 고감성을 가지면서 항균성이 우수한 열접착형 복합섬유 및 이를 높은 양산성으로 제조하는 방법에 관한 것이다.The present invention relates to a heat-sealable composite fiber with high sensitivity such as excellent elasticity and soft touch and excellent antibacterial properties, and a method for manufacturing the same with high mass productivity.
열접착형 복합섬유는 일반적으로 2성분으로 구성되고, 열에 의해 특정 성분을 용융시킴으로써 섬유끼리의 접착을 통해 벌키한 부직포를 용이하게 얻을 수 있어서 산업자재에 널리 이용되고 있다. 폴리에스테르(PET)계 열접착형 복합섬유는 자동차용, 건축자재용, 위생재용 등의 생활용품이나 필터용 부직포로 널리 사용되고 있다.Heat-bonded composite fibers are generally composed of two components, and are widely used in industrial materials because they can easily obtain bulky nonwoven fabrics through adhesion of fibers by melting specific components with heat. Polyester (PET)-based heat-sealable composite fibers are widely used as nonwoven fabrics for filters and household goods such as automobiles, building materials, and sanitary materials.
예를 들어, 미국등록특허 제4,129,675호에는 테레프탈산(terephthalic acid: TPA)과 이소프탈산(isophthalic acid: IPA)을 이용하여 공중합된 저융점 폴리에스테르가 소개되어 있으며, 또한, 한국등록특허 제10-1216690호 에는 접착성을 개선시키기 위한 이소프탈산, 디에틸렌글리콜을 포함하여 구현된 저융점 폴리에스테르 섬유를 개시하고 있다.For example, US Patent No. 4,129,675 introduces a low melting point polyester copolymerized using terephthalic acid (TPA) and isophthalic acid (IPA), and Korean Patent No. 10-1216690. Discloses a low melting point polyester fiber containing isophthalic acid and diethylene glycol to improve adhesion.
그러나 위와 같은 종래의 저융점 폴리에스테르 섬유는 일정 수준이상의 방사성 및 접착성을 가질 수 있지만, 강직한 개질제의 고리구조로 인해 열접착 후 딱딱한 느낌의 부직포 또는 직물 구조체를 얻는 문제점이 있다.However, although the conventional low melting point polyester fibers described above may have spinnability and adhesiveness above a certain level, there is a problem in obtaining a hard-feeling non-woven fabric or fabric structure after heat bonding due to the ring structure of the rigid modifier.
또한, 피부에 직접 닿는 부직포 제품 또는 필터에 적용되는 부직포 제조에 사용되는 섬유에 항균성을 부여하기 위하여 종래에는 섬유 제조시 유제를 부여할 때 유제에 항균물질을 함께 사용하여 섬유에 항균성을 부여했는데, 기존 항균성 섬유는 유제에 항균제를 사용하기 때문에 공정상 항균제 손실에 따른 가공비용 상승, 섬유내 항균제 흡수 부족으로 인한 항균력 저하 및 섬유의 소프트성 증가가 미흡하였다.In addition, in order to impart antibacterial properties to the fibers used in the manufacture of non-woven fabrics applied to non-woven products or filters that come in direct contact with the skin, conventionally, when adding an emulsion during fiber manufacturing, antibacterial substances were used together with the emulsion to give anti-bacterial properties to the fiber. Existing antibacterial fibers use antibacterial agents in the emulsion, which increases processing costs due to loss of antibacterial agents during the process, reduces antibacterial activity due to insufficient absorption of antibacterial agents into the fiber, and does not increase the softness of the fiber.
따라서, 기존 열접착형 섬유의 소프트성 부족을 개선할 수 있고, 우수한 항균성을 확보할 수 있으면서, 기존 섬유의 유리한 물성을 가지는 섬유에 대한 개발이 필요하다.Therefore, there is a need to develop a fiber that can improve the lack of softness of existing heat-bonded fibers, secure excellent antibacterial properties, and have the advantageous physical properties of existing fibers.
본 발명의 목적은 상기와 같은 문제점을 해결하기 위하여 안출된 것으로, 본 발명의 목적은 기계적 물성이 우수하면서도, 터치감 및 항균성이 우수한 열접착형 복합섬유 및 이를 이용한 부직포를 제공하고자 하며, 또한, 이를 높은 상업성으로 제조할 수 있는 방법을 제공하고자 한다. The purpose of the present invention was created to solve the above problems. The purpose of the present invention is to provide a heat-sealable composite fiber with excellent mechanical properties as well as excellent touch and antibacterial properties and a non-woven fabric using the same, We aim to provide a method for manufacturing this with high commercial value.
상술한 과제를 해결하기 위하여 본 발명의 열접착형 복합섬유는 시스부 및 코어부를 포함하는 시스-코어(sheath-core) 복합섬유로서, 상기 시스부는 산화아연 및 산화게르마늄을 포함하는 무기미립자 및 고분자 수지를 포함한다.In order to solve the above-mentioned problems, the heat-bonded composite fiber of the present invention is a sheath-core composite fiber including a sheath portion and a core portion, and the sheath portion contains inorganic fine particles and polymers containing zinc oxide and germanium oxide. Contains resin.
본 발명의 바람직한 일실시예로서, 상기 시스부는 상기 무기미립자 0.4 ~ 2.0 중량% 및 잔량의 고분자 수지;를 포함할 수 있다.As a preferred embodiment of the present invention, the sheath portion may include 0.4 to 2.0% by weight of the inorganic fine particles and the remaining amount of polymer resin.
본 발명의 바람직한 일실시예로서, 상기 무기미립자는 산화아연 92 ~ 97 중량% 및 산화게르마늄 3 ~ 8 중량%를 포함할 수 있다.As a preferred embodiment of the present invention, the inorganic fine particles may contain 92 to 97% by weight of zinc oxide and 3 to 8% by weight of germanium oxide.
본 발명의 바람직한 일실시예로서, 상기 무기미립자는 평균입경 10 ㎛ 이하일 수 있다.As a preferred embodiment of the present invention, the inorganic fine particles may have an average particle diameter of 10 ㎛ or less.
본 발명의 바람직한 일실시예로서, 상기 고분자 수지는 선형 폴리에틸렌(polyethylene), 선형 저밀도 폴리에틸렌(linear low density polyethylene), 고밀도 폴리에틸렌(high density polyethylene) 및 저밀도 폴리에틸렌(low density polyethylene) 중에서 선택된 1종 이상을 포함할 수 있다.In a preferred embodiment of the present invention, the polymer resin is one or more selected from linear polyethylene, linear low density polyethylene, high density polyethylene, and low density polyethylene. It can be included.
본 발명의 바람직한 일실시예로서, 상기 코어부는 폴리에틸렌테레프탈레이트(poly(ethylene terephthalate)) 및 폴리부틸렌테레프탈레이트(poly(butylene terephthalate) 중에서 선택된 1종 이상을 포함하는 폴리에스테르(polyester)계 수지, 또는 폴리프로필렌(polypropylene) 수지를 포함할 수 있다.In a preferred embodiment of the present invention, the core portion is a polyester resin containing at least one selected from poly(ethylene terephthalate) and poly(butylene terephthalate), Alternatively, it may include polypropylene resin.
본 발명의 바람직한 일실시예로서, 상기 시스-코어 복합섬유는 섬도 0.8 ~ 20 de 및 섬유장 20 ~ 70 mm일 수 있다.As a preferred embodiment of the present invention, the sheath-core composite fiber may have a fineness of 0.8 to 20 de and a fiber length of 20 to 70 mm.
본 발명의 다른 목적은 앞서 설명한 열접착형 복합섬유를 제조하는 방법에 관한 것으로서, 시스부용 칩 및 코어부용 칩 각각을 용융시킨 후, 용융된 수지 각각을 복합방사구금을 통해 복합방사하여 시스-코어형 미연신 서브토우를 제조하는 1단계; 상기 미연신 서브토우를 연신시키는 2단계; 연신된 토우에 유제 부여 및 권축(crimping)시키는 3단계; 및 권축된 토우를 열고정 및 절단하는 4단계;를 포함하는 공정을 수행하며, 상기 시스부용 수지는 산화아연 및 산화게르마늄을 포함하는 무기미립자를 포함한다.Another object of the present invention relates to a method of manufacturing the heat-bonded composite fiber described above. After melting each of the chips for the sheath portion and the chip for the core portion, each of the melted resins is composite spun through a composite spinneret to form a sheath-core. Step 1 of manufacturing a type unstretched subtow; Step 2 of stretching the unstretched subtow; 3 steps of applying emulsion and crimping to the stretched tow; and a fourth step of heat setting and cutting the crimped tow. The resin for the sheath part includes inorganic fine particles containing zinc oxide and germanium oxide.
본 발명의 또 다른 목적은 상기 복합섬유를 이용하여 제조한 부직포를 제공하는데 있다.Another object of the present invention is to provide a nonwoven fabric manufactured using the composite fiber.
본 발명의 또 다른 목적은 상기 부직포를 이용한 응용제품으로서, 기저귀용 탑시트(top sheet), 기저귀용 백시트(back sheet), 생리대용 시트, 공기청정기용 필터, 수처리용 필터, 청소기용 필터, 마스크용 필터, 물티슈재에 적용할 수 있다. Another object of the present invention is an application product using the non-woven fabric, such as a top sheet for diapers, a back sheet for diapers, a sheet for sanitary napkins, a filter for an air purifier, a filter for water treatment, a filter for a vacuum cleaner, and a mask. It can be applied to filters and wet tissue materials.
본 발명의 복합섬유는 기계적 물성이 우수하고, 높은 발현권축수, 미소권축 사이클 및 적정 보풀수를 가지며, 항균성이 우수할 뿐만 아니라, 소프트성이 우수한 바, 피부에 직접 닿는 부직포 제품 등에 사용하기 적합하다.The composite fiber of the present invention has excellent mechanical properties, high crimp count, micro-crimp cycle, and appropriate fluff count, and has excellent antibacterial properties as well as excellent softness, making it suitable for use in non-woven products that come in direct contact with the skin. do.
이하 본 발명의 열접착형 복합섬유를 제조하는 방법을 통해서 본 발명을 자세하게 설명을 하겠다.Hereinafter, the present invention will be described in detail through the method of manufacturing the heat-bonded composite fiber of the present invention.
본 발명의 열접착형 복합섬유는 기존에 복합섬유 제조시 유제 부여를 할 때, 상기 유제에 항균성분을 도입하여 복합섬유에 항균성을 부여한 것과 달리, 복합섬유의 시스부(시스성분) 자체에 항균 기능을 가지는 특정 무기미립자를 가지도록 제조한 복합섬유이다.The heat-bonded composite fiber of the present invention has an antibacterial effect on the sheath portion (sheath component) of the composite fiber itself, unlike the existing case where an antibacterial component was introduced into the emulsion to provide antibacterial properties to the composite fiber when applying an emulsion during the production of composite fiber. It is a composite fiber manufactured to contain specific functional inorganic fine particles.
이러한, 본 발명의 열접착형 복합섬유는 시스부용 칩 및 코어부용 칩 각각을 용융시킨 후, 용융된 수지 각각을 복합방사구금을 통해 복합방사하여 시스-코어형 미연신 서브토우를 제조하는 1단계; 상기 미연신 서브토우를 연신시키는 2단계; 연신된 토우에 유제 부여 및 권축(crimping)시키는 3단계; 권축된 토우를 열고정 및 절단하는 4단계;를 포함하는 공정을 수행하여 제조할 수 있다.The heat-bonded composite fiber of the present invention is a first step of manufacturing a sheath-core type unstretched subtow by melting each of the chips for the sheath portion and the chip for the core portion, and then composite spinning each of the melted resins through a composite spinneret. ; Step 2 of stretching the unstretched subtow; 3 steps of applying emulsion and crimping to the stretched tow; It can be manufactured by performing a process including 4 steps of heat setting and cutting the crimped tow.
1단계의 상기 시스부용 칩은 무기미립자 및 고분자 수지를 포함하는 혼합수지를 칩화시켜 제조한 것으로서, 무기미립자 0.4 ~ 2.0 중량% 및 잔량의 고분자 수지를 포함하며, 바람직하게는 무기미립자 0.6 ~ 1.8 중량% 및 잔량의 고분자 수지를 포함하고, 더욱 바람직하게는 무기미립자 0.8 ~ 1.6 중량% 및 잔량의 고분자 수지를 포함할 수 있다. 이때, 상기 무기미립자가 0.4 중량% 미만이면 제조된 복합섬유가 충분한 항균성을 갖지 못할 수 있고, 2.0 중량%를 초과하면 복합방사 중 섬유와 방사구금 등의 금속 마찰이 감소되어 방사성이 불균일해지는 문제가 있을 수 있다.The chip for the sheath part in the first stage is manufactured by chipping a mixed resin containing inorganic fine particles and polymer resin, and contains 0.4 to 2.0% by weight of inorganic fine particles and the remaining amount of polymer resin, preferably 0.6 to 1.8 weight% of inorganic fine particles. % and the remaining amount of polymer resin, more preferably 0.8 to 1.6 wt% of inorganic fine particles and the remaining amount of polymer resin. At this time, if the inorganic fine particles are less than 0.4% by weight, the produced composite fiber may not have sufficient antibacterial properties, and if it exceeds 2.0% by weight, the friction between the fiber and metal such as the spinneret is reduced during composite spinning, causing a problem of non-uniform spinning properties. There may be.
그리고, 상기 무기미립자는 산화아연 92 ~ 97 중량% 및 산화게르마늄 3 ~ 8 중량%를 포함하며, 바람직하게는 산화아연 93.5 ~ 97.0 중량% 및 산화게르마늄 3.0 ~ 6.5 중량%를 포함하며, 더욱 바람직하게는 산화아연 94.5 ~ 96.5 중량% 및 산화게르마늄 3.5 ~ 5.5 중량%를 포함할 수 있다. 이때, 산화게르마늄 함량이 3 중량% 미만이면 복합섬유의 소프트성이 부족한 문제가 있을 수 있고, 8 중량%를 초과하여 사용하더라도 소프트성 향상이 없으면서 오히려 항균성이 떨어질 수 있으므로 상기 범위 내로 사용하는 것이 좋다.In addition, the inorganic fine particles contain 92 to 97 wt% of zinc oxide and 3 to 8 wt% of germanium oxide, preferably 93.5 to 97.0 wt% of zinc oxide and 3.0 to 6.5 wt% of germanium oxide, and more preferably It may include 94.5 to 96.5% by weight of zinc oxide and 3.5 to 5.5% by weight of germanium oxide. At this time, if the germanium oxide content is less than 3% by weight, there may be a problem of insufficient softness of the composite fiber, and even if it is used in excess of 8% by weight, the softness is not improved and the antibacterial properties may be reduced, so it is recommended to use within the above range. .
그리고, 상기 무기미립자는 평균입경 10 ㎛ 이하인 것을, 바람직하게는 평균입경 8.0㎛ 이하인 것이, 더욱 바람직하게는 평균입경 0.5 ~ 6.5 ㎛인 것이 좋으며, 평균입경이 10㎛를 초과하면 무기미립자가 복합섬유 시스부에 균일하게 분산되지 않아서 소프트성 및 항균성이 떨어지는 문제가 있을 수 있고, 평균입경이 너무 작으면 관리 및 섬유 제조시 섬유로부터 이탈하는 문제가 발생할 수 있으므로 상기 범위 내의 입경 크기를 가지는 무기미립자를 도입하는 것이 좋다.In addition, the inorganic fine particles preferably have an average particle diameter of 10 ㎛ or less, preferably 8.0 ㎛ or less, and more preferably 0.5 to 6.5 ㎛, and if the average particle diameter exceeds 10 ㎛, the inorganic fine particles form composite fibers. Since they are not uniformly dispersed in the sheath, there may be a problem of poor softness and antibacterial properties, and if the average particle size is too small, problems may arise from separation from the fiber during management and fiber manufacturing, so inorganic fine particles with a particle size within the above range are used. It is good to introduce it.
상기 고분자 수지는 폴리에틸렌 수지를 사용할 수 있으며, 바람직하게는 선형 폴리에틸렌(polyethylene), 선형 저밀도 폴리에틸렌(linear low density polyethylene), 고밀도 폴리에틸렌(high density polyethylene) 및 저밀도 폴리에틸렌(low density polyethylene) 중에서 선택된 1종 이상을 포함할 수 있고, 더욱 바람직하게는 선형 폴리에틸렌 및 고밀도 폴리에틸렌 중에서 선택된 1종 이상을 포함할 수 있다. The polymer resin may be a polyethylene resin, and is preferably one or more selected from linear polyethylene, linear low density polyethylene, high density polyethylene, and low density polyethylene. It may include, and more preferably, it may include one or more types selected from linear polyethylene and high-density polyethylene.
그리고, 상기 고분자 수지는 ASTM D 1238에 의하여 측정시 190℃에서의 용융흐름지수(MI) 8 ~ 25 g/10분인 것을, 바람직하게는 용융흐름지수 15 ~ 23 g/10분(190℃)인 것을, 더욱 바람직하게는 용융흐름지수 17 ~ 22 g/10분(190℃)인 것을 사용하는 것이 좋으며, 이때, 고분자 수지의 용융지수가 8g/10분 미만이면 방사 압력 증가로 과도한 용융 온도를 설정이 필요하여 열분해가 발생되는 문제가 있을 수 있고, 고분자 수지의 용융지수가 25 g/10분을 초과하면 방사 중 섬유가 절단되어 품질이 저하되는 문제가 있을 수 있다.In addition, the polymer resin has a melt flow index (MI) of 8 to 25 g/10 min at 190°C as measured by ASTM D 1238, and preferably a melt flow index of 15 to 23 g/10 min (190°C). It is recommended to use one with a melt flow index of 17 to 22 g/10 min (190°C), more preferably, and at this time, if the melt index of the polymer resin is less than 8 g/10 min, an excessive melt temperature must be set by increasing the spinning pressure. There may be a problem of thermal decomposition due to the need for this, and if the melt index of the polymer resin exceeds 25 g/10 minutes, the fiber may be cut during spinning and the quality may deteriorate.
시스부용 칩 형성에 사용되는 무기미립자 및 고분자 수지를 포함하는 혼합수지,즉 시스부칩용 수지는 190℃에서의 용융흐름지수(MI) 20 ~ 30 g/10분, 바람직하게는 24 ~ 30 g/10분(190℃), 더욱 바람직하게는 25 ~ 29 g/10분(190℃)일 수 있다.The mixed resin containing inorganic particles and polymer resin used to form chips for sheath parts, that is, the resin for sheath chips, has a melt flow index (MI) of 20 to 30 g/10 min at 190°C, preferably 24 to 30 g/ It may be 10 minutes (190°C), more preferably 25 to 29 g/10 minutes (190°C).
상기 코어부용 칩은 ASTM D2857에 의하여 측정된 고유점도 (IV, Intrinsic viscosity) 0.5 ~ 0.9 dl/g을 갖는 폴리에틸렌테레프탈레이트(poly(ethylene terephthalate)) 및 폴리부틸렌테레프탈레이트(poly(butylene terephthalate) 중에서 선택된 1종 이상을 포함하는 폴리에스테르(polyester)계 수지; 또는 폴리프로필렌(polypropylene) 수지;를 포함할 수 있다.The chip for the core portion is made of poly(ethylene terephthalate) and poly(butylene terephthalate) having an intrinsic viscosity (IV) of 0.5 to 0.9 dl/g as measured by ASTM D2857. It may include a polyester-based resin containing at least one selected type, or a polypropylene resin.
상기 폴리프로필렌 수지는 ASTM D 1238에 의하여 측정시, 230℃에서의 용융흐름지수 8 ~ 20 g/10분인 것을, 바람직하게는 용융흐름지수 10 ~ 18 g/10분(230℃)인 것을, 더욱 바람직하게는 용융흐름지수 12.5 ~ 17.5 g/10분(230℃)인 것을 사용하는 것이 섬유의 균일한 섬도와 신도의 물성 제어 측면에서 좋다.When measured according to ASTM D 1238, the polypropylene resin has a melt flow index of 8 to 20 g/10 min at 230°C, preferably a melt flow index of 10 to 18 g/10 min (230°C). Preferably, the use of a melt flow index of 12.5 to 17.5 g/10 minutes (230°C) is good in terms of controlling the physical properties of uniform fineness and elongation of the fiber.
1단계에서 앞서 설명한 시스부용 칩 및 코어부용 칩 각각을 각 칩 소재에 따른 용융 온도로 가열하여 용융시킨 후, 용융된 수지 각각을 복합방사구금을 통해 복합방사시켜서 시스-코어형 미연신 서브토우를 제조한다. 이때, 상기 복합방사구금은 당업계에서 사용하는 일반적인 시스-코어 섬유 제조용 복합방사구금을 사용할 수 있다. In step 1, each of the chips for the sheath portion and the chip for the core portion described above are melted by heating to the melting temperature according to each chip material, and then each of the molten resins is composite spun through a composite spinneret to produce a sheath-core type unstretched subtow. manufacture. At this time, the composite spinneret can be a general composite spinneret for manufacturing sheath-core fibers used in the industry.
그리고, 2단계의 연신은 미연신 서브토우를 연신비 3.0 ~ 5.0배로, 바람직하게는 3.5 ~ 4.5배로, 더욱 바람직하게는 4.0 ~ 4.5배로 연신하여 연신된 토우를 제조할 수 있다.In addition, in the second stage of stretching, stretched tow can be produced by stretching the unstretched subtow at a stretching ratio of 3.0 to 5.0 times, preferably 3.5 to 4.5 times, and more preferably 4.0 to 4.5 times.
3단계는 연신된 토우에 유제를 부여한 후, 권축(crimping) 공정을 수행하며, 상기 유제 부여는 후가공의 정전기 제거, 마찰 감소 및 친수성 또는 소수성능을 발현하기 위해 수행하는 것으로서, 당업계에서 사용하는 일반적인 방법으로 수행할 수 있으며, 바람직하게는 오일-롤(oil roll) 및 스프레이 도포(spraying)법 또는 침적(dipping)법을 이용하여 수행할 수 있다.In the third step, an emulsion is applied to the stretched tow, and then a crimping process is performed. The emulsion application is performed to remove static electricity in post-processing, reduce friction, and develop hydrophilic or hydrophobic properties, and is used in the art. It can be performed by a general method, preferably by using an oil roll, spraying method, or dipping method.
그리고, 상기 권축 공정은 크림퍼(crimper)를 이용하여 연신되 토우에 권축을 부여하여 수행할 수 있다. 상기 권축 공정을 수행한 권축된 토우는 권축수 5 ~ 20 개/inch, 바람직하게는 권축수 7 ~ 18 개/inch 일 수 있다. 이때, 권축된 토우의 권축수가 5 개/inch 미만이면 부직포의 단위 중량단 두께가 감소 하는 문제가 있을 수 있고, 토우의 권축수가 20 개/inch 를 초과하면 부직포의 균제도가 떨어지는 문제가 있을 수 있다.Additionally, the crimping process can be performed by applying crimping to the stretched tow using a crimper. The crimped tow that has undergone the crimping process may have a crimping number of 5 to 20 pieces/inch, and preferably a crimping number of 7 to 18 pieces/inch. At this time, if the number of crimps of the crimped tow is less than 5 pieces/inch, there may be a problem that the thickness of the unit weight of the nonwoven fabric decreases, and if the number of crimps of the tow exceeds 20 pieces/inch, there may be a problem of poor uniformity of the nonwoven fabric. .
4단계는 상기 열고정은 권축된 토우를 45℃ ~ 130℃ 하에서, 더욱 바람직하게는 50℃ ~ 120℃ 하에서, 더욱 바람직하게는 55℃ ~ 120℃ 하에서 수행할 수 있다.In step 4, the heat setting may be performed on the crimped tow at 45°C to 130°C, more preferably at 50°C to 120°C, and even more preferably at 55°C to 120°C.
이러한 방법으로 제조한 본 발명의 열접착형 복합섬유는 코어부 및 시스부의 단면적비가 1 : 0.40 ~ 2.40, 바람직하게는 단면적비가 1 : 0.50 ~ 2.00 일 수 있다. 이때, 코어부의 단면적에 대해서 시스부의 단면적비가 0.4 미만이면 열접착성이 크게 낮은 문제가 있을 수 있고, 시스부의 단면적비가 2.40을 초과하면 복합섬유의 기계적 물성이 너무 낮은 문제가 있을 수 있으므로, 상기 범위의 단면적비 범위를 가지도록 복합섬유를 제조하는 것이 바람직하다.The heat-bonded composite fiber of the present invention manufactured by this method may have a cross-sectional area ratio of the core portion and the sheath portion of 1:0.40 to 2.40, preferably 1:0.50 to 2.00. At this time, if the cross-sectional area ratio of the sheath part to the cross-sectional area of the core part is less than 0.4, there may be a problem of significantly low thermal adhesiveness, and if the cross-sectional area ratio of the sheath part exceeds 2.40, there may be a problem that the mechanical properties of the composite fiber are too low, so it is within the above range. It is desirable to manufacture composite fibers to have a cross-sectional area ratio range of.
본 발명의 복합섬유의 코어부 및/또는 시스부의 단면 형태는 특별하게 한정하지 않으며, 복합방사구금의 노즐 형태 조절을 통해, 원형, 타원형, 오각형, 사각형, 삼각형 등 다양한 형태를 가지도록 제조할 수 있다. The cross-sectional shape of the core portion and/or sheath portion of the composite fiber of the present invention is not particularly limited, and can be manufactured to have various shapes such as circular, oval, pentagonal, square, and triangular shape by adjusting the nozzle shape of the composite spinneret. there is.
또한, 본 발명의 복합섬유는 섬도 0.8 ~ 20 de, 바람직하게는 1.0 ~ 15.0 de,더욱 바람직하게는 1.0 ~ 10.0 de일 수 있으며, 섬유장은 20 ~ 70 mm, 바람직하게는 22 ~ 64 mm, 더욱 바람직하게는 26 ~ 50 mm일 수 있다.In addition, the composite fiber of the present invention may have a fineness of 0.8 to 20 de, preferably 1.0 to 15.0 de, more preferably 1.0 to 10.0 de, and the fiber length may be 20 to 70 mm, preferably 22 to 64 mm, more preferably 1.0 to 10.0 de. Preferably it may be 26 to 50 mm.
그리고, 본 발명의 복합섬유는 ASTM D 3822에 의거하여 측정시, 섬유의 강도는 2.5 ~ 5.0g/de, 바람직하게는 2.8 ~ 4.5g/de 일 수 있다.In addition, when the composite fiber of the present invention is measured according to ASTM D 3822, the fiber strength may be 2.5 to 5.0 g/de, preferably 2.8 to 4.5 g/de.
이러한 본 발명의 복합섬유는 정균 감소율이 99.0% 이상, 바람직하게는 99.5% 이상으로 항균성이 우수하면서도 항균성이 장기간 지속되며, 소프트성이 매우 우수하다.The composite fiber of the present invention has excellent antibacterial properties with a bacteriostatic reduction rate of 99.0% or more, preferably 99.5% or more, and the antibacterial properties last for a long time and have excellent softness.
본 발명의 상기 복합섬유를 열접착 섬유 등으로 이용하여 부직포를 제조할 수 있으며, 바람직한 일 구현예를 들면, 상기 복합섬유를 이용하여 에어스루본딩(air through bonding) 부직포, 써멀본딩(thermal bonding) 부직포 및/또는 스펀레이스(spunlace) 부직포를 제조할 수 있다.Nonwoven fabrics can be manufactured using the composite fibers of the present invention as heat-bonded fibers, etc., and as a preferred embodiment, the composite fibers can be used to manufacture air through bonding nonwovens and thermal bonding. Nonwoven and/or spunlace nonwoven fabrics can be produced.
그리고, 상기 부직포는 다양한 응용제품으로 적용할 수 있으며, 바람직한 일구현예를 들면, 기저귀용 탑시트(top sheet), 기저귀용 흡수분산층(Acquisition distribution layer), 기저귀용 백시트(back sheet), 생리대용 시트, 공기청정기용 필터, 수처리용 필터, 청소기용 필터, 마스크용 필터, 물티슈, 건자재 등에 사용되는 부직포 제품으로 적용할 수 있다.In addition, the non-woven fabric can be applied to various application products, for example, a top sheet for diapers, an absorption distribution layer for diapers, a back sheet for diapers, and sanitary napkins. It can be applied to non-woven products used in medical sheets, air purifier filters, water treatment filters, vacuum cleaner filters, mask filters, wet tissues, and construction materials.
이하, 실시예를 통하여 본 발명을 더욱 구체적으로 설명하기로 하지만, 하기 실시예가 본 발명의 범위를 제한하는 것은 아니며, 이는 본 발명의 이해를 돕기 위한 것으로 해석되어야 할 것이다.Hereinafter, the present invention will be described in more detail through examples. However, the following examples do not limit the scope of the present invention, and should be interpreted to aid understanding of the present invention.
[실시예] [Example]
준비예 1 : 시스부 칩의 준비Preparation Example 1: Preparation of sheath chip
산화아연 95.2 중량% 및 산화게르마늄 4.8 중량%를 포함하는 무기미립자를 준비하였다. 이때, 상기 무기미립자는 평균입경이 약 1.5㎛였다.Inorganic fine particles containing 95.2% by weight of zinc oxide and 4.8% by weight of germanium oxide were prepared. At this time, the inorganic fine particles had an average particle diameter of about 1.5㎛.
이와는 별도로 용융흐름지수(MI) 19 ~ 20 g/10분(190℃)인 고밀도 폴리에틸렌(HDPE) 수지를 준비하였다.Separately, a high-density polyethylene (HDPE) resin with a melt flow index (MI) of 19 to 20 g/10 minutes (190°C) was prepared.
다음으로, 상기 무기미립자 1.2 중량% 및 잔량의 상기 고밀도 폴리에틸렌(HDPE) 수지를 혼합하여 용융흐름지수(MI) 27 g/10분(190℃)인 시스부 칩용 수지를 제조한 후, 이를 칩화하여 시스부 칩을 제조하였다.Next, 1.2% by weight of the inorganic particles and the remaining amount of the high-density polyethylene (HDPE) resin were mixed to prepare a resin for a sheath chip with a melt flow index (MI) of 27 g/10 minutes (190°C), and then chipped. A sheath chip was manufactured.
준비예 2 ~ 4 및 비교준비예 1 ~ 6Preparation Examples 2 to 4 and Comparative Preparation Examples 1 to 6
상기 준비예 1과 동일한 방법으로 시스부 칩을 제조하되, 하기 표 1과 같은 조성의 시스부 칩용 수지를 제조한 후, 이를 칩화하여 시스부 칩을 각각 제조하여 준비예 2 ~ 4 및 비교준비예 1 ~ 6를 각각 실시하였다.A sheath chip was prepared in the same manner as in Preparation Example 1, except that a resin for a sheath chip having the composition shown in Table 1 below was prepared and then chipped to produce sheath chips, respectively, in Preparation Examples 2 to 4 and Comparative Preparation Examples. 1 to 6 were carried out respectively.
종류polymer resin
type
내 함량Resin for sheath chip
my content
아연Oxidation
zinc
게르마늄Oxidation
germanium
입경average
particle size
중량%96.0
weight%
중량%4.0
weight%
중량%96.8
weight%
중량%3.2
weight%
중량%6.5
weight%
중량%96.0
weight%
중량%4.0
weight%
2Comparison preparation example
2
중량%100
weight%
3Comparison preparation example
3
중량%97.5
weight%
중량%2.5
weight%
중량%97.5
weight%
중량%8.5
weight%
5Comparison preparation example
5
중량%96.0
weight%
중량%4.0
weight%
중량%96.0
weight%
중량%4.0
weight%
실시예 1 : 열접착성 복합섬유의 제조Example 1: Preparation of heat-adhesive composite fiber
(1) 코어부 칩의 준비(1) Preparation of core chip
용융흐름지수(MI) 17g/10분(230℃)인 폴리프로필렌(PP)수지를 칩화시켜서 코어부 칩을 제조하였다.A core chip was manufactured by chipping polypropylene (PP) resin with a melt flow index (MI) of 17 g/10 minutes (230°C).
(2) 시스-코어 복합섬유 제조(2) Manufacture of sheath-core composite fiber
상기 준비예 1의 시스부 칩을 240℃로 가열하여 용융시키고, 상기 코어부 칩을 265℃로 가열하여 용융시켰다.The sheath chip of Preparation Example 1 was melted by heating to 240°C, and the core chip was melted by heating to 265°C.
다음으로, 용융된 각각의 수지를 시스-코어 섬유 제조용 복합방사구금을 통해 복합방사시켜서 미연신 서브토우를 제조하였다.Next, each melted resin was composite spun through a composite spinneret for producing cis-core fibers to produce unstretched subtow.
이때, 상기 복합방사는 방사속도 980 m/분 조건으로 수행하였다.At this time, the composite spinning was performed under the conditions of a spinning speed of 980 m/min.
다음으로, 제조한 미연신 서브토우를 연신비 4.2 배로 연신하여 연신된 토우를 제조하였다.Next, the prepared unstretched subtow was stretched at a draw ratio of 4.2 to produce stretched tow.
다음으로, 연신된 토우에 오일-롤(oil roll) 및 오일-가이드(oil-guide)를 이용하여 비이온성 계면활성제 및 음이온성 계면활성제를 포함하는 유제를 부여한 후, 크림퍼를 이용하여 권축을 가하여 권축수 12 개/inch인 권축된 토우를 제조하였다.Next, an emulsion containing a nonionic surfactant and an anionic surfactant is applied to the stretched tow using an oil roll and an oil guide, and then crimped using a crimper. By adding this, a crimped tow with a crimping number of 12 pieces/inch was manufactured.
다음으로, 권축된 토우를 100℃의 열을 가하여 열고정시키고 절단시켜서 섬도 2de, 섬유장 38 mm이며, 단면이 원형인 시스-코어 형태의 열접착성 복합섬유를 제조하였다.Next, the crimped tow was heat set at 100°C and cut to produce a heat-sealable sheath-core composite fiber with a fineness of 2de, a fiber length of 38 mm, and a circular cross-section.
이때, 열접착성 복합섬유의 시스부 및 코어부의 단면적비는 1:1였다.At this time, the cross-sectional area ratio of the sheath portion and core portion of the heat-adhesive composite fiber was 1:1.
실시예 2 ~ 4 및 비교예 1 ~ 6Examples 2 to 4 and Comparative Examples 1 to 6
상기 실시예 1과 동일한 코어부 칩 및 방법으로 열접착성 복합섬유를 제조하되, 하기 표 2와 같이 시스부 칩을 달리하여 열접착성 복합섬유를 각각 제조하여, 실시예 2 ~ 4 및 비교예 1 ~ 6를 각각 실시하였다. Heat-adhesive composite fibers were manufactured using the same core chip and method as in Example 1, but the heat-adhesive composite fibers were manufactured with different sheath chips as shown in Table 2 below, Examples 2 to 4 and Comparative Examples. 1 to 6 were carried out respectively.
비교예 7Comparative Example 7
무기미립자를 사용하지 않은 비교준비예 1의 시스부 칩용 수지로 제조한 시스부 칩을 사용하여 실시예 1 과 동일한 방법으로 시스-코어 복합섬유를 제조하되, 연신된 토우에 유제를 부여할 때, 무기미립자를 포함하는 유제를 사용하였다.Sheath-core composite fibers were manufactured in the same manner as in Example 1 using the sheath chip made from the sheath chip resin of Comparative Preparation Example 1 without the use of inorganic fine particles, except that when an emulsion was applied to the drawn tow, An emulsion containing inorganic fine particles was used.
이때, 상기 유제는 무기미립자 1.0 중량%, 비이온성 계면활성제 및 음이온성 계면활성제를 포함하는 유제를 잔량으로 포함한다. 그리고, 상기 무기미립자는 산화아연 96.0 중량% 및 산화게르마늄 4.0 중량%를 포함하며, 상기 무기미립자는 평균입경이 약 1.1㎛였다.At this time, the emulsion contains 1.0% by weight of inorganic fine particles, a nonionic surfactant, and an anionic surfactant in the remaining amount. In addition, the inorganic fine particles contained 96.0% by weight of zinc oxide and 4.0% by weight of germanium oxide, and the average particle diameter of the inorganic fine particles was about 1.1㎛.
단면적비Core part: Sheath part
cross-sectional area ratio
(개/inch)Number of windings
(pcs/inch)
상기 실시예와 비교예에서 실시한 열접착성 복합섬유 제조에 있어서, 실시예 1 ~ 4, 비교예 1 ~ 3및 비교예 7의 경우 방사성이 양호하여 섬유의 균제도가 양호한 것을 확인한 반면, 비교예 4 과 같이 시스부 칩의 무기미립자 성분 내 산화게르마늄의 함유량을 증가시킨 경우 및 비교예 5와 같이 시스부 칩용 수지 제조시 무기미립자 함량이 2.0 중량% 초과한 경우, 복합방사 중 끈김 현상이 간헐적으로 발생되어 균일한 섬유를 얻기 어려운 점이 있었다. In the production of heat-adhesive composite fibers carried out in the above Examples and Comparative Examples, it was confirmed that Examples 1 to 4, Comparative Examples 1 to 3, and Comparative Example 7 had good spinnability and good uniformity of the fiber, while Comparative Example 4 When the content of germanium oxide in the inorganic particulate component of the sheath chip is increased as shown, and when the inorganic particulate content exceeds 2.0% by weight when manufacturing the resin for the sheath chip as in Comparative Example 5, stickiness occurs intermittently during composite spinning. Therefore, it was difficult to obtain uniform fibers.
또한, 시스부 칩용 수지 제조에 사용된 무기미립자의 평균입경이 10.0㎛를 초과한 것을 사용한 비교예 6의 경우 초기 방사성은 양호하나 압력 증가율이 급격하게 발생되어 복합섬유의 연속 생산이 어려운 문제점이 있었다.In addition, in the case of Comparative Example 6, where the average particle diameter of the inorganic particles used to manufacture the resin for the sheath chip exceeded 10.0㎛, the initial spinnability was good, but the pressure increase rate occurred rapidly, making continuous production of composite fibers difficult. .
실험예 : 물성 측정Experimental example: Measurement of physical properties
상기 실시예 및 비교예에서 제조한 시스-코어 열접착성 복합섬유에 대한 기계적 물성(강력/신도), 항균성, 소취성, 소프트성을 측정하고, 그 결과를 하기 표 3에 나타내었다. Prepared in the above examples and comparative examples The mechanical properties (strength/elongation), antibacterial property, deodorization, and softness of the sheath-core heat-adhesive composite fiber were measured, and the results are shown in Table 3 below.
(1) 강력 및 신도 측정 (1) Strength and elongation measurements
TEXTEXHNO사의 섬유인장시험기를 이용하여 ASTM D 3822 평가법을 기준으로 섬유 강도 및 신도를 측정하였다. 측정 횟수는 20회로 하고, 그 평균값을 강도와 신도로 하였다.Fiber strength and elongation were measured based on the ASTM D 3822 evaluation method using a fiber tensile tester from TEXTEXHNO. The number of measurements was 20, and the average values were taken as strength and elongation.
(2) 항균성 측정 (2) Measurement of antibacterial activity
KS K 0693-2006에 준하여 정균감소율(%)로서 평가하였다. 적용 균주는 황색포도상구균(Staphylococcus aureus ATCC 6538), 폐렴균(Klebsiella pneumonia ATCC 4352)을 적용하여 시험하였다.It was evaluated as bacteriostatic reduction rate (%) according to KS K 0693-2006. The applied strains were Staphylococcus aureus ATCC 6538 and Klebsiella pneumonia ATCC 4352.
(3) 소취성 측정 (3) Deodorization measurement
일본섬유평가기술협의회 JTETC 검지관법(암모니아 가스에 대한 흡착성)에 따라 소취성을 측정하였다.Deodorization was measured according to the Japan Textile Evaluation and Technology Council JTETC detection tube method (adsorption to ammonia gas).
(4) 소프트터치성 측정 (4) Soft touch measurement
소프트 터치 평가는 샘플 정보가 없으면서 해당 분야에 5년 이상 근무한 자 5명을 대상으로 블라인드 테스트를 수행한 후, 섬유 촉감상 부드러운 느낌 정도를 1 ~ 5점으로 평가하였고, 평균값을 반올림하여 소프트 터치성을 측정하였다(1점:매우 나쁨, 2점 : 나쁨, 3점 : 보통, 4점: 좋음, 5점 : 매우 좋음).For the soft touch evaluation, a blind test was conducted on 5 people who had worked in the field for more than 5 years without sample information, and then the softness of the fabric was evaluated on a scale of 1 to 5, and the average value was rounded to determine the soft touch property. was measured (1 point: very bad, 2 points: bad, 3 points: average, 4 points: good, 5 points: very good).
(g/de)robbery
(g/de)
(%)believer
(%)
(정균감소율,%)antibacterial
(Bacteriostatic reduction rate,%)
(암모니아,%)Deodorizing
(ammonia,%)
터치성soft
touchability
상기 실시예 및 실험예를 통하여 실시예 1 ~ 3의 열접착성 복합섬유가 우수한 기계적 물성, 접착강도를 가지면서도, 항균성, 소취성 및 소프트터치성이 높은 복합섬유임을 확인할 수 있었다. Through the above examples and experimental examples, it was confirmed that the heat-sealable composite fibers of Examples 1 to 3 were composite fibers with excellent mechanical properties and adhesive strength, as well as high antibacterial properties, deodorization properties, and soft touch properties.
이에 반해, 비교예 1 ~ 6은 실시예 1 ~ 3과 비교할 때, 전반적으로 강도가 너무 낮거나, 신도가 다소 높은 경향을 보였다. 그리고, 시스부칩 내 무기미립자를 포함하지 않는 비교예 1은 항균성이 거의 없을 뿐만 아니라, 소취성도 없는 결과를 보였다.On the other hand, Comparative Examples 1 to 6 showed a tendency for the overall strength to be too low or the elongation to be somewhat high when compared to Examples 1 to 3. In addition, Comparative Example 1, which did not contain inorganic particles in the sheath chip, not only had almost no antibacterial properties, but also showed no deodorizing properties.
그리고, 무기미립자 내 산화게르마늄 함량이 3중량% 미만인 시스부 칩으로 제조한 비교예 3의 경우, 실시예 2와 비교할 때, 소프트성이 크게 감소하는 문제가 있었다. In addition, in the case of Comparative Example 3, which was manufactured with a sheath chip with a germanium oxide content of less than 3% by weight in the inorganic fine particles, compared to Example 2, there was a problem in that the softness was greatly reduced.
또한, 무기미립자 내 산화게르마늄 함량이 8중량% 초과한 시스부 칩으로 제조한 비교예 4 실시예 3과 비교할 때, 항균성, 소취성, 소프트성은 우수하나, 앞서 설명한 바와 같이 기계적 물성이 오히려 낮아지는 문제가 있었다.In addition, compared to Comparative Example 4 and Example 3 manufactured with a sheath chip with a germanium oxide content in the inorganic fine particles exceeding 8% by weight, antibacterial properties, deodorization, and softness are excellent, but as described above, mechanical properties are rather lower. There was a problem.
그리고, 무기미립자 함량이 2.0 중량%를 초과한 시스부 칩을 사용하여 제조한 비교예 5의 경우, 기계적 물성도 낮으면서 소프트성도 좋지 않은 문제가 있었다.In addition, in the case of Comparative Example 5, which was manufactured using a sheath chip with an inorganic fine particle content exceeding 2.0% by weight, there was a problem of low mechanical properties and poor softness.
또한, 비교예 7의 경우, 기계적 물성,항균성, 소취성은 우수하나, 소프트 성이 좋지 않은 결과를 보였다.In addition, in the case of Comparative Example 7, the mechanical properties, antibacterial properties, and deodorizing properties were excellent, but the soft properties were poor.
이러한, 본 발명의 복합섬유는 바인더 섬유로서, 에어스루본딩(air through bonding) 부직포, 에어레이드(air-laid) 부직포, 써멀본딩(thermal bonding) 부직포, 스펀레이스(spunlace) 부직포 또는 레이트(wet laid) 부직포를 제조할 수 있으며, 이를 이용한 다양한 항균성 있는 고기능성 응용제품을 제조할 수 있다. These composite fibers of the present invention are binder fibers, such as air through bonding nonwoven fabric, air-laid nonwoven fabric, thermal bonding nonwoven fabric, spunlace nonwoven fabric, or rate ( Wet laid non-woven fabric can be manufactured, and various antibacterial and high-functional application products can be manufactured using it.
Claims (8)
상기 시스부는 무기미립자 및 고분자 수지를 포함하며,
상기 무기미립자는 산화아연 92 ~ 97 중량% 및 산화게르마늄 3 ~ 8 중량%를 포함하는 것을 특징으로 하는 항균성 및 소프트성이 우수한 열접착형 복합섬유.
A sheath-core composite fiber comprising a sheath portion and a core portion,
The sheath portion contains inorganic particles and polymer resin,
The inorganic fine particles are heat-bonded composite fibers with excellent antibacterial properties and softness, characterized in that they contain 92 to 97% by weight of zinc oxide and 3 to 8% by weight of germanium oxide.
The heat-bonded composite fiber with excellent antibacterial properties and softness according to claim 1, wherein the inorganic fine particles have an average particle diameter of 10 ㎛ or less.
상기 고분자 수지는 선형 폴리에틸렌(polyethylene), 선형 저밀도 폴리에틸렌(linear low density polyethylene), 고밀도 폴리에틸렌(high density polyethylene) 및 저밀도 폴리에틸렌(low density polyethylene) 중에서 선택된 1종 이상을 포함하는 것을 특징으로 하는 항균성 및 소프트성이 우수한 열접착형 복합섬유.
The method of claim 1, wherein the sheath portion includes 0.4 to 2.0% by weight of the inorganic fine particles and a remaining amount of polymer resin,
The polymer resin is antibacterial and soft, characterized in that it contains at least one selected from linear polyethylene, linear low density polyethylene, high density polyethylene, and low density polyethylene. Heat-sealable composite fiber with excellent properties.
The method of claim 1, wherein the core portion is made of polyester resin containing at least one selected from poly(ethylene terephthalate) and poly(butylene terephthalate), or polypropylene. A heat-sealable composite fiber with excellent antibacterial properties and softness, characterized by containing (polypropylene) resin.
The heat-bonded composite fiber according to any one selected from claims 1 to 4, wherein the sheath-core composite fiber has a fineness of 0.8 to 20 de and a fiber length of 20 to 70 mm. .
상기 미연신 서브토우를 연신시키는 2단계;
연신된 토우에 유제 부여 및 권축(crimping)시키는 3단계;
권축된 토우를 열고정 및 절단하는 4단계;를 포함하는 공정을 수행하며,
상기 시스부용 칩은 산화아연 및 산화게르마늄을 포함하는 무기미립자를 포함하는 것을 특징으로 하는 항균성 및 소프트성이 우수한 열접착형 복합섬유.
A first step of manufacturing a sheath-core type unstretched subtow by melting each of the chips for the sheath portion and the chip for the core portion and then composite spinning each of the melted resins through a composite spinneret;
Step 2 of stretching the unstretched subtow;
3 steps of applying emulsion and crimping to the stretched tow;
Performing a process including 4 steps of heat fixing and cutting the crimped tow,
The chip for the sheath is a heat-bonded composite fiber with excellent antibacterial properties and softness, characterized in that it contains inorganic fine particles containing zinc oxide and germanium oxide.
A nonwoven fabric comprising the thermally bonded composite fiber of claim 5.
상기 부직포는 기저귀용 탑시트(top sheet), 기저귀용 백시트(back sheet), 생리대용 시트, 공기청정기용 필터, 수처리용 필터, 청소기용 필터, 마스크용 필터, 물티슈로 사용되는 것을 특징으로 하는 부직포 제품.
Including the non-woven fabric of paragraph 7,
The nonwoven fabric is characterized in that it is used as a top sheet for diapers, a back sheet for diapers, a sheet for sanitary napkins, a filter for an air purifier, a filter for water treatment, a filter for a vacuum cleaner, a filter for a mask, and wet tissues. product.
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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US4129675A (en) | 1977-12-14 | 1978-12-12 | E. I. Du Pont De Nemours And Company | Product comprising blend of hollow polyester fiber and crimped polyester binder fiber |
KR102061805B1 (en) | 2018-06-27 | 2020-01-03 | 도레이첨단소재 주식회사 | Thermal adhesive polyester composition, thermal adhesive polyester complex-fiber comprising the same, and non-woven fabric |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4129675A (en) | 1977-12-14 | 1978-12-12 | E. I. Du Pont De Nemours And Company | Product comprising blend of hollow polyester fiber and crimped polyester binder fiber |
KR102061805B1 (en) | 2018-06-27 | 2020-01-03 | 도레이첨단소재 주식회사 | Thermal adhesive polyester composition, thermal adhesive polyester complex-fiber comprising the same, and non-woven fabric |
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