KR20240002368A - Method of manufacturing pure hydrogen ion water using a circulator - Google Patents

Method of manufacturing pure hydrogen ion water using a circulator Download PDF

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KR20240002368A
KR20240002368A KR1020220079480A KR20220079480A KR20240002368A KR 20240002368 A KR20240002368 A KR 20240002368A KR 1020220079480 A KR1020220079480 A KR 1020220079480A KR 20220079480 A KR20220079480 A KR 20220079480A KR 20240002368 A KR20240002368 A KR 20240002368A
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hydrogen ion
ion water
water
pure hydrogen
circulator
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Korean (ko)
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이해창
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이해창
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C02F2001/46185Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only anodic or acidic water, e.g. for oxidizing or sterilizing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/46115Electrolytic cell with membranes or diaphragms
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/4612Controlling or monitoring

Abstract

본 발명은 유격막 이온수기에서 생성된 불순물이 포함된 수소이온수를 순환기를 이용 불순물을 제거하는 순수 수소이온수 생성에 관한 것으로서, 구체적으로는 이온수기에서 생성된 수소이온과 불순물이 함 유된 원수를 순환펌프를 포함하는 순환기를 이용하여 음용이 가능하고 인체에 유익한 순수 수소이온수를 만드는 순수 수소이온수 생성에 관한 것이다.
본 발명의 전체적인 구성은 정수한 물을 전기 분해하는 이온수생성 공정과; 이온수에 함유 되어 있는 차아염소산 및 기타 불순물을 순환기가 포함된 순환 탱크에서 제거하여 순수 수소이온수를 만드는 불순물 제거하는 공정; 생산된 순수 수소이온수를 저장하는 저수통으로 구성된 것이다.
The present invention relates to the generation of pure hydrogen ion water by removing impurities from hydrogen ion water containing impurities generated in a diaphragm membrane ionizer using a circulator. Specifically, the raw water containing hydrogen ions and impurities generated in the ion water ionizer is removed using a circulation pump. It is about the creation of pure hydrogen ion water using a circulator that contains pure hydrogen ion water that is drinkable and beneficial to the human body.
The overall configuration of the present invention includes an ion water generation process of electrolyzing purified water; A process of removing hypochlorous acid and other impurities contained in ionized water in a circulation tank containing a circulator to create pure hydrogen ionized water; It consists of a reservoir that stores the produced pure hydrogen ion water.

Description

순환기를 이용한 순수수소이온수 제조방법{Method of manufacturing pure hydrogen ion water using a circulator}Method of manufacturing pure hydrogen ion water using a circulator}

정수된 물을 전해질과 전기로 차아염소산 등 불순물이 함유된 수소이온수를 만들고 이를 음용 및 인체 사용이 가능 하도록 하기 위해 불순물을 제거하여야 한다. Hydrogen ion water containing impurities such as hypochlorous acid is created from purified water using electrolytes and electricity, and impurities must be removed to make it drinkable and usable by the human body.

본 발명은 순환기를 포함하는 탱크를 이용하여 수소이온수의 불순물을 제거 순수 수소이온수를 제조하는 방법에 관한 것으로, 더욱 상세하게는 활성산소 제거 및 항염증 건강음료, 피부 미백/보습/수렴 화장품 원료, 여드름 건선 등 피부병 개선 화장품, 숙취해소 음료 등의 원료물질인 수소이온 농도 0.01~500ppm 사이의 순수 수소이온수 생산 기술에 관한 것이다.The present invention relates to a method of removing impurities in hydrogen ion water using a tank including a circulator and producing pure hydrogen ion water. More specifically, it relates to active oxygen removal and anti-inflammatory health drinks, skin whitening/moisturizing/astringent cosmetic ingredients, It is about technology for producing pure hydrogen ion water with a hydrogen ion concentration between 0.01 and 500 ppm, which is a raw material for cosmetics that improve skin diseases such as acne and psoriasis and hangover relief drinks.

근래에 건강하고 아름다운 삶에 대한 욕구와 관심이 증대하면서 수소에 대한 연구와 관련제품 개발이 여러 방면에서 이어지고 있다.In recent years, as desire and interest in a healthy and beautiful life have increased, research on hydrogen and development of related products are continuing in various fields.

실생활과 관련해서 수소와 수소이온은 강력한 환원력을 보유하고 있는 원소이기에 질병의 근원물질이라고 알려져 있는 활성 산소를 제거하는 용도로 널리 활용되고 있다. 물을 전기 분해하여 전해환원수를 만드는 것은 알칼리 이온수기가 일반적이며, 수소를 고온,고압의 플라즈마 상태에서 칼슘 등의 미네랄에 흡착 시킨 분말제품, 마그네슘 등의 금속과 물과의 화학반응을 이용하여 수소를 생성하는 스틱 제품, 용존 수소 농도를 높인 고농도 수소수 음료 등 다 양한 형태로 출시되고 있다.In relation to real life, hydrogen and hydrogen ions are elements with strong reducing power, so they are widely used to remove oxygen radicals, which are known to be the source of disease. It is common to use alkaline water ionizers to create electrolytic reduced water by electrolyzing water. It is a powder product that absorbs hydrogen into minerals such as calcium in a high-temperature, high-pressure plasma state, and uses a chemical reaction between metals such as magnesium and water to produce hydrogen. It is being released in various forms, such as stick products and high-concentration hydrogen water drinks with increased dissolved hydrogen concentration.

수소의 환원력을 인체의 건강과 관련해서 적용한 상기의 상품과 기술들은 제품의 가격이 매우 높거나 용존 수소 포함 여부가 불분명한 사례가 많고 대중의 편의성에 기반한 다루기 쉬우 면서도 우수한 제품을 찾아보기가 어렵다.The above products and technologies that apply the reducing power of hydrogen in relation to human health often have very high product prices or are unclear as to whether they contain dissolved hydrogen, and it is difficult to find excellent products that are easy to handle and based on public convenience.

한편, 용존 수소를 다량으로 함유한 수소수가 강력한 환원작용으로 암을 비롯한 여러 질병에 효과가 있다는 연구발표가 많아지면서 수소환원수를 만들어 내는 제품들이 등장하고 있는 데, 이는 생체의 신진대사 과정에서 발생하는 활성산소를 제거하는 활성수소가 포함되어 있기 때문이며 활성수소는 인체 내에서 유해한 활성산소와 결합하여 안전한 물로 변환하여 배출시키므로 세포의 산화를 방지하고 각종 난치 병의 치료와 노화예방에 도움을 주기 때문이다.Meanwhile, as research reports that hydrogen water, which contains a large amount of dissolved hydrogen, is effective in treating cancer and other diseases through its strong reducing effect, products that produce hydrogen reduced water are appearing. This is because it contains active hydrogen that removes active oxygen. Active hydrogen combines with harmful active oxygen in the human body and converts it into safe water to be discharged, preventing oxidation of cells and helping to treat various incurable diseases and prevent aging. .

한편 수소분자는 기체의 형태이므로 시중에서 판매되는 대부분의 수소음료는 수소기체를 고압으로 강제로 물에 녹여 유통하므로 수소분자의 작은 사이즈와 강한 압력으로 인해 유통 중 많은 수소가 없어지거나 제품을 오픈시 기화하여 용존수소가 많이 감소하므로 효과를 기대하기 어렵다. Meanwhile, since hydrogen molecules are in the form of a gas, most hydrogen drinks sold on the market are distributed by forcibly dissolving hydrogen gas in water at high pressure. Due to the small size and strong pressure of the hydrogen molecules, a lot of hydrogen is lost during distribution or when the product is opened. It is difficult to expect any effect because dissolved hydrogen is greatly reduced due to vaporization.

이러한 수소수의 유통의 단점을 보완하여 유통 및 보관에 문제점이 적고 수소이온의 살균 및 항염증 기능을 더한 수소이온수 제조 방법에 관한 기술연구가 진행중에 있다. Technical research is in progress on a method for producing hydrogen ion water that complements these shortcomings in the distribution of hydrogen water, has fewer problems with distribution and storage, and adds sterilization and anti-inflammatory functions of hydrogen ions.

본 발명은 상기와 같은 문제점을 해결하기 위해 안출 된 것으로서, 그 목적은 물을 촉매를 사용 유격막 전해 이온화 하여 생산된 불순물이 함유된 수소이온수 원수를 순환기를 포함하는 탱크를 이용한 후처리 공정으로 불순물을 제거한 순수 수소이온수를 만드는데 있다. The present invention was developed to solve the above problems, and its purpose is to remove impurities from raw hydrogen ion water containing impurities produced by diaphragm membrane electrolytic ionization using a catalyst through a post-treatment process using a tank containing a circulator. The purpose is to make pure hydrogen ion water with the removal of .

상기의 목적을 달성하기 위한 본 발명의 특징에 따르면, 정수 된 물을 유격막 전해조를 포함하는 전해 이온수기를 사용해서 불순물이 함유된 고농도의 수소이온수를 생성하고 순환기를 이용한 순환 공정을 통해 수소이온수에 포함된 불순물을 제거하여 순수 수소이온수를 제공한다. According to the features of the present invention for achieving the above object, high-concentration hydrogen ion water containing impurities is generated using purified water using an electrolytic ionizer including a diaphragm membrane electrolyzer, and the hydrogen ion water is converted to hydrogen ion water through a circulation process using a circulator. It provides pure hydrogen ion water by removing impurities.

한편 사용용도에 적합 하도록 수소이온의 농도를 0.01~500ppm 사이에서 조정할 수 있으며 또한 처리 중 직접 또는 간접 측정을 통한 차아염소산 등 불순물 농도를 측정하여 불순물이 없어질 때까지 물을 순환시켜 불순물을 제거하는 순환펌프를 포함하는 순환기를 이용 순수 수소이온수를 생성한다. Meanwhile, the concentration of hydrogen ions can be adjusted between 0.01 and 500 ppm to suit the intended use. In addition, the concentration of impurities such as hypochlorous acid is measured through direct or indirect measurement during treatment, and the impurities are removed by circulating water until the impurities disappear. Pure hydrogen ion water is generated using a circulator including a circulation pump.

본 발명에 의한 순수 수소이온수는 물을 전해 이온화 하여 수소이온의 농도를 높인 물질로 뛰어난 반응성으로 체내 활성산소 제거, 멜라닌 색소 분해에 의한 피부미백, 수렴작용, 살균작용에 의한 여드름 및 피부병의 치료와 개선, 숙취해소 등에 효과를 기대할 수 있다. The pure hydrogen ion water according to the present invention is a substance that increases the concentration of hydrogen ions by electrolytically ionizing water. It has excellent reactivity and is used to remove active oxygen in the body, whiten skin by decomposing melanin pigment, and treat acne and skin diseases through astringent and sterilizing effects. You can expect effects such as improvement, hangover relief, etc.

또한, 수소이온수의 여러 효능에 대한 과학적 근거 자료를 확립하였으며, 각종 논문을 통한 수소 및 수소이온수의 우수성을 확인할 수 있으며, 추가적인 연구를 통해 국제적 홍보 및 학술 논문 발표와 이를 통한 수소이온수 제품 생산과 세계적인 판매를 기대할 수 있다.In addition, scientific basis data for the various effects of hydrogen ion water have been established, and the excellence of hydrogen and hydrogen ion water can be confirmed through various papers. Through additional research, international promotion and academic paper presentations have been conducted, and through this, the production of hydrogen ion water products and world-class Sales can be expected.

도 1은 본 발명에 따른 수소이온수 원수 제조 공정을 도식한 흐름도
도 2는 순환기를 이용한 순수 수소이온수내 불순물 제거 공정 흐름도
도 3은 순환기를 포함하는 순수 수소이온수 생산기 평면도
도 4는 순환기를 포함하는 순수수소이온수 생산 탱크 실제 운용 사진 이미지
도 5는 순환기를 포함하는 순수수소이온수 생산 탱크 병렬 연결 실제 운용 사진 이미지
Figure 1 is a flow chart schematically illustrating the process for producing raw hydrogen ion water according to the present invention.
Figure 2 is a flow chart of the process for removing impurities in pure hydrogen ion water using a circulator.
Figure 3 is a plan view of a pure hydrogen ion water producer including a circulator.
Figure 4 is a photographic image of the actual operation of a pure hydrogen ion water production tank including a circulator.
Figure 5 is a photo image of the actual operation of a parallel connection of a pure hydrogen ion water production tank including a circulator.

인간의 많은 질병과 노화의 주요 원인이 활성산소인 것은 많은 연구를 통해서 밝혀지면서 이들 활성산소를 제거하는 것이 각종 질병의 예방과, 노화지연, 피부미용, 숙취해소 등에 효과적이다. 항산화 물질인 수소이온수는 연속적인 산화과정에 의해 생성되는 활성산소를 제거를 통해서 건강하고 아름다운 삶을 영위할 수 있다.As it has been revealed through many studies that the main cause of many human diseases and aging is free radicals, removing these free radicals is effective in preventing various diseases, delaying aging, skin care, and relieving hangovers. Hydrogen ion water, an antioxidant, helps you live a healthy and beautiful life by removing free radicals generated by continuous oxidation processes.

본 발명에서는 아래의 화학식과 같이 OH-, H2O2와 같은 대표적인 활성산소류를 제거하는데 탁월한 수소이온수를 유효성분으로 포함하는 기능성 순수 수소이온수를 제조하는 방법을 제시하였다. The present invention presents a method for producing functional pure hydrogen ion water containing hydrogen ion water as an active ingredient, which is excellent for removing representative active oxygen species such as OH - and H 2 O 2 as shown in the formula below.

OH- + H+ = H2OOH - + H + = H 2 O

H2O2 + 2H+ + 2e-(자유전자) = 2H2OH 2 O 2 + 2H + + 2e-(free electron) = 2H 2 O

순수 수소이온수는 복잡하지 않은 단분자 조성물로 생산 단가가 낮아 다른 기능성 제품과 차별화 될 수 있다.Pure hydrogen ion water is an uncomplicated single molecule composition that can be differentiated from other functional products with low production costs.

수소이온수 제조 Hydrogen ion water production

먼저, 본 발명에 따른 수소이온수 제조 공정을 첨부된 도 1을 참조하여 살펴보면, 수도물이나 지하수를 정수기를 통해 불순물을 제거하여 유격막 전해이온수기에 공급하고, 전해이온수 전용 촉매인 전해질을 전해이온수기의 전해조에 투입하여 원하는 농도의 수소이온수가 생산 될 때까지 순환 가동 후 원하는 수소이온 농도에 도달하면 생산된 수소이온원수를 탱크에 보관한다. First, looking at the hydrogen ion water production process according to the present invention with reference to the attached FIG. 1, impurities are removed from tap water or groundwater through a water purifier and supplied to the diaphragm electrolytic water ionizer, and the electrolyte, which is a catalyst exclusively for electrolytic ion water, is added to the electrolyzer of the electrolytic ion water machine. It is operated in circulation until hydrogen ion water of the desired concentration is produced. When the desired hydrogen ion concentration is reached, the produced hydrogen ion water is stored in the tank.

이때 투입되는 전기량과 가동시간, 촉매의 농도를 달리하여 0.01~500ppm의 수소이온수를 만들 수 있다.At this time, hydrogen ion water of 0.01 to 500 ppm can be produced by varying the amount of electricity input, operating time, and catalyst concentration.

본 발명에 있어서, "수소이온수"란 물을 전해 이온화 하여 정제수내의 수소이온(H+)이온 농도를 높이는 방식이며 많아진 수소이온은 물과 결합하여 옥소늄 이온(H3O+) 형태로 물속에 존재 한다. 옥소늄 이온은 일반적인 중성의 물에도 존재하는 물질로, 전기 에너지와 전해질을 이용하여 그 농도를 높여 본 발명에서 원하는 효과를 나타낼 수 있다. In the present invention, "hydrogen ion water" is a method of increasing the hydrogen ion (H + ) ion concentration in purified water by electrolytically ionizing water. The increased hydrogen ions combine with water and form oxonium ions (H 3 O + ) in the water. exist. Oxonium ion is a substance that exists in general neutral water, and its concentration can be increased using electrical energy and electrolyte to achieve the desired effect in the present invention.

최초 생산된 원수에는 차아염소산(HOCl)이 높은 농도로 함유되어 있어 수소이온수로소 역할을 할 수가 없다.The initially produced raw water contains a high concentration of hypochlorous acid (HOCl), so it cannot function as hydrogen ion water.

따라서 생산된 수소이온수 원수의 차아염소산을 완전히 제거하여 순수 수소이온수로 만들어야 한다.Therefore, the hypochlorous acid in the produced hydrogen ion water must be completely removed to make it pure hydrogen ion water.

이하에서는, 본 발명을 한정하지 않는 실시예에 따라 본 발명을 상세히 설명한다. 본 발명의 하기 실시예는 본 발명을 구체화하기 위한 것일 뿐 본 발명의 권리범위를 제한하거나 한정하는 것이 아님은 물론이다. 따라서, 본 발명의 상세한 설명 및 실시예로부터 본 발명이 속하는 기술분야의 전문가가 용이하게 유추할 수 있는 것은 본 발명의 권리범위에 속하는 것으로 해석된다.Below, the present invention will be described in detail according to examples that do not limit the present invention. Of course, the following examples of the present invention are only intended to embody the present invention and do not limit or limit the scope of the present invention. Accordingly, what can be easily inferred by an expert in the technical field to which the present invention belongs from the detailed description and examples of the present invention is interpreted to fall within the scope of the rights of the present invention.

순환기를 이용한 순수 수소이온수 생산Production of pure hydrogen ion water using a circulator

상기에서 이온수기를 통해 만들어진 수소이온수 원수는 차아염소산수가 수십~수백ppm이 용존 되어 있어 음용은 물론The raw hydrogen ion water produced through the water ionizer above has tens to hundreds of ppm of hypochlorous acid dissolved in it, making it suitable for drinking.

인체 사용은 어려움이 있다. Use on the human body is difficult.

따라서 본발명을 도3을 참조하여 상세하게 설명하면 불순물이 포함된 수소이온수원수 공급관을 통해 원수를 공급하고 Therefore, if the present invention is described in detail with reference to Figure 3, raw water is supplied through a hydrogen ion water raw water supply pipe containing impurities,

순환펌프를 포함하는 순환기를 이용하여 수소수원수를 계속 순환시켜 낙차에 의한 마찰로 용존 차아염소산수를 By continuously circulating the hydrogen water source using a circulator including a circulation pump, dissolved hypochlorous acid water is

수소이온수와 분리시키며 불순 가스가 재결합하지 못하도록 불순가스 배출관을 통해 강제로 외부로 배출한다.It is separated from hydrogen ion water and forcibly discharged to the outside through the impurity gas discharge pipe to prevent impurity gases from recombining.

이때 수소이온수 탱크 상부에 차아염소산 자동 측정기를 연결하고 탱크내의 차아염소산이 불검출되면 순수 수소이온수로 At this time, connect an automatic hypochlorous acid meter to the top of the hydrogen ion water tank, and if hypochlorous acid is not detected in the tank, pure hydrogen ion water is used.

볼 수 있어 자동으로 순환기의 가동이 멈추도록 설비한다. 또한 사용 목적에 따라 잔존 차아염소산 농도를 조절할 수 있다 It is installed so that it can be seen and the operation of the circulator is automatically stopped. Additionally, the concentration of remaining hypochlorous acid can be adjusted depending on the purpose of use.

본 발명에 의한 순환기라 함은 일반펌프 또는 워터펌프와 자동 개폐기와 원격조정기 등을 포함하는 기계장치로 탱크의 크기The circulator according to the present invention is a mechanical device including a general pump or water pump, an automatic open/closer, and a remote controller, depending on the size of the tank.

모양 등에 따라 펌프의 용량, 연결방법 등은 달라질 수 있다 The pump capacity, connection method, etc. may vary depending on the shape, etc.

한편 1톤의 수소이온수원수를 순수 수소이온수로 만들기 위해서는 차아염소산의 농도, 주변환경 등의 차이에 의해 많은 Meanwhile, in order to make 1 ton of hydrogen ion water source water into pure hydrogen ion water, many steps are required due to differences in hypochlorous acid concentration, surrounding environment, etc.

차이가 있으나 일반적으로는 2~4일 정도의 시간이 소요되므로 도4의 순환기 사진과 같은 순환기 설비를 다수 만들어 도 2의 Although there are differences, it generally takes about 2 to 4 days, so a number of circulatory facilities such as the circulatory system photo in Figure 4 are made and the circulatory system in Figure 2 is made.

모식도와 도5의 사진과 같이 병렬 연결하여 생산원수를 분산 처리함으로 수소이온수 생산 효율을 높일 수 있다 The production efficiency of hydrogen ion water can be increased by dispersing the production water by connecting it in parallel as shown in the schematic diagram and the photo in Figure 5.

순환기를 포함한 순수 수소이온수 생산 탱크의 상세한 설치예는 도 3의 사진을 참조한다.For a detailed installation example of a pure hydrogen ion water production tank including a circulator, refer to the photo in FIG. 3.

Claims (3)

유격막 전기분해장치를 통해 생성된 불순물이 포함된 수소이온수를 순수 수소이온수로 만드는 방법에 있어서, 순환 펌프를 포함하는 순환기를 이용 원수를 순환시켜 불순물 제거하여 순수 수소이온수 생성방법In the method of converting hydrogen ion water containing impurities generated through a diaphragm electrolysis device into pure hydrogen ion water, a method of generating pure hydrogen ion water by circulating raw water using a circulator including a circulation pump to remove impurities 제 1항에 있어서 차아염소산 및 기타 불순물을 강제 순환, 공기중에 휘산시켜 배출하는 시스템을 포함하는 순수 수소이온수 제조 방법The method of producing pure hydrogen ion water according to claim 1, which includes a system for discharging hypochlorous acid and other impurities by forcing them to circulate and volatilize them into the air. 제1항 있어서 불순물 농도를 자동 측정하여 미리 설정한 범위 값에 따라 자동 운전 되는 순수 수소이온수 제조방법The method of producing pure hydrogen ion water according to claim 1, which automatically measures impurity concentration and operates automatically according to a preset range value.
KR1020220079480A 2022-06-29 2022-06-29 Method of manufacturing pure hydrogen ion water using a circulator KR20240002368A (en)

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