KR20230076265A - High Thermal Storage Cementitious Mortar Adhesive for Masonry Stacking with Micro-capsulation Phase Change Material - Google Patents
High Thermal Storage Cementitious Mortar Adhesive for Masonry Stacking with Micro-capsulation Phase Change Material Download PDFInfo
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- 239000012782 phase change material Substances 0.000 title claims abstract description 66
- 239000004570 mortar (masonry) Substances 0.000 title claims abstract description 50
- 239000000853 adhesive Substances 0.000 title claims abstract description 48
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 48
- 238000005338 heat storage Methods 0.000 claims abstract description 28
- 239000000203 mixture Substances 0.000 claims abstract description 26
- 239000011449 brick Substances 0.000 claims abstract description 18
- 239000002086 nanomaterial Substances 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims abstract description 14
- 239000011230 binding agent Substances 0.000 claims description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 19
- 239000002041 carbon nanotube Substances 0.000 claims description 16
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 15
- 239000006185 dispersion Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000004568 cement Substances 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 9
- 239000003094 microcapsule Substances 0.000 claims description 8
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 claims description 8
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 claims description 6
- YCOZIPAWZNQLMR-UHFFFAOYSA-N pentadecane Chemical compound CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 claims description 6
- IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical compound CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 238000010276 construction Methods 0.000 claims description 4
- 238000007580 dry-mixing Methods 0.000 claims description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 3
- 229940038384 octadecane Drugs 0.000 claims description 3
- 239000002798 polar solvent Substances 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 238000005265 energy consumption Methods 0.000 abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 230000008569 process Effects 0.000 description 7
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- -1 polypropylene Polymers 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000012783 reinforcing fiber Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 2
- 238000009435 building construction Methods 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229920001795 coordination polymer Polymers 0.000 description 2
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- 238000009472 formulation Methods 0.000 description 2
- 239000005431 greenhouse gas Substances 0.000 description 2
- 239000002114 nanocomposite Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 229910021487 silica fume Inorganic materials 0.000 description 2
- 239000008030 superplasticizer Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000012753 anti-shrinkage agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910021387 carbon allotrope Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000003823 mortar mixing Methods 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000002135 phase contrast microscopy Methods 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
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- 238000011160 research Methods 0.000 description 1
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- 238000012360 testing method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000001132 ultrasonic dispersion Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/022—Carbon
- C04B14/026—Carbon of particular shape, e.g. nanotubes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
- C04B2103/0071—Phase-change materials, e.g. latent heat storage materials used in concrete compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/30—Water reducers, plasticisers, air-entrainers, flow improvers
- C04B2103/34—Flow improvers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
Abstract
본 발명은 마이크로캡슐화시킨 상변화물질, 및 전도성 나노소재를 포함하는 조적벽돌 쌓기용 고축열 PCM 시멘트질 모르타르 접착제 조성물 및 이의 제조방법에 관한 것으로서, 본 발명에 따르면 마이크로캡슐화시킨 PCM 물질과 CNT를 활용한 모르타르 접착제는 상변화 물질의 축열 및 발열 성능을 통해 구조 내부의 온도차를 줄임으로써 구조 에너지 효율을 최대화할 수 있으며 또한 구조 에너지 소비를 최소화할 수 있다.The present invention relates to a high heat storage PCM cementitious mortar adhesive composition for masonry brick building containing a microencapsulated phase change material and a conductive nanomaterial and a manufacturing method thereof. The mortar adhesive can maximize structural energy efficiency and minimize structural energy consumption by reducing the temperature difference inside the structure through the heat storage and exothermic performance of the phase change material.
Description
본 발명은 마이크로캡슐화된 상변화물질 적용 조적벽돌 쌓기용 고축열 시멘트질 모르타르 접착제 및 이의 제조방법에 관한 것으로, 보다 상세하게는 강도 및 내구성이 우수하고 축열 및 발열 성능을 향상시킬 수 있는 마이크로캡슐화된 상변화물질 적용 조적벽돌 쌓기용 고축열 시멘트질 모르타르 접착제 및 이의 제조방법에 관한 것이다. The present invention relates to a high heat storage cementitious mortar adhesive for masonry brickwork using a microencapsulated phase change material and a manufacturing method thereof, and more particularly, to a microencapsulated phase having excellent strength and durability and capable of improving heat storage and exothermic performance. It relates to a high heat storage cementitious mortar adhesive for building masonry bricks applied with a changeable material and a manufacturing method thereof.
현대 주거 및 상업용 건물은 경량화 되고 있으며 사람들은 열저장 잠재력 실내 열 쾌적성에 대한 우려를 제기했다. 환경에 미치는 영향이 적은 보다 효율적인 구조를 만드는 구동력과 더 많은 품질을 증가시켜 축열을 진행하는 추세 사이에 강한 장력이 있다. 이러한 문제들은 더욱 전 세계의 기후 변화와 에너지 비용의 지속적인 상승의 영향을 받는다. Modern residential and commercial buildings are becoming lightweight and people have raised concerns about their heat storage potential and indoor thermal comfort. There is a strong tension between the driving force to create more efficient structures with less environmental impact and the trend toward more quality incremental heat storage. These issues are further affected by global climate change and the continued rise in energy costs.
상변화물질(Phase Change Materail, PCM)의 건축에서의 사용은 1940년대 중반부터 시작되었으며, 이러한 축열 능력을 갖춘 수동 태양열 시스템은 당시 연구의 응용 중 하나이다. 건축 시공에 PCM을 적용하면 외부 태양광에서 나오는 열과 기계 가열 및 냉각 시스템에서 발생하는 열 부하를 이용할 수 있다. 그 다음에는 이러한 에너지를 효과적으로 저장하여 적절한 시간에 건축물의 에너지 수요를 충분히 맞출 수 있도록 해야 한다. The use of Phase Change Material (PCM) in construction began in the mid-1940s, and a passive solar system with such heat storage capability was one of the applications of research at that time. The application of PCM in building construction can take advantage of heat from external sunlight and heat loads from mechanical heating and cooling systems. This energy must then be effectively stored so that the building's energy demand can be fully met at the right time.
수십 년 동안 건축 공사에 PCM이 물에 잠긴 벽돌이나 기타 건축자재를 사용해 열 관성을 높이고 이와 관련 없는 중품질의 구조에 응용해 왔다. 그러나 블록 재료에 PCM을 넣는 것은 복잡한 기술 과정이다. 일부 문제점에는 용해 및 냉동 과정의 체적 변화, 무기질 PCM 제품의 열 전달속도 지연, PCM 누출 문제, PCM 탑재체 재료의 물리적 성능에 대한 악영향이 포함된다.For decades, PCMs have been used in building construction to increase thermal inertia using waterlogged bricks and other building materials, and have been applied to medium-quality structures that are not related to this. However, incorporating PCM into block materials is a complex technological process. Some of the problems include volume changes during melting and freezing, slow heat transfer rates in inorganic PCM products, PCM leakage problems, and adverse effects on the physical performance of PCM payload materials.
따라서 PCM을 조적벽돌 쌓기용 고축열 시멘트질 모르타르 접착제 등의 건축 자재로 사용함에 따른 축열 성능을 유지할 수 있는 기술의 개발이 필요한 실정이다.Therefore, it is necessary to develop a technology capable of maintaining heat storage performance as PCM is used as a building material such as a high heat storage cementitious mortar adhesive for building masonry bricks.
한국 등록특허 10-2098039에서는 결합재, 규사, 보강재, 폴리머, 수축방지제, 실리카 흄, 클링커, 플라스터, 플라스틱 복합체, 재생 폴리프로필렌 수지, 하소포졸라나, 마이크로실리카, 소포제, 팽창제, 경화촉진제, 유동화제 및 증점제를 미리 설정된 중량 비율로 형성하는 것을 특징으로 하며, 상기 폴리머는 친환경 PLA 수지와 아크릴계 재유화 수지의 혼합물을 사용하는 것을 특징으로 하고, 상기 플라스틱 복합체는 보강섬유, PCM캡슐 파우더, 유기금속 폴리머 및 CNT나노 복합재로 이루어지되, 상기 보강섬유는 폴리프로필렌 섬유 20 내지 50 중량비율, 나일론 섬유 20 내지 50 중량비율 및 아르보셀 섬유 30 내지 60 중량비율로 포함하여 이루어진 것을 사용하는 것을 특징으로 하고, 상기 플라스틱 복합체는 보강섬유 90 내지 100 중량부를 기준으로 PCM캡슐 파우더 20 내지 30 중량부, 유기금속 폴리머 10 내지 20 중량부 및 CNT 나노 복합재 5 내지 7 중량부로 이루어진 것을 사용하여 복합 플라스틱 레진을 형성하여 사용하는 것을 특징으로 하는 수중 콘크리트 구조물 보수 보강용 친환경 모르타르 조성물을 제시하였다.Korean Registered Patent No. 10-2098039 discloses a binder, silica sand, reinforcing material, polymer, anti-shrinkage agent, silica fume, clinker, plaster, plastic composite, recycled polypropylene resin, calcined polypropylene resin, calcined polypropylene resin, microsilica, antifoaming agent, expanding agent, curing accelerator, glidant and It is characterized in that the thickener is formed in a preset weight ratio, and the polymer is characterized in that a mixture of an environmentally friendly PLA resin and an acrylic re-emulsification resin is used, and the plastic composite is a reinforcing fiber, PCM capsule powder, organometallic polymer and It is made of CNT nanocomposite, and the reinforcing fibers are characterized by using polypropylene fibers in a weight ratio of 20 to 50, nylon fibers in a weight ratio of 20 to 50, and arbocel fibers in a weight ratio of 30 to 60. The composite is composed of 20 to 30 parts by weight of PCM capsule powder, 10 to 20 parts by weight of organometallic polymer, and 5 to 7 parts by weight of CNT nanocomposite based on 90 to 100 parts by weight of reinforcing fibers to form and use a composite plastic resin. An eco-friendly mortar composition for repair and reinforcement of underwater concrete structures is proposed.
한국공개특허 2018-0043102에서는 교량에 수직하게 삽입 형성되어 교량을 보강하기 위한 보강부; 상기 보강부의 노출면에 평행하게 도포되기 위한 도포부; 및 상기 도포부에 도포되어 교량을 방수하기 위한 방수부를 포함하는 교량 탄성 도막 방수 시공 구조를 제시하였으며, 상기 도포부로서 물 100중량부에 대하여, 시멘트 60~80중량부, 아크릴계 공중합체 수지 20~50중량부, 실리카 에어로젤 0.5~3중량부, 폴리에테르에테르케톤 공중합체 수지 1~10중량부, 평균직경 50~100nm와 평균길이 1~30㎛를 갖는 탄소나노튜브 0.1~5중량부, 분산제 0.5~3중량부 및 소포제 0.3~1중량부를 포함하는 조성을 제시하였다.In Korean Patent Publication No. 2018-0043102, a reinforcing part formed by inserting vertically into a bridge to reinforce the bridge; an application unit for applying parallel to the exposed surface of the reinforcing unit; and a bridge elastic coating film waterproofing construction structure including a waterproofing part applied to the application part to waterproof the bridge, and based on 100 parts by weight of water as the application part, 60 to 80 parts by weight of cement, 20 to 80 parts by weight of acrylic copolymer resin 50 parts by weight, 0.5 to 3 parts by weight of silica airgel, 1 to 10 parts by weight of polyether ether ketone copolymer resin, 0.1 to 5 parts by weight of carbon nanotubes having an average diameter of 50 to 100 nm and an average length of 1 to 30 μm, 0.5 parts by weight of a dispersant A composition containing ~ 3 parts by weight and 0.3 ~ 1 part by weight of an antifoaming agent was presented.
최근 탄소 배출 저감을 목적으로 국내 에너지 배출량 중 30%를 차지하는 건축 및 건설분야에서의 온실가스 저감이 필수화됨에 있어서 주거용 에너지 절감 기술개발에 대한 중요성 또한 높아지게 되었다. Recently, as the reduction of greenhouse gases in the building and construction sectors, which account for 30% of domestic energy emissions, has become essential for the purpose of reducing carbon emissions, the importance of developing residential energy saving technologies has also increased.
본 발명은 PCM을 적용한 모르타르 접착제의 강도 저하를 탄소나노튜브로 해결하고, 마이크로캡슐화시킨 PCM을 사용하여 PCM의 축열 성능을 활용한 조적벽돌 쌓기용 고축열 시멘트질 모르타르 접착제를 제공하는 데 그 목적이 있다.The purpose of the present invention is to solve the decrease in strength of PCM-applied mortar adhesive with carbon nanotubes, and to provide a high heat storage cementitious mortar adhesive for masonry brick stacking utilizing the heat storage performance of PCM by using microencapsulated PCM. .
또한, 본 발명의 다른 목적은 상기 조적벽돌 쌓기용 고축열 시멘트질 모르타르 접착제의 제조방법을 제공하는 데도 있다.In addition, another object of the present invention is to provide a method for manufacturing a high heat storage cementitious mortar adhesive for laying masonry bricks.
본 발명에 따른 조적벽돌 쌓기용 고축열 PCM 시멘트질 모르타르 접착제 조성물은 마이크로캡슐화시킨 상변화물질, 및 전도성 나노소재를 포함하는 것을 그 특징으로 한다. The high heat storage PCM cementitious mortar adhesive composition for masonry brickwork according to the present invention is characterized in that it includes a microencapsulated phase change material and a conductive nanomaterial.
본 발명의 일 실시예에 따르면, 상기 상변화물질은 트리데칸, 테트라데칸, 펜타데칸, n-헥사데칸, 옥타데칸 및 에이코산으로 이루어진 그룹으로부터 선택되는 1종 이상의 파라핀 알칸 계열의 물질이 바람직하다. According to one embodiment of the present invention, the phase change material is preferably at least one paraffin alkane-based material selected from the group consisting of tridecane, tetradecane, pentadecane, n-hexadecane, octadecane, and eicosan. .
본 발명의 일 실시예에 따르면, 상기 마이크로캡슐화시킨 상변화물질은 조성물에 포함되는 바인더 중량 대비 0.1~15%로 포함되는 것이 바람직하다. According to one embodiment of the present invention, the microencapsulated phase change material is preferably included in an amount of 0.1 to 15% based on the weight of the binder included in the composition.
본 발명의 일 실시예에 따르면, 상기 전도성 나노소재는 카본 나노 튜브가 바람직하게 이용될 수 있다. According to one embodiment of the present invention, carbon nanotubes may be preferably used as the conductive nanomaterial.
상기 전도성 나노소재는 극성 용매인 물에 분산시킨 전도성 나노소재 수분산액 형태로 포함되는 것이 바람직하다. The conductive nanomaterial is preferably included in the form of an aqueous dispersion of conductive nanomaterial dispersed in water, which is a polar solvent.
상기 전도성 나노소재 수분산액의 농도는 0.5~1중량%인 것이 바람직하다. The concentration of the conductive nanomaterial aqueous dispersion is preferably 0.5 to 1% by weight.
본 발명의 일 실시예에 따르면, 상기 전도성 나노소재는 조성물에 포함되는 바인더 중량 대비 0.01~0.1%로 포함되는 것이 바람직하다. According to an embodiment of the present invention, the conductive nanomaterial is preferably included in an amount of 0.01 to 0.1% based on the weight of the binder included in the composition.
또한, 본 발명에 따른 상기 조성물은 시멘트 바인더 40.0~45.0중량%, 잔골재 32.0~36.0중량%, 유동화재(SP) 0.1~0.3중량% 및 잔량의 물을 더 포함할 수 있다. In addition, the composition according to the present invention may further include 40.0 to 45.0% by weight of a cement binder, 32.0 to 36.0% by weight of fine aggregate, 0.1 to 0.3% by weight of a fluidizer (SP) and a balance of water.
본 발명은 상기 나열된 조성물로부터 제조된 조적벽돌 쌓기용 고축열 PCM 시멘트질 모르타르 접착제를 제공할 수 있다.The present invention can provide a high heat storage PCM cementitious mortar adhesive for masonry bricks prepared from the above-listed compositions.
또한 본 발명은 상변화물질을 마이크로캡슐로 코팅시켜 마이크로캡슐화된 상변화물질을 준비하는 단계, 1차 건비빔에서 바인더, 잔골재를 혼합하는 단계, 여기에 2차 비빔에서 물, 상기 마이크로캡슐화시킨 상변화물질, CNT 나노 분산액, 및 유동화제를 첨가하여 혼합하는 단계, 및 이를 타설하는 단계를 포함하는 조적벽돌 쌓기용 고축열 PCM 시멘트질 모르타르 접착제의 제조방법을 제공할 수 있다. In addition, the present invention provides a step of preparing a microencapsulated phase change material by coating the phase change material with microcapsules, mixing a binder and fine aggregate in the first dry mixing step, and water and the microencapsulated phase in the second mixing step. It is possible to provide a method for preparing a high heat storage PCM cementitious mortar adhesive for masonry bricks, comprising the steps of adding and mixing a modifier, a CNT nano-dispersion, and a glidant, and pouring them.
본 발명에 따르면, 마이크로캡슐화된 PCM 물질과 CNT를 활용한 모르타르 접착제는 상변화 물질의 축열 및 발열 성능을 통해 구조 내부의 온도차를 줄임으로써 구조 에너지 효율을 최대화할 수 있으며 또한 구조 에너지 소비를 최소화할 수 있으며, CNT의 혼합으로 물성 저하 문제를 해결할 수 있다. According to the present invention, the mortar adhesive using microencapsulated PCM material and CNT can maximize structural energy efficiency and minimize structural energy consumption by reducing the temperature difference inside the structure through the heat storage and exothermic performance of the phase change material. and the problem of deterioration in physical properties can be solved by mixing CNTs.
이러한 본 발명의 마이크로캡슐화된 PCM 적용 조적벽돌 쌓기용 모르타르 접착제는 2050년까지 탄소 순 배출량이 0이 되는 탄소중립정책에 맞추어 사회적 및 경제적 가치가 높다고 판단되며, 다음과 같은 효과를 기대할 수 있다.The mortar adhesive for masonry bricks using the microencapsulated PCM of the present invention is judged to have high social and economic value in line with the carbon neutral policy of zero carbon emissions by 2050, and the following effects can be expected.
(a) 건축물에서 축열 및 방열하는 조적벽돌 쌓기용 모르타르 접착제 개발(a) Development of mortar adhesive for building masonry bricks that stores and dissipates heat in buildings
(b) 고축열 특성 및 열방출 특성으로 인한 에너지 절감이 가능(b) Energy saving is possible due to high heat storage and heat dissipation characteristics
(c) 에너지 절감으로 인한 건축물이 차지하는 온실가스 저감(c) Reduction of greenhouse gas emissions from buildings due to energy savings
(d) 에너지 절감으로 인한 에너지 소비 비용 최소화로 인한 경제성 향상(d) Improving economic feasibility by minimizing energy consumption costs due to energy savings
(e) 에너지 낭비를 최소화하여 탄소 배출 및 친환경적 기술로 활용 가능(e) It can be used as a carbon emission and eco-friendly technology by minimizing energy waste
(f) PCM 모르타르 접착제의 축열 및 고 내구성 특성으로 구조의 내장재 및 외장재로 활용 가능(f) Due to the heat storage and high durability characteristics of PCM mortar adhesive, it can be used as an interior and exterior material of a structure.
(g) 마이크로캡슐 코팅 기술을 활용하여 가공한 PCM은 유실 및 누출을 방지하며 또한 직접적으로 시멘트와 접착하지 않아 강도저감을 최소화 할 수 있음(g) PCM processed using microcapsule coating technology prevents loss and leakage, and also minimizes strength reduction as it does not adhere directly to cement.
도 1은 본 발명에 따른 마이크로캡슐화된 PCM 적용 조적벽돌 쌓기용 모르타르 접착제 제조 공정을 나타낸 것이다.1 shows a process for manufacturing a mortar adhesive for building masonry bricks using microencapsulated PCM according to the present invention.
이하에서 본 발명을 더욱 상세하게 설명하면 다음과 같다.Hereinafter, the present invention will be described in more detail.
본 명세서에서 사용된 용어는 특정 실시예를 설명하기 위하여 사용되며, 본 발명을 제한하기 위한 것이 아니다.Terms used in this specification are used to describe specific embodiments and are not intended to limit the present invention.
본 명세서에서 사용된 바와 같이, 단수 형태는 문맥상 다른 경우를 분명히 지적하는 것이 아니라면, 복수의 형태를 포함할 수 있다. 또한, 본 명세서에서 사용되는 경우 "포함한다(comprise)" 및/또는 "포함하는 (comprising)"은 언급한 형상들, 숫자, 단계, 동작, 부재, 요소 및/또는 이들 그룹의 존재를 특정하는 것이며, 하나 이상의 다른 형상, 숫자, 동작, 부재, 요소 및/또는 그룹들의 존재 또는 부가를 배제하는 것이 아니다.As used herein, the singular form may include the plural form unless the context clearly indicates otherwise. Also, when used herein, "comprise" and/or "comprising" specifies the presence of the recited shapes, numbers, steps, operations, elements, elements, and/or groups thereof. and does not exclude the presence or addition of one or more other shapes, numbers, operations, elements, elements and/or groups.
본 발명은 PCM 물질을 마이크로캡슐화하여 액상 형태의 PCM 물질의 유출을 방지하고 PCM을 적용한 모르타르 접착제의 강도 저하의 단점을 해결하기 위해 모르타르 배합 시 물리적 특성이 뛰어난 탄소나노튜브(Carbon Nano Tube, CNT)를 혼입하여 모르타르 접착제의 내구성 및 강도를 향상시킨 마이크로캡슐화된 상변화물질 적용 조적벽돌 쌓기용 고축열 시멘트질 모르타르 접착제 및 이의 제조방법에 관한 것이다.The present invention microencapsulates the PCM material to prevent the leakage of the PCM material in liquid form and to solve the disadvantage of lowering the strength of the mortar adhesive to which the PCM is applied, carbon nano tubes (CNTs) with excellent physical properties when mixing mortar It relates to a high heat storage cementitious mortar adhesive for building masonry bricks applied with a microencapsulated phase change material in which durability and strength of the mortar adhesive is improved by incorporating the same, and a manufacturing method thereof.
본 발명에 따른 마이크로캡슐화된 상변화물질 적용 조적벽돌 쌓기용 고축열 시멘트질 모르타르 접착제는 바인더, 잔골재, 초가소제(유동화제), 마이크로캡슐화된 상변화물질, 및 탄소나노튜브를 포함하는 구성으로 이루어질 수 있으며, 구체적으로는 다음과 같다.The high heat storage cementitious mortar adhesive for masonry bricks applying microencapsulated phase change material according to the present invention may be composed of a binder, fine aggregate, superplasticizer (fluidizing agent), microencapsulated phase change material, and carbon nanotubes. , and specifically:
(1) 시멘트 (Cement)(1) Cement
일반 목적 1종 표준 시멘트를 사용하며, 접착제 조성에서 바인더로 사용된다.General purpose Class 1 standard cement is used and used as a binder in adhesive formulations.
상기 바인더로 사용되는 시멘트는 전체 모르타르 접착제 조성에서 40.0~45.0중량%로 포함되는 것이 내구성 및 강도 측면에서 바람직하다The cement used as the binder is preferably included in an amount of 40.0 to 45.0% by weight in the total mortar adhesive composition in terms of durability and strength.
(2) 잔골재 (2) fine aggregate
KS F 2527의 표준에 적합한 골재로서 최대 사이즈는 4mm를 초과하지 않는 것이 바람직하다. 상기 잔골재는 규사 등이 있으나, 이에 한정되지 않으며 전체 모르타르 접착제 조성에서 32.0~36.0중량%로 포함되는 것이 내구성 및 강도 측면에서 바람직하다.As an aggregate that meets the standard of KS F 2527, it is desirable that the maximum size does not exceed 4mm. The fine aggregate includes silica sand, but is not limited thereto, and is preferably included in an amount of 32.0 to 36.0% by weight in the total mortar adhesive composition in terms of durability and strength.
(3) 유동화제 (Superplasticizers, SP)(3) Superplasticizers (SP)
상기 유동화제(SP)는 모르타르 접착제를 작업 시 작업성(Workability)을 개선시키고 배합 시 물의 함량을 효과적으로 감소시켜 모르타르 접착제의 유동성을 유지하면서 재료 분리현상을 방지하기 위해 포함된다. 이러한 초가소제는 전체 모르타르 접착제 조성에서 0.1~0.3중량%로 포함되는 것이 모르타르 워커빌리티(작업성) 면에서 바람직하다. The fluidizing agent (SP) is included to improve workability when working with the mortar adhesive and to effectively reduce the water content during mixing to prevent material separation while maintaining the fluidity of the mortar adhesive. It is preferable in terms of mortar workability (workability) that these superplasticizers are included in an amount of 0.1 to 0.3% by weight in the total mortar adhesive composition.
(4) 마이크로캡슐화시킨 상변화물질 (Microcapsulated PCM)(4) Microcapsulated PCM
본 발명에서는 모르타르 접착제에 축열 성능을 부여하기 위하여 일정 온도 범위 내에서 상변화 반응이 발생하여 열에너지를 흡수 및 방출할 수 있는 유기 파라핀계 상변화물질(PCM)을 활용할 수 있다. 상변화 반응이 발생하는 온도 범위는 PCM 제조 공정에서 조정할 수 있으며, 적용 범위에 맞는 상변화 온도를 선택하여 사용한다. In the present invention, an organic paraffinic phase change material (PCM) capable of absorbing and releasing thermal energy by a phase change reaction occurring within a certain temperature range can be utilized to impart heat storage performance to the mortar adhesive. The temperature range in which the phase change reaction occurs can be adjusted in the PCM manufacturing process, and a phase change temperature suitable for the application range is selected and used.
상기 유기 파라핀계 상변화물질(PCM)은 트리데칸, 테트라데칸, 펜타데칸, n-헥사데칸, 옥타데칸 및 에이코산으로 이루어진 그룹으로부터 선택되는 1종 이상의 파라핀 알칸 계열의 물질이 바람직하다.The organic paraffinic phase change material (PCM) is preferably at least one paraffinic alkane-based material selected from the group consisting of tridecane, tetradecane, pentadecane, n-hexadecane, octadecane, and eicosan.
본 발명에서는 특별히 상기 PCM을 얇은 고체 껍질(마이크로캡슐)로 코팅하여 상변화 동안 PCM의 유실을 방지하고, 단위 부피당 더 큰 표면적을 통해 높은 열전달률을 제공할 수 있다. 마이크로캡슐은 일반적으로 1㎛ 내지 1000㎛ 범위의 크기를 갖는 천연 및 합성 중합체가 바람직하다. In the present invention, the PCM is coated with a thin solid shell (microcapsule) to prevent loss of the PCM during phase change and to provide a high heat transfer rate through a larger surface area per unit volume. The microcapsules are preferably natural and synthetic polymers, generally having a size ranging from 1 μm to 1000 μm.
이러한 마이크로캡슐화시킨 PCM은 상기 바인더 중량 대비 0.1~15%로 포함되는 것이 모르타르 축열 및 발열성 면에서 바람직하다. The microencapsulated PCM is preferably included in an amount of 0.1 to 15% based on the weight of the binder in terms of heat storage and exothermic properties of the mortar.
(5) 탄소나노튜브 (Carbon Nano Tube) (5) Carbon Nano Tube
본 발명에서 사용되는 전도성 나노재료인 CNT는 하나의 탄소원자가 3개의 다른 탄소 원자와 결합되어 육각형 벌집무늬로 원통형 모양을 이루고 있는 탄소 동소체이며, 철강보다 100배 뛰어난 강도, 구리와 비슷한 전기전도도, 다이아몬드와 같은 열전도율의 우수한 물리적 특성을 가진 첨단 신소재이다. CNT, the conductive nanomaterial used in the present invention, is a carbon allotrope in which one carbon atom is combined with three other carbon atoms to form a cylindrical shape with a hexagonal honeycomb pattern. It is a high-tech new material with excellent physical properties such as thermal conductivity.
본 발명에 따른 CNT는 직경 5~7nm, 길이 50~150㎛, BET 비표면적 500~700m2/g, 비중(Bulk Density) 0.07~0.09g/ml인 것이 바람직하다. The CNT according to the present invention preferably has a diameter of 5 to 7 nm, a length of 50 to 150 μm, a BET specific surface area of 500 to 700 m 2 /g, and a specific gravity of 0.07 to 0.09 g/ml.
본 발명에서는 상기 상변화물질을 적용한 모르타르 접착제에서 강도가 저하되는 문제를 해결하기 위해 상기 CNT를 첨가하여 물리적 강도를 보완하고자 한 것이다.In the present invention, in order to solve the problem of strength deterioration in mortar adhesives to which the phase change material is applied, physical strength is supplemented by adding the CNT.
본 발명에서는 상기 무극성인 CNT를 극성 용매인 물 안에서 초음파 분산(Sonication)을 통해 분산시킨 전도성 나노소재 분산액으로 사용하는 것이 바람직하다. 상기 전도성 나노소재 분산액은 0.5~1중량%의 농도로 포함되는 것이 바람직하며, CNT 농도가 0.5중량% 미만에서는 CNT 넣은 효과가 없고, 1중량% 초과시에는 상대적인 물의 양이 줄어들기 때문에 분산이 어려워 작업성에 문제가 있을 수 있다. In the present invention, it is preferable to use the non-polar CNTs as a conductive nanomaterial dispersion in which the non-polar CNTs are dispersed through ultrasonic dispersion in water, which is a polar solvent. The conductive nanomaterial dispersion is preferably contained in a concentration of 0.5 to 1% by weight, and when the CNT concentration is less than 0.5% by weight, there is no effect of adding CNTs, and when the concentration exceeds 1% by weight, the relative amount of water decreases, making it difficult to disperse. Sex may be a problem.
또한, 상기 전도성 나노소재인 CNT는 전체 모르타르 접착제 조성물 내에서는 바인더 중량 대비 0.01~0.1%로 포함되는 것이 강도증진 및 내구성 한 면에서 바람직하다. In addition, the conductive nanomaterial CNT is preferably included in an amount of 0.01 to 0.1% based on the weight of the binder in the entire mortar adhesive composition in terms of strength enhancement and durability.
또한, 본 발명에 따른 상기 CNT 분산액을 제조한 다음, 계면활성제인 유동화제(Superplasticizer)를 첨가하여 입자 간 반데르발스힘에 의한 재응집 현상(Aggolomeration)을 줄이는 것이 바람직하다. In addition, after preparing the CNT dispersion according to the present invention, it is preferable to add a superplasticizer, which is a surfactant, to reduce reagglomeration caused by van der Waals forces between particles.
상기 모르타르 접착제 조성을 이용한 조적벽돌 쌓기용 고축열 PCM 시멘트질 모르타르 접착제의 제조 과정을 다음 도 1을 참조하여 설명하면 다음과 같다. A manufacturing process of a high heat storage PCM cementitious mortar adhesive for masonry brick stacking using the mortar adhesive composition will be described with reference to FIG. 1 below.
상기 접착제 제조 과정은 모르타르 접착제 제조 공정(100)과 마이크로캡슐화된 PCM 제조 전처리 공정(200)로 구분된다. The adhesive manufacturing process is divided into a mortar adhesive manufacturing process (100) and a microencapsulated PCM manufacturing pretreatment process (200).
마이크로캡슐화된 PCM 제조 전처리 공정(200)은 PCM을 준비(210)하여 마이크로캡슐(220)로 코팅하고 완성된 마이크로캡슐화된 PCM(230)을 준비한다. 또한, 모르타르 배합 전 CNT 분산액을 미리 준비한다.In the microencapsulated PCM preparation pretreatment process (200), PCM is prepared (210), coated with microcapsules (220), and the finished microencapsulated PCM (230) is prepared. In addition, the CNT dispersion is prepared in advance before mortar mixing.
또한, 모르타르 접착제 제조 공정(100)에서는 1차 건비빔(110)에서 잔골재와 시멘트를 투입하고 2차 투입(120)에서 상기 마이크로캡슐화된 PCM 제조 전처리 공정(200)에서 준비한 마이크로캡슐 PCM과 CNT 분산액, 물, 및 유동화제(SP)를 투입하여 슬러리 상태로 잘 배합시킨다. 마지막 타설 (130) 과정을 통해 모르타르 접착제 제작을 마친다.In addition, in the mortar
이하에서 본 발명의 바람직한 실시예를 상세히 설명하기로 한다. 이하의 실시예는 본 발명을 예시하기 위한 것일 뿐, 본 발명의 범위가 이들 실시예에 의해 제한되는 것으로 해석되어서는 안 된다. 또한, 이하의 실시예에서는 특정 화합물을 이용하여 예시하였으나, 이들의 균등물을 사용한 경우에 있어서도 동등 유사한 정도의 효과를 발휘할 수 있음은 당업자에게 자명하다.Hereinafter, preferred embodiments of the present invention will be described in detail. The following examples are only for illustrating the present invention, and the scope of the present invention should not be construed as being limited by these examples. In addition, in the following examples, specific compounds were exemplified, but it is obvious to those skilled in the art that equivalent or similar effects can be exerted even when equivalents thereof are used.
실시예 1~2 : 모르타르 접착제 제조Examples 1 and 2: Preparation of mortar adhesive
다음 실시 예는 PCM을 바인더 중량 대비 10%, 0.5중량%의 CNT 수분산액을 바인더 중량 대비 0.05, 0.1%로 포함된 배합표로서 조적벽돌 쌓기용 고축열 PCM 시멘트질 모르타르 접착제는 다음과 같이 제조할 수 있다. The following example is a formulation table containing PCM at 10% by weight of binder and 0.5% by weight of CNT aqueous dispersion at 0.05 and 0.1% by weight of binder, and high heat storage PCM cementitious mortar adhesive for masonry bricks can be prepared as follows .
다음 도 1과 같이, 1차 건비빔(110)에서 잔골재로서 모래와 바인더로서 시멘트를 투입하고 2차 투입(120)에서 마이크로캡슐화된 PCM과 CNT 분산액, 물, SP를 투입시켰다. 이를 타설 (130) 과정을 통해 모르타르 접착제를 제조하였다. As shown in FIG. 1, in the first
(2) CNT : 직경 5~7nm, 길이 50~150㎛, BET 비표면적 500~700m2/g, 비중(Bulk Density) 0.07~0.09g/ml인 것으로 바인더인 시멘트 중량 대비 포함된 함량임
(3) 마이크로캡슐화된 PCM: 바인더인 시멘트 중량 대비 포함된 함량으로, PCM은 테트라데칸을 사용함(1) Fine aggregate: sand with particle size <4mm
(2) CNT: Diameter 5~7nm, length 50~150㎛, BET specific surface area 500~700m 2 /g, Bulk Density 0.07~0.09g/ml, which is included in the weight of cement, which is a binder.
(3) Microencapsulated PCM: The amount included in the weight of cement as a binder, PCM uses tetradecane
실험예 : 기계적 강도 측정Experimental Example: Measurement of mechanical strength
상기 실시예 1~2에서와 같이 카본 나노 튜브의 함량이 바인더 중량 대비 각각 0.05, 0.1%로 포함된 모르타르 접착제와 카본 나노 튜브를 첨가하지 않고 제조된 모르타르 접착제(비교예 1)의 기계적 압축강도를 ASTM C39/C39M-21에 준하여 변위 제어 방식으로 만능 재료 시험기(Universal Testing Machine, UTM)으로 측정하였으며, 그 결과를 다음 표 2에 나타내었다.As in Examples 1 and 2, the mechanical compressive strength of the mortar adhesive containing 0.05 and 0.1% of the carbon nanotube content relative to the weight of the binder and the mortar adhesive prepared without adding carbon nanotubes (Comparative Example 1) In accordance with ASTM C39 / C39M-21, it was measured with a universal testing machine (UTM) in a displacement control method, and the results are shown in Table 2 below.
상기 표 2의 결과를 참조하면, CNT가 포함되지 않은 비교예 1의 모르타르 접착제에 비해 CNT 가 포함된 실시예 1과 2의 모르타르 접착제의 압축강도가 현저히 증가함을 확인할 수 있다. 또한, CNT 함량이 증가할수록 모르타르 접착제의 압축강도 또한 증가되는 효과를 확인하였다. Referring to the results of Table 2, it can be seen that the compressive strength of the mortar adhesives of Examples 1 and 2 containing CNTs significantly increased compared to the mortar adhesive of Comparative Example 1 not containing CNTs. In addition, as the CNT content increased, the compressive strength of the mortar adhesive also increased.
이러한 결과로부터 PCM을 적용한 모르타르 접착제에서 강도가 저하되는 문제를 본 발명과 같이 탄소나노튜브를 첨가함으로써 해결할 수 있음을 확인하였다. From these results, it was confirmed that the problem of strength deterioration in the PCM-applied mortar adhesive can be solved by adding carbon nanotubes as in the present invention.
Claims (10)
A high heat storage PCM cementitious mortar adhesive composition for masonry brick construction comprising a microencapsulated phase change material and a conductive nanomaterial.
상기 상변화물질은 트리데칸, 테트라데칸, 펜타데칸, n-헥사데칸, 옥타데칸 및 에이코산으로 이루어진 그룹으로부터 선택되는 1종 이상의 파라핀 알칸 계열의 물질인 것인 조성물.
According to claim 1,
The phase change material is tridecane, tetradecane, pentadecane, n- hexadecane, octadecane, and one or more types of paraffin alkane-based material selected from the group consisting of eicosan composition.
상기 마이크로캡슐화시킨 상변화물질은 조성물에 포함되는 바인더 중량 대비 0.1~15%로 포함되는 것인 조성물.
According to claim 1,
The microencapsulated phase change material is a composition that is included in 0.1 to 15% by weight of the binder included in the composition.
상기 전도성 나노소재는 카본 나노 튜브인 것인 조성물.
According to claim 1,
Wherein the conductive nanomaterial is a carbon nanotube.
상기 전도성 나노소재는 극성 용매인 물에 분산시킨 전도성 나노소재 수분산액 형태로 포함되는 것인 조성물.
According to claim 1,
The conductive nanomaterial is a composition that is included in the form of a conductive nanomaterial aqueous dispersion dispersed in water, which is a polar solvent.
상기 전도성 나노소재 수분산액의 농도는 0.5~1중량%인 것인 조성물.
According to claim 5,
The concentration of the conductive nanomaterial aqueous dispersion is 0.5 to 1% by weight of the composition.
상기 전도성 나노소재는 조성물에 포함되는 바인더 중량 대비 0.01~0.05%로 포함되는 것인 조성물.
According to claim 1,
The conductive nanomaterial is a composition that is included in 0.01 to 0.05% by weight of the binder included in the composition.
상기 조성물은 시멘트 바인더 40.0~45.0중량%, 잔골재 32.0~36.0중량%, 유동화재(SP) 0.1~0.3중량% 및 잔량의 물을 더 포함하는 것인 조성물.
According to claim 1,
The composition further comprises 40.0 to 45.0% by weight of cement binder, 32.0 to 36.0% by weight of fine aggregate, 0.1 to 0.3% by weight of fluidizing agent (SP) and the balance of water.
A high heat storage PCM cementitious mortar adhesive for masonry bricks prepared from the composition according to claim 1.
1차 건비빔에서 바인더, 잔골재를 혼합하는 단계,
여기에 2차 비빔에서 물, 상기 마이크로캡슐화시킨 상변화물질, CNT 나노 분산액, 및 유동화제를 첨가하여 혼합하는 단계, 및
이를 타설하는 단계를 포함하는 조적벽돌 쌓기용 고축열 PCM 시멘트질 모르타르 접착제의 제조방법. Preparing a microencapsulated phase change material by coating the phase change material with microcapsules;
Mixing the binder and the fine aggregate in the first dry mixing step,
Adding and mixing water, the microencapsulated phase change material, CNT nano-dispersion, and fluidizing agent in the second mixing, and
A method for producing a high heat storage PCM cementitious mortar adhesive for masonry bricks, comprising the step of pouring it.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101090526B1 (en) * | 2011-07-26 | 2011-12-08 | 김보현 | Motar with improved thermal storage performance comprising phase change materials |
| KR20130069320A (en) * | 2011-12-14 | 2013-06-26 | (주)케미우스코리아 | Hydration heat dissipation concrete composition using cnt |
| US20180043102A1 (en) | 2016-08-09 | 2018-02-15 | Becton, Dickinson And Company | O-Ring Plunger for a Prefilled Syringe and Method |
| KR20200006675A (en) * | 2018-07-11 | 2020-01-21 | 가천대학교 산학협력단 | Mortar composition having improved thermal performance at low temperatures, concrete including the same and mortar composition preparation method |
| KR102098039B1 (en) | 2019-07-15 | 2020-04-09 | 주식회사 아이앤엘 | Eco-friendly Mortar composition for repairing and reinforcing underwater concrete structures, and method of repairing and reinforcing using the same |
-
2021
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101090526B1 (en) * | 2011-07-26 | 2011-12-08 | 김보현 | Motar with improved thermal storage performance comprising phase change materials |
| KR20130069320A (en) * | 2011-12-14 | 2013-06-26 | (주)케미우스코리아 | Hydration heat dissipation concrete composition using cnt |
| US20180043102A1 (en) | 2016-08-09 | 2018-02-15 | Becton, Dickinson And Company | O-Ring Plunger for a Prefilled Syringe and Method |
| KR20200006675A (en) * | 2018-07-11 | 2020-01-21 | 가천대학교 산학협력단 | Mortar composition having improved thermal performance at low temperatures, concrete including the same and mortar composition preparation method |
| KR102098039B1 (en) | 2019-07-15 | 2020-04-09 | 주식회사 아이앤엘 | Eco-friendly Mortar composition for repairing and reinforcing underwater concrete structures, and method of repairing and reinforcing using the same |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102651041B1 (en) * | 2023-06-08 | 2024-03-25 | 주식회사 대하맨텍 | Phase change material microcapsule, method for manufacturing the same, and thermal energy storage concrete composite using the same |
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