KR20230049425A - Footwear and clothing industry Ultra High Density Polyurethane Slab Foam production method - Google Patents

Footwear and clothing industry Ultra High Density Polyurethane Slab Foam production method Download PDF

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KR20230049425A
KR20230049425A KR1020210132575A KR20210132575A KR20230049425A KR 20230049425 A KR20230049425 A KR 20230049425A KR 1020210132575 A KR1020210132575 A KR 1020210132575A KR 20210132575 A KR20210132575 A KR 20210132575A KR 20230049425 A KR20230049425 A KR 20230049425A
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raw materials
rubber
foam block
footwear
foam
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KR1020210132575A
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Korean (ko)
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임현승
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임현승
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Priority to PCT/IB2022/000571 priority patent/WO2023057815A1/en
Publication of KR20230049425A publication Critical patent/KR20230049425A/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B11/00Making preforms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B11/00Making preforms
    • B29B11/02Making preforms by dividing preformed material, e.g. sheets, rods
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B11/00Making preforms
    • B29B11/06Making preforms by moulding the material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/74Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/74Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
    • B29B7/7404Mixing devices specially adapted for foamable substances
    • B29B7/7409Mixing devices specially adapted for foamable substances with supply of gas
    • B29B7/7414Mixing devices specially adapted for foamable substances with supply of gas with rotatable stirrer, e.g. using an intermeshing rotor-stator system
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/20Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of indefinite length
    • B29C44/28Expanding the moulding material on continuous moving surfaces without restricting the upwards growth of the foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/20Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of indefinite length
    • B29C44/30Expanding the moulding material between endless belts or rollers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/3442Mixing, kneading or conveying the foamable material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/56After-treatment of articles, e.g. for altering the shape
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2075/00Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2503/00Use of resin-bonded materials as filler
    • B29K2503/04Inorganic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2507/00Use of elements other than metals as filler
    • B29K2507/04Carbon

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

The present invention provides a manufacturing method of UHD PUF foam, a special new material with ultra-high specific gravity for footwear and clothing industries, in which synthetic rubber materials (neoprene rubber, etc.), which have been used for a long time around the world in footwear, shoemaking, and special clothing industries, can be replaced with polyurethane slab foam, which has ultra-high specific gravity, bending resistance, resilience, and high rebound elastic characteristics. According to the present invention, the manufacturing method comprises: a raw material receiving process of receiving raw materials containing polyol and toluene diisocyanate and inspecting temperature, quantity, and receipt; a process of adding the raw materials to each tank and adding a compounding agent and additives, continuously and automatically measuring the raw materials stored in each tank using a precise, automatic chemical metering pump, and mixing the raw materials while a head rotates at high speed after arriving at a mixing/discharging machine along a sealed pipe; a process of manufacturing a foam block by discharging the mixed raw materials from the mixing/discharging machine and transferring the mixed raw materials to an open conveyor moving at a constant speed to foam; a process of cutting the foam block in a vertical direction to a certain length and then moving and stacking the cut foam block; a process of aging the cut foam block for more than 96 hours; a process of cutting the aged foam block in a horizontal direction to a thickness which meets customer requirements; and a process of packaging, loading, and shipping a cut product after screening for defects. Accordingly, costs can be reduced and the supply and demand problem of neoprene rubber can be solved.

Description

신발 및 의류 산업용 특수 신소재 UHD PUF 제조방법 {Footwear and clothing industry Ultra High Density Polyurethane Slab Foam production method}UHD PUF manufacturing method, a special new material for the footwear and clothing industry {Footwear and clothing industry Ultra High Density Polyurethane Slab Foam production method}

본 발명은 신발 및 의류 산업용 신소재 UHD PUF 제조방법에 관한 것으로서, 더욱 상세히는 신발 및 제화, 특수 의류산업 분야 등에서 전 세계적으로 장기간 사용해 오던 합성고무 소재(Neoprene Rubber 등)를 초고비중(Ultra High Density), 내굴곡성, 복원성, 고 반발 탄성 특성을 가진 특수 신소재 Polyurethane Slab Foam(이하 "신소재 UHD PU Slab Foam", 간략히 "신소재 UHD PUF"라 약칭한다) 소재로 대체할 수 있도록 한 신발 및 의류 산업용 초고비중 특수 신소재 UHD PUF 제조방법을 제공 코자 하는 것이다.The present invention relates to a method for manufacturing UHD PUF, a new material for the footwear and apparel industry, and more specifically, synthetic rubber materials (Neoprene Rubber, etc.) , Polyurethane Slab Foam, a new special material with bending resistance, resilience, and high rebound elasticity (hereinafter referred to as "new material UHD PU Slab Foam", simply abbreviated as "new material UHD PUF") It is to provide a special new material UHD PUF manufacturing method.

일반적으로 합성고무는 중합하는 재료의 종류, 중합공정 및 중합도에 따라 서로 다른 다양한 고유 물리적, 화학적 특성을 가지며, 제조원가에도 큰 차이가 발생한다.In general, synthetic rubber has various unique physical and chemical properties that are different from each other depending on the type of material to be polymerized, the polymerization process, and the degree of polymerization, and a large difference occurs in manufacturing cost.

따라서 합성고무를 개별 산업분야에 적용하고자 할 때에는 생산하고자 하는 제품의 용도를 세심히 고려하여 다양한 종류의 합성고무가 가지고 있는 고유 특성별 장단점을 기술적으로 분석하고 시험과정을 거쳐 선별적으로 적용하여야 한다.Therefore, when applying synthetic rubber to individual industrial fields, it is necessary to carefully consider the use of the product to be produced, technically analyze the advantages and disadvantages of each unique characteristic of various types of synthetic rubber, and apply it selectively through a test process.

즉, 중합 재료의 종류에 따라 합성고무의 종류는 다음과 같이 다종이 존재한다.That is, according to the type of polymeric material, there are various types of synthetic rubber as follows.

가. 스티렌부타디엔고무(Styrene Butadien Rubber, SBR): 스티렌과 부타디엔의 비율이 약 1:3이 되도록 에멀션화 중합[乳化重合]시켜서 얻은 중합체이다.go. Styrene Butadien Rubber (SBR): It is a polymer obtained by emulsification polymerization so that the ratio of styrene and butadiene is about 1:3.

SBR은 가장 일반적인 합성고무이며, GR-S, 부나-S라고도 한다. 스티렌과 부타디엔은 석유화학공업에서 대량으로 얻을 수 있다.SBR is the most common synthetic rubber and is also called GR-S or Buna-S. Styrene and butadiene can be obtained in large quantities from the petrochemical industry.

SBR의 성질은 천연고무와 거의 같아서 황으로 가황할 수 있다. 또 스티렌을 50% 정도 함유하는 하이스티렌고무는 특히 경도(硬度)가 높아 구두창, 뒤축 등 경도가 높은 고무제품으로서의 특수 용도에 사용된다.The properties of SBR are almost the same as natural rubber, so it can be vulcanized with sulfur. In addition, high styrene rubber containing about 50% of styrene has particularly high hardness and is used for special purposes as rubber products with high hardness such as soles and heels.

그리고 에멀션 그대로 고분자 가공제나 종이의 사이징 또는 접착제로 사용되는 용액 SBR도 있다.And there is also solution SBR that is used as an emulsion as a polymer processing agent, paper sizing, or adhesive.

나. 폴리클로로프렌고무(Polychloroprene Rubber, CR): 클로로프렌의 트랜스형 중합체이며 잘 알려진 대로 Neoprene(듀폰사의 상품명) 또는 Neoprene Rubber 라고도 한다.me. Polychloroprene Rubber (CR): It is a trans polymer of chloroprene and is also called Neoprene (DuPont's trade name) or Neoprene Rubber as it is well known.

중합방법에는 용액중합, 에멀션화 중합이 있는데, 공업적으로는 에멀tus화 중합이 많이 사용되며, 산화마그네슘으로 가황한다.Polymerization methods include solution polymerization and emulsification polymerization. Industrially, emulsification polymerization is widely used, and vulcanization is performed with magnesium oxide.

내열성·내후성(耐候性), 특히 내유성이 높으나 내한성은 좀 떨어진다. 탄성고무로 사용되며, 이 밖에 자동차, 신발에서 금속-고무, 플라스틱-고무, 고무 상호간, 천을 입힌 고무-가죽 등의 접합제로 널리 사용된다.Heat resistance and weather resistance (耐候性), especially oil resistance is high, but cold resistance is a bit low. It is used as elastic rubber, and is also widely used as a bonding agent for metal-rubber, plastic-rubber, rubber-to-rubber, cloth-coated rubber-leather, etc. in automobiles and shoes.

다. 니트릴고무(Acrylonitrile-Butadiene Rubber, NBR): 부타디엔과 아크릴로니트릴을 약 2:1의 비율로 에멀션화 중합시킨 혼성중합체이다.all. Acrylonitrile-Butadiene Rubber (NBR): It is a copolymer obtained by emulsifying butadiene and acrylonitrile at a ratio of about 2:1.

잘 알려진 대로 아크릴로니트릴부타디엔고무(NBR)라고도 한다. 탄화수소에 대한 내유성이 가장 뛰어나고 내열성, 내오존성, 내마멸성도 우수하다.As is well known, it is also called acrylonitrile butadiene rubber (NBR). It has the best oil resistance to hydrocarbons, and also has excellent heat resistance, ozone resistance and abrasion resistance.

NBR에 폴리염화비닐을 40% 이상 혼합한 고무는 난연성(難燃性), 내오존성이며, 소규모이지만 실용화되었다.Rubber obtained by mixing 40% or more of polyvinyl chloride with NBR is flame retardant and ozone resistant, and has been put into practical use, albeit on a small scale.

또 아크릴로니트릴을 26% 함유하는 이소프렌아크릴로니트릴 고무라고 하는 이소프렌-아크릴로니트릴 혼성중합체인 고무도 있는데, 이것의 내한성은 보통 NBR보다 좋다.There is also a rubber that is an isoprene-acrylonitrile copolymer called isoprene-acrylonitrile rubber containing 26% of acrylonitrile, and its cold resistance is usually better than that of NBR.

라. 부틸고무(Isoprene-Isobutylene Rubber, IIR): 이소부틸렌 중합체를 주성분으로 하며, 황으로 가황할 수 있도록 약 5% 이소프렌을 혼성중합시킨 것이다.la. Butyl rubber (Isoprene-Isobutylene Rubber, IIR): It is mainly composed of isobutylene polymer, and is copolymerized with about 5% isoprene so that it can be vulcanized with sulfur.

이소프렌-이소부틸렌 고무라고도 한다. 불포화결합이 적으므로 내노화성, 내오존성이 우수하나, 가황한계가 낮고 반발탄성(反撥彈性)이 적다.Also known as isoprene-isobutylene rubber. It has excellent aging resistance and ozone resistance because it has few unsaturated bonds, but it has low vulcanization limit and low rebound elasticity.

또 접착성이 적은 등의 결점이 있으므로 타이어 제품에는 별로 사용되지 않으나, 기체투과율이 작다는 등의 특징이 있어 타이어 내부 튜브, 전선케이블 등에 사용된다.In addition, it is not used much in tire products because of its drawbacks such as low adhesiveness, but it is used for tire inner tubes and wire cables because of its characteristics such as low gas permeability.

마. 부타디엔고무(Butadiene Rubber, BR): 부타디엔을 중합하여 시스-1, 4구조를 가지는 중합체로 만든 것이다.mind. Butadiene Rubber (BR): It is made of a polymer having cis-1, 4 structures by polymerizing butadiene.

이 중합법은 1956년부터 수년간에 걸쳐 미국과 이탈리아에서 발명되었다. 일정한 입체구조를 가지기 때문에 다음에 설명하는 IR와 마찬가지로 입체특이성 고무(스테레오고무)라고도 한다.This polymerization method was invented in the United States and Italy over several years from 1956. Because it has a certain three-dimensional structure, it is also called stereospecific rubber (stereo rubber) like IR described below.

SBR보다 기계적으로 우수하며, 특히 반발탄성·내한·내마멸성이 높고, 게다가 발열성이 낮으므로 타이어용으로 생산되며, 장차는 천연고무의 대체품으로서 주종을 이룰 것으로 생각된다.It is mechanically superior to SBR, and especially has high resilience, cold resistance, and abrasion resistance, and also has low exothermic properties, so it is produced for tires and is expected to dominate as a substitute for natural rubber in the future.

그리고 트랜스-1, 4구조인 것은 골프공 등 경질제품으로서의 용도를 가지며, 또 최근에는 시스·트랜스·비닐 구조가 혼합된 고무가 치핑현상을 억제하는 타이어 재료로서 제조된다.In addition, the trans-1, 4 structure has a use as a hard product such as a golf ball, and recently, rubber mixed with a cis-trans-vinyl structure is manufactured as a tire material that suppresses chipping.

바. 이소프렌고무(Isoprene Rubber: IR): 이소프렌을 중합하여 얻은 천연고무의 성분인 1, 4-폴리이소프렌을 말하며, 합성천연고무라고도 하는 스테레오고무이다.bar. Isoprene Rubber (IR): Refers to 1, 4-polyisoprene, a component of natural rubber obtained by polymerizing isoprene, and is also called synthetic natural rubber.

전에는 트랜스 및 시스의 1, 2, 3, 4 구조가 혼합된 고무밖에 합성하지 못했으나, 치글러 촉매 등을 사용하는 스테레오고무 합성법이 1954년 미국에서 완성되었다. 천연고무보다 백색인 것을 얻을 수 있는 이점이 있다.Previously, only rubbers in which 1, 2, 3, and 4 structures of trans and cis were mixed had been synthesized, but a stereo rubber synthesis method using a Ziegler catalyst and the like was completed in 1954 in the United States. There is an advantage of obtaining a whiter color than natural rubber.

사. 에틸렌프로필렌고무(Ethylene Propylene Rubber, EPR): 에틸렌 60~70%, 프로필렌 30~40% 비율로 혼성 중합시킨 무작위공중합체이다.buy. Ethylene Propylene Rubber (EPR): It is a random copolymer copolymerized with 60-70% of ethylene and 30-40% of propylene.

이중결합이 함유되어 있지 않아 내열성, 내오존성은 우수하지만 황으로 가황할 수 없으므로, 제3성분으로서 디엔화합물을 넣어 삼원공중합시키면 고리 모양으로 가황할 수 있는 것이 된다.Since it does not contain a double bond, it has excellent heat resistance and ozone resistance, but cannot be vulcanized with sulfur. Therefore, when a diene compound is added as a third component and ternary copolymerization is performed, it can be vulcanized in a ring shape.

이것을 잘 알려진 대로 EPDM이라 하며, 내후성·유전성(誘電性) 등 여러 성질이 우수하나 제3성분인 디엔단위체 값이 비싼 편이다. 전선·케이블의 피복, 컨베이어 벨트 등의 제조에 이용된다.This is known as EPDM, and it is excellent in various properties such as weatherability and dielectricity, but the price of the third component, the diene unit, is on the high side. It is used in the manufacture of wire and cable sheathing and conveyor belts.

아. 다황화물계(多黃化物系)고무(Polysulfide Rubber): 알칼리성 폴리설파이드와 적당한 알칼할라이드의 축합중합으로 제조된 선 모양 중합체이다. 티오콜(Thiokol)이라고도 한다.ah. Polysulfide Rubber: A linear polymer produced by condensation polymerization of an alkaline polysulfide and a suitable alkali halide. Also known as Thiokol.

원료로는 여러 다황화나트륨과 유기 이염화물이 이용되며, 이에 따라 성질이 약간 다른 다황화고무들을 제조할 수 있다. 다황화고무는 다른 중합체가 그물 모양을 형성함으로써 가황되는 데 대하여 분자 끝의 메르캅탄기―SH에 의한 선모양 성장반응으로 숙성된다. 내유성·내용매성 등이 우수하며, 기체가 거의 통과하지 못하고, 또 내노화성, 내오존성도 좋으나 나쁜 냄새가 나며, 내열성, 내마멸성, 인장강도 등이 좋지 않다. 따라서, 가솔린 호스, 유류탱크, 격막, 개스킷 등의 제조에 주로 사용된다. 액상 다황화고무는 상온에서 숙성시켜 질기고 내용매성인 고무를 만들 수 있으며, 여러 기기의 내장 등에 사용된다. Various sodium polysulfide and organic dichloride are used as raw materials, and thus polysulfide rubbers with slightly different properties can be manufactured. Polysulfurized rubber is matured by linear growth reaction by mercaptan group-SH at the end of the molecule while other polymers are vulcanized by forming a net shape. It has excellent oil resistance and solvent resistance, hardly passes gas, has good aging resistance and ozone resistance, but has bad smell, and has poor heat resistance, abrasion resistance, and tensile strength. Therefore, it is mainly used for manufacturing gasoline hoses, oil tanks, diaphragms, gaskets, and the like. Liquid polysulfide rubber can be aged at room temperature to make tough and solvent-resistant rubber, and is used for the interior of various devices.

자. 실리콘고무(Silicone Rubber): 디클로로실란을 가스분해하여 얻은 선 모양의 고무상 고분자물질이다. 유기과산화물로 가황(加黃)할 수 있다. 분자 내에 비닐기를 도입하여 가황이 쉽게 되도록 한 것이며, 내열성·내한성이 우수하고, 내수성·전기절연성이 좋으므로 여러 개스킷·실, 전선 및 케이블 피복, 더운 유체의 도관 등 내열 및 전기절연재료로 이용된다.ruler. Silicone Rubber: It is a linear rubber-like polymer obtained by gas decomposition of dichlorosilane. It can be vulcanized with organic peroxides. It is easily vulcanized by introducing a vinyl group into the molecule. It has excellent heat and cold resistance, and good water resistance and electrical insulation, so it is used as a heat-resistant and electrical insulating material for various gaskets, seals, wire and cable sheaths, and conduits for hot fluids. .

차. 플루오로고무(Fluororubber): 플루오린을 함유하는 합성고무의 총칭. 많은 종류가 있으나 플루오린화 아크릴레이트계·플루오린화비닐리덴계·플루오린화폴리에스테르계 등이 대표적인 것이다.car. Fluororubber: A generic term for synthetic rubber containing fluorine. There are many types, but fluorinated acrylate-based, fluorinated vinylidene-based, fluorinated polyester-based, etc. are representative.

내열성이 매우 좋으나 값이 비싸기 때문에 내열성이 요구되는 특수한 용도에만 사용된다. 또 플루오로고무에는 테트라플루오로에틸렌과 트리플루오로니트로소메탄의 혼성중합체가 있는데, 이것은 니트로소고무라고 하며, 내용제성·내유성·내한성이 매우 좋다.It has very good heat resistance, but because it is expensive, it is used only for special applications that require heat resistance. In addition, there is a copolymer of tetrafluoroethylene and trifluoronitrosomethane in fluororubber, which is called nitroso rubber and has excellent solvent resistance, oil resistance and cold resistance.

카. 우레탄고무(Urethane Rubber): 수지와 마찬가지로 폴리에스테르나 폴리에테르의 글리콜과 디이소시아네이트를 반응시켜 제조한다. 폴리에스테르글리콜로는 에틸렌·프로필렌·부틸렌 등의 글리콜을 아디프산 등과 반응시켜 제조하며, 분자량은 1,000~2,000이다.card. Urethane Rubber: Like resin, it is produced by reacting polyester or polyether glycol with diisocyanate. Polyester glycol is prepared by reacting glycol such as ethylene·propylene·butylene with adipic acid and the like, and has a molecular weight of 1,000 to 2,000.

폴리에테르글리콜로는 폴리옥시에틸렌·폴리옥시프로필렌·폴리옥시테트라히드로푸란 등의 글리콜이 사용되며, 디이소시아네이트로는 톨루엔디이소시아네이트·4,4-디페닐메탄디이소시아네이트 등이 사용된다.As the polyether glycol, glycols such as polyoxyethylene, polyoxypropylene, and polyoxytetrahydrofuran are used, and as the diisocyanate, toluene diisocyanate, 4,4-diphenylmethane diisocyanate, and the like are used.

탄성·내유성·내용매성이 우수하여 타이어의 표면, 소형의 공업용 바퀴, 구두 뒤축 표면 등의 제조에 많이 사용된다. 합성시에 이산화탄소를 발생시켜 거품고무로 만드는 일도 많다.Because of its excellent elasticity, oil resistance and solvent resistance, it is widely used in the manufacture of tire surfaces, small industrial wheels, and shoe heel surfaces. In many cases, carbon dioxide is generated during synthesis to make foam rubber.

타. 아크릴고무(Acrylic Rubber): 아크릴산에틸과 아크릴산부틸 등의 아크릴산에스테르를 중합시켜 제조하는데, 가공성을 좋게 하기 위해서 아크릴산-2-클로로에틸·아크릴로니트릴 등과 혼성중합시키는 것이 보통이다.get on. Acrylic Rubber: It is produced by polymerization of acrylic acid esters such as ethyl acrylate and butyl acrylate. It is common to copolymerize acrylic acid-2-chloroethyl acrylonitrile, etc. to improve processability.

폴리아민과 황으로 가황한다. 내열성·내유성은 좋으나 물·수증기에 약하며, 아크릴로니트릴과 혼성중합체는 그 양이 많아질수록 내유성은 좋아지나 저온에서의 특성이 나빠지므로 대개 12% 정도 함유시킨다.Vulcanized with polyamine and sulfur. It has good heat resistance and oil resistance, but is weak against water and steam. As the amount of acrylonitrile and copolymer increases, oil resistance improves, but the properties at low temperatures deteriorate, so they are usually contained at about 12%.

상기에서 언급한 바와 같이 합성고무는 서로 다른 물리적, 화학적 특성과 제조(조달)비용 등에서 다양한 차이를 보이고 있기 때문에, 이를 사용하여 제품을 생산하고자 하는 산업분야에서는 생산할 제품의 사용용도에 적합한 필수적인 특성과 보조특성 및 원가를 종합적으로 고려하여 기술적으로 엄선함이 중요하다고 하겠다.As mentioned above, since synthetic rubber shows various differences in different physical and chemical properties and manufacturing (procurement) cost, in industries that want to produce products using it, essential properties and It is important to select technically by comprehensively considering auxiliary characteristics and costs.

일반적으로 연관 산업계에서는 합성고무의 종류별 조달비용, 경도, 내후성, 내유성, 내열성, 내오존성, 내약품성, 내굴곡성, 내노화성, 인장강도, 신율, 반발탄성, 내마멸성, 저발열성, 내용제성, 내용매성, 난연성, 내한성, 접착성, 기체투과율, 유전성(誘電性), 냄새 등의 특성 차이를 기술적으로 분석하고 다양한 적용 시험을 거쳐 선별한 후 다이어프램, 개스킷, 실, 패킹, 고무벨트, 컨베이어 벨트, 고무라이닝, 타이어 및 타이어 내부 튜브, 전선 케이블 피복, 내열 및 전기절연재료, 외장이나 브라운관 고압단자의 커버, 고무라이닝, 타이어, 타이어의 표면, 공업용 바퀴, 신발겉창, 구두창. 뒤축용 소재 뿐만 아니라, 자동차·신발에서 금속-고무, 플라스틱-고무, 고무-고무 상호간, 천을 입힌 고무-가죽 등의 접합제로도 널리 사용되고 있다.In general, in related industries, procurement costs for each type of synthetic rubber, hardness, weather resistance, oil resistance, heat resistance, ozone resistance, chemical resistance, bending resistance, aging resistance, tensile strength, elongation, rebound elasticity, abrasion resistance, low heat generation, solvent resistance, content After technically analyzing differences in properties such as solvency, flame retardancy, cold resistance, adhesiveness, gas permeability, dielectric properties, and odor, and selecting them through various application tests, diaphragms, gaskets, seals, packings, rubber belts, conveyor belts, Rubber lining, tire and tire inner tube, wire cable sheath, heat-resistant and electrical insulating material, exterior or cathode ray tube high voltage terminal cover, rubber lining, tire, tire surface, industrial wheels, shoe outsole, shoe sole. It is widely used not only as a material for heels, but also as a bonding agent for metal-rubber, plastic-rubber, rubber-rubber, and cloth-coated rubber-leather in automobiles and shoes.

(1) 신발산업분야 신발 갑피용 합성고무 소재 적용 사례 및 문제점:(1) Application cases and problems of synthetic rubber materials for shoe uppers in the footwear industry:

가. 현상 및 문제점: go. Symptoms and Problems:

사람이 신고 다니는 신발은 수시로 움직이거나 장소를 이동하기 때문에, 일반적으로 신발을 구입 후 사용하는 기간이 경과함에 따라 초기에 만족스러웠던 사이즈, 착화감, 밀착감, 일체감이 서서히 떨어지게 되는데, 이는 신발의 갑피(Upper) 부분 중 특히 발등, 발등 뒤 좌우부분 및 발뒤꿈치 부분 등에서 집중적으로 발생하게 된다.Since the shoes worn by people often move or move from place to place, generally, as the period of use after purchase of shoes elapses, the initial satisfactory size, fit, fit, and sense of unity gradually decrease. ), especially in the instep, the left and right parts behind the instep, and the heel part.

이는 걷거나 특히 조깅 시에 갑피의 발등, 발등 뒤 좌우부분 및 발뒤꿈치 부위 등에 [담김.인장↔원위치복원]력이 반복적으로 작용하여 그곳에 사용된 갑피의 일반적인 소재인 섬유, 합성피혁, 피혁 등의 소재가 장기간 반복적인 [담김.인장↔원위치복원]력 작용의 결과 피로도에 의해 인장된 상태에서 복원력을 서서히 상실함으로 초기에 느꼈던 사이즈, 착화감, 밀착감, 일체감이 떨어지게 된다. 물론 이를 보완하기 위해 발등 위에 있는 신발끈을 조이거나 발뒤꿈치의 경우 조임.늘림 가능한 벨트를 부착하여 허리띠 같이 필요시 조이고 늘리는 기능을 더하기도 한다.This is because [immersion. tension ↔ restoration in situ] force repeatedly acts on the instep of the upper, the left and right parts of the back of the instep, and the heel during walking or jogging, so that the general upper material used there, such as fiber, synthetic leather, leather, etc. As a result of the long-term repetitive action of [immersion.tension ↔ restoration in place] force, the restoring force is gradually lost in the tensioned state due to fatigue, and the size, fit, fit, and unity felt at the beginning are lost. Of course, to compensate for this, tighten the shoelaces on the top of the foot or, in the case of heels, attach a belt that can be tightened and stretched to add a function that can be tightened and stretched when necessary, such as a waistband.

나. 합성고무 소재 적용:me. Application of synthetic rubber materials:

이를 보완하기 위해 신발산업 분야에서는 오래전부터 위에서 소개한 고가의 고탄성, 우수한 복원력을 가진 합성고무(예를 들면 Neoprene 고무 등)를 직사각형의 평판시트로 뽑아 이를 (통상 폭 x 길이 x 두께(조절가능) =100mm x 200mm x 2.0mm)의 얇은 Sheet로 슬라이싱(Slicing) 가공한 후, 개별 고무 Sheet 자체의 내굴곡성, 복원성, 반발탄성 특성을 유지, 보완하고 소재의 인장강도, 신율을 개선하면서 소재 표면의 보호와 인체와의 접촉감을 개선하기 위해 개별 고무 Sheet 앞뒷면에 반발탄성, 복원성 특성을 가진 스판덱스(의류의 경우 수영복이나 에어로빅용, 일부 신축성을 부여하기 위해 활동성, 캐쥬얼 바지류에도 섞어 직조하며, 영문 표기는 Spandex Fabric임) 교직 원단 소재 등으로 접착.합포(Coating-Laminating)하여 3겹의 적층복합체(Triflex Composite)로 만들어서 상기에서 제시한 신발의 [담김.인장↔원위치복원]력이 반복 작용하는 갑피의 발등, 발등 뒤 좌우부분 및 발뒤꿈치 부위 등에 본 복합체 소재를 사용하고 있다.To compensate for this, in the shoe industry, synthetic rubber (e.g., Neoprene rubber, etc.), which has been introduced above for a long time and has high elasticity and excellent restoring power, is pulled out into a rectangular flat sheet (usually width x length x thickness (adjustable)). = 100mm x 200mm x 2.0mm) after slicing with a thin sheet, maintaining and supplementing the bending resistance, recovery, and resilience characteristics of the individual rubber sheet itself and improving the tensile strength and elongation of the material, while improving the surface of the material. Spandex with resilience and resilience on the front and back of individual rubber sheets to improve protection and contact with the human body is Spandex Fabric) Upper that is made into a three-layered Triflex Composite by coating-laminating with a nonwoven fabric material, etc., and the [immersion, tension ↔ restoration to original position] force of the shoe repeatedly acts. This composite material is used for the instep of the instep, the left and right parts of the back of the instep, and the heel.

다. 합성고무 소재 적용으로 인한 문제점: all. Problems caused by the application of synthetic rubber materials:

여기서 주목할 것은 신발산업 분야에서 고가의 Neoprene Rubber 등을 사용한 Triflex 적층 복합체[Spandex Fabric-Neoprene Rubber-Spandex Fabric] 등을 신발 갑피의 소재로 사용하면서:What is noteworthy here is that in the footwear industry, Triflex laminated composite [Spandex Fabric-Neoprene Rubber-Spandex Fabric] using expensive neoprene rubber is used as a material for shoe uppers:

① 본 복합체가 가진 내굴곡성, 복원성, 반발탄성 특성으로 걷거나 특히 조깅 시에 신발의 발등, 발등 뒤 좌우부분 및 발뒤꿈치 부위 등을 [담김.인장↔원위치복원]력으로 적절히 조여 주고 풀어주기 때문에 소비자가 신발구입 초기 가졌던 사이즈, 착화감, 밀착감, 일체감을 사용 중에도 유지할 수 있게 하는 데는 소기의 목적을 달성할 수 있겠으나① Due to the flex resistance, resilience, and resilience of this composite, it appropriately tightens and releases the instep of the shoe, the left and right back of the instep, and the heel area during walking or jogging, with [embedding. tension ↔ restoration to original position] force. It is possible to achieve the intended purpose of maintaining the size, fit, fit, and sense of unity that you had at the beginning of purchasing shoes.

② 본 Neoprene Rubber 소재의 물리적 특성인 내굴곡성, 복원성, 반발탄성 외에 Neoprene Rubber 자체의 고유 화학적 특성인 우수한 내열성·내후성(耐候性), 특히 탁월한 내유성(이로 인해 고가이며 특수 산업분야에서 본 특성을 감안하여 선별적으로 사용 중임)은 신발 갑피용에는 필요한 특성이 아닐 뿐만 아니라 이로 인해 수급과정에서 고비용을 지불하고 있으며,② In addition to the physical properties of this neoprene rubber material, such as flex resistance, recovery, and rebound elasticity, Neoprene Rubber itself has excellent heat resistance and weather resistance, which are unique chemical properties, and especially excellent oil resistance is not only a necessary characteristic for shoe uppers, but also pays high costs in the supply and demand process.

③ Neoprene Rubber 소재는 신발 갑피용 소재로써 내굴곡성, 복원성, 반발탄성 특성을 제외하고는 근본적으로 아래와 같은 근본적이고도 고질적인 문제를 안고 있으나 현재까지 본 합성고무를 대체할 대체재 개발을 못하여 계속 사용 중에 있다.③ Neoprene rubber material is a material for shoe uppers, and it has the following fundamental and chronic problems except for flex resistance, resilience, and resilience. .

라. 신발 갑피 소재로써의 합성고무가 지닌 고질적인 문제점la. Chronic problems of synthetic rubber as a shoe upper material

① 합성고무 자체의 고비중(주로 200kg/m3)으로 경량화 해야 할 신발이 무겁게 됨① Due to the high specific gravity of synthetic rubber itself (mainly 200kg/m3), shoes that need to be lightweight become heavy.

② 합성고무 중합제조 과정에서 필수적으로 첨가하는 물질(예를 들어, Neoprene Rubber의 경우 톨루엔 및 염소성분 등)이 신발 완제품에서 검출되어 조만간 전 세계적으로 독성물질 사용규제 대상으로 지정될 예상임② Substances that are necessarily added during the polymerization process of synthetic rubber (e.g., toluene and chlorine in the case of Neoprene Rubber) have been detected in the finished shoe product, and are expected to be designated as toxic substance use restrictions worldwide in the near future.

③ 시장수급이 불안정하여 빈번히 문제가 발생③ Frequent problems due to unstable market supply and demand

④ 수급가격이 고가임④ Supply and demand prices are high

⑤ 고무 자체에 혐오성 나쁜 냄새 발생⑤ Repulsive bad smell is generated in the rubber itself

⑥ 통기성(Air Permeability)이 없어 장시간 착화 시나 걷거나 운동 시 땀이 차서 외부로 증기의 발산을 막아 불쾌감, 냄새 발생⑥ Due to the lack of air permeability, sweat builds up when wearing for a long time or when walking or exercising, preventing the release of steam to the outside, causing discomfort and odor.

이는 Neoprene Rubber 등을 사용한 적층 복합체를 신발 갑피의 발등, 발등 뒤 좌우부분 및 발뒤꿈치 등의 부위에 적용하면 본 복합체가 가진 내굴곡성, 복원성, 반발탄성 특성으로 걷거나 특히 조깅 시에 이들 부위에 [담김.인장↔원위치복원]력이 반복적으로 작용하여 갑피의 발등, 발등 뒤 좌우부분 및 발뒤꿈치 등의 부위를 적절히 조여 주기 때문에 소비자가 신발구입 초기 가졌던 사이즈, 착화감, 밀착감, 일체감을 착화 중에도 지속적으로 유지하게 하나, 발생한 땀과 수증기는 외부로 빠져 나가지 못하도록 반복적으로 조여 주기 때문에 되어 내외부 환기를 방해하여 불쾌감, 냄새의 원인이 됨When a laminated composite using Neoprene Rubber, etc. is applied to the instep of the shoe upper, left and right parts behind the instep, and heel, these composites have properties such as resistance to flexion, resilience, and resilience. .Tension ↔ restoration in place] force repeatedly acts to appropriately tighten the instep of the upper, the left and right parts behind the instep, and the heel, so that the size, fit, fit, and unity that consumers had at the beginning of shoe purchase are continuously maintained even during wearing. However, since it is repeatedly tightened to prevent sweat and steam from escaping to the outside, it interferes with internal and external ventilation, causing discomfort and odor.

⑦ 개개의 평판시트(통상 폭 x 길이 x 두께(조절가능) =100mm x 200mm x 2.0mm)로 공급되기 때문에 스판덱스 원단 등을 Neoprene Rubber 개개Sheet 앞뒷면에 접착.합포(Coating-Laminating)하여 3겹의 적층복합체(Triflex Composite) 가공공정에서 연속(Nonstop/Continuous) 생산이 불가하여 가공비 증가 및 수율이 저조함⑦ As each flat sheet is supplied (usually width x length x thickness (adjustable) = 100mm x 200mm x 2.0mm), spandex fabric, etc. is attached to the front and back of each sheet of Neoprene Rubber. Nonstop/Continuous production is not possible in the Triflex Composite processing process, resulting in increased processing cost and low yield.

(2) 잠수복 소재 합성고무 소재 적용 사례 및 문제점:(2) Application examples and problems of wetsuit material synthetic rubber:

바다나 물속을 잠수하는 사람이 착용하는 잠수복의 경우에도 신발용과 동일한 사례이며, 잠수복의 경우 사용상 필요한 특성이 착용감, 밀착감, 일체감, 보온성, 내굴곡성, 반발탄성, 복원성 등이나 신발 갑피 경우와 동일하게 오래 전부터 합성고무(예를 들어 Neoprene Rubber 등) 평판시트(통상 폭 x 길이 x 두께(조절가능) =100mm x 200mm x 2.0mm) 양면에 스판덱스 교직 원단 소재 등을 양면에 접착.합포(Coating-Laminating)하여 3겹의 적층복합체(Triflex Composite) 소재로 가공하여 이 소재를 잠수복의 소재로 사용해 왔으며, 신발 갑피용에서 사용하는 소재와 대부분 동일한 소재이다.In the case of wetsuits worn by people diving in the sea or water, the case is the same as for shoes. For a long time, synthetic rubber (for example, Neoprene Rubber, etc.) flat sheet (usual width x length x thickness (adjustable) = 100mm x 200mm x 2.0mm) is bonded to both sides of spandex woven fabric material, etc. on both sides. ) and processed into a three-layered Triflex Composite material, this material has been used as a material for wetsuits, and is mostly the same material as the material used for shoe uppers.

물론, 합성고무 소재의 탁월한 내굴곡성, 반발탄성 특성 외에 합성고무 자체가 가진 장점과 특성(이로 인해 고가이므로 특수 산업분야에서 선별적으로 사용 중임), 즉 내후성, 내유성, 내열성, 내약품성, 내마멸성, 저발열성, 내용제성, 내한성 등의 특성 경우 잠수복용에는 대부분 필요한 성질이나 특성이 아닐 뿐만 아니라 이로 인해 고비용을 지불하고 있고, 내굴곡성, 반발탄성 특성을 제외하고 아래와 같이 고질적이고도 근본적인 문제를 안고 있으나 이를 대체할 소재를 해결하지 못하고 있던 차에 잠수복의 경우에도 신발용과 동일한 소재를 사용하기 때문에 잠수복 분야에서도 대체 소재의 개발이 필요했던 것이다.Of course, in addition to the excellent bending resistance and resilience characteristics of synthetic rubber materials, the advantages and characteristics of synthetic rubber itself (because it is expensive, it is selectively used in special industries), namely weather resistance, oil resistance, heat resistance, chemical resistance, abrasion resistance, In the case of characteristics such as low heat resistance, solvent resistance, and cold resistance, not only are they not most necessary properties or characteristics for wetsuits, but they are paying high costs for this, and have chronic and fundamental problems as follows, except for bending resistance and resilience characteristics However, it was not possible to solve the material to replace it, and in the case of wetsuits, the same material used for shoes was used, so it was necessary to develop alternative materials in the field of wetsuits as well.

가. 잠수복 소재 합성고무 소재로써의 합성고무가 지닌 고질적인 문제점go. Chronic problems of synthetic rubber as a wetsuit material synthetic rubber material

① 합성고무 자체의 고비중(주로 200kg/m3)으로 경량화 해야 할 잠수복이 무거움① Due to the high specific gravity of synthetic rubber itself (mainly 200kg/m3), the wetsuit that needs to be lightened is heavy.

② 합성고무 제조과정에서 필수적으로 첨가한 물질(예를 들어 Neoprene Rubber의 경우 톨루엔 및 염소성분 등)이 잠수복 제품에서도 검출되어 조만간 전세계적으로 독성물질 사용규제 대상으로 지정될 예상임② Substances essential to the synthetic rubber manufacturing process (e.g., toluene and chlorine in the case of Neoprene Rubber) are also detected in wetsuit products, and are expected to be designated as toxic substance use regulations worldwide in the near future.

③ 안정적인 시장수급에 문제가 빈번히 발생③ Frequent problems in stable market supply and demand

④ 수급가격이 고가이며④ Supply and demand prices are high

⑤ 고무자체에 혐오성 나쁜 냄새 발생⑤ Repulsive bad smell occurs in rubber itself

⑥ 개개 평판시트(통상 폭 x 길이 x 두께(조절가능) =100mm x 200mm x 2.0mm)로 공급되므로 스판덱스 교직 원단 소재 등을 양면에 접착.합포(Coating-Laminating)하여 3겹의 적층복합체(Triflex Composite) 공정에서 연속(Nonstop/continuous) 가공이 불가하여 가공비 증가 및 수율 저조와 같은 문제점을 안고 있었던 것이다.⑥ Since it is supplied as an individual flat sheet (usually width x length x thickness (adjustable) = 100mm x 200mm x 2.0mm), 3 layers of laminated composite (Triflex) are applied by bonding and coating-laminating spandex woven fabric materials on both sides. Since nonstop/continuous processing was not possible in the composite process, it had problems such as increased processing cost and low yield.

KR 공개특허 10-2011-0056568KR Patent Publication 10-2011-0056568

이에 본 발명에서 제공하는 신발 및 의류 산업용 신소재 UHD PUF 제조방법은 신발 및 제화, 특수 의류산업 분야 등에서 사용해 오던 합성고무 소재(Neoprene Rubber 등)를 초고비중, 내굴곡성, 복원성 고 반발 탄성 특성을 가진 Polyurethane Slab Foam 소재로 대체할 수 있도록 한 신발 및 의류 산업용 초고비중의 특수 신소재 UHD PUF 제조방법을 제공코자 하는 것이다.Therefore, the manufacturing method of UHD PUF, a new material for the footwear and apparel industry provided by the present invention, uses synthetic rubber materials (Neoprene Rubber, etc.), which have been used in the footwear and shoemaking and special apparel industries, as Polyurethane, which has ultra-high specific gravity, bending resistance, resilience and high rebound elasticity. It is to provide a method for manufacturing UHD PUF, a special new material with high specific gravity for the footwear and clothing industry, which can be replaced with slab foam material.

또한, 본 발명은 내굴곡성, 반발탄성, 내후성, 내열성, 저발열성을 가진 초고비중의 특수 신소재 UHD PUF 소재를 제공하여 합성고무를 대체할 수 있도록 하며, 독성물질이 없고, 안정적인 시장수급, 비용이 저렴하며, 혐오성 나쁜 냄새 발생 없으며, 통기성 부여로 불쾌감, 냄새 발생이 없으며, 개개 평판시트를 가공하는 Neoprene Rubber 경우와는 달리 연속 생산 및 원재료 수율이 획기적으로 향상되어 원가절감, Neoprene Rubber 수급문제도 해소할 수 있도록 한 초고비중 특수 신소재 UHD PUF 제조방법을 제공코자 하는 것이다.In addition, the present invention provides a UHD PUF material, a special new material with high specific gravity with bending resistance, rebound resistance, weather resistance, heat resistance, and low heat generation, so that it can replace synthetic rubber, is free of toxic substances, has stable market supply and demand, and costs. It is inexpensive, does not generate an aversive bad odor, and does not generate unpleasant odor or odor due to breathability. Unlike the case of Neoprene Rubber, which processes individual flat sheets, continuous production and raw material yield are dramatically improved, reducing costs and Neoprene Rubber supply and demand problems. It is to provide a method for manufacturing UHD PUF, a special new material with high specific gravity, that can solve the problem.

본 발명의 신발 및 의류 산업용 특수 신소재 UHD PUF 제조방법은;The manufacturing method of UHD PUF, a special new material for the footwear and apparel industry of the present invention;

폴리올, 톨루엔 디이소시아네이트, 카본 블랙, 실리콘, 아민을 포함하는 원료를 입고하여 온도, 수량, 수입 검사하는 원료 입고 공정과;A raw material warehousing process of receiving raw materials including polyol, toluene diisocyanate, carbon black, silicon, and amine and inspecting temperature, quantity, and receipt;

상기 원료를 각 탱크에 투입하여 배합 및 첨가제를 투입하고, 각 탱크에 저장된 원료를 정밀, 자동 케미컬 메터링 펌프에 의해 연속, 자동으로 계량하여 밀폐 배관을 따라 연속 공급과 동시에 배합/토출기(헤드)에서 헤드가 고속 회전되면서 배합하는 공정과;The above raw materials are put into each tank to mix and add additives, and the raw materials stored in each tank are continuously and automatically metered by a precision, automatic chemical metering pump, continuously supplied along the sealed pipe and blended/discharger (head ) A step of blending while the head rotates at high speed;

상기 배합된 원료들은 고속 회전되는 배합/토출기에서 배합/토출과 동시에 정속으로 움직이는 오픈된 컨베이어에 옮겨 발포시켜 발포 블록을 제조하는 공정과;manufacturing a foam block by transferring the blended raw materials to an open conveyor moving at a constant speed while blending/discharging from a blender/discharger rotating at high speed;

상기 발포 블록을 일정 길이로 수직방향으로 재단 후 이동, 적재하는 공정과;Step of moving and stacking the foam block after cutting it in a vertical direction to a certain length;

상기 재단된 발포 블록을 최소 96시간 이상 숙성하는 숙성 공정과;an aging step of aging the cut foam block for at least 96 hours;

상기 숙성된 발포 블록을 고객의 요구 조건에 맞는 연속 일정한 두께로 수평방향으로 재단하는 공정과;a step of horizontally cutting the aged foam block to a continuous constant thickness that meets customer requirements;

상기 재단된 제품을 불량 선별 후 포장, 상차, 출고하는 공정을 포함하는 것을 특징으로 한다.It is characterized in that it includes a process of packaging, loading, and shipping after screening the cut product as defective.

또한, 상기 발포 공정 시 발포 온도는 27±5℃, 압력은 1±0.5bar(오픈된 대기압하)로 이루어지는 것을 특징으로 한다.In addition, during the foaming process, the foaming temperature is 27±5° C. and the pressure is 1±0.5 bar (under open atmospheric pressure).

본 발명에서 제공하는 신발 및 의류 산업용 초고비중, 특수 신소재 UHD PUF 제조방법은 다음과 같은 다수의 효과를 제공한다.The ultra-high specific gravity, special new material UHD PUF manufacturing method for the footwear and apparel industry provided by the present invention provides a number of effects as follows.

① 합성고무(예를 들어 Neoprene Rubber 등)가 가진 탁월한 내굴곡성, 반발탄성, 내후성, 내열성, 저발열성을 가진 초고비중(약 100-170kg/m3) 특수 신소재 UHD PUF 소재를 개발, 합성고무를 대체함.① Developed ultra-high specific gravity (approximately 100-170kg/m3) special new UHD PUF material with excellent bending resistance, rebound elasticity, weather resistance, heat resistance, and low heat generation properties of synthetic rubber (eg Neoprene Rubber, etc.), and synthetic rubber Replaced.

② 신발 완제품에서 검출될 수 있는 규제대상 독성물질 없음.② No toxic substances subject to regulation that can be detected in finished shoes.

③ 안정적인 시장수급 가능.③ Stable market supply and demand.

④ 합성고무 대비 수급비용 저렴 및 피로도 우수.④ Low supply cost and excellent fatigue compared to synthetic rubber.

⑤ 소재 자체에 혐오성 나쁜 냄새 발생 없음.⑤ No repulsive or bad smell in the material itself.

⑥ 통기성(Air Permeability) 부여가 가능하므로 장시간 착화 시나 걷거나 운동 시 땀과 증기가 외부로 발산되어 불쾌감, 냄새 발생 없음⑥ Air permeability is provided, so sweat and steam are emitted outside during long hours of wearing or walking or exercising, so there is no discomfort or odor.

⑦ 연속 Slab Foam 생산 공정 특성으로 수요자의 요구길이 만큼 이음 매듭이 없는 연속 롤(Roll)단위 공급이 가능하기 때문에 스판덱스 교직 원단 소재 등을 양면에 접착.합포(Coating-Laminating)하여 3겹의 적층복합체(Triflex Composite) 가공 공정에서 연속(Nonstop/continuous) 생산이 가능하며 원재료 수율이 획기적으로 향상됨⑦ Due to the characteristics of the continuous slab foam production process, it is possible to supply a continuous roll unit without a joint knot as long as the length requested by the consumer, so it is a 3-layer laminated composite by bonding and coating-laminating spandex woven fabric materials on both sides. (Triflex Composite) Nonstop/continuous production is possible in the processing process, and the yield of raw materials is dramatically improved.

또한, 합성고무가 지닌 고질적인 문제점 해결은 물론, Neoprene Rubber보다 중량이 낮은 소재로 제품의 무게를 낮추는 효과와 함께 원가절감에도 기여할 뿐만 아니라, 불안정한 Neoprene Rubber 수급문제 해소에도 크게 기여할 수 있는 것이다.In addition, it not only solves the chronic problems of synthetic rubber, but also contributes to cost reduction with the effect of lowering the weight of the product as a material with a lower weight than neoprene rubber, and can greatly contribute to solving the unstable neoprene rubber supply and demand problem.

도 1은 본 발명에서 제공하는 신발 및 의류 산업용 초고비중 특수 신소재 UHD PUF 제조방법의 바람직한 일 실시 예를 보인 전체 공정 블록도
도 2는 본 발명에서 제공하는 신발 및 의류 산업용 초고비중 특수 신소재 UHD PUF 제조방법의 바람직한 일 실시예를 보인 전체 공정 사진 및 블록도
1 is an overall process block diagram showing a preferred embodiment of a method for manufacturing UHD PUF, a special new material with high specific gravity for the footwear and apparel industry provided by the present invention.
Figure 2 is a photograph and block diagram of the entire process showing a preferred embodiment of the UHD PUF manufacturing method, a special new material with high specific gravity for the footwear and clothing industry provided by the present invention.

이하에서 첨부된 도면을 참조하여 본 발명의 실시를 위한 구체적인 내용을 설명한다. 그리고 본 발명을 설명함에 있어서 관련된 공지기능에 대하여 이 분야의 기술자들에게 자명한 사항으로서 본 발명의 요지를 불필요하게 흐릴 수 있다고 판단되는 경우에는 그 상세한 설명을 생략한다. Hereinafter, specific details for the practice of the present invention will be described with reference to the accompanying drawings. In addition, in the description of the present invention, if it is determined that the related known function may unnecessarily obscure the subject matter of the present invention as an obvious matter to those skilled in the art, the detailed description thereof will be omitted.

본 명세서에서 사용되는 정도의 용어 "약", "실질적으로" 등은 언급된 의미에 고유한 제조 및 물질 허용오차가 제시될 때 그 수치에서 또는 그 수치에 근접한 의미로 사용되고, 본 발명의 이해를 돕기 위해 정확하거나 절대적인 수치가 언급된 개시 내용을 비양심적인 침해자가 부당하게 이용하는 것을 방지하기 위해 사용된다.As used herein, the terms "about," "substantially," and the like are used in a sense at or approximating that number when manufacturing and material tolerances inherent in the stated meaning are given, and do not convey an understanding of the present invention. Accurate or absolute figures are used to help prevent exploitation by unscrupulous infringers of the disclosed disclosure.

본 발명에서 제공하는 신발 및 의류 산업용 초고비중 특수 신소재 UHD PUF 제조방법은 합성고무 소재를 대체 할 수 있는 것으로, 합성고무(예를 들어 Neoprene Rubber 등)가 가진 탁월한 내굴곡성, 반발탄성, 내후성, 내열성, 저발열성을 가진 초고비중(약 100-170kg/m3) 특수 신소재 UHD PUF를 제공토록 한 것을 특징으로 한다.The manufacturing method of UHD PUF, a special new material with high specific gravity for the footwear and apparel industry provided by the present invention, can replace synthetic rubber materials, and has excellent bending resistance, rebound elasticity, weather resistance, and heat resistance of synthetic rubber (eg Neoprene Rubber, etc.) , It is characterized by providing ultra-high specific gravity (about 100-170kg/m3) special new material UHD PUF with low heat generation.

또한, 신발 완제품에서 검출될 수 있는 규제대상 독성물질이 없으며, 안정적인 시장수급이 가능하고, 합성고무 대비 수급비용이 저렴하다.In addition, there are no regulated toxic substances that can be detected in the finished shoe product, stable market supply and demand is possible, and supply and demand costs are lower than synthetic rubber.

그리고 소재 자체에 혐오성 나쁜 냄새 발생이 없고, 통기성(Air Permeability) 부여가 가능하므로 장시간 착화 시나 걷거나 운동 시 땀과 증기가 외부로 발산되어 불쾌감, 냄새 발생이 없다.In addition, since the material itself does not generate an aversive bad smell and can be given air permeability, sweat and steam are emitted to the outside during long-term ignition, walking or exercise, so there is no discomfort or odor.

또한, 일정한 요구 두께의 연속 Slab Foam 생산공정 특성으로 수요자의 요구길이 만큼 이음 매듭이 없는 연속 롤(Roll) 단위 공급이 가능하기 때문에 스판덱스 교직 원단 소재 등을 양면에 접착.합포(Coating-Laminating)하여 3겹의 적층복합체 (Triflex Composite) 가공공정에서 연속(Nonstop/continuous) 생산이 가능하며 원재료 수율이 획기적으로 향상되는 특징을 갖는다.In addition, due to the continuous slab foam production process characteristics of a certain required thickness, it is possible to supply continuous roll units without joint knots as much as the length requested by the consumer, so spandex woven fabric materials are bonded to both sides and coated-laminated. Nonstop/continuous production is possible in the 3-ply layered composite (Triflex Composite) processing process, and the yield of raw materials is dramatically improved.

도 1, 2는 본 발명에서 제공하는 신발 및 의류 산업용 초고비중 특수 신소재UHD PUF 제조방법의 바람직한 일 실시예를 보인 전체 공정도로서, 이들 도면과 함께 본 발명의 제조방법을 설명키로 한다.1 and 2 are overall process diagrams showing a preferred embodiment of a method for manufacturing UHD PUF, a special new material with high specific gravity for the footwear and apparel industry provided by the present invention, and the manufacturing method of the present invention will be described together with these drawings.

1. 원료 입고1. Receipt of raw materials

원부자재로 폴리올, 톨루엔 디이소시아네이트, 카본 블랙, 실리콘, 아민 등 수종을 입고하여 온도, 수량, 수입검사를 실시한다.Several types of raw and subsidiary materials, such as polyol, toluene diisocyanate, carbon black, silicon, and amine, are received and inspected for temperature, quantity, and import.

상기 원료의 성상은 액체이며, 외견, 색상 로트 No, 고형분, 점도 등을 표준규격 및 종전 입고 로트와 비교 측정한다.The properties of the raw material are liquid, and the appearance, color lot No., solid content, viscosity, etc. are compared and measured with standard specifications and previous warehousing lots.

2. 배합2. Formulation

각 탱크에 원료를 배합하고, 첨가제를 투입한다.Raw materials are blended in each tank, and additives are introduced.

각 탱크에 구분 저장된 원료를 각 탱크 마다 설치되어 있는 정밀, 자동 케미컬 메터링 펌프에 의해 연속, 자동으로 계량(metering)하면서 밀폐 배관을 따라 동시에 배합/토출기(헤드)에 도착한 후 헤드가 고속회전 되면서 원료의 배합이 이루어진다.Raw materials stored separately in each tank are continuously and automatically metered by precision and automatic chemical metering pumps installed in each tank, and simultaneously arrive at the mixer/discharger (head) along the sealed pipe, and the head rotates at high speed The mixing of raw materials takes place.

이때 주 원료인 폴리올, 톨루엔 디이소시아네이트 외의 원료로 블로잉(Blowing) 상태, 셀 사이즈(cell size) 조정, 숙성속도 등을 조정한다.At this time, the blowing state, cell size adjustment, aging rate, etc. are adjusted with raw materials other than polyol and toluene diisocyanate, which are the main raw materials.

원료의 배합 온도는 27±5℃에서 배합되며, 배합/토출기에서 순간적으로 배합이 이루어진다.The blending temperature of raw materials is blended at 27±5°C, and blending is done instantaneously in the blender/discharge machine.

3. 발포3. Foaming

배합된 원료들은 고속 회전되는 배합/토출기에서 토출되어 정속으로 움직이는 오픈된 컨베이어에 옮겨지면서 발포가 이루어져 발포 블록이 제조된다.Mixed raw materials are discharged from a mixer/discharger rotating at high speed and moved to an open conveyor moving at a constant speed, whereby foaming is performed to manufacture a foamed block.

발포 시 온도는 27±5℃, 압력은 1±0.5bar(오픈된 대기압하)이다.When foaming, the temperature is 27±5℃ and the pressure is 1±0.5 bar (under open atmospheric pressure).

상기 발포작업 시 핀홀(Pin hole)과 원료액 흐름 상태를 주의 깊게 관리한다.During the foaming operation, carefully manage the pin hole and the flow state of the raw material solution.

즉, 믹싱 헤드(Mixing Head) 토출부 기포(Pin hole)관찰과 더불어 경화속도를 관찰하여 원료액의 쳐짐을 주의토록 하며, 컨베이어 스피드를 살펴 액 겹침을 주의토록 한다.In other words, pay attention to sagging of the raw material solution by observing the pin hole of the mixing head discharge part and observing the curing speed, and pay attention to the overlapping of the liquid by looking at the conveyor speed.

4. 초고비중 특수 신소재 UHD PUF 가공공정4. UHD PUF processing process, a special new material with high specific gravity

(1) 재단 및 적재(1) Cutting and stacking

발포 블록을 길이별로 재단한다.Cut the foam block by length.

발포된 동일 로트의 연속 발포 블록을 일정 길이(표준 50±2m)로 수직방향으로 재단 후 재단된 개별 발포 블록을 호이스트로 이동 후 적재한다. 로트별 발포 블록 외관 및 표면 상태를 육안으로 확인 관리토록 한다.After cutting the foamed continuous foam blocks of the same lot in the vertical direction to a certain length (standard 50±2m), the cut individual foam blocks are moved to a hoist and loaded. Visually check and manage the appearance and surface condition of foam blocks for each lot.

(2) 숙성(2) Aging

재단된 발포 블록을 96시간 이상 숙성한다.The cut foam block is aged for 96 hours or more.

숙성 공정은 액체 상태의 제품이 형태 안정성을 유지하는 고체화되는 과정으로 외기에 오픈된 상태에서 이루어진다.The aging process is a process in which a product in a liquid state is solidified while maintaining shape stability, and is performed in an open state.

(3) 재단(3) foundation

숙성된 발포 블록을 고객의 요구 조건에 맞는 두께로 수평방향으로 재단한다.The aged foam block is cut in the horizontal direction to the thickness that meets the customer's requirements.

(4) 포장 및 이동 적재, 출고(4) Packing and moving, loading and shipping

로트별 오염, 주름, 접힘 등 외관 상태를 육안 확인하여 불량을 선별한 후 완제품을 포장한다.Visually check the appearance of each lot, such as contamination, wrinkles, and folds, select defects, and then pack the finished product.

포장된 완제품을 적재 장소로 이동하여 로트별 포장재의 찢김, 외관상태 등 손상을 확인한다.Move the packaged finished product to the loading area and check for damage such as tearing of the packing material for each lot and appearance condition.

로트별 아이템 및 규격별로 적재 후 최종 점검을 마친 후 출고 차량에 상차하여 출고한다.After loading by item and size by lot and final inspection, it is loaded onto the delivery vehicle and shipped.

이상과 같이 구성되는 본 발명은 탁월한 내굴곡성, 반발탄성, 내후성, 내열성, 저발열성을 가진 초고비중의 특수 신소재 UHD PUF 소재를 제공하여, 신발 갑피용 Neoprene Rubber 등과 같은 합성고무를 대체할 수 있으며, 신발 완제품에서 검출될 수 있는 규제대상 독성물질이 없으며, 안정적인 시장수급이 가능하고, 합성고무 대비 수급비용이 저렴하며 제품의 경량화 실현도 가능하다.The present invention configured as described above provides a special new UHD PUF material with excellent bending resistance, rebound resistance, weather resistance, heat resistance, and low heat generation, and can replace synthetic rubber such as Neoprene Rubber for shoe uppers. , There are no toxic substances subject to regulation that can be detected in the finished shoe product, stable market supply and demand is possible, and supply and demand costs are lower than synthetic rubber, and it is possible to realize lightweight products.

그리고 소재 자체에 혐오성 악취 발생이 없을 뿐만 아니라, 통기성을 제공하여 장시간 착화 시 땀과 증기가 외부로 발산되어 불쾌감, 냄새 발생이 없다.In addition, the material itself does not generate an aversive odor, and provides breathability, so that sweat and steam are emitted to the outside during long-term ignition, so there is no discomfort or odor.

또한, 연속 Slab Foam 생산 공정 특성으로 수요자의 두께 및 요구길이 만큼 이음 매듭이 없는 연속 롤(Roll)단위 공급이 가능하기 때문에 스판덱스 교직 원단 소재 등을 양면에 접착.합포(Coating-Laminating)하여 3겹의 적층복합체(Triflex Composite) 재단 및 가공공정에서 연속(Nonstop/continuous) 생산이 가능하며 원재료 수율이 획기적으로 향상되는 것이다.In addition, due to the characteristics of the continuous slab foam production process, it is possible to supply continuous roll units without joint knots as much as the thickness and length requested by the consumer, so that spandex woven fabric materials are bonded to both sides and coated-laminated to form 3 layers. Nonstop/continuous production is possible in the cutting and processing process of Triflex Composite, and the yield of raw materials is dramatically improved.

이상과 같이 본 발명의 상세한 설명에는 신발 및 의류 산업용 초고비중의 특수 신소재 UHD PUF 제조방법의 가장 바람직한 실시 예에 관하여 설명하였으나, 본 발명의 기술범위에 벗어나지 않는 범위 내에서는 다양한 변형실시도 가능하다 할 것이다. 따라서 본 발명의 보호범위는 상기 실시 예에 한정하여 정하여 질 것이 아니라 후술하는 특허청구 범위의 기술들과 이들 기술로부터 균등한 기술수단들에까지 보호범위가 인정되어야 할 것이다.As described above, in the detailed description of the present invention, the most preferred embodiment of the method for manufacturing UHD PUF, a special new material with high specific gravity for the footwear and clothing industry, has been described, but various modifications are possible within the scope of the present invention. will be. Therefore, the scope of protection of the present invention should not be limited to the above embodiments, but the scope of protection should be recognized from the techniques of the claims to be described later and from these techniques to equivalent technical means.

Claims (2)

폴리올, 톨루엔 디이소시아네이트, 카본 블랙, 실리콘, 아민을 포함하는 원료를 입고하여 온도, 수량, 수입 검사하는 원료 입고 공정과;
상기 원료를 각 탱크에 투입하여 배합 및 첨가제를 투입하고, 각 탱크에 저장된 원료를 정밀, 자동 케미컬 메터링 펌프에 의해 연속, 자동으로 계량하며 밀폐 배관을 따라 동시에 배합/토출기에 도착한 후 고속회전에 의해 배합하는 공정과;
상기 배합된 원료들은 고속 회전되는 배합/토출기에서 토출되어 정속으로 움직이는 오픈된 컨베이어에 옮겨 발포시켜 발포 블록을 제조하는 발포 공정과;
상기 발포 블록을 일정 길이로 수직방향으로 재단 후 이동, 적재하는 공정과;
상기 재단된 발포 블록을 96시간 이상 숙성하여 고체화시키는 숙성 공정과;
상기 숙성된 발포 블록을 고객의 요구 조건에 맞는 두께로 수평방향으로 재단하는 공정과;
상기 재단된 완제품을 불량 선별 후 포장하여 출고하는 공정을 포함하는 것을 특징으로 하는 신발 및 의류 산업용 초고비중 특수 신소재 UHD PUF 제조방법.
A raw material warehousing process of receiving raw materials including polyol, toluene diisocyanate, carbon black, silicon, and amine and inspecting temperature, quantity, and receipt;
The above raw materials are put into each tank to mix and add additives, and the raw materials stored in each tank are continuously and automatically metered by a precision, automatic chemical metering pump, and simultaneously arrive at the mixer/discharger along the sealed pipe and rotate at high speed a step of blending by;
A foaming step of manufacturing a foam block by transferring the blended raw materials from a blender/discharger rotating at high speed and moving to an open conveyor moving at a constant speed to foam;
Step of moving and stacking the foam block after cutting it in a vertical direction to a certain length;
An aging step of solidifying the cut foam block by aging for 96 hours or more;
a step of horizontally cutting the aged foam block to a thickness that meets customer requirements;
A method for manufacturing UHD PUF, a special new material with high specific gravity for the footwear and clothing industry, comprising a step of packaging and shipping the cut finished product after screening for defects.
제 1 항에 있어서;
상기 원료의 배합은 27±5℃의 온도에서 이루어지며,
상기 발포 공정 시 발포 온도는 27±5℃, 압력은 1±0.5bar로 이루어지는 것을 특징으로 신발 및 의류 산업용 초고비중 특수 신소재 UHD PUF 제조방법.
According to claim 1;
The mixing of the raw materials is performed at a temperature of 27 ± 5 ° C,
During the foaming process, the foaming temperature is 27 ± 5 ° C and the pressure is 1 ± 0.5 bar. UHD PUF manufacturing method, a special new material with high specific gravity for the footwear and clothing industry.
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