KR20230038898A - Lithium metal anode for lithium secondary battery, method of preparing the same and lithium secondry battery using the same - Google Patents

Abstract

The present embodiments relate to a lithium metal electrode for a secondary battery, a manufacturing method thereof, and a secondary battery including the same. According to one embodiment, provided is a lithium metal electrode for a secondary battery including: a current collector; and a metal layer positioned on at least one surface of the current collector and including a lithium component, wherein a protective layer including amorphous carbon and electronic insulating ceramic particles is formed on the surface of the metal side.

Description

Lithium metal electrode for secondary battery, manufacturing method thereof, and lithium secondary battery including the same

The present embodiments relate to a lithium metal electrode for a secondary battery, a manufacturing method thereof, and a lithium secondary battery including the same.

Recently, thanks to the explosive demand of electric vehicles and the demand for increased mileage, the development of secondary batteries having high capacity and high energy density to meet this demand is actively progressing around the world.

In order to reduce the price of a secondary battery and improve its high energy density, it has been proposed to use a lithium metal electrode as a negative electrode of a lithium secondary battery.

In order to form such a lithium metal negative electrode, a method of rolling a lithium foil on a current collector is generally used. However, in the case of rolling, it is difficult to implement a lithium metal negative electrode having a thickness of 20 μm or less.

Meanwhile, in order to substantially implement a secondary battery having a high energy density using a lithium metal negative electrode, a lithium metal negative electrode having a thickness of 10 to 20 μm is required.

However, when lithium metal is used as an anode in an all-solid-state battery, a high-resistance phase is generated by the reaction between lithium and the all-solid electrolyte, and lithium dendrites are continuously generated due to local non-uniformity of current density during the charging and discharging process. As lithium by-products of resistance are generated, a short circuit or overvoltage during charging and discharging causes a failure or lowers the capacity.

In order to solve this problem, various methods have been proposed, such as forming a protective coating layer on lithium metal or forming a lithium alloy layer for the purpose of preventing the reaction with the all-solid-state battery and the precipitation growth of lithium dendrites. (EV) has not obtained sufficient life characteristics at a level that can be used.

In order to satisfy these demands, research on secondary batteries using a non-cathode coating layer in which amorphous carbon and silver (Ag) nanoparticles are mixed is used to precipitate lithium during charging and discharging processes is actively conducted.

However, during the charging and discharging process, materials having electronic conductivity such as lithium-based alloys or lithium-containing compounds are generated in the non-cathode coating layer or at the interface, causing current concentration and lithium dendrites, thereby shortening the lifespan. .

In addition, there is a problem in that the initial Coulombic efficiency is low due to the problem of an irreversible reaction by amorphous carbon, which is the main material of the non-cathode coating layer.

In order to solve this problem, not only a sacrificial anode is used, but also price competitiveness is greatly reduced due to the use of a large amount of noble metal nanoparticles, so commercialization is difficult.

Therefore, the development of a technology capable of manufacturing an electrode having excellent initial efficiency and excellent charge/discharge characteristics is required.

In this embodiment, it is intended to provide a lithium metal electrode for a secondary battery that prevents dendrite formation by a protective layer included in the electrode layer and has excellent charge and discharge characteristics, a manufacturing method thereof, and a lithium secondary battery including the same.

A lithium metal electrode for a secondary battery according to an embodiment includes a current collector, a metal layer positioned on at least one surface of the current collector, and containing a lithium alloy, and a protective layer positioned on the metal layer, wherein the protective layer is Amorphous carbon and electronic insulating ceramic particles may be included.

According to the present embodiment, by including electronic insulating ceramic particles in the electronic insulating protective layer and forming a lithium-containing metal layer between the electronic insulating protective layer and the current collector, the problem of deterioration in initial Coulombic efficiency is solved and the charging and discharging characteristics are remarkably improved. can be improved

1 schematically shows a lithium metal electrode manufactured according to an embodiment.
2 schematically shows a lithium metal electrode according to another embodiment.
3 schematically illustrates a method of manufacturing a lithium metal electrode for a secondary battery according to an embodiment.
4 is a SEM photograph showing a cross section of a current collector on which an alloy material coating layer is formed in the process of manufacturing a lithium metal electrode according to Example 1.
5 is a SEM photograph showing a cross-section of a current collector in which an alloy material coating layer and an electronic insulating protective layer are formed in the process of manufacturing a lithium metal electrode according to Example 1.
6a, 6b, 6c, and 6d are SEM images showing cross-sections of lithium metal electrodes prepared according to Example 1 and Comparative Examples 1 to 3.
7a, 7b, 8a, 8b, 9a, 9b, 10a and 10b are photographs showing surface microstructure and component analysis results of lithium metal electrodes prepared according to Example 1 and Comparative Examples 1 to 3.
11 is a view showing results of evaluating initial effects of secondary batteries manufactured according to Example 1 and Comparative Examples 1 to 3;
12 is a view showing the results of evaluating the charge/discharge lifespan of secondary batteries manufactured according to Example 1 and Comparative Examples 1 to 3;
13 is a view showing the results of evaluating the charge and discharge lifespan of the secondary batteries manufactured according to Examples 1 to 4 and Comparative Example 2.
14 is a schematic diagram of a secondary battery to which a lithium metal electrode manufactured according to the present invention is applied.

Terms such as first, second and third are used to describe, but are not limited to, various parts, components, regions, layers and/or sections. These terms are only used to distinguish one part, component, region, layer or section from another part, component, region, layer or section. Accordingly, a first part, component, region, layer or section described below may be referred to as a second part, component, region, layer or section without departing from the scope of the present invention.

The terminology used herein is only for referring to specific embodiments and is not intended to limit the present invention. As used herein, the singular forms also include the plural forms unless the phrases clearly indicate the opposite. The meaning of "comprising" as used herein specifies particular characteristics, regions, integers, steps, operations, elements and/or components, and the presence or absence of other characteristics, regions, integers, steps, operations, elements and/or components. Additions are not excluded.

When a part is referred to as being “on” or “on” another part, it may be directly on or on the other part or may be followed by another part therebetween. In contrast, when a part is said to be “directly on” another part, there is no intervening part between them.

Although not defined differently, all terms including technical terms and scientific terms used herein have the same meaning as commonly understood by those of ordinary skill in the art to which the present invention belongs. Terms defined in commonly used dictionaries are additionally interpreted as having meanings consistent with related technical literature and currently disclosed content, and are not interpreted in ideal or very formal meanings unless defined.

Hereinafter, embodiments of the present invention will be described in detail. However, this is presented as an example, and the present invention is not limited thereby, and the present invention is only defined by the scope of the claims to be described later.

1 schematically shows a lithium metal electrode manufactured according to one embodiment, FIG. 2 schematically shows a lithium metal electrode according to another embodiment, and FIG. 3 shows a lithium metal electrode for a secondary battery according to an embodiment. The manufacturing method is schematically shown.

Referring to FIG. 1 , a lithium metal electrode 100 for a secondary battery according to an embodiment includes a current collector 11 and a metal layer 12 positioned on at least one surface of the current collector 11, and also, A protective layer 30 positioned on the other surface of the metal layer 12 facing the current collector 11 is included.

The current collector 11 is for electrical connection in a lithium secondary battery.

The current collector 11 may have a form of a foil, but is not limited thereto, and may include, for example, a mesh, a foam, a rod, a wire, and a wire rod. It may also have a form of a sheet in which (wire, fiber) is woven.

As a material for the current collector 11 , a material having electrical conductivity and limited reaction with lithium may be used. As the material of the current collector 11, for example, a conductive layer on copper, nickel, titanium, stainless steel, gold, platinum, silver, tantalum, ruthenium, alloys thereof, carbon, conductive polymer, and non-conductive polymer Any one or a combination of these coated composite fibers may be used.

If the thickness of the current collector 11 is thick, the weight of the battery increases and the energy density of the battery decreases. If the thickness of the current collector 11 becomes thin, there is a risk of overheating and damage during high current operation, and the battery manufacturing process may be damaged. Accordingly, the thickness of the current collector 11 may range from 1 μm to 50 μm.

The metal layer 12 is positioned on the current collector 11 and includes a lithium alloy layer 21 including a lithium alloy and a lithium metal layer 41 positioned on the lithium alloy layer 21 . Here, the lithium alloy layer 21 is formed by applying a current between the current collector 11 and the lithium supply source to form an alloy of lithium-friendly components included in the coating layer of the current collector 11 and lithium deposited from the lithium supply source. It may be a layer containing an alloy. When the electrodeposition process is performed by applying a high current in order to increase the rate of electrodeposition when forming the metal layer, there is a problem in that the performance of the lithium secondary battery is deteriorated. However, when the metal layer 12 is formed with a structure including the lithium alloy layer 21 containing a lithium component as in the present embodiment, even when the electrodeposition process is performed by applying a high current, an excessive amount of fine lithium particles are generated or electrodeposited It is possible to prevent the destruction of the coating, which is the surface protective layer of the lithium metal layer already generated in the process.

More specifically, since the metal layer 12 of the present embodiment includes a lithium alloy layer containing a lithium component, when a lithium metal layer is formed on the lithium alloy layer by applying a high current in an electrodeposition process, initially generated lithium particles is induced to grow well, so that particles having a coarse structure are formed, and at the same time, the lithium metal layer, consequently, the metal layer 12 can have a uniform surface.

Therefore, the performance of the secondary battery to which the lithium metal electrode according to the present embodiment is applied, specifically, the charge/discharge characteristics can be remarkably improved. In addition, since a high-performance lithium metal electrode for a secondary battery can be manufactured even when the electrodeposition process is performed at a high speed by applying a high current, productivity of the lithium metal electrode for a secondary battery can be significantly improved.

The lithium alloy layer 21 may be an alloy made of lithium and a lithium-friendly metal, wherein the lithium-friendly metal may be at least one selected from the group consisting of In, Ag, Sn, Zn, Si, Al, and Bi. However, it is not limited thereto.

In this embodiment, the lithium alloy layer includes a lithium-friendly metal. In this way, when the lithium alloy layer includes a lithium-friendly metal, since electrons are smoothly supplied from the current collector and lithium ions are reduced, electrodeposition of the lithium metal layer is easily performed because the lithium alloy layer includes a lithium-friendly metal having high electronic conductivity. .

The thickness of the metal layer 12 may be in the range of 1 μm to 100 μm, more specifically, 5 μm to 30 μm.

If the thickness of the metal layer 12 is too thick, when the lithium metal electrode of this embodiment is applied to a secondary battery, there is a problem in that the energy density is lowered due to the increase in weight and volume of the battery. In addition, since the time and cost of the electrodeposition process increases in proportion to the thickness when forming the metal layer 12, the thickness of the metal layer 12 is preferably 100 μm or less.

In addition, if the thickness of the metal layer 12 is too thin, when the lithium metal electrode of this embodiment is applied to a secondary battery, there is a problem in that the charge/discharge life of the battery is reduced. Specifically, during charging and discharging of the battery, lithium in the battery is gradually consumed due to a side reaction between lithium contained in the negative electrode active material layer, that is, the metal layer of the present invention, and the electrolyte, and the battery capacity is reduced. However, when the thickness of the metal layer 12 is thin, the amount of lithium that can replenish the lithium consumed during charging and discharging is reduced, and thus the charge and discharge lifespan of the battery is reduced. Therefore, the thickness of the metal layer 12 is preferably 1 μm or more.

The protective layer 30 is located on the metal layer 12 and includes amorphous carbon and electronic insulating ceramic particles.

When lithium metal is used as an anode in an all-solid-state battery, high resistance is generated by the reaction between the all-solid electrolyte and lithium, and lithium dendrites are continuously generated due to local non-uniformity of current density during the charging and discharging process. As the by-product is generated, a short circuit or overvoltage during charging and discharging causes a failure or lowers the battery capacity.

However, as in the present embodiment, the protective layer including amorphous carbon and electronically insulating ceramic particles can further improve structural safety as well as output characteristics and lifetime characteristics of the lithium metal electrode.

More specifically, since the lithium metal electrode of the present embodiment includes the protective layer 30 including amorphous carbon and electronic insulating ceramic particles, it is possible to promote the movement of lithium ions on the electrode surface during charging and discharging, and the interface It is possible to suppress the generation of electron conductive materials in In addition, it may play a role of reducing the electronic conductivity of the inside of the protective layer 30 .

Therefore, the performance of the secondary battery to which the lithium metal electrode according to the present embodiment is applied, specifically, the output characteristics and lifespan characteristics of the battery can be remarkably improved.

The amorphous carbon may be at least one selected from the group consisting of acetylene black, super P black, carbon black, denka black, activated carbon, graphite, hard carbon, and soft carbon. However, it is not limited thereto.

In addition, the electronically insulating ceramic particles may be at least one selected from the group consisting of particles having low electronic conductivity, such as BN, AlN, C ₃ N ₄ , SiC, and Al ₂ O ₃ , but are not limited thereto.

In this embodiment, the average particle size D (50) of the electronic insulating ceramic particles may be in the range of 100 nm to 1,000 nm. When the average particle size D (50) of the electronic insulating ceramic particles is less than 100 nm, there may be a problem of non-uniform distribution of ceramic particles in the coating layer due to aggregation between primary particles, and when it is larger than 1,000 nm, the large particles resist It acts as a layer, and there may be a problem of lowering the lithium ion conductivity.

In addition, the electronically insulating ceramic particles may be configured in a plate shape, but are not limited thereto. When the ceramic particles are in the form of a plate, the bonding strength of the metal layer 12 and the protective layer 30 are increased due to the increase in wettability, thereby increasing the mechanical bonding between the metal layer 12 and the protective layer 30, thereby improving the performance of the lithium metal electrode. advantageous to

The electronic insulating protective layer may include a weight ratio of amorphous carbon and electronic insulating ceramic particles in a range of 99.5:0.5 to 40:60. Specifically, it may include 98.5:1.5 to 50:50, and more specifically, it may include 97:3 to 70:30.

If too few electronically insulating ceramic particles are mixed, the effect of inhibiting the formation of electronically conductive substances due to the mixing of the electronically insulating ceramic particles cannot be sufficiently obtained, and if too many electronically insulating ceramic particles are mixed, the resistance of the entire coating layer becomes too large, preventing lithium ion conduction. There are problems that hinder it.

Meanwhile, the protective layer of this embodiment may include a binder.

In this case, the binder may be an aqueous binder, and the aqueous binder may include a rubber-based binder selected from the group consisting of acrylonitrile-butadiene rubber, styrene-butadiene rubber (SBR) and acrylic rubber, and hydroxy It may be at least one selected from the group consisting of polymer resins such as ethyl cellulose, carboxymethyl cellulose and polyvinylidene fluoride, but is not limited thereto.

Here, the binder may be added in an amount of 1 to 15 parts by weight, more specifically 3 to 10 parts by weight, based on the weight of the slurry formed by mixing the electronically insulating ceramic particles, amorphous carbon, and water.

When the added amount of the binder satisfies the above range, a protective layer with excellent performance is formed by efficiently binding the particles constituting the protective layer without causing a decrease in battery energy density due to an increase in weight and volume, thereby forming a secondary battery. life characteristics can be further improved. If the amount of the binder is mixed too little, there is a problem in that the bonding strength between particles decreases in forming the protective layer, and if the amount of the binder is mixed too much, the energy density not only decreases, but also the resistance of the protective layer increases significantly, leading to lithium ion conduction. There is a problem that hinders

The thickness of the protective layer including the amorphous carbon, the electronic insulating ceramic particles, and the binder may range from 0.01 μm to 50 μm, more specifically from 1 μm to 20 μm. When the thickness of the protective layer satisfies the above range, it is possible to suppress the generation of electronically conductive materials at the interface, which is an effect obtained by including the above-described amorphous carbon and electronic insulating ceramic particles, and to reduce the electronic conductivity inside the protective layer. do. On the other hand, if the thickness of the protective layer containing amorphous carbon and electronically insulating ceramic particles is too thin, it cannot function as a protective layer. On the other hand, if the thickness of the protective layer is too thick, the resistance of the protective layer is too large, causing an increase in overvoltage during operation of the secondary battery, and also causing a decrease in energy density of the battery due to an increase in weight and volume. . However, the thickness of the protective layer may be variably adjusted according to the design of the secondary battery structure.

Meanwhile, although not shown, the metal layer 12 of the present embodiment may further include a solid-electrolyte interphase (SEI) layer positioned on the surface of the metal layer 12 .

The film layer is formed in the process of manufacturing the metal layer 12 by a reaction between the lithium metal of the electrodeposited lithium source and the plating solution, etc., and the thickness, composition, characteristics, etc. of the film are adjusted by adjusting the composition of the plating solution used and the conditions of the electrodeposition process. You can control it.

The thickness of the coating layer may be, for example, 2 nm to 2 μm, more specifically, 10 nm to 500 nm.

If the thickness of the coating layer located on the surface of the metal layer 12 is too thick, lithium ion conductivity is lowered and interfacial resistance is increased, so that charging and discharging characteristics may be deteriorated when a battery is applied. In addition, if the thickness of the coating layer is too thin, the coating layer may be easily lost in the process of applying the lithium metal electrode according to the embodiment to the battery.

Therefore, it is preferable that the film layer is uniformly and densely formed on the entire surface of the metal layer 12 with a thin thickness within the range satisfying the above thickness range.

In this case, the coating layer may include one or more materials selected from the group consisting of a Li-NCHO-based ionic compound, a Li-PCHO-based ionic compound, LiF, and Li ₃ N.

2 schematically shows a lithium metal electrode according to another embodiment.

Referring to FIG. 2 , a lithium metal electrode 100 for a secondary battery according to another embodiment is located on a current collector 11 and at least one surface of the current collector 11, and is composed of a mixture of lithium and a lithium alloy. A metal layer 12 is included. Here, in the lithium alloy, a current is applied between the current collector 11 and the lithium supply source so that the lithium-friendly component included in the coating layer formed on the current collector 11 and the lithium deposited from the lithium supply source are alloyed. may have been formed.

In this case, the metal layer 12 may include a lithium-friendly metal. Here, the lithium-friendly metal may be, for example, one or more selected from the group consisting of In, Ag, Sn, Zn, Si, Al, and Bi, but is not limited thereto.

In this embodiment, the metal layer 12 is a form containing a lithium-friendly metal. In the case of forming the metal layer 12 including a lithium-friendly metal as described above, since the nucleation free energy can be lowered in the initial stage of nucleation of lithium particles in the electrodeposition process, a lithium metal layer having a coarse particle structure can be formed even under high current and overvoltage conditions. can form

In this embodiment, The thickness of the metal layer 12 may be in the range of 1 μm to 100 μm, more specifically, 5 μm to 30 μm. In this embodiment, when the metal layer 12 satisfies the above thickness range, it is possible to maximize the energy density of the battery while improving the charge/discharge life of the battery, and also to minimize the time and cost of the electrodeposition process when forming the metal layer 12. There are advantages to doing so. When the thickness of the metal layer is too thin, the initial Coulombic efficiency is lowered due to the initial irreversibility and the charge/discharge performance is lowered due to the lack of excess lithium. On the other hand, when the thickness of the metal layer is too thick, not only the energy density of the battery is reduced, but also there is a problem in that the process time and the amount of metal raw materials are increased when forming the metal layer.

Meanwhile, although not shown in FIG. 2, the metal layer of this embodiment may further include a film layer positioned on the surface of the metal layer.

The coating layer is the same as that described in the lithium metal electrode for a secondary battery according to the above-described embodiment, and thus will be omitted herein.

A method of manufacturing a lithium metal electrode according to an embodiment includes forming a coating layer on at least one surface of a current collector using a coating composition containing a lithium-friendly component; forming a protective layer on the surface of the coating layer using a slurry containing amorphous carbon and electronic insulating particles; placing a current collector on which the coating layer and the protective layer are formed in a plating solution and then positioning a lithium supply source at a predetermined distance from the protective layer; and forming a metal layer including a lithium alloy in which a lithium-friendly component included in the coating layer and lithium precipitated from the lithium source are alloyed by applying a current between the current collector and the lithium source.

In the step of forming a protective layer on the surface of the coating layer using the slurry containing the amorphous carbon and electronic insulating particles, the electronic insulating protective layer includes a weight ratio of amorphous carbon and electronic insulating ceramic particles of 99.5: 0.5 to 40:60 can do. Specifically, it may include 98.5:1.5 to 50:50, and more specifically, it may include 97:3 to 70:30.

First, a step of forming an alloy material coating layer on at least one surface of the current collector by using a coating composition containing a lithium-friendly metal is performed.

In this case, the lithium-friendly metal may be, for example, one or more selected from the group consisting of In, Ag, Sn, Zn, Si, Al, and Bi, but is not limited thereto.

In addition, the alloy material coating layer, for example, may be performed using at least one method of electrolytic and electroless plating, sputtering, electron beam and thermal vapor deposition.

Meanwhile, in the step of forming the alloy material coating layer, the thickness of the alloy material coating layer formed on at least one surface of the current collector may range from 0.001 μm to 10 μm, specifically from 0.01 μm to 1 μm, and more specifically from 100 nm to 500 nm. there is.

If the thickness of the alloy material coating layer is too thin, it is insufficient to perform the role of forming lithium and lithium alloy, and if the thickness is too thick, a large amount of cost and time is consumed to form the alloy material coating layer, so production efficiency And economic feasibility is lowered, and the weight and weight of the battery are increased, resulting in lower energy density.

After the forming of the alloy material coating layer, a step of applying a protective layer to the surface of the formed alloy material coating layer is performed.

In this case, the protective layer may be an electronic insulating protective layer, and may include amorphous carbon and electronic insulating ceramic particles.

In this case, the amorphous carbon may be at least one selected from the group consisting of acetylene black, super blood black, carbon black, denka black, activated carbon, graphite, hard carbon, and soft carbon, but is not limited thereto.

In addition, the electronically insulating ceramic particles may be at least one selected from the group consisting of particles having low electronic conductivity, such as BN, AlN, C ₃ N ₄ , SiC, and Al ₂ O ₃ , but are not limited thereto.

Meanwhile, in this case, a binder may be added to the electronic insulating protective layer.

The binder may be an aqueous binder, and the aqueous binder may include a rubber-based binder selected from the group consisting of acrylonitrile-butadiene rubber, styrene-butadiene rubber (SBR), and acrylic rubber, and hydroxyethyl cellulose , It may be at least one selected from the group consisting of polymer resins such as carboxymethyl cellulose and polyvinylidene fluoride, but is not limited thereto.

The electronic insulating protective layer is formed by mixing the amorphous carbon, electronically insulating ceramic particles, and the binder with water by using at least one of a doctor blade method, a dip method, a reverse roll method, a direct roll method, a gravure method, an extrusion method, and a brush coating method. The resulting slurry can be applied.

Here, the electronic insulating protective layer may include a weight ratio of amorphous carbon and electronic insulating ceramic particles of 99.5:0.5, specifically 98.5:1.5 to 50:50, and more specifically 97:3 to 70:30 can include

In addition, the binder may be added in an amount of 0.5 to 10 parts by weight, more specifically, 1 to 3 parts by weight based on the mixed weight of the electronic insulating ceramic particles, amorphous carbon, and water.

Meanwhile, in the step of forming the electronic insulating protective layer, the thickness of the electronic insulating protective layer formed on the surface of the alloy material coating layer may range from 0.01 μm to 50 μm, more specifically from 1 μm to 20 μm.

When the thickness of the alloy material coating layer and the electronic insulating protective layer satisfy the above range, it can be manufactured to have a lithium metal electrode for a secondary battery according to an embodiment, more specifically, a lithium metal electrode structure as shown in FIG. 1 or 2 there is.

After the electronic insulating protective layer forming step, positioning a current collector in which the alloy material coating layer and the electronic insulating protective layer are sequentially formed in a plating solution, and then positioning a lithium supply source at a predetermined distance from the current collector, and A step of forming a metal layer by applying a current between the whole and the lithium source is performed.

Referring to FIG. 3 , the step of forming the metal layer will be described in more detail.

First, the current collector 11 having the alloy material coating layer 20 and the electronic insulating protective layer 30 is placed in the plating solution 50, and then the lithium supply source 40 is placed at a predetermined distance from the electronic insulating protective layer 30. to place

The lithium source 40 may use, for example, lithium metal, a lithium alloy, a foil obtained by pressing the lithium metal or lithium alloy on a current collector, a plating solution in which a lithium salt is dissolved, or the like.

The current collector 11 is the same as that described above, and will be omitted here.

The plating solution 50 may be prepared by dissolving a lithium salt in a non-aqueous solvent.

More specifically, the lithium salt is LiCl, LiBr, LiI, LiCO ₃ , LiNO ₃ , LiFSI, LiTFSI, LiBF ₄ , LiPF 6 , LiAsF ₆ , LiClO ₄ , LiN(SO _{2 CF 3 ) 2} , LiBOB, or any of these can be a combination. The concentration of the lithium salt may be 0.1 to 3.0M based on the total electrolyte solution.

More specifically, in this embodiment, the plating solution is characterized in that it contains a nitrogen-based compound as at least one of the lithium salt and the non-aqueous solvent.

The nitrogen-based compound, for example, lithium nitrate, lithium bis fluorosulfonyl imide, lithium bis trifluoromethane sulfonimide, caprolactam (e-caprolactam), methyl caprolactam (N-methyl-e-caprolactam), triethylamine (triethylamine) and tributylamine (tributylamine) may include at least one selected from the group consisting of.

Among the nitrogen-based compounds, at least one of lithium nitrate, lithium bis fluorosulfonyl imide, and lithium bis trifluoromethane sulfonimide is a lithium salt, can be used

Among the nitrogen-based compounds, at least one of e-caprolactam, N-methyl-e-caprolactam, triethylamine, and tributylamine may be used as a non-aqueous solvent. there is.

Meanwhile, a general non-aqueous solvent may be added as a solvent in consideration of the viscosity of the plating solution. This is because if the viscosity of the plating solution is too high, the mobility of lithium ions is lowered and the ionic conductivity of the plating solution is lowered, so that the time required for the electrodeposition process is increased and the productivity is reduced.

The solvent is, for example, ethylene carbonate (ethylene carbonate), propylene carbonate (propylene carbonate), dimethyl carbonate (dimethyl carbonate), ethyl methyl carbonate (ethyl methyl carbonate), diethyl carbonate (diethyl carbonate), 1 ,2-dimethoxyethane, diethylene glycol dimethyl ether, tetraethylene glycol dimethyl ether, tetrahydrofuran, 1,3-dioxy Contains at least one selected from the group consisting of 1,3-dioxolane, 1,4-dioxane and 1,3,5-trioxane can do.

By applying the current, the current density of the current applied in the step of forming the lithium metal layer on at least one surface of the current collector is in the range of 0.1 mA/cm ² to 100 mA/cm ² , more specifically 0.2 mA/cm ² to 50 mA/cm ² , 5 mA/cm ² to 30 mA/cm ² , or 7 mA/cm ² to 25 mA/cm ² .

In addition, the time for applying the current may be in the range of 0.05 hours to 50 hours, more specifically in the range of 0.25 hours to 25 hours.

As described above, in this embodiment, the lithium metal electrode having a metal layer including a lithium metal layer having a coarse particle structure by preventing the excessive generation of fine lithium particles even under high current conditions and inducing the initially generated lithium particles to grow well can be manufactured. In addition, the metal layer prepared in this way has excellent surface uniformity. Therefore, specifically, as shown in FIG. 1, a lithium metal electrode including a lithium alloy layer 21 containing a lithium component and a lithium metal layer 41 positioned on the lithium alloy layer 21 and a metal layer 12 It may be manufactured to have a structure or a lithium metal electrode structure having a metal layer 12 composed of a mixture of lithium and a lithium alloy as shown in FIG. 2 . The thickness of the metal layer 12 may be in the range of 1 μm to 100 μm, more specifically, 5 μm to 30 μm.

When the lithium metal electrode manufactured according to the present embodiment is applied, the charge/discharge characteristics of the secondary battery can be significantly improved.

A secondary battery according to an embodiment includes a positive electrode, a negative electrode, and an electrolyte disposed between the positive electrode and the negative electrode. Here, the negative electrode may be a lithium metal electrode according to the present invention.

14 schematically illustrates the structure of a secondary battery according to an exemplary embodiment.

Referring to FIG. 14 , the secondary battery 200 of this embodiment is an electrode assembly including a positive electrode 70, a negative electrode 100, and a separator 90 disposed between the positive electrode 70 and the negative electrode 100. can include

This electrode assembly is wound or folded and accommodated in the battery case 95 .

Thereafter, the electrolyte 80 is injected into the battery case 95 and sealed to complete the secondary battery 200 . At this time, the battery case 95 may have a shape such as a cylindrical shape, an angular shape, a pouch shape, or a coin shape.

Although FIG. 14 shows the negative electrode according to one embodiment as the negative electrode 100 for convenience, all lithium metal electrodes for secondary batteries according to the above-described embodiments can be applied as the negative electrode.

The cathode 70 may include a cathode active material layer and a cathode current collector.

The cathode active material layer is, for example, made of at least one metal selected from among Ni, Co, Mn, Al, Cr, Fe, Mg, Sr, V, La, and Ce, O, F, S, P, and a combination thereof. It may include a Li compound containing at least one non-metal element selected from the group consisting of The positive electrode active material layer may include active material particles having an average particle size of about 0.01 μm to about 200 μm, and may be appropriately selected according to required characteristics of the battery.

In some cases, a conductive material may be added to the cathode active material layer.

The conductive material may be, for example, carbon black and ultrafine graphite particles, fine carbon such as acetylene black, nano metal particle paste, etc., but is not limited thereto.

The cathode current collector serves to support the cathode active material layer. As the cathode current collector, for example, an aluminum foil, a nickel foil, or a combination thereof may be used, but is not limited thereto.

As the electrolyte 80 filled in the lithium secondary battery 200, a non-aqueous electrolyte solution or a solid electrolyte may be used.

The non-aqueous electrolyte solution may include, for example, a lithium salt such as lithium hexafluorophosphate and lithium perchlorate and a solvent such as ethylene carbonate, propylene carbonate, and butylene carbonate. In addition, as the solid electrolyte, for example, a gel polymer electrolyte obtained by impregnating an electrolyte solution into a polymer electrolyte such as polyethylene oxide or polyacrylonitrile, or an inorganic solid electrolyte such as LiI or Li ₃ N may be used.

The separator 90 separates the positive electrode and the negative electrode and provides a passage for lithium ions to move, and any one commonly used in a lithium secondary battery may be used. That is, an electrolyte having low resistance to ion movement of the electrolyte and excellent ability to absorb the electrolyte may be used. Here, the separator may be, for example, one selected from glass fiber, polyester, polyethylene, polypropylene, polytetrafluoroethylene, or a combination thereof, and may be in the form of a nonwoven fabric or a woven fabric. Meanwhile, when a solid electrolyte is used as the electrolyte 80 , the solid electrolyte may serve as the separator 90 .

Hereinafter, embodiments of the present invention will be described in detail. However, this is presented as an example, and the present invention is not limited thereby, and the present invention is only defined by the scope of the claims to be described later.

Example 1

A lithium metal electrode for a secondary battery according to Example 1 was manufactured in the same process as in FIG. 1 .

First, a coating layer 20 containing silver (Ag) was formed to a thickness of about 300 nm using an electroless plating method on one surface of the copper current collector 11 (see FIG. 4 ).

Then, a protective layer 30 was formed to a thickness of about 5 μm by slurry coating using a comma coater on the surface of the coating layer 20, and specifically, an electronic insulating protective layer was formed (see FIG. 5).

Here, in the protective layer 30, the weight ratio of amorphous carbon using acetylene black and electronic insulating ceramic particles using hexagonal boron nitride (h-BN) is 7: 3, and a solvent using water mixed in. At this time, a slurry was prepared by adding 1.5% by weight of carboxymethyl cellulose and a styrene-butadiene rubber binder, respectively, based on the weight of the mixture composed of acetylene black, hexagonal boron nitride, and water.

After placing the current collector 11 on which the coating layer 20 and the protective layer 30 are formed in the plating solution 50 as described above, the lithium supply source 40 is placed at a predetermined distance from the protective layer 30. .

The plating solution 50 contains 40% by weight and 10% by weight of nitrogen-based compounds, lithium bis(fluorosulfonyl)imide and lithium nitrate, respectively, based on 100% by weight of the plating solution, in a 1,2-dimethoxyethane solvent. and prepared by adding 10% by weight of fluoroethylene carbonate, a fluorine-based compound, based on 100% by weight of the plating solution.

In addition, as the lithium source 40, a lithium metal plate having a purity of 99.9% or more and having a thickness of 500 μm was pressed onto a copper current collector plate (Cu plate) and used.

After stacking the lithium source 40 and the current collector 11 in an electrically insulated state in the plating solution 50, the lithium source 40 and the current collector 11 are connected to (+) and A metal layer was formed by depositing lithium between the current collector 11 and the electronic insulating protective layer 30 by applying a current using a (-) electrode.

At this time, the average current density of the process was 4 mA/cm ² , and the process time was about 15 minutes to prepare a lithium metal electrode, that is, a negative electrode, on which a metal layer having a thickness of about 5 μm was formed.

Examples 2, 3, 4 and Reference Example 1

In preparing the protective layer, an anode was prepared in the same manner as in Example 1, except that the weight ratio of amorphous carbon and electronic insulating ceramic particles was adjusted as shown in Table 3 below.

Comparative Example 1

A negative electrode was prepared in the same manner as in Example 1 except that a coating layer was not formed on one side of the current collector, a protective layer was formed using 100% amorphous carbon, and a metal layer was not formed between the current collector and the protective layer. did

Comparative Example 2

A negative electrode was prepared in the same manner as in Example 1, except that the protective layer was formed using 100% amorphous carbon.

Comparative Example 3

An anode was manufactured in the same manner as in Example 1, except that a coating layer was not formed on one surface of the current collector and a metal layer was not formed between the current collector and the protective layer.

(Experimental Example 1)

The cross-sectional structures of the negative electrodes prepared according to Example 1 and Comparative Examples 1, 2, and 3 were analyzed and shown in FIGS. 6A, 6B, 6C, and 6D, respectively.

That is, FIGS. 6a, 6b, 6c, and 6d are photographs of cross-sections of cathodes prepared in Example 1 and Comparative Examples 1, 2, and 3 analyzed using a scanning electron microscope (SEM). it is shown

Referring to FIGS. 6B and 6D , in the anodes manufactured according to Example 1 and Comparative Example 2, it can be seen that a metal layer is uniformly formed between the protective layer and the current collector.

(Experimental Example 2)

The surface microstructures of the negative electrodes prepared according to Example 1 and Comparative Examples 1, 2, and 3 are shown in FIGS. 7A, 8A, 9A, and 10A, respectively, and according to Example 1 and Comparative Examples 1, 2, and 3 Components of the surface of the prepared anode were analyzed and shown in FIGS. 7b, 8b, 9b, and 10b.

The cathode surface microstructure was analyzed using a scanning electron microscope (SEM), and component analysis of the cathode surface was performed by energy dispersive X-ray spectroscopy.

Comparing FIGS. 7a, 7b, 10a, and 10b with FIGS. 8a, 8b, 9a, and 9b, the surfaces of the negative electrodes prepared according to Example 1 and Comparative Example 3 including electronic insulating ceramic particles It can be confirmed that boron (B) and nitrogen (N) elements are observed in This is considered to be due to the use of hexagonal boron nitride as the electronic insulating ceramic particles. On the other hand, fluorine (F) and sulfur (S) are additionally observed on the surface of the negative electrode manufactured according to Example 1 and Comparative Example 2 to which the electrodeposition plating process is applied. It is believed that this is due to the surface coating layer (SEI) produced according to the decomposition reaction of the plating solution in the electrodeposition process. From this, it can be confirmed that the surface of the anode contains an ion conductive material such as LiF formed by a coating layer containing a Li-N-C-H-O-based ionic compound and a fluorine-based compound included in the plating solution.

(Experimental Example 3)

An all-solid-state battery was prepared as shown in FIG. 14 using the negative electrode, that is, the lithium metal electrode prepared according to Example 1 and Comparative Examples 1, 2, and 3, and then the initial Coulombic efficiency was evaluated.

To evaluate the initial coulombic efficiency of the all-solid-state battery cell, a pressurized exclusive evaluation cell capable of maintaining an inert atmosphere was used.

Specifically, sulfide-based azirodite (Li ₆ PS ₅ Cl) was used as the solid electrolyte. The solid electrolyte was manufactured in the form of pellets having a thickness of about 0.7 mm, and the density was improved by pressing at a pressure of 370 MPa.

Lithium having a thickness of 0.5 mm was disposed on one side of the solid electrolyte, and negative electrodes prepared in Example 1 and Comparative Examples 1, 2, and 3 were disposed on the other side. Here, the positive electrode and the negative electrode according to the present invention were attached to the solid electrolyte by applying pressure of 50 MPa.

During evaluation of the initial coulombic efficiency, a pressure of 16 MPa was applied to the dedicated evaluation cell.

Here, in the first charging process, the initial coulombic efficiency is charged with a constant current of 1 mA/cm2 for 3 hours to charge a total of 3 mAh/cm2, and then discharged with a constant current of 1 mA/cm2 to discharge at the point where the discharge voltage exceeds 1V was completed and the discharge capacity was measured and calculated.

Results of evaluating the initial coulombic efficiency of the secondary battery are shown in FIG. 11 and Table 1 below.

Referring to FIGS. 8a, 8b, 10a, 10b and Table 1, the all-solid-state battery to which the negative electrode manufactured according to Comparative Example 1 and Comparative Example 3 in which the metal layer is not formed between the current collector and the protective layer is applied has 81.3% and 88.8%, respectively. It showed a low initial coulombic efficiency of %. From this, it can be confirmed that a significant amount of lithium is consumed in the initial irreversible reaction during the charging process, which is thought to be mainly due to the irreversible reaction by amorphous carbon in the protective layer.

On the other hand, the secondary batteries to which the anodes manufactured according to Example 1 and Comparative Example 2 in which a metal layer was formed between the current collector and the protective layer through the electrodeposition plating process exhibited high initial Coulomb effects of 131.0% and 144.0%, respectively. It is believed that the initial discharge capacity is greater than the charge capacity due to lithium included in the metal layer and surplus lithium in the lithium alloy.

Therefore, it can be seen that when the cathode having the metal layer is manufactured in the same manner as in the present embodiment, the problem of the discharge capacity being reduced due to the initial irreversibility does not occur.

(Experimental Example 4)

(Experimental Example 4-1)

An all-solid-state battery was prepared as shown in FIG. 14 using the negative electrode, that is, the lithium metal electrode prepared according to Example 1 and Comparative Examples 1, 2, and 3, and then the charge/discharge characteristics were evaluated.

The all-solid-state battery cell used in the charge/discharge evaluation was the pressurized exclusive evaluation cell used in Experimental Example 3.

The evaluation of charge and discharge performance was performed as follows.

Charging for 1 hour at a constant current of 1 mA/cm 2 and discharging for 1 hour at a constant current of 1 mA/cm 2 was defined as one cycle.

In addition, the charge and discharge life was defined as the end of the life when a short circuit occurred between the positive electrode and the negative electrode manufactured according to the present invention during the charge and discharge process or when the voltage between the two electrodes exceeded 2V.

The results of evaluating the charge/discharge performance are shown in FIG. 12 and Table 2 below.

Referring to FIG. 12 and Table 2, the charge and discharge lifespan of the all-solid-state battery to which the negative electrode manufactured according to Comparative Example 1 and Comparative Example 3 in which no metal layer is formed between the current collector and the protective layer is applied is 68 and 215 cycles, respectively. It was found that the charge and discharge lifespan of the all-solid-state battery to which the negative electrode manufactured according to Comparative Example 2 and Example 1 in which the metal layer was formed between the current collector and the protective layer was applied was 292 times and 881 times, respectively. That is, it can be confirmed that the all-solid-state battery to which the negative electrode in which the metal layer is formed between the current collector and the protective layer is applied has significantly superior charge and discharge life compared to the all-solid-state battery to which the negative electrode in which the metal layer is not formed between the current collector and the protective layer is applied. can

Therefore, it can be seen that when the negative electrode having the metal layer formed between the current collector and the protective layer is applied, the charge/discharge life of the secondary battery is remarkably improved.

In addition, comparing Example 2 and Example 1 in which a metal layer is formed between the current collector and the protective layer, charging and discharging of the all-solid-state battery to which the negative electrode manufactured according to Example 1 containing ceramic particles is applied in the protective layer The lifespan was 881 cycles, which was significantly superior to the charge/discharge life of 292 cycles of the all-solid-state battery to which the negative electrode manufactured according to Comparative Example 2 was applied without ceramic particles in the protective layer.

Similarly, comparing Case 1 and Comparative Example 3 in which no metal layer is formed between the current collector and the protective layer, the charging of the all-solid-state battery to which the negative electrode manufactured according to Comparative Example 3 containing ceramic particles is applied is applied to the protective layer. The discharge life was 215 cycles, which was significantly superior to the charge and discharge life of 68 cycles of the all-solid-state battery to which the negative electrode manufactured according to Comparative Example 1 was applied without ceramic particles in the protective layer.

Accordingly, it can be confirmed that the charge/discharge life of the secondary battery including the ceramic particles in the protective layer is remarkably improved.

In particular, a metal layer is formed between the current collector and the protective layer, and the charge/discharge life of the all-solid-state battery to which the negative electrode manufactured according to Example 1 including ceramic particles is applied to the protective layer is 881 cycles, Comparative Examples 1, 2, and 3 It was found to be far superior to the charge and discharge life of an all-solid-state battery to which the anode manufactured according to the method was applied.

Therefore, it can be confirmed that the charge/discharge life of a secondary battery can be remarkably improved when the negative electrode forming the metal layer between the current collector and the protective layer including ceramic particles according to the present invention is applied.

(Experimental Example 4-2)

13 and 13 by evaluating the charge and discharge characteristics of the all-solid-state battery to which the negative electrode manufactured according to Examples 2, 3, 4 and Reference Example 1 with different weight ratios of amorphous carbon and electronic insulating ceramic particles were applied during the manufacture of the electronic insulating protective layer. It is shown in Table 3 below.

Referring to FIG. 13 and Table 3, as the amount of electronic insulating ceramic particles in the electronic insulating protective layer increases, the charge and discharge life of the all-solid-state battery increases and then decreases again.

When the weight ratio of the electronic insulating ceramic particles and the amorphous carbon included in the electronic insulating protective layer was 70:30, the charge/discharge life was shorter than that of the all-solid-state battery including the protective layer composed of 100% amorphous carbon.

The present invention is not limited to the above embodiments, but can be manufactured in a variety of different forms, and those skilled in the art to which the present invention pertains may take other specific forms without changing the technical spirit or essential features of the present invention. It will be understood that it can be implemented as. Therefore, the embodiments described above should be understood as illustrative in all respects and not limiting.

Claims (17)

current collector;
a metal layer located on at least one surface of the current collector and containing a lithium alloy; and
Including; a protective layer located on the metal layer,
The protective layer is a lithium metal electrode for a secondary battery comprising amorphous carbon and electronic insulating ceramic particles.
According to claim 1,
The electronic insulating ceramic particles are plate-shaped particles having an average particle size D (50) in the range of 100 nm to 1,000 nm, a lithium metal electrode for a secondary battery.
According to claim 1,
The electronic insulating ceramic particles are lithium metal electrodes for secondary batteries containing at least one of BN, AlN, C ₃ N ₄ , SiC and Al ₂ O ₃ .
According to claim 1,
The protective layer is a lithium metal electrode for a secondary battery comprising a weight ratio of amorphous carbon and electronic insulating ceramic particles of 99.5: 0.5 to 40:60.
According to claim 1,
The metal layer containing the lithium alloy,
A lithium metal electrode for a secondary battery comprising a lithium alloy layer positioned on the current collector and a lithium metal layer positioned on the lithium alloy layer.
According to claim 1,
The metal layer containing the lithium alloy is a lithium metal electrode for a secondary battery that is a composite layer containing lithium and a lithium alloy.
According to claim 1,
The metal layer containing the lithium alloy is a lithium metal electrode for a secondary battery that is a composite layer containing one or more of In, Ag, Sn, Zn, Si, Al, and Bi.
According to claim 1,
The average thickness of the metal layer is a lithium metal electrode for a secondary battery of 1㎛ to 100㎛.
According to claim 1,
The average thickness of the protective layer is a lithium metal electrode for a secondary battery of 1㎛ to 20㎛.
According to claim 1,
The protective layer,
Further comprising a coating layer located on the surface of the protective layer,
The coating layer is a lithium metal electrode for a secondary battery comprising at least one material selected from the group consisting of a Li-NCHO-based ionic compound, a Li-PCHO-based ionic compound, LiF, and Li ₃ N.
Forming a coating layer on at least one surface of the current collector using a coating composition containing a lithium-friendly component;
forming a protective layer on the surface of the coating layer using a slurry containing amorphous carbon and electronic insulating ceramic particles;
placing a current collector on which the coating layer and the protective layer are formed in a plating solution and then positioning a lithium supply source at a predetermined distance from the protective layer;
forming a metal layer including a lithium alloy in which a lithium-friendly component included in the coating layer and lithium precipitated from the lithium source are alloyed by applying a current between the current collector and the lithium source; A method for manufacturing a metal electrode.
According to claim 11,
In the step of forming the coating layer,
The thickness of the coating layer formed on at least one surface of the current collector is a method of manufacturing a lithium metal electrode for a secondary battery in the range of 0.001 μm to 10 μm.
According to claim 11,
In the step of forming a protective layer on the surface of the coating layer using a slurry containing amorphous carbon and electronic insulating ceramic particles,
The weight ratio of the amorphous carbon and the electronically insulating ceramic particles is 99.5: 0.5 to 40: 60 manufacturing method of a lithium metal electrode for a secondary battery.
According to claim 11,
In the step of forming the metal layer,
The metal layer,
A lithium alloy layer containing the lithium alloy;
Method for producing a lithium metal electrode for a secondary battery that is formed in a multi-layered structure including a lithium metal layer formed on the lithium alloy layer.
According to claim 11,
In the step of forming the metal layer,
The metal layer,
Method for producing a lithium metal electrode for a secondary battery that is formed in a single-layer structure including the lithium alloy and the lithium metal precipitated from the lithium source.
According to claim 11,
In the step of forming a metal layer containing the lithium alloy,
The method of manufacturing a lithium metal electrode for a secondary battery in which the thickness of the metal layer is 1 μm to 100 μm.
cathode;
anode; and
contains electrolytes;
The negative electrode is a secondary battery comprising the lithium metal electrode for a secondary battery according to any one of claims 1 to 0.

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