KR20230035206A - Adhesive composition for wrapping paper and adhesive wrapping paper comprising the same - Google Patents
Adhesive composition for wrapping paper and adhesive wrapping paper comprising the same Download PDFInfo
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- KR20230035206A KR20230035206A KR1020220112355A KR20220112355A KR20230035206A KR 20230035206 A KR20230035206 A KR 20230035206A KR 1020220112355 A KR1020220112355 A KR 1020220112355A KR 20220112355 A KR20220112355 A KR 20220112355A KR 20230035206 A KR20230035206 A KR 20230035206A
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- wrapping paper
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- 239000000853 adhesive Substances 0.000 title claims abstract description 83
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 83
- 239000000203 mixture Substances 0.000 title claims abstract description 62
- 239000002904 solvent Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000758 substrate Substances 0.000 claims abstract description 14
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 12
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 12
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 9
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 9
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 9
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229940093858 ethyl acetoacetate Drugs 0.000 claims abstract description 9
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 8
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 claims abstract description 7
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920001577 copolymer Polymers 0.000 claims abstract description 5
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910000077 silane Inorganic materials 0.000 claims abstract description 4
- 239000000945 filler Substances 0.000 claims description 16
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000395 magnesium oxide Substances 0.000 claims description 10
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 10
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 10
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 239000010445 mica Substances 0.000 claims description 6
- 229910052618 mica group Inorganic materials 0.000 claims description 6
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 4
- BQTBDXBEZUOJJE-UHFFFAOYSA-N CN1SC=CC1=O.CN1SC=CC1=O Chemical compound CN1SC=CC1=O.CN1SC=CC1=O BQTBDXBEZUOJJE-UHFFFAOYSA-N 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000011256 inorganic filler Substances 0.000 claims description 3
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 3
- 239000012766 organic filler Substances 0.000 claims description 3
- 150000004756 silanes Chemical class 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- 230000014509 gene expression Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
- C09J129/02—Homopolymers or copolymers of unsaturated alcohols
- C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F16/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an alcohol radical
- C08F16/04—Acyclic compounds
- C08F16/06—Polyvinyl alcohol ; Vinyl alcohol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/24—Homopolymers or copolymers of amides or imides
- C08L33/26—Homopolymers or copolymers of acrylamide or methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L39/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
- C08L39/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
- C08L39/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
본 발명은 포장지 접착제 조성물 및 이를 포함하는 접착성 포장지에 관한 것이다.The present invention relates to a wrapping paper adhesive composition and an adhesive wrapping paper comprising the same.
종이 등의 기판을 포장지로 사용하는 경우, 원하는 형태로 포장을 함에 따라 상기 기판을 고정시키기 위한 접착성 물질 또는 접착성 부재가 필요하다. 환경 오염 및 인체에 대한 유해성에 관한 우려로 플라스틱 및 비닐 포장지를 종이 포장지로 대체하고 있으나, 접착성 물질 또는 접착성 부재가 독성을 가지거나 여전히 플라스틱 및 비닐을 포함하는 경우, 여전히 환경 오염 및 인체에 대한 유해성을 발생하여, 상기와 같이 재료를 종이로 치환하는 취지가 몰각될 수 있다. 따라서, 종이 포장지 등에 사용될 수 있는 접착제 조성물의 개발이 요구된다.When a substrate such as paper is used as a wrapping paper, an adhesive material or an adhesive member for fixing the substrate is required while packaging in a desired shape. Although plastic and vinyl wrappers are being replaced with paper wrappers due to concerns about environmental pollution and harm to the human body, if the adhesive substance or adhesive member is toxic or still contains plastic and vinyl, it still pollutes the environment and harms the human body. However, the purpose of replacing the material with paper as described above may be overlooked. Therefore, development of an adhesive composition that can be used for paper wrappers and the like is required.
본 발명의 일 목적은 종이 등의 기판을 접착할 수 있는 포장지 접착제 조성물을 제공하는 것이다.One object of the present invention is to provide a wrapping paper adhesive composition capable of bonding substrates such as paper.
본 발명의 다른 목적은 상기 포장지 접착제 조성물이 사전에 도포된 접착성 포장지를 제공하는 것이다.Another object of the present invention is to provide an adhesive wrapping paper to which the wrapping paper adhesive composition is pre-coated.
일 측면에서 본 발명은 물을 포함하는 용매; 상기 용매에 용해된, 실란으로 개질된 폴리비닐알코올(Polyvinylalcohol; PVA)를 포함하는 제1 성분; 상기 용매에 용해된, 에틸아세토아세테이트(ethylacetoacetate; EAA)를 포함하는 제2 성분; 상기 용매에 용해된, 암모늄 폴리포스페이트(ammonium polyphosphate; APP)를 포함하는 제3 성분; 상기 용매에 용해된, 비닐피롤리돈/디메틸아미노프로필메타아크릴아마이드 코폴리머(vinylpyttolidone/dimethylaminopropylmethacrylamide copolymer)를 포함하는 제4 성분; 및 폴리우레탄 수지; 5-클로로-2-메틸-2H-이소싸이아졸-3-온(5-chloro-2-methyl-2H-isothiazol-3-one); 및 2-메틸-2H-이소싸이아졸-3-온(2-methyl-2H-isothiazol-3-one);을 포함하는 제5 성분;을 포함하는, 포장지 접착제 조성물을 제공한다.In one aspect, the present invention provides a solvent comprising water; A first component comprising silane-modified polyvinylalcohol (PVA) dissolved in the solvent; a second component comprising ethylacetoacetate (EAA) dissolved in the solvent; a third component comprising ammonium polyphosphate (APP) dissolved in the solvent; a fourth component comprising vinylpyrrolidone/dimethylaminopropylmethacrylamide copolymer dissolved in the solvent; and polyurethane resins; 5-chloro-2-methyl-2H-isothiazol-3-one; And 2-methyl-2H-isothiazol-3-one (2-methyl-2H-isothiazol-3-one); a fifth component comprising; provides a wrapping paper adhesive composition comprising a.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 제1 성분을 상기 물에 대하여 중량으로 약 220 내지 270% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 220 to 270% by weight of the first component with respect to the water.
일 실시예에 있어서, 상기 폴리비닐알코올을 개질한 실란은 비닐트리에톡시실란(vinyltriethoxysilane)일 수 있다.In one embodiment, the silane modified with polyvinyl alcohol may be vinyltriethoxysilane.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 제2 성분을 상기 물에 대하여 중량으로 약 20 내지 40% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 20 to 40% by weight of the second component with respect to the water.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 제3 성분을 상기 물에 대하여 중량으로 약 18 내지 23% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 18 to 23% by weight of the third component with respect to the water.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 제4 성분을 상기 물에 대하여 중량으로 약 14 내지 18% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 14 to 18% by weight of the fourth component with respect to the water.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 제5 성분을 상기 물에 대하여 중량으로 약 19 내지 21% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 19 to 21% by weight of the fifth component with respect to the water.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 폴리우레탄 수지를 상기 제5 성분에 대하여 중량으로 약 99.97 내지 99.99 % 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 99.97 to 99.99% by weight of the polyurethane resin based on the weight of the fifth component.
일 실시예에 있어서, 상기 제5 성분 내 5-클로로-2-메틸-2H-이소싸이아졸-3-온 및 2-메틸-2H-이소싸이아졸-3-온의 중량비는 약 2:1 내지 4:1일 수 있다.In one embodiment, the weight ratio of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one in the fifth component is about 2:1 to It may be 4:1.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 용매에 용해된, 티타늄 옥사이드(TiO2), 알루미나(Alumina), 탄산칼슘(CaCO3), 운모(mica), 마스네슘 옥사이드(MgO), 나트륨 옥사이드(Na2O), 오산화 인(P2O5) 및 실리카(SiO2)를 포함하는 군에서 선택된 하나 이상의 물질을 포함하는 무기충진재; 및 스타치(starch)를 포함하는 유기충진재;를 포함하는 충진재;를 더 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition is dissolved in the solvent, titanium oxide (TiO 2 ), alumina (Alumina), calcium carbonate (CaCO 3 ), mica (mica), magnesium oxide (MgO), sodium oxide (Na 2 O), phosphorus pentoxide (P 2 O 5 ), and silica (SiO 2 ) Inorganic filler containing one or more materials selected from the group containing; And organic fillers including starch; fillers including; may further include.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 마그네슘 옥사이드를 상기 충진재에 대하여 중량으로 약 20 내지 25% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 20 to 25% by weight of the magnesium oxide based on the weight of the filler.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 나트륨 옥사이드를 상기 충진재에 대하여 중량으로 약 6 내지 8% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 6 to 8% by weight of the sodium oxide based on the weight of the filler.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 오산화 인을 상기 충진재에 대하여 중량으로 약 4 내지 6% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 4 to 6% by weight of the phosphorus pentoxide based on the weight of the filler.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 실리카를 상기 충진재에 대하여 중량으로 약 45 내지 55% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 45 to 55% by weight of the silica based on the weight of the filler.
다른 측면에서 본 발명은, 종이를 포함하는 기판; 및 상기 기판의 적어도 일면 상에 형성된 접착제 조성물;을 포함하고, 상기 접착제 조성물은 상기 포장지 접착제 조성물을 포함하는, 접착성 포장지를 제공한다.In another aspect, the present invention provides a substrate comprising paper; and an adhesive composition formed on at least one surface of the substrate, wherein the adhesive composition includes the wrapping paper adhesive composition, and provides an adhesive wrapping paper.
본 발명의 실시예에 따른 포장지 접착제 조성물은 종이 등의 기판에 도포되어 접착면을 형성할 수 있다.Wrapping paper adhesive composition according to an embodiment of the present invention can be applied to a substrate such as paper to form an adhesive surface.
본 발명의 실시예에 따른 접착성 포장지는 상기 포장지 접착제 조성물에 의해 접착면이 형성되어 종이 포장지에서도 접착력을 가질 수 있다.The adhesive wrapping paper according to the embodiment of the present invention has an adhesive surface formed by the wrapping paper adhesive composition, so it can have adhesive strength even in paper wrapping paper.
이하, 첨부한 도면을 참조하여 본 발명의 실시예에 대해 상세히 설명한다. 본 발명은 다양한 변경을 가할 수 있고 여러 가지 형태를 가질 수 있는 바, 특정 실시 예들을 도면에 예시하고 본문에 상세하게 설명하고자 한다. 그러나 이는 본 발명을 특정한 개시 형태에 대해 한정하려는 것이 아니며, 본 발명의 사상 및 기술 범위에 포함되는 모든 변경, 균등물 내지 대체물을 포함하는 것으로 이해되어야 한다. 각 도면을 설명하면서 유사한 참조부호를 유사한 구성요소에 대해 사용하였다. 첨부된 도면에 있어서, 구조물들의 치수는 본 발명의 명확성을 기하기 위하여 실제보다 확대하여 도시한 것이다. Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings. Since the present invention can have various changes and various forms, specific embodiments will be illustrated in the drawings and described in detail in the text. However, this is not intended to limit the present invention to a specific form disclosed, and should be understood to include all modifications, equivalents, and substitutes included in the spirit and scope of the present invention. Like reference numerals have been used for like elements throughout the description of each figure. In the accompanying drawings, the dimensions of the structures are shown enlarged than actual for clarity of the present invention.
본 출원에서 사용한 용어는 단지 특정한 실시 예를 설명하기 위해 사용된 것으로, 본 발명을 한정하려는 의도가 아니다. 단수의 표현은 문맥상 명백하게 다르게 뜻하지 않는 한, 복수의 표현을 포함한다. 본 출원에서, "포함하다" 또는 "가지다" 등의 용어는 명세서 상에 기재된 특징, 숫자, 단계, 동작, 구성요소 또는 이들을 조합한 것이 존재함을 지정하려는 것이지, 하나 또는 그 이상의 다른 특징들이나 숫자, 단계, 동작, 구성요소 또는 이들을 조합한 것들의 존재 또는 부가 가능성을 미리 배제하지 않는 것으로 이해되어야 한다.Terms used in this application are only used to describe specific embodiments, and are not intended to limit the present invention. Singular expressions include plural expressions unless the context clearly dictates otherwise. In this application, terms such as "comprise" or "have" are intended to designate that there is a feature, number, step, operation, component, or combination thereof described in the specification, but one or more other features or numbers However, it should be understood that it does not preclude the presence or addition of steps, operations, components, or combinations thereof.
다르게 정의되지 않는 한, 기술적이거나 과학적인 용어를 포함해서 여기서 사용되는 모든 용어들은 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에 의해 일반적으로 이해되는 것과 동일한 의미를 가지고 있다. 일반적으로 사용되는 사전에 정의되어 있는 것과 같은 용어들은 관련 기술의 문맥 상 가지는 의미와 일치하는 의미를 가지는 것으로 해석되어야 하며, 본 출원에서 명백하게 정의하지 않는 한, 이상적이거나 과도하게 형식적인 의미로 해석되지 않는다. Unless defined otherwise, all terms used herein, including technical or scientific terms, have the same meaning as commonly understood by one of ordinary skill in the art to which the present invention belongs. Terms such as those defined in commonly used dictionaries should be interpreted as having a meaning consistent with the meaning in the context of the related art, and unless explicitly defined in the present application, they should not be interpreted in an ideal or excessively formal meaning. don't
일 측면에서 본 발명은 물을 포함하는 용매; 상기 용매에 용해된, 실란으로 개질된 폴리비닐알코올(Polyvinylalcohol; PVA)를 포함하는 제1 성분; 상기 용매에 용해된, 에틸아세토아세테이트(ethylacetoacetate; EAA)를 포함하는 제2 성분; 상기 용매에 용해된, 암모늄 폴리포스페이트(ammonium polyphosphate; APP)를 포함하는 제3 성분; 상기 용매에 용해된, 비닐피롤리돈/디메틸아미노프로필메타아크릴아마이드 코폴리머(vinylpyttolidone/dimethylaminopropylmethacrylamide copolymer)를 포함하는 제4 성분; 및 폴리우레탄 수지; 5-클로로-2-메틸-2H-이소싸이아졸-3-온(5-chloro-2-methyl-2H-isothiazol-3-one); 및 2-메틸-2H-이소싸이아졸-3-온(2-methyl-2H-isothiazol-3-one);을 포함하는 제5 성분;을 포함하는, 포장지 접착제 조성물을 제공한다.In one aspect, the present invention provides a solvent comprising water; A first component comprising silane-modified polyvinylalcohol (PVA) dissolved in the solvent; a second component comprising ethylacetoacetate (EAA) dissolved in the solvent; a third component comprising ammonium polyphosphate (APP) dissolved in the solvent; a fourth component comprising vinylpyrrolidone/dimethylaminopropylmethacrylamide copolymer dissolved in the solvent; and polyurethane resins; 5-chloro-2-methyl-2H-isothiazol-3-one; And 2-methyl-2H-isothiazol-3-one (2-methyl-2H-isothiazol-3-one); a fifth component comprising; provides a wrapping paper adhesive composition comprising a.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 제1 성분을 상기 물에 대하여 중량으로 약 220 내지 270% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 220 to 270% by weight of the first component with respect to the water.
일 실시예에 있어서, 상기 폴리비닐알코올을 개질한 실란은 비닐트리에톡시실란(vinyltriethoxysilane)일 수 있다.In one embodiment, the silane modified with polyvinyl alcohol may be vinyltriethoxysilane.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 제2 성분을 상기 물에 대하여 중량으로 약 20 내지 40% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 20 to 40% by weight of the second component with respect to the water.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 제3 성분을 상기 물에 대하여 중량으로 약 18 내지 23% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 18 to 23% by weight of the third component with respect to the water.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 제4 성분을 상기 물에 대하여 중량으로 약 14 내지 18% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 14 to 18% by weight of the fourth component with respect to the water.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 제5 성분을 상기 물에 대하여 중량으로 약 19 내지 21% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 19 to 21% by weight of the fifth component with respect to the water.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 폴리우레탄 수지를 상기 제5 성분에 대하여 중량으로 약 99.97 내지 99.99 % 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 99.97 to 99.99% by weight of the polyurethane resin based on the weight of the fifth component.
일 실시예에 있어서, 상기 제5 성분 내 5-클로로-2-메틸-2H-이소싸이아졸-3-온 및 2-메틸-2H-이소싸이아졸-3-온의 중량비는 약 2:1 내지 4:1일 수 있다.In one embodiment, the weight ratio of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one in the fifth component is about 2:1 to It may be 4:1.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 용매에 용해된, 티타늄 옥사이드(TiO2), 알루미나(Alumina), 탄산칼슘(CaCO3), 운모(mica), 마스네슘 옥사이드(MgO), 나트륨 옥사이드(Na2O), 오산화 인(P2O5) 및 실리카(SiO2)를 포함하는 군에서 선택된 하나 이상의 물질을 포함하는 무기충진재; 및 스타치(starch)를 포함하는 유기충진재;를 포함하는 충진재;를 더 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition is dissolved in the solvent, titanium oxide (TiO 2 ), alumina (Alumina), calcium carbonate (CaCO 3 ), mica (mica), magnesium oxide (MgO), sodium oxide (Na 2 O), phosphorus pentoxide (P 2 O 5 ), and silica (SiO 2 ) Inorganic filler containing one or more materials selected from the group containing; And organic fillers including starch; fillers including; may further include.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 마그네슘 옥사이드를 상기 충진재에 대하여 중량으로 약 20 내지 25% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 20 to 25% by weight of the magnesium oxide based on the weight of the filler.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 나트륨 옥사이드를 상기 충진재에 대하여 중량으로 약 6 내지 8% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 6 to 8% by weight of the sodium oxide based on the weight of the filler.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 오산화 인을 상기 충진재에 대하여 중량으로 약 4 내지 6% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 4 to 6% by weight of the phosphorus pentoxide based on the weight of the filler.
일 실시예에 있어서, 상기 포장지 접착제 조성물은 상기 실리카를 상기 충진재에 대하여 중량으로 약 45 내지 55% 포함할 수 있다.In one embodiment, the wrapping paper adhesive composition may include about 45 to 55% by weight of the silica based on the weight of the filler.
이상에서 살펴본 바와 같이, 본 발명의 실시예에 따른 포장지 접착제 조성물은 종이 등의 기판에 도포되어 접착면을 형성할 수 있다.As described above, the wrapping paper adhesive composition according to the embodiment of the present invention can be applied to a substrate such as paper to form an adhesive surface.
다른 측면에서 본 발명은, 종이를 포함하는 기판; 및 상기 기판의 적어도 일면 상에 형성된 접착제 조성물;을 포함하고, 상기 접착제 조성물은 상기 포장지 접착제 조성물을 포함하는, 접착성 포장지를 제공한다.In another aspect, the present invention provides a substrate comprising paper; and an adhesive composition formed on at least one surface of the substrate, wherein the adhesive composition includes the wrapping paper adhesive composition, and provides an adhesive wrapping paper.
일 실시예에 있어서, 상기 코팅용 조성물은 상기 기판의 접촉이 예정된 일면의 일부 상에 형성될 수 있다.In one embodiment, the coating composition may be formed on a portion of one surface of the substrate to be contacted.
이상에서 살펴본 바와 같이, 본 발명의 실시예에 따른 접착성 포장지는 상기 포장지 접착제 조성물에 의해 접착면이 형성되어 종이 포장지에서도 접착력을 가질 수 있다.As described above, the adhesive wrapping paper according to the embodiment of the present invention has an adhesive surface formed by the wrapping paper adhesive composition, so that it can have adhesive strength even in paper wrapping paper.
이하 본 발명의 실시예에 대해 상술한다. 다만, 하기에 기재된 실시예는 본 발명의 일부 실시 형태에 불과한 것으로서, 본 발명의 범위가 하기 실시예에 한정되는 것은 아니다. Hereinafter, embodiments of the present invention will be described in detail. However, the examples described below are merely some embodiments of the present invention, and the scope of the present invention is not limited to the following examples.
포장지 접착제 조성물의 제조Preparation of wrapping paper adhesive composition
포장지 접착제 조성물을 하기와 같은 성분들을 혼합하여 제조하였다.A wrapping paper adhesive composition was prepared by mixing the following components.
접착성 포장지의 제조Manufacture of adhesive wrapping paper
상기와 같이 제조된 포장지 접착제 조성물을 종이 기판 상, 접착이 예정된 일면의 일부에 도포한 후, 50℃에서 24시간 동안 용매를 제거하여 접착면을 형성하였다.After applying the wrapping paper adhesive composition prepared as described above to a portion of one surface to be bonded on a paper substrate, the solvent was removed at 50° C. for 24 hours to form an adhesive surface.
상기에서는 본 발명의 바람직한 실시예를 참조하여 설명하였지만, 해당 기술 분야의 숙련된 당업자는 하기의 특허 청구 범위에 기재된 본 발명의 사상 및 영역으로부터 벗어나지 않는 범위 내에서 본 발명을 다양하게 수정 및 변경시킬 수 있음을 이해할 수 있을 것이다.Although the above has been described with reference to preferred embodiments of the present invention, those skilled in the art can variously modify and change the present invention without departing from the spirit and scope of the present invention described in the claims below. You will understand that you can.
Claims (15)
상기 용매에 용해된, 실란으로 개질된 폴리비닐알코올(Polyvinylalcohol; PVA)를 포함하는 제1 성분;
상기 용매에 용해된, 에틸아세토아세테이트(ethylacetoacetate; EAA)를 포함하는 제2 성분;
상기 용매에 용해된, 암모늄 폴리포스페이트(ammonium polyphosphate; APP)를 포함하는 제3 성분;
상기 용매에 용해된, 비닐피롤리돈/디메틸아미노프로필메타아크릴아마이드 코폴리머(vinylpyttolidone/dimethylaminopropylmethacrylamide copolymer)를 포함하는 제4 성분; 및
폴리우레탄 수지; 5-클로로-2-메틸-2H-이소싸이아졸-3-온(5-chloro-2-methyl-2H-isothiazol-3-one); 및 2-메틸-2H-이소싸이아졸-3-온(2-methyl-2H-isothiazol-3-one);을 포함하는 제5 성분;을 포함하는,
포장지 접착제 조성물.solvents including water;
A first component comprising silane-modified polyvinylalcohol (PVA) dissolved in the solvent;
a second component comprising ethylacetoacetate (EAA) dissolved in the solvent;
a third component comprising ammonium polyphosphate (APP) dissolved in the solvent;
a fourth component comprising vinylpyrrolidone/dimethylaminopropylmethacrylamide copolymer dissolved in the solvent; and
polyurethane resin; 5-chloro-2-methyl-2H-isothiazol-3-one; And 2-methyl-2H-isothiazol-3-one (2-methyl-2H-isothiazol-3-one); a fifth component comprising;
Wrapping paper adhesive composition.
상기 제1 성분을 상기 물에 대하여 중량으로 220 내지 270% 포함하는,
포장지 접착제 조성물.According to claim 1,
Comprising 220 to 270% by weight of the first component with respect to the water,
Wrapping paper adhesive composition.
상기 폴리비닐알코올을 개질한 실란은 비닐트리에톡시실란(vinyltriethoxysilane)인,
포장지 접착제 조성물.According to claim 2,
The silane modified with the polyvinyl alcohol is vinyltriethoxysilane,
Wrapping paper adhesive composition.
상기 제2 성분을 상기 물에 대하여 중량으로 20 내지 40% 포함하는,
포장지 접착제 조성물.According to claim 1,
Comprising 20 to 40% by weight of the second component with respect to the water,
Wrapping paper adhesive composition.
상기 제3 성분을 상기 물에 대하여 중량으로 18 내지 23% 포함하는,
포장지 접착제 조성물.According to claim 1,
Comprising 18 to 23% by weight of the third component with respect to the water,
Wrapping paper adhesive composition.
상기 제4 성분을 상기 물에 대하여 중량으로 14 내지 18% 포함하는,
포장지 접착제 조성물.According to claim 1,
Comprising 14 to 18% by weight of the fourth component relative to the water,
Wrapping paper adhesive composition.
상기 제5 성분을 상기 물에 대하여 중량으로 19 내지 21% 포함하는,
포장지 접착제 조성물.According to claim 1,
Comprising 19 to 21% by weight of the fifth component with respect to the water,
Wrapping paper adhesive composition.
상기 폴리우레탄 수지를 상기 제5 성분에 대하여 중량으로 99.97 내지 99.99 % 포함하는,
포장지 접착제 조성물.According to claim 7,
Comprising 99.97 to 99.99% by weight of the polyurethane resin based on the fifth component,
Wrapping paper adhesive composition.
상기 제5 성분 내 5-클로로-2-메틸-2H-이소싸이아졸-3-온 및 2-메틸-2H-이소싸이아졸-3-온의 중량비는 2:1 내지 4:1인,
포장지 접착제 조성물.According to claim 8,
The weight ratio of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one in the fifth component is 2: 1 to 4: 1,
Wrapping paper adhesive composition.
상기 용매에 용해된, 티타늄 옥사이드(TiO2), 알루미나(Alumina), 탄산칼슘(CaCO3), 운모(mica), 마스네슘 옥사이드(MgO), 나트륨 옥사이드(Na2O), 오산화 인(P2O5) 및 실리카(SiO2)를 포함하는 군에서 선택된 하나 이상의 물질을 포함하는 무기충진재; 및 스타치(starch)를 포함하는 유기충진재;를 포함하는 충진재;를 더 포함하는,
포장지 접착제 조성물.According to claim 1,
Dissolved in the solvent, titanium oxide (TiO 2 ), alumina (Alumina), calcium carbonate (CaCO 3 ), mica (mica), magnesium oxide (MgO), sodium oxide (Na 2 O), phosphorus pentoxide (P 2 O 5 ) and silica (SiO 2 ) Inorganic filler containing one or more materials selected from the group containing; And an organic filler including starch; a filler comprising a; further comprising,
Wrapping paper adhesive composition.
상기 마그네슘 옥사이드를 상기 충진재에 대하여 중량으로 20 내지 25% 포함하는,
포장지 접착제 조성물.According to claim 10,
Containing 20 to 25% by weight of the magnesium oxide with respect to the filler,
Wrapping paper adhesive composition.
상기 나트륨 옥사이드를 상기 충진재에 대하여 중량으로 6 내지 8% 포함하는,
포장지 접착제 조성물.According to claim 10,
Containing 6 to 8% by weight of the sodium oxide based on the filler,
Wrapping paper adhesive composition.
상기 오산화 인을 상기 충진재에 대하여 중량으로 4 내지 6% 포함하는,
포장지 접착제 조성물.According to claim 10,
Containing 4 to 6% by weight of the phosphorus pentoxide relative to the filler,
Wrapping paper adhesive composition.
상기 실리카를 상기 충진재에 대하여 중량으로 45 내지 55% 포함하는,
포장지 접착제 조성물.According to claim 10,
Comprising 45 to 55% by weight of the silica with respect to the filler,
Wrapping paper adhesive composition.
상기 기판의 적어도 일면 상에 형성된 접착제 조성물;을 포함하고,
상기 접착제 조성물은 제1항 내지 제14항 중 어느 한 항에 따른 포장지 접착제 조성물을 포함하는,
접착성 포장지.a substrate comprising paper; and
An adhesive composition formed on at least one surface of the substrate; includes,
The adhesive composition comprises the wrapping paper adhesive composition according to any one of claims 1 to 14,
adhesive wrapping paper.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000136369A (en) * | 1998-11-02 | 2000-05-16 | Kuraray Co Ltd | Aqueous adhesive |
| JP2009084316A (en) * | 2007-09-27 | 2009-04-23 | Miki Riken Kogyo Kk | Water-based composition containing vinyl alcohol polymer, and adhesive using the same |
| KR20130045947A (en) * | 2004-10-08 | 2013-05-06 | 바스프 에스이 | Stabilisation of aqueous solutions of homopolymers and copolymers of n-vinylpyrrolidones |
| JP2014156595A (en) * | 2013-01-21 | 2014-08-28 | Nippon Synthetic Chem Ind Co Ltd:The | Silyl group-containing polyvinyl alcohol resin and application thereof |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000136369A (en) * | 1998-11-02 | 2000-05-16 | Kuraray Co Ltd | Aqueous adhesive |
| KR20130045947A (en) * | 2004-10-08 | 2013-05-06 | 바스프 에스이 | Stabilisation of aqueous solutions of homopolymers and copolymers of n-vinylpyrrolidones |
| JP2009084316A (en) * | 2007-09-27 | 2009-04-23 | Miki Riken Kogyo Kk | Water-based composition containing vinyl alcohol polymer, and adhesive using the same |
| JP2014156595A (en) * | 2013-01-21 | 2014-08-28 | Nippon Synthetic Chem Ind Co Ltd:The | Silyl group-containing polyvinyl alcohol resin and application thereof |
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