KR20220134718A - Visable ray absorbent solder paste composition - Google Patents

Abstract

The present invention forms a light absorbing epoxy coating layer on the outside of a low melting point solder forming a contact part around a pad of a semiconductor substrate, thereby capable of mitigating an interference phenomenon caused by the reflected light of the solder. The present invention can omit a process of building an additional wall near the contact part of the substrate, which was performed to suppress the reflected light of the solder, and is to provide the light absorbing solder paste composition having an excellent process cost reduction effect since a light absorbing material used in the present invention has a very low manufacturing cost. The light absorbing solder paste composition comprises a surface-modified light absorbing material, an epoxy resin, a surfactant, a catalyst, a curing agent, a reducing agent, isobornyl methacrylate, dihydroxy phenylalanine, a low melting point solder, and a non-aqueous silicone antifoaming agent.

Description

Light absorbing solder paste composition {Visable ray absorbent solder paste composition}

The present invention relates to a light-absorbing solder paste composition.

Recently, as small electronic devices become highly functional, the density of semiconductors and integrated circuit boards is rapidly increasing. Accordingly, the soldering process has become an essential bonding technology, which is also a required process for bonding a micro LED and a printed circuit board or a semiconductor substrate.

The soldering process is a method of joining by melting metal between two dissimilar materials at a temperature of 450° C. or less, and the recent soldering process is developing in the direction of using a solder ball or a solder bump. A solder ball is a solder accessory that makes electrical and mechanical connections between a chip and a board. It refers to a precision material in the form of small beads that enables electrical signal transmission between the final chip and the circuit board.

A recent soldering process employs a reflow method in which a solder paste including an epoxy resin is applied and the applied solder paste is cured by convection of heat. In the heated state, the reaction of the epoxy curing agent is initiated, and the low-melting-point solder is melted. At this time, due to the difference in cohesion between the solder and the epoxy, the solder gathers inward to form a metal joint between the substrate and the component, and the epoxy resin causes the solder to melt. Contributes to maintaining a chemically stable state by enclosing metal joints, including

BACKGROUND ART Light emitting diodes (LEDs) have received attention in terms of low power consumption and low pollution factors, and their demand is increasing explosively. LEDs are mainly in demand for lighting devices, backlights of LCD display devices, and display devices. LED is a kind of solid-state device that converts electrical energy into light, and consists of an n-type semiconductor layer and a p-type semiconductor layer, and includes an active layer existing between the two layers. When a voltage is applied between the two layers, electrons and holes flow into the active layer, and then recombine within the active layer to generate light.

As described above, the LED is characterized by low power consumption, driving at a low voltage, and high energy efficiency and low heat generation. Due to the above-described characteristics, the LED is attracting attention as an electric device for display.

However, there is a problem in that light interference occurs due to the reflected light of the LED that is incident and reflected to the metal junction, which is the result of the above-described soldering process, and this interference phenomenon affects the resolution and color of the display.

In order to prevent this, a microarray substrate having a patterned thin film layer that blocks reflected light (Republic of Korea Patent Publication No. 10-0634505, 06.10.16.) is known, and technology based on the known information is widely used until now. , the micro-process is added to the substrate manufacturing process, so the process is expensive, and when a physical impact is applied to the substrate, the alignment of the micro-array is misaligned, and the light reinforcement phenomenon and interference phenomenon become severe, thereby reducing the overall quality.

Accordingly, it is necessary to introduce a method for effectively suppressing the reflected light of the LED that is generated due to the inexpensive process and the metal junction.

Republic of Korea Patent Publication No. 10-2202937 (2021.01.14.) Republic of Korea Patent Publication No. 10--2101345 (2020.04.09.) Republic of Korea Patent Publication No. 10-1826950 (2018.02.01.) Republic of Korea Patent Publication No. 10-1732965 (2017.04.27.) Republic of Korea Patent Publication No. 10-1219754 (2013.01.02.) Republic of Korea Patent Publication No. 10-1163172 (2012.06.29.)

In order to solve the above problems, an object of the present invention is to provide a light-absorbing solder paste composition capable of absorbing visible light.

One aspect of the present invention for solving the above problems is a surface-modified light absorbing material, an epoxy resin, a curing agent, a catalyst, a low melting point solder, isobornyl methacrylate, dihydroxy phenylalanine, a reducing agent, a surfactant, and a non-aqueous system It relates to a light-absorbing solder paste composition comprising a silicone antifoaming agent.

In one aspect, the surface-modified light absorbing material may include a light absorbing material including carbon black.

In one aspect, the surface-modified light absorbing material is 2-(3,4 epoxycyclohexyl)ethyltrimethoxysilane, 3-glycidoxypropylmethyldimethoxysilane, 3-glycidoxypropyltrimethoxy One containing a light absorbing material surface-modified by any one or two or more selected from the group of epoxy-based silane coupling agents consisting of silane, 3-glycidoxypropylmethyldiethoxysilane, and 3-glycidoxypropyltriethoxysilane can

In one aspect, the epoxy-based resin may include any one or two or more selected from the group consisting of a bifunctional epoxy, a trifunctional epoxy, and a tetrafunctional epoxy.

In one aspect, the curing agent may include any one or two or more selected from the group consisting of an amine family material and an anhydride family.

In one aspect, the curing agent may be characterized in that it may further include a thixotropic agent or a diluent.

In one aspect, the catalyst may include any one or two or more selected from the group consisting of benzyldimethylamine, BF ₃ -monoethylamine, tris(dimethylaminomethyl)phenol, dimethylbenzanthracene, and methylimidazole. have.

In the one aspect, the low melting point solder is Sn-In-based material, Sn-Bi-based material, Sn-Ag-based material, In-Ag-based material, Sn-Bi-Ag-based material, Sn-Bi-Pb-based material And Sn-Ag-Cu may be one comprising any one or two or more of the group consisting of a material.

In one aspect, the reducing agent may include any one or two or more selected from the group consisting of glutaric acid, maleic acid, azelaic acid, abietic acid, adipic acid, ascorbic acid, acrylic acid and citric acid. .

In one aspect, the surfactant may include any one or two or more selected from the group consisting of a nonionic surfactant and a fluorine-based surfactant. The fluorine-based surfactant may be, for example, perfluoroalkylamine oxide, perfluoroalkylpolyoxyethyleneethanol and fluorinated alkyl esters.

In one aspect, the non-aqueous silicone antifoaming agent may be a dimethyl silicone oil having a kinematic viscosity of 200 to 1500 cSt at 25°C.

The light-absorbing solder paste composition may be characterized in that it is suitable for infrared reflow soldering.

In one aspect, the composition may have a viscosity of 20,000 to 40,000 cps.

Another aspect of the present invention relates to a method for preparing the light-absorbing solder paste composition.

In another aspect, the manufacturing method comprises:

(First step) modifying the surface of the light absorbing material with an epoxy-based silane coupling agent;

(Second step) mixing an epoxy-based resin, a curing agent, and a surface-modified light-absorbing material to form a first mixture;

(3rd step) adding a catalyst, low melting point solder, isobornyl methacrylate and dihydroxy phenylalanine to the first mixture and mixing to form a second mixture;

(Step 4) adding and mixing a reducing agent to the second mixture to form a third mixture; and

(Step 5) adding and mixing a surfactant to the third mixture to form a light-absorbing solder paste composition;

may include.

Another aspect of the present invention relates to an arrangement and soldering method of micro LEDs on a semiconductor substrate using the solder paste composition.

In another aspect, the arrangement and soldering method of the micro LED in the semiconductor substrate,

(Step A) applying a light absorbing paste composition to a pad of a semiconductor substrate;

(Step B) manufacturing a laminate by adhering the microLED-attached sheet so that the microLED electrode is in contact with the upper part of the pad of the semiconductor substrate; and

(Step C) Heat of 90 to 200° C. is applied to the laminate to agglomerate and melt the low-melting-point solder in the solder paste composition around the electrode of the micro LED and the pad of the semiconductor substrate, so as to connect the micro LED and the semiconductor substrate. While forming, forming a light-absorbing epoxy coating layer to the outside of the contact portion;

may include.

The light-absorbing solder paste composition according to the present invention forms a light-absorbing epoxy coating layer on the outside of the low-melting-point solder having a contact portion formed around the pad of the semiconductor substrate, thereby mitigating the interference phenomenon caused by the reflected light of the solder.

By providing the present invention, it is possible to omit the process of erecting an additional wall near the contact portion of the substrate, which was implemented to suppress the reflected light of the solder, and the light absorbing material of the present invention has a very low manufacturing cost, so the cost of the process is reduced The effect is excellent.

Figure 1 (a) is a solder contact portion and an epoxy coating layer produced as a result of solder ball reflow without adding a light absorbing material.
FIG. 1(b) shows a solder contact portion and a light-absorbing epoxy coating layer produced as a result of solder ball reflow by adding 1 phr of a surface-modified light-absorbing material.
FIG. 1(c) shows a solder contact portion and a light-absorbing epoxy coating layer produced as a result of solder ball reflow by adding 3 phr of a surface-modified light-absorbing material.
FIG. 1( d ) shows a solder contact portion and a light-absorbing epoxy coating layer produced as a result of solder ball reflow by adding 5 phr of a surface-modified light-absorbing material.
2 is a substrate contact and an epoxy coating layer prepared according to an embodiment of the present invention.

Hereinafter, the light absorbing solder paste composition according to the present invention will be described in detail. The drawings introduced below are provided as examples so that the spirit of the present invention can be sufficiently conveyed to those skilled in the art. Accordingly, the present invention is not limited to the drawings presented below and may be embodied in other forms, and the drawings presented below may be exaggerated to clarify the spirit of the present invention. At this time, if there is no other definition in the technical terms and scientific terms used, it has the meaning commonly understood by those of ordinary skill in the art to which this invention belongs, and the gist of the present invention in the following description and accompanying drawings Descriptions of known functions and configurations that may be unnecessarily obscure will be omitted.

One aspect of the present invention provides a surface-modified light absorption material, an epoxy resin, a curing agent, a catalyst, a low melting point solder, isobornyl methacrylate, dihydroxy phenylalanine, a reducing agent, a surfactant, and a non-aqueous silicone antifoaming agent. It relates to a photonic solder paste composition.

The surface-modified light absorbing material is not particularly limited as long as it is a black pigment. Specifically, the surface-modified light absorbing material is preferably carbon black, and in this case, it is best to use carbon black having a particle size of 10 to 50 nm to exhibit light absorption performance.

The surface-modified light absorbing material is 2-(3,4 epoxycyclohexyl)ethyltrimethoxysilane, 3-glycidoxypropylmethyldimethoxysilane, 3-glycidoxypropyltrimethoxysilane, 3-glycy It may include a light absorbing material surface-modified by any one or two or more selected from the epoxy-based silane coupling agent group consisting of doxypropylmethyldiethoxysilane and 3-glycidoxypropyltriethoxysilane.

The amount of the silane coupling agent added at the time of surface modification of the surface-modified light absorbing material may be 1 to 20% by weight relative to carbon black, preferably 5 to 15% by weight, more preferably 7 to 13% by weight. It is good to add In such a range, the epoxy resin and the light-absorbing material can directly participate in the reaction during surface modification, so it is good to improve the dispersibility and adhesive performance of the light-absorbing material.

The epoxy-based resin is preferably a difunctional epoxy (DiGlycidylEther of Bisphenol of A, DGEBA), a trifunctional epoxy (Tri-Glycidyl p-Aminophenol, TGAP) and a tetrafunctional epoxy (TetraGlycidyl Diamine Diphenyl Methane, TGDDM) It may include any one or two or more selected from the group consisting of, but is not particularly limited as long as it is a known epoxy-based resin.

The curing agent may include any one or two or more selected from the group consisting of an amine family material and an anhydride family.

The amine-based material may be any one or two or more selected from the group consisting of meta-phenylenediamine, diaminodiphenyl methane and diaminodiphenyl sulfone, It is not particularly limited as long as it is a used material.

The anhydride-based material is 2-methyl-4-nitroaniline (2-methyl-4-nitroaniline), dodecenyl succinic anhydride, methyltetrahydrophthalic anhydride, It may be any one or two or more selected from the group consisting of tetrahydrophthalic anhydride and alc pyromellitic dianhydride, but is not particularly limited as long as it is a known material.

The curing agent may further include a thixotropic agent or a diluent.

The thixotropic agent includes hydrogenated castor wax, carnauba wax, ethylene glycol, polyglycols, polypropylene glycols, acrylate oligomers , glycerides, simethicone, tributyl phosphate, and preferably any one or two or more selected from the group consisting of silica compounds. However, it is not particularly limited as long as it is a material that can be used as a known thixotropic agent.

It is preferable to use an organic solvent such as brominated diphenyl ethers as the diluent. However, it is not particularly limited as long as it is a material that can be used as a known diluent.

The catalyst may include any one or two or more selected from the group consisting of benzyldimethylamine, BF ₃ -monoethylamine, tris(dimethylaminomethyl)phenol, dimethylbenzanthracene, and methylimidazole, but a known catalyst It is not particularly limited as long as it can be used as a material.

The low melting point solder includes a Sn-In-based material, a Sn-Bi-based material, a Sn-Ag-based material, an In-Ag-based material, a Sn-Bi-Ag-based material, a Sn-Bi-Pb-based material, and a Sn-Ag-Cu It may include any one or two or more from the group consisting of series materials. For example, the low melting point solder may be formed of a composition ratio such as 58Sn/42Bi, 60Sn/40Bi, 52In/48Sn, 97In/3Ag, 57Bi/42Sn/1Ag, 58Bi/32Pb/16Sn, and 96.5Sn/3Ag/0.5Cu. have.

The size of the low melting point solder particles may be selected according to the size (e.g. pitch) of the applied pattern, and as the size of the pattern increases, larger low melting point solder particles may be used. The size of the low-melting-point solder particles may be selected in the range of 5 nm to 100 μm.

The isobornyl methacrylate and dihydroxy phenylalanine contain 5 to 10 parts by weight of isobornyl methacrylate and 10 parts by weight of dihydroxyphenylalanine based on 100 parts by weight of the curing agent in order to increase the adhesion efficiency of the light absorbent solder paste composition of the present invention. to 20 parts by weight may be added.

The reducing agent is glutaric acid, maleic acid, azelaic acid, abietic acid, adipic acid, ascorbic acid, acrylic acid (acrylic acid) and citric acid may be one or two or more selected from the group consisting of, but is not particularly limited as long as it is an organic acid that can be used as a known reducing agent.

The surfactant may include any one or two or more selected from the group consisting of nonionic surfactants and fluorine-based surfactants. The fluorine-based surfactant may be, for example, perfluoroalkylamine oxide, perfluoroalkylpolyoxyethyleneethanol and fluorinated alkyl esters.

The non-aqueous silicone antifoaming agent is used to reduce the generation of bubbles, and exhibits defoaming performance by lowering the surface tension due to low attractive force between molecules and water repellency and non-contact properties of the surface to prevent stable formation of bubbles.

The non-aqueous silicone antifoaming agent may be included in 3 to 7 parts by weight based on 100 parts by weight of the curing agent. When it exceeds the above range, the viscosity of the composition is lowered, so it is difficult to immerse the substrate and uniformly apply it, and when it is less than the above range, the bubble suppression effect is insufficient.

The non-aqueous silicone antifoaming agent may be a dimethyl silicone oil having a kinematic viscosity of 200 to 1500 cSt at 25°C. When it exceeds the above range, miscibility with other materials is lowered, and when it is below the above range, the viscosity of the composition is lowered, making uniform application difficult.

According to one embodiment of the present invention, the composition of the present invention may further include auxiliary additives such as rheology modifiers or thickeners.

The rheology modifier or thickener may be an acrylate polymer compound, modified cellulose, or the like, and is not particularly limited as long as it is a known material.

The rheology modifier and the thickener may each contain 1 to 15 parts by weight based on 100 parts by weight of the curing agent.

The light absorbing solder paste composition may be suitable for infrared reflow soldering.

The light-absorbing solder paste composition may have a viscosity of 20,000 to 40,000 cps. When the viscosity of the composition is out of the above range, the adhesion efficiency of the micro-LED is lowered, and it may be difficult to uniformly apply the composition to the substrate.

The light absorbing solder paste may include 1 to 10 parts by weight of the light absorbing material based on 100 parts by weight of the epoxy resin. In such a range, the light absorption performance of the present invention is maximized, and a more specific range and effect will be described in the method for preparing the light absorption solder paste composition to be described later.

The light absorbing solder paste may include a curing agent in an equivalent ratio of 0.3 to 0.5 compared to the epoxy resin. In addition, the light absorbing solder paste is based on 100 parts by weight of the curing agent, 50 to 60 parts by weight of a diluent, 5 to 15 parts by weight of a thixotropic agent, 10 to 15 parts by weight of a catalyst, 10 to 15 parts by weight of a low melting point solder, 5 to 10 parts by weight of isobornyl methacrylate, 10 to 20 parts by weight of dihydroxyphenylalanine, 20 to 25 parts by weight of a reducing agent, 5 to 25 parts by weight of a surfactant, and 3 to 7 parts by weight of a non-aqueous silicone antifoaming agent may include. Within this range, the process efficiency of the light-absorbing solder paste composition of the present invention can be maximized, and a more specific range and effect will be described in the method for preparing the light-absorbing solder paste composition to be described later.

Another aspect of the present invention relates to a method for preparing a light-absorbing solder paste composition.

The manufacturing method is

(First step) modifying the surface of the light absorbing material with an epoxy-based silane coupling agent;

(Second step) mixing an epoxy resin, a curing agent, and a light absorbing material to form a first mixture;

(3rd step) adding a catalyst, low melting point solder, isobornyl methacrylate and dihydroxy phenylalanine to the first mixture and mixing to form a second mixture;

(Step 4) adding and mixing a reducing agent to the second mixture to form a third mixture; and

(Step 5) adding and mixing a surfactant to the third mixture to form a light-absorbing solder paste composition;

may include.

In the first step, 2-(3,4 epoxycyclohexyl)ethyltrimethoxysilane, 3-glycidoxypropylmethyldimethoxysilane, 3-glycidoxypropyltrimethoxysilane, 3-glycidoxy It may include one that is surface-modified by any one or two or more selected from the group of epoxy-based silane coupling agents consisting of propylmethyldiethoxysilane and 3-glycidoxypropyltriethoxysilane.

The amount of the silane coupling agent added during surface modification of the light absorbing material may be 1 to 20% by weight relative to the light absorbing material, preferably 5 to 15% by weight, more preferably 7 to 13% by weight. it's good When the surface is modified in this range, the epoxy functional group of the silane coupling agent on the surface of the light absorbing material can directly participate in the reaction, which is preferable to improve the dispersibility and adhesive performance of the light absorbing material.

In the second step, the amount of the curing agent constituting the first mixture is preferably contained in an equivalent ratio of 0.3 to 0.5 compared to the epoxy resin. When it exceeds the above range, the properties and chemical resistance to withstand high temperature, high humidity of the cured epoxy-based resin are deteriorated, and when it is less than the above range, curing of the epoxy-based resin is not smooth, which is not preferable.

In the second step, the amount of the light absorbing material included in the first mixture may be 1 to 10 parts by weight based on 100 parts by weight of the epoxy resin. In this case, it is preferable to include 1 to 7.5 parts by weight of the light absorbing material based on 100 parts by weight of the epoxy-based resin, and more preferably 1 to 5 parts by weight. When the above range is exceeded, the adhesive strength between the LED and the substrate is lowered and there may be a problem in durability, and when it is less than the above range, a sufficient light absorption effect cannot be obtained, which is not preferable.

In the second step, a diluent or a thixotropic agent may be further added to the curing agent.

In the second step, the diluent is organic such as dimethyl sulfoxide (DMSO), N,N-dimethylformamide (DMF) or brominated diphenylether (BDE). Any one or two or more selected from the group consisting of solvents are preferred, but if it is a material that can be used as a known diluent, it is not particularly limited. The diluent may be included in an amount of 50 to 60 parts by weight based on 100 parts by weight of the curing agent.

In the second step, the thixotropic agent is hydrogenated castor wax, carnauba wax, ethylene glycol, propylene glycol, polyglycols, polypropylene glycol (polypropylene glycol), acrylate oligomers (acrylate oligomers), glycerides (glycerides), simethicone (simethicone), the group consisting of organic substances such as tributyl phosphate (tributyl phosphate); Or any one or two or more selected from the group consisting of silica compounds. The thixotropic agent may be included in an amount of 5 to 15 parts by weight based on 100 parts by weight of the curing agent.

In the second step, the diluent and the thixotropic agent are preferably added within the above ranges to control the viscosity and thixotropic properties of the first mixture.

In the third step, the second mixture preferably contains 10 to 15 parts by weight of the catalyst based on 100 parts by weight of the curing agent. When the catalyst is included within the above range, the probability of bubbles being formed when the sealing layer is formed on the metal joint portion formed by bonding the solder of the substrate and the lead of the component through the heating process is low, so it is good to maximize the effect of the present invention .

In the third step, the second mixture preferably contains 10 to 15 parts by weight of the low-melting solder based on 100 parts by weight of the curing agent. When the above range is exceeded, the metal junction portion between the micro LED and the semiconductor becomes excessively large, which may cause a leakage current or a short circuit.

In the third step, the second mixture preferably contains 5 to 10 parts by weight of isobornyl methacrylate and 10 to 20 parts by weight of dihydroxyphenylalanine based on 100 parts by weight of the curing agent. The isobornyl methacrylate and dihydroxy phenylalanine serve to increase the adhesion efficiency of the light-absorbing solder paste composition of the present invention. When the isobornyl methacrylate or dihydroxy phenylalanine is included in less than the above range, the micro LED may not be bound to the upper portion of the semiconductor substrate, so that the yield of the process is very low.

In the fourth step, the reducing agent is glutaric acid, maleic acid, azelaic acid, abietic acid, adipic acid, ascor It may include any one or two or more selected from the group consisting of ascorbic acid, acrylic acid, and citric acid, but is not particularly limited as long as it is an organic acid that can be used as a known reducing agent.

The reducing agent is preferably included in an amount of 20 to 25 parts by weight based on 100 parts by weight of the curing agent. It is preferable that the electrode of the micro LED and the pad of the semiconductor substrate do not oxidize due to the reducing agent within this range.

In the fifth step, the light absorbing solder paste composition preferably contains 20 to 25 parts by weight of a surfactant based on 100 parts by weight of the curing agent. The surfactant may be a fluorine-based surfactant or a nonionic surfactant. Specifically, the fluorine-based surfactant may include any one or two or more selected from the group consisting of perfluoroalkylamine oxide, perfluoroalkylpolyoxyethyleneethanol, and fluorinated alkyl ester, and using a fluorine-based surfactant It is preferable because it can improve the physical properties of the epoxy layer, such as chemical resistance, moisture resistance, high temperature durability.

The surfactant may improve adhesion of the light-absorbing solder paste composition and reduce interfacial tension to promote uniform mixing between the mixtures. When the above range is exceeded, the flowability of the light absorbing paste composition is increased, so that it cannot be uniformly wrapped around the electrode of the micro LED and the pad of the semiconductor substrate. .

Another aspect of the present invention relates to a method for arranging and soldering micro LEDs on a semiconductor substrate using the light-absorbing solder paste composition.

The arrangement and soldering method of the micro LED on the semiconductor substrate,

(Step A) applying a light absorbing paste composition to a pad of a semiconductor substrate;

(Step B) manufacturing a laminate by adhering the microLED-attached sheet so that the microLED electrode is in contact with the upper part of the pad of the semiconductor substrate; and

(Step C) Heat of 90 to 200° C. is applied to the laminate to agglomerate and melt the low-melting-point solder in the solder paste composition around the electrode of the micro LED and the pad of the semiconductor substrate, so as to connect the micro LED and the semiconductor substrate. While forming, forming a light-absorbing epoxy coating layer to the outside of the contact portion;

may include.

Hereinafter, the light absorbing solder paste composition according to the present invention and a manufacturing method thereof will be described in more detail through examples. However, the following examples are only a reference for describing the present invention in detail, and the present invention is not limited thereto, and may be implemented in various forms.

Further, unless otherwise defined, all technical and scientific terms have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used herein is for the purpose of effectively describing particular embodiments only and is not intended to limit the invention. In addition, the unit of additives not specifically described in the specification may be weight %.

[Production Example 1]

9 g of carbon black having an average particle size of 40 nm was prepared. To modify the surface of the carbon black particles, ethanol and carbon black particles were mixed in a 1:1 weight ratio, and the mixture was stirred for 1 hour. Next, 1 g of Shinetsu's KBM-403 (3-glycidoxypropyltrimethoxysilane) was added and stirred in a thermostat maintained at 40° C. for 2 hours. Thereafter, ethanol was removed in a rotary evaporator to finally obtain a surface-modified light-absorbing material.

[Example 1]

100 g of diaminodiphenyl sulfone as a curing agent was added to 60 g of diphenyl ether as a diluent and 10 g of simethicone as a thixotropic agent, and the mixture was mixed at 130° C. for 20 minutes until all of the diaminodimethyl sulfone was dissolved. The trifunctional epoxy resin and the light absorbing material of Preparation Example 1 were added to the thus prepared solution and mixed at 25° C. for 20 minutes. At this time, the curing agent was included in an equivalent ratio of 0.4 to the epoxy resin, and 17 g of the light absorbing material of Preparation Example 1 was added to prepare a first mixture.

To the first mixture at room temperature, 10 g of BF3-monoethylamine, 30 g of low-melting solder, 5 g of isobornyl methacrylate, and 15 g of dihydroxyphenylalanine were added and mixed for 5 minutes to prepare a second mixture.

Then, 20 g of maleic acid as a reducing agent was added to the mixture containing the catalyst and mixed for 5 minutes, and then the mixture to which maleic acid was added was stirred at a speed of 30 rpm to prepare a third mixture, and then the third mixture was stirred at a speed of 30 rpm With continuous stirring, 20 g of Florad FC-4430, a surfactant, was added dropwise at a rate of 30 g/min to finally prepare a light-absorbing solder paste composition of the present invention.

[Examples 2 to 7]

The same procedure as in Example 1 was performed except that the content of the surface-modified light absorbing material was changed as shown in Table 1 below.

[Comparative Examples 1 to 3]

The same procedure as in Examples 1 to 3 was performed, except that carbon black having an average particle size of 40 nm and not subjected to surface modification treatment was used instead of Preparation Example 1.

[Comparative Example 7]

It proceeded in the same manner as in Example 1 except that the light absorbing material was not included.

Content of light-absorbing material compared to epoxy-based resin (wt%) Whether the surface of the light-absorbing material is modified Example 1 5 ○ Example 2 3 ○ Example 3 One ○ Example 4 0.1 ○ Example 5 0.5 ○ Example 6 10 ○ Example 7 20 ○ Comparative Example 1 5 × Comparative Example 2 3 × Comparative Example 3 One × Comparative Example 4 - -

[Characteristic evaluation method]

A. Visible light reflectance measurement

The reflectance of visible light (red light: 660 nm, green light: 550 nm, blue light: 470 nm) emitted by the micro LED was measured for the epoxy coating layer produced using the light-absorbing paste composition.

Red light (660nm) reflectance (%) Green light (550nm) reflectance (%) Blue light (470 nm) reflectance (%) Example 1 6.6 5.7 5.1 Example 2 7.4 6.1 5.5 Example 3 9.2 8.8 6.4 Example 4 43.8 22.1 15.3 Example 5 25.1 12.3 8.9 Comparative Example 1 6.8 6.0 5.0 Comparative Example 2 7.7 6.2 5.8 Comparative Example 3 10.1 9.3 8.8 Comparative Example 4 65.2 45.3 18.1

As can be seen from Table 2, as the light absorbing material is included, it can be seen that the reflectance of the three light sources decreases. In this case, Examples 1 to 3 showed particularly good results in that the reflectance for the three light sources was less than 10%.

B. Adhesive performance evaluation

The adhesive performance of the solder paste composition described in Table 1 and the sealing property of the epoxy enclosing the metal joint were compared.

First, a solder paste composition was applied to a substrate, and then heat of 150° C. was applied to the substrate and the solder paste composition for 5 minutes, and a reflow process was performed using an infrared laser process. The solder and the lead are combined through a reflow process to form a metal joint, and the cured epoxy surrounds the metal joint as a whole to form an epoxy sealing layer.

Bonding strength was measured using a tensile strength measuring device for the metal joint portion and the epoxy sealing layer. In addition, the epoxy layer was visually observed to evaluate the degree of formation and sealability of the epoxy coating layer (double-circle: excellent, o: good, Δ: poor, x: below standard). Table 3 shows the evaluation results of the solder paste compositions of Examples 1 to 3 and Comparative Examples 1 to 7 according to the above evaluation method.

metal joint
Bonding strength (kgf) epoxy layer
Bonding strength (kgf) of epoxy layer
Formation degree and sealability Example 1 29.0 1.38 ◎ Example 2 28.7 1.41 ◎ Example 3 28.6 1.42 ◎ Example 4 28.7 1.44 ◎ Example 5 27.4 1.43 ◎ Example 6 26.6 1.29 ○ Example 7 24.5 0.82 △ Comparative Example 1 26.3 0.97 × Comparative Example 2 26.9 1.02 × Comparative Example 3 28.4 1.25 △ Comparative Example 4 29.1 1.46 ◎ ◎: Epoxy layer is uniform and there is no flaw
○: Epoxy layer is not uniform or there is a flaw
△: The epoxy layer is not uniform and there is a very thin part
×: The epoxy layer is not uniform and the metal joint is exposed to the outside

As can be seen from Table 3, the joint strength of all metal joints was measured to be 15 kgf or more.

In Comparative Examples 1 to 3 including carbon black whose surface was not modified, the bonding strength of the epoxy layer was decreased, and the sealing of the epoxy layer was not perfect, so that the metal joint was exposed to the outside. In addition, Examples 6 to 7 containing a relatively large amount of the surface-modified light absorbing material showed a tendency that the epoxy layer was not formed to a uniform thickness or had poor sealing properties.

Such a result becomes clearer when referring to FIG. 2 below. In the case of Comparative Examples 1 and 2, an empty space (void) was observed in the epoxy layer, and Comparative Example 3 was sealed, but a very thin part was present, and Examples 1 to 3 including the surface-modified light absorbing material were excellent showed sealing properties.

Although the present invention has been described through specific matters and limited examples as described above, these are only provided to help a more general understanding of the present invention, and the present invention is not limited to the above examples, and the present invention pertains to Various modifications and variations are possible from these descriptions by those of ordinary skill in the art.

Therefore, the spirit of the present invention should not be limited to the described embodiments, and not only the claims described below, but also all those with equivalent or equivalent modifications to the claims will be said to belong to the scope of the spirit of the present invention. .

Claims (15)

A light-absorbing solder paste composition comprising a surface-modified light-absorbing material, an epoxy-based resin, a surfactant, a catalyst, a curing agent, a reducing agent, isobornyl methacrylate, dihydroxy phenylalanine, a low melting point solder, and a non-aqueous silicone antifoaming agent. The method of claim 1,
The light-absorbing solder paste composition comprising a light-absorbing material including carbon black, wherein the surface-modified light-absorbing material includes carbon black. 3. The method of claim 2,
The surface-modified light absorbing material is 2-(3,4 epoxycyclohexyl)ethyltrimethoxysilane, 3-glycidoxypropylmethyldimethoxysilane, 3-glycidoxypropyltrimethoxysilane, 3-glycy A light absorption solder paste composition comprising a light absorption material surface-modified by any one or two or more selected from the group of epoxy-based silane coupling agents consisting of doxypropylmethyldiethoxysilane and 3-glycidoxypropyltriethoxysilane. The method of claim 1,
The composition is a light-absorbing solder paste composition having a viscosity of 20,000 to 40,000 cps. The method of claim 1,
The epoxy-based resin is a light-absorbing solder paste composition comprising any one or two or more selected from the group consisting of a bifunctional epoxy, a trifunctional epoxy, and a tetrafunctional epoxy. The method of claim 1,
The light-absorbing solder paste composition, characterized in that the composition may further include a thixotropic agent or a diluent. The method of claim 1,
The surfactant is a light-absorbing solder paste composition comprising any one or two or more selected from the group consisting of a nonionic surfactant and a fluorine-based surfactant. The method of claim 1,
The catalyst is a light-absorbing solder paste composition comprising any one or two or more selected from the group consisting of benzyl dimethylamine, BF ₃ -monoethylamine, tris(dimethylaminomethyl)phenol, dimethylbenzanthracene, and methylimidazole. The method of claim 1,
The curing agent is a light-absorbing solder paste composition comprising any one or two or more selected from the group consisting of an amine family material and an anhydride family. The method of claim 1,
The reducing agent comprises any one or two or more selected from the group consisting of glutaric acid, maleic acid, azelaic acid, abietic acid, adipic acid, ascorbic acid, acrylic acid and citric acid. The method of claim 1,
The low melting point solder includes a Sn-In-based material, a Sn-Bi-based material, a Sn-Ag-based material, an In-Ag-based material, a Sn-Bi-Ag-based material, a Sn-Bi-Pb-based material, and a Sn-Ag-Cu A light-absorbing solder paste composition comprising any one or two or more of the group consisting of series materials. The method of claim 1,
The light-absorbing solder paste composition, characterized in that the non-aqueous silicone antifoaming agent is dimethyl silicone oil having a kinematic viscosity of 200 to 1500 cSt at 25°C. 13. The method according to any one of claims 1 to 12,
The light-absorbing solder paste composition is a light-absorbing solder paste composition, characterized in that it is suitable for infrared reflow soldering. (First step) modifying the surface of the light absorbing material with an epoxy-based silane coupling agent;
(Second step) mixing an epoxy-based resin, a curing agent, and a surface-modified light-absorbing material to form a first mixture;
(3rd step) adding a catalyst, low melting point solder, isobornyl methacrylate and dihydroxy phenylalanine to the first mixture and mixing to form a second mixture;
(Step 4) adding and mixing a reducing agent to the second mixture to form a third mixture; and
(Step 5) adding and mixing a surfactant to the third mixture to form a light-absorbing solder paste composition;
A method for producing a light absorbing solder paste composition comprising a. (Step A) applying the light absorbing paste composition of claim 1 to a pad of a semiconductor substrate;
(Step B) manufacturing a laminate by adhering the micro-LED-attached sheet so that the micro-LED electrode is in contact with the upper part of the pad of the semiconductor substrate; and
(Step C) Heat of 90 to 200° C. is applied to the laminate so that the low-melting-point solder in the solder paste composition is aggregated and melted around the electrode of the micro LED and the pad of the semiconductor substrate, so as to connect the micro LED and the semiconductor substrate. While forming, forming a light-absorbing epoxy coating layer to the outside of the contact portion;
An arrangement and soldering method of micro LEDs on a semiconductor substrate comprising a.

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