KR20220134290A - Cleaning method of black sapphire grapes - Google Patents
Cleaning method of black sapphire grapes Download PDFInfo
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- KR20220134290A KR20220134290A KR1020210039774A KR20210039774A KR20220134290A KR 20220134290 A KR20220134290 A KR 20220134290A KR 1020210039774 A KR1020210039774 A KR 1020210039774A KR 20210039774 A KR20210039774 A KR 20210039774A KR 20220134290 A KR20220134290 A KR 20220134290A
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- sapphire
- black sapphire
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- 241000219094 Vitaceae Species 0.000 title claims abstract description 88
- 235000021021 grapes Nutrition 0.000 title claims abstract description 88
- 229910052594 sapphire Inorganic materials 0.000 title claims abstract description 69
- 239000010980 sapphire Substances 0.000 title claims abstract description 69
- 238000000034 method Methods 0.000 title claims abstract description 30
- 238000004140 cleaning Methods 0.000 title abstract description 13
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000292 calcium oxide Substances 0.000 claims abstract description 20
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 19
- 238000001035 drying Methods 0.000 claims abstract description 16
- 239000000052 vinegar Substances 0.000 claims abstract description 9
- 235000021419 vinegar Nutrition 0.000 claims abstract description 9
- 238000005406 washing Methods 0.000 claims description 118
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims description 52
- 239000000243 solution Substances 0.000 claims description 35
- 230000001954 sterilising effect Effects 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000008213 purified water Substances 0.000 claims description 12
- 238000004659 sterilization and disinfection Methods 0.000 claims description 11
- 239000012425 OXONE® Substances 0.000 claims description 7
- OKBMCNHOEMXPTM-UHFFFAOYSA-M potassium peroxymonosulfate Chemical compound [K+].OOS([O-])(=O)=O OKBMCNHOEMXPTM-UHFFFAOYSA-M 0.000 claims description 7
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 21
- 239000000126 substance Substances 0.000 abstract description 9
- 239000000463 material Substances 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 description 22
- 238000002360 preparation method Methods 0.000 description 11
- 238000000354 decomposition reaction Methods 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 241000219095 Vitis Species 0.000 description 4
- 235000009754 Vitis X bourquina Nutrition 0.000 description 4
- 235000012333 Vitis X labruscana Nutrition 0.000 description 4
- 235000014787 Vitis vinifera Nutrition 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- 239000000447 pesticide residue Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 230000000593 degrading effect Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 235000002597 Solanum melongena Nutrition 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 235000020281 long black Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
- A23L5/57—Chemical peeling or cleaning of harvested fruits, vegetables or other foodstuffs
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3481—Organic compounds containing oxygen
- A23L3/3508—Organic compounds containing oxygen containing carboxyl groups
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23N—MACHINES OR APPARATUS FOR TREATING HARVESTED FRUIT, VEGETABLES OR FLOWER BULBS IN BULK, NOT OTHERWISE PROVIDED FOR; PEELING VEGETABLES OR FRUIT IN BULK; APPARATUS FOR PREPARING ANIMAL FEEDING- STUFFS
- A23N12/00—Machines for cleaning, blanching, drying or roasting fruits or vegetables, e.g. coffee, cocoa, nuts
- A23N12/02—Machines for cleaning, blanching, drying or roasting fruits or vegetables, e.g. coffee, cocoa, nuts for washing or blanching
- A23N12/023—Machines for cleaning, blanching, drying or roasting fruits or vegetables, e.g. coffee, cocoa, nuts for washing or blanching for washing potatoes, apples or similarly shaped vegetables or fruit
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23N—MACHINES OR APPARATUS FOR TREATING HARVESTED FRUIT, VEGETABLES OR FLOWER BULBS IN BULK, NOT OTHERWISE PROVIDED FOR; PEELING VEGETABLES OR FRUIT IN BULK; APPARATUS FOR PREPARING ANIMAL FEEDING- STUFFS
- A23N12/00—Machines for cleaning, blanching, drying or roasting fruits or vegetables, e.g. coffee, cocoa, nuts
- A23N12/06—Machines for cleaning, blanching, drying or roasting fruits or vegetables, e.g. coffee, cocoa, nuts for washing or blanching, combined with subsequent drying
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/12—Carbonates bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/20—Water-insoluble oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
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- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Emergency Medicine (AREA)
- Storage Of Fruits Or Vegetables (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
본 발명은 블랙사파이어 포도의 세척방법에 관한 것으로, 더욱 상세하게는 포도의 당도나 외관품질을 저하시키지 않으면서도, 포도 표면에 잔존하는 이물질과 잔류농액에 대해 우수한 제거효과를 나타내는 블랙사파이어 포도의 세척방법에 관한 것이다.The present invention relates to a method of washing black sapphire grapes, and more particularly, washing of black sapphire grapes exhibiting an excellent removal effect on foreign substances and residual concentrate remaining on the surface of grapes without reducing the sugar content or appearance quality of the grapes. it's about how
일반적으로 농약은 농작물 및 과일 등에 해로운 병균, 해충 및 잡초 등의 유해생물을 제거하거나, 이로부터 발생되는 피해를 방지하기 위하여 사용되는 현대농업의 필수품이다. 최근에는 농산물의 수요 증가와 함께 농약 및 화학 비료의 사용량도 해마다 증가되는 실정이며, 현재 우리나라에서 사용되는 농약의 종류는 약 850여 종이 있으며, 주로 유기인계 화합물인 살충제와 제초제가 사용된다.In general, pesticides are essential items of modern agriculture that are used to remove harmful organisms such as germs, pests and weeds that are harmful to crops and fruits, or to prevent damage from them. Recently, along with the increase in the demand for agricultural products, the usage of pesticides and chemical fertilizers is also increasing year by year. Currently, there are about 850 kinds of pesticides used in Korea, and pesticides and herbicides, which are organophosphorus compounds, are mainly used.
이와 같은 농약과 화학 비료의 사용 증가로 인하여 농작물에 대한 오염이 가중되고 있으며, 수입 개방에 따른 외국산 농작물의 경우 오랜 유통기간 동안 그 신선도를 유지하기 위해 각종 살균제와 방부제 등의 화학적 처리를 과도하게 하여 이에 의한 오염이 증가되고 있다.Due to the increased use of pesticides and chemical fertilizers, contamination of crops is aggravated, and in the case of foreign crops following the opening of imports, chemical treatments such as various disinfectants and preservatives are excessively applied to maintain their freshness during a long distribution period. Pollution due to this is increasing.
이와 같이 농작물에 살포된 농약의 잔류상태는 농작물의 표면에 부착, 농작물 표면층에 용해, 및 농작물 내에 침투 등 3 가지 상태로 구분되는데, 현재 일반적으로 사용되고 있는 농약의 성분은 대부분 물에 불용성이기 때문에 물로 세척하더라도 잘 제거되지 않으며, 특히 이와 같은 잔류농약의 90% 이상이 껍질 부분에 존재하는 것으로 알려져 있다.As such, the residual state of the pesticide sprayed on crops is divided into three states: adhered to the surface of crops, dissolved in the surface layer of crops, and penetrated into crops. It is not easily removed even after washing, and in particular, it is known that more than 90% of such residual pesticides are present in the skin.
한편, 블랙 사파이어 포도는 미국에서 개발된 신품종 포도로, 일반 포도처럼 열매가 동그랗지 않고 길쭉한 타원형 형태를 나타내는데, 이러한 모양 때문에 가지 포도라고도 불리우며, 아삭한 식감에 씨가 없고 평균 당도가 20 내지 23 Brix로 고당도를 나타내기 때문에 해외 뿐만 아니라, 국내에서도 입소문을 타고 소비량이 급증하고 있다.On the other hand, black sapphire grapes are a new grape variety developed in the United States, and the fruits are not round like regular grapes, but have an elongated oval shape. Because of this shape, they are also called eggplant grapes. Because of its high sugar content, consumption is rapidly increasing through word of mouth not only overseas but also domestically.
블랙 사파이어 포도는 2018년 국내에 처음 선보여진 후 문드롭, 스위트 사파이어, 롱 블랙 포도 등과 같이 다양한 별명이 붙여졌는데, 높아지는 인기에도 물량이 많지 않아 시중에서 보기 힘들고 국내에서 생산이 이루어지기도 하나, 해외에서 수입되는 물량도 지속적으로 증가하고 있는데, 해외에서 수입되는 블랙 사파이어 포도의 경우 주로 선박을 통해 수입되기 때문에, 포도의 재배 과정에서 사용되는 잔류농약 뿐만 아니라, 포도의 변질을 방지하기 위해 살포하는 농약 성분이 포도의 표면에 다량 잔존하게 되는 문제점이 있었다.After being first introduced to Korea in 2018, black sapphire grapes have been given various nicknames such as moondrop, sweet sapphire, and long black grapes. The quantity of imported black sapphire grapes is also continuously increasing. Since black sapphire grapes imported from overseas are mainly imported through ships, not only residual pesticides used in the grape growing process, but also pesticides applied to prevent deterioration of grapes There was a problem with the large amount remaining on the surface of these grapes.
본 발명의 목적은 포도의 당도나 외관품질을 저하시키지 않으면서도, 포도 표면에 잔존하는 이물질과 잔류농액에 대해 우수한 제거효과를 나타내는 블랙사파이어 포도의 세척방법을 제공하는 것이다.It is an object of the present invention to provide a method for washing black sapphire grapes that exhibits an excellent removal effect on foreign substances and residual concentrate remaining on the surface of the grapes without degrading the sugar content or appearance quality of the grapes.
본 발명의 다른 목적은 과초산의 분해가 억제되는 과초산 수용액을 사용하여 우수한 살균효과를 나타내는 블랙사파이어 포도의 세척방법을 제공하는 것이다.Another object of the present invention is to provide a method for washing black sapphire grapes which exhibits an excellent sterilization effect using an aqueous peracetic acid solution in which the decomposition of peracetic acid is suppressed.
본 발명의 목적은 블랙사파이어 포도를 베이킹 파우더 및 식초를 함유하는 제1세척액이 채워진 제1버블세척기에서 세척하는 제1세척단계, 상기 제1세척단계를 통해 세척된 블랙사파이어 포도를 베이킹파우더 및 산화칼슘을 함유하는 제2세척액이 채워진 제2버블세척기에서 세척하는 제2세척단계 및 상기 제2세척단계를 통해 세척된 블랙사파이어 포도를 건조하는 건조단계로 이루어지는 것을 특징으로 하는 블랙사파이어 포도의 세척방법을 제공함에 의해 달성된다.An object of the present invention is a first washing step of washing black sapphire grapes in a first bubble washing machine filled with a first washing solution containing baking powder and vinegar, and baking powder and oxidation of black sapphire grapes washed through the first washing step. A method of washing black sapphire grapes, comprising a second washing step of washing in a second bubble washer filled with a second washing solution containing calcium and a drying step of drying the black sapphire grapes washed through the second washing step This is achieved by providing
본 발명의 바람직한 특징에 따르면, 상기 제1세척액은 정제수 100 중량부, 베이킹 파우더 0.05 내지 0.15 중량부 및 식초 0.05 내지 0.15 중량부로 이루어지는 것으로 한다.According to a preferred feature of the present invention, the first washing solution is to be composed of 100 parts by weight of purified water, 0.05 to 0.15 parts by weight of baking powder, and 0.05 to 0.15 parts by weight of vinegar.
본 발명의 더 바람직한 특징에 따르면, 상기 제1세척단계는 20 내지 30℃의 온도에서 20 내지 40초 동안 이루어지는 것으로 한다.According to a more preferred feature of the present invention, the first washing step is performed at a temperature of 20 to 30° C. for 20 to 40 seconds.
본 발명의 더욱 바람직한 특징에 따르면, 상기 제2세척액은 정제수 100 중량부, 베이킹 파우더 0.05 내지 0.15 중량부 및 산화칼슘 0.05 내지 0.15 중량부로 이루어지는 것으로 한다.According to a more preferred feature of the present invention, the second washing solution is to be composed of 100 parts by weight of purified water, 0.05 to 0.15 parts by weight of baking powder, and 0.05 to 0.15 parts by weight of calcium oxide.
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 산화칼슘은 질량농도가 97 내지 99%인 것으로 한다.According to an even more preferred feature of the present invention, the calcium oxide is assumed to have a mass concentration of 97 to 99%.
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 제2세척단계는 13 내지 15℃의 온도에서 20 내지 40초 동안 이루어지는 것으로 한다.According to an even more preferred feature of the present invention, the second washing step is performed at a temperature of 13 to 15° C. for 20 to 40 seconds.
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 제2세척단계와 상기 건조단계 사이에는 상기 제2세척단계를 통해 세척된 블랙사파이어 포도를 과초산 수용액으로 살균하는 살균단계가 더 진행되는 것으로 한다.According to an even more preferred feature of the present invention, a sterilization step of sterilizing the black sapphire grapes washed through the second washing step with an aqueous peracetic acid solution is further performed between the second washing step and the drying step.
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 과초산 수용액은 정제수 100 중량부, 과초산 0.01 내지 1 중량부, 에티드론산 0.1 내지 5 중량부 및 포타슘퍼옥시모노설페이트 0.1 내지 1 중량부로 이루어지는 것으로 한다.According to an even more preferred feature of the present invention, the aqueous peracetic acid solution is 100 parts by weight of purified water, 0.01 to 1 parts by weight of peracetic acid, 0.1 to 5 parts by weight of etidronic acid, and 0.1 to 1 parts by weight of potassium peroxymonosulfate. .
본 발명에 따른 블랙사파이어 포도의 세척방법은 포도의 당도나 외관품질을 저하시키지 않으면서도, 포도 표면에 잔존하는 이물질과 잔류농액에 대해 우수한 제거효과를 나타낸다.The method for washing black sapphire grapes according to the present invention exhibits an excellent removal effect on foreign substances and residual concentrate remaining on the grape surface without degrading the sugar content or appearance quality of the grapes.
또한, 과초산의 분해가 억제되는 과초산 수용액을 사용하여 우수한 살균효과를 나타낸다.In addition, it shows an excellent sterilization effect by using an aqueous peracetic acid solution in which the decomposition of peracetic acid is suppressed.
도 1은 블랙사파이어 포도의 외관을 촬영하여 나타낸 사진이다.
도 1는 본 발명의 일 실시예에 따른 블랙사파이어 포도의 세척방법을 나타낸 순서도이다.
도 2는 본 발명의 다른 실시예에 따른 블랙사파이어 포도의 세척방법을 나타낸 순서도이다.1 is a photograph showing the appearance of black sapphire grapes.
1 is a flowchart illustrating a method of washing black sapphire grapes according to an embodiment of the present invention.
2 is a flowchart illustrating a method of washing black sapphire grapes according to another embodiment of the present invention.
이하에는, 본 발명의 바람직한 실시예와 각 성분의 물성을 상세하게 설명하되, 이는 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 발명을 용이하게 실시할 수 있을 정도로 상세하게 설명하기 위한 것이지, 이로 인해 본 발명의 기술적인 사상 및 범주가 한정되는 것을 의미하지는 않는다.Hereinafter, a preferred embodiment of the present invention and the physical properties of each component will be described in detail, which is intended to describe in detail enough that a person of ordinary skill in the art to which the present invention pertains can easily carry out the invention, This does not mean that the technical spirit and scope of the present invention is limited.
본 발명에 따른 블랙사파이어 포도의 세척방법은 블랙사파이어 포도를 베이킹 파우더 및 식초를 함유하는 제1세척액이 채워진 제1버블세척기에서 세척하는 제1세척단계(S101), 상기 제1세척단계(S101)를 통해 세척된 블랙사파이어 포도를 베이킹파우더 및 산화칼슘을 함유하는 제2세척액이 채워진 제2버블세척기에서 세척하는 제2세척단계(S103) 및 상기 제2세척단계(S103)를 통해 세척된 블랙사파이어 포도를 건조하는 건조단계(S105)로 이루어진다.The method of washing black sapphire grapes according to the present invention includes a first washing step (S101) of washing black sapphire grapes in a first bubble washing machine filled with a first washing solution containing baking powder and vinegar, the first washing step (S101) The black sapphire washed through the second washing step (S103) and the second washing step (S103) of washing the black sapphire grapes washed through in a second bubble washing machine filled with a second washing solution containing baking powder and calcium oxide It consists of a drying step (S105) of drying the grapes.
상기 제1세척단계(S101)는 블랙사파이어 포도를 베이킹 파우더 및 식초를 함유하는 제1세척액이 채워진 제1버블세척기에서 세척하는 단계로, 제1버블세척기에 정제수 100 중량부, 베이킹 파우더 0.05 내지 0.15 중량부 및 식초 0.05 내지 0.15 중량부로 이루어진 제1세척액을 채운 후에, 버블을 발생시켜 블랙사파이어 포도를 세척하는 과정으로 이루어지는데, 상기의 과정으로 이루어지는 제1세척단계(S101)를 거치면 블랙사파이어 포도의 표면에 잔존하는 세균, 이물질 및 잔류농약의 일부가 제거된다.The first washing step (S101) is a step of washing the black sapphire grapes in a first bubble washing machine filled with a first washing solution containing baking powder and vinegar, 100 parts by weight of purified water, 0.05 to 0.15 baking powder in the first bubble washing machine After filling the first washing solution consisting of 0.05 to 0.15 parts by weight of vinegar and 0.05 to 0.15 parts by weight, it consists of a process of washing black sapphire grapes by generating bubbles. Some of the bacteria, foreign substances and residual pesticides remaining on the surface are removed.
이때, 상기 제1세척단계(S101)는 13 내지 15℃의 온도에서 20 내지 40초 동안 이루어지는데, 이때, 상기 제1버블세척기는 통상적으로 버블을 발생시키는 세척기라면 특별히 한정되지 않고 어떠한 것이든 사용가능하다.In this case, the first washing step (S101) is performed at a temperature of 13 to 15° C. for 20 to 40 seconds. At this time, the first bubble washing machine is not particularly limited as long as it is a washing machine that typically generates bubbles, and any type of washing machine is used. It is possible.
블랙사파이어 포도는 아래 도 1에 나타낸 것처럼, 포도알 사이에 공간이 존재하기 때문에, 상기 제1버블세척기를 통해 발생되는 버블이 포도알 사이 공간으로 침투하여 포도알 표면에 대해 전체적으로 우수한 세척효과 및 잔류농약 제거효과를 나타낸다.As the black sapphire grapes have a space between the grapes, as shown in FIG. 1 below, the bubbles generated through the first bubble washing machine penetrate into the space between the grapes, so that the overall excellent cleaning effect and residue on the surface of the grapes. Shows the effect of removing pesticides.
이때, 상기 제1세척단계(S101)의 온도가 13℃ 미만이면 세척효과나 잔류농약 제거효과가 저하되며, 상기 제1세척단계(S101)의 온도가 15℃를 초과하게 되면 포도의 품질이 저하될 수 있다.At this time, if the temperature of the first washing step (S101) is less than 13 ℃, the cleaning effect or the residual pesticide removal effect is reduced, and when the temperature of the first washing step (S101) exceeds 15 ℃, the quality of grapes is lowered can be
또한, 상기 제1세척단계(S101)의 시간이 20초 미만이면 세척효과나 잔류농약 제거효과가 저하되며, 상기 제1세척단계(S101)의 시간이 40초를 초과하게 되면 블랙사파이어 포도의 당도가 저하될 수 있다.In addition, if the time of the first washing step (S101) is less than 20 seconds, the washing effect or the residual pesticide removal effect is reduced, and if the time of the first washing step (S101) exceeds 40 seconds, the sugar content of the black sapphire grapes may be lowered.
또한, 상기 제1세척단계(S101)에서는 산화칼슘 대신 탄산칼슘을 사용해도 무방하다.Also, in the first washing step (S101), calcium carbonate may be used instead of calcium oxide.
상기 제2세척단계(S103)는 상기 제1세척단계(S101)를 통해 세척된 블랙사파이어 포도를 베이킹파우더 및 산화칼슘을 함유하는 제2세척액이 채워진 제2버블세척기에서 세척하는 단계로, 상기 제1세척단계(S101)를 통해 세청된 블랙사파이어 포도를 컨베이어 등을 이용하여 제2세척액이 채워진 제2버블세척기로 이송한 후에 세척하는 과정으로 이루어진다.The second washing step (S103) is a step of washing the black sapphire grapes washed through the first washing step (S101) in a second bubble washing machine filled with a second washing solution containing baking powder and calcium oxide. It consists of a process of washing the black sapphire grapes washed through the first washing step (S101) after transferring them to a second bubble washing machine filled with a second washing solution using a conveyor or the like.
이때, 상기 제2세척액은 정제수 100 중량부, 베이킹 파우더 0.05 내지 0.15 중량부 및 산화칼슘 0.05 내지 0.15 중량부로 이루어지는데, 상기 산화칼슘은 통상적으로 소성패각 분말로부터 얻어지는데, 블랙 사파이어의 표면에 잔존하는 잔류농약에 대해 우수한 제거효과를 나타낸다.At this time, the second washing solution consists of 100 parts by weight of purified water, 0.05 to 0.15 parts by weight of baking powder, and 0.05 to 0.15 parts by weight of calcium oxide, and the calcium oxide is usually obtained from calcined shell powder, remaining on the surface of black sapphire. It shows an excellent removal effect for residual pesticides.
이때, 상기 산화칼슘의 질량농도는 97 내지 99%인 것을 사용하는 것이 바람직하며, 불가피하게 질량농도가 낮은 산화칼슘을 사용하는 경우에는 산화칼슘의 농도에 따라 그 양을 증가시키는 것이 바람직하다.At this time, it is preferable to use a mass concentration of 97 to 99% of the calcium oxide, and when calcium oxide having a low mass concentration is used inevitably, it is preferable to increase the amount according to the concentration of the calcium oxide.
상기 산화칼슘의 함량이 0.05 중량부 미만이면 잔류농약 제거효과가 미미하며, 상기 산화칼슘의 함량이 0.15 중량부를 초과하게 되면 잔류농약의 제거효과는 크게 향상되지 않으면서 블랙사파이어 포도의 표면에 산화칼슘 성분이 지나치가 많이 잔존하여 외관품질을 저하시킬 수 있다.When the content of calcium oxide is less than 0.05 parts by weight, the effect of removing pesticide residues is insignificant, and when the content of calcium oxide exceeds 0.15 parts by weight, the effect of removing residual pesticides is not significantly improved, but calcium oxide on the surface of black sapphire grapes Excessive amount of ingredients may remain, which may deteriorate the appearance quality.
이때, 상기 제2세척단계(S103)는 13 내지 15℃의 온도에서 20 내지 40초 동안 이루어지는데, 이때, 상기 제2버블세척기는 통상적으로 버블을 발생시키는 세척기라면 특별히 한정되지 않고 어떠한 것이든 사용가능하다.At this time, the second washing step (S103) is performed at a temperature of 13 to 15° C. for 20 to 40 seconds. At this time, the second bubble washing machine is not particularly limited as long as it is a washing machine that typically generates bubbles, and any type of washing machine is used. It is possible.
블랙사파이어 포도는 아래 도 1에 나타낸 것처럼, 포도알 사이에 공간이 존재하기 때문에, 상기 제2버블세척기를 통해 발생되는 버블이 포도알 사이 공간으로 침투하여 포도알 표면에 대해 전체적으로 우수한 잔류농약 제거효과를 나타낸다.As the black sapphire grapes have a space between the grapes, as shown in FIG. 1 below, the bubbles generated through the second bubble washing machine penetrate into the space between the grapes, so that the overall excellent effect of removing pesticide residues on the surface of the grapes. indicates
이때, 상기 제2세척단계(S103)의 온도가 13℃ 미만이면 산화칼슘의 용해효과 저해로 인해 잔류농약 제거효과가 저하되며, 상기 제2세척단계(S103)의 온도가 15℃를 초과하게 되면 포도의 품질이 저하될 수 있다.At this time, if the temperature of the second washing step (S103) is less than 13 ℃, the effect of removing the residual pesticide is lowered due to the inhibition of the dissolution effect of calcium oxide, and when the temperature of the second washing step (S103) exceeds 15 ℃ The quality of the grapes may be reduced.
또한, 상기 제2세척단계(S103)의 시간이 20초 미만이면 잔류농약 제거효과가 저하되며, 상기 제2세척단계(S103)의 시간이 40초를 초과하게 되면 블랙사파이어 포도의 당도가 저하될 수 있다.In addition, if the time of the second washing step (S103) is less than 20 seconds, the residual pesticide removal effect is reduced, and if the time of the second washing step (S103) exceeds 40 seconds, the sugar content of the black sapphire grapes is lowered. can
또한, 상기 제2세척단계(S103)에서는 산화칼슘 대신 탄산칼슘을 사용해도 무방하다.Also, in the second washing step (S103), calcium carbonate may be used instead of calcium oxide.
상기 건조단계(S105)는 상기 제2세척단계(S103)를 통해 세척된 블랙사파이어 포도를 건조하는 단계로, 상기 제2세척단계(S103)를 통해 세척된 블랙사파이어 포도를 컨베이어 벨트 등을 이용하여 그늘지고 상온의 온도조건인 공간으로 이송하여 자연건조하거나, 건조장치에 투입하고 15 내지 25℃의 온도에서 건조하는 과정으로 이루어지거나, 컨베이어 벨트 라인에 구비되어 있는 송풍기를 이용하여 건조하는 과정으로 이루어진다.The drying step (S105) is a step of drying the black sapphire grapes washed through the second washing step (S103). It can be naturally dried by transporting it to a shaded space at room temperature, put in a drying device and dried at a temperature of 15 to 25°C, or it can be dried using a blower provided in a conveyor belt line. .
또한, 상기 제2세척단계(S103)와 상기 건조단계(S105) 사이에는 상기 제2세척단계(S103)를 통해 세척된 블랙사파이어 포도를 과초산 수용액으로 살균하는 살균단계(S104)가 더 진행될 수도 있는데, 상기 제2세척단계(S103)를 통해 세척된 블랙사파이어 포도를 컨베이어 벨트 등을 이용하여 과초산 수용액이 채워진 살균조로 이송하고 10 내지 20초 동안 함침하는 과정으로 이루어진다.In addition, between the second washing step (S103) and the drying step (S105), a sterilization step (S104) of sterilizing the black sapphire grapes washed through the second washing step (S103) with an aqueous peracetic acid solution may be further performed. There, the black sapphire grapes washed through the second washing step (S103) are transferred to a sterilization tank filled with an aqueous peracetic acid solution using a conveyor belt, etc. and impregnated for 10 to 20 seconds.
상기의 과정으로 이루어지는 살균단계(S104)를 통해 블랙사파이어 포도를 과초산 수용액으로 살균하게 되면, 블랙사파이어 포도의 표면에 잔존하는 세균이 제거되어 블랙사파이어 포도의 변질이 억제되어 보존성이 더욱 향상될 수 있다.When the black sapphire grapes are sterilized with an aqueous peracetic acid solution through the sterilization step (S104) consisting of the above process, the bacteria remaining on the surface of the black sapphire grapes are removed, thereby suppressing the deterioration of the black sapphire grapes and further improving the preservation. have.
이때, 상기 과초산 수용액은 정제수 100 중량부, 과초산 0.01 내지 1 중량부, 에티드론산 0.1 내지 5 중량부 및 포타슘퍼옥시모노설페이트 0.1 내지 1 중량부로 이루어지는 것이 바람직한데, 상기와 같이 에티드론산이나 포타슘퍼옥시모노설페이트가 함유되면 과초산의 자연분해가 지연되어 상기 살균조에 채워진 과초산 수용액의 교체 주기를 향상시킬 수 있기 때문에, 블랙사파이어 포도의 세척공정의 효율성을 향상시킬 수 있다.At this time, the aqueous peracetic acid solution is preferably composed of 100 parts by weight of purified water, 0.01 to 1 parts by weight of peracetic acid, 0.1 to 5 parts by weight of etidronic acid, and 0.1 to 1 parts by weight of potassium peroxymonosulfate. However, when potassium peroxymonosulfate is contained, the natural decomposition of peracetic acid is delayed and the replacement cycle of the aqueous peracetic acid solution filled in the sterilization tank can be improved, so that the efficiency of the washing process of black sapphire grapes can be improved.
상기 에티드론산 및 포타슘퍼옥시모노설페이트는 과초산을 안정화하여 과초산이 자연분해되는 것을 억제하는 역할을 하는데, 특히, 상기 포타슘퍼옥시모노설페이트는 상기 과초산과 평형을 이루면서, 과초산의 합성에 관여하여 안정성을 향상시키는 역할을 한다.The etidronic acid and potassium peroxymonosulfate serve to stabilize peracetic acid to inhibit the natural decomposition of peracetic acid. In particular, the potassium peroxymonosulfate is in equilibrium with the peracetic acid, the synthesis of peracetic acid It plays a role in improving stability.
이하에서는, 본 발명에 따른 블랙사파이어 포도의 세척방법 및 그 세척방법을 통해 세척된 블랙사파이어 포도의 물성을 실시예를 들어 설명하기로 한다.Hereinafter, the method for washing black sapphire grapes according to the present invention and the physical properties of the black sapphire grapes washed through the washing method will be described with reference to examples.
<제조예 1> 제1세척액의 제조<Preparation Example 1> Preparation of first washing solution
정제수 1L에 베이킹 파우더 1g 및 식초 1ml를 혼합하여 제1세척액을 제조하였다.A first washing solution was prepared by mixing 1 g of baking powder and 1 ml of vinegar in 1 L of purified water.
<제조예 2> 제2세척액의 제조<Preparation Example 2> Preparation of the second washing solution
정제수 1L에 베이킹 파우더 1g 및 산화칼슘(질량농도 97.8%) 1g을 혼합하여 제2세척액을 제조하였다.A second washing solution was prepared by mixing 1 g of baking powder and 1 g of calcium oxide (mass concentration of 97.8%) in 1 L of purified water.
<제조예 3> 과초산 수용액의 제조<Preparation Example 3> Preparation of aqueous peracetic acid solution
정제수 1L에 과초산 5g, 에티드론산 30g 및 포타슘퍼옥시모노설페이트 5g을 혼합하여 과초산 수용액을 제조하였다.An aqueous solution of peracetic acid was prepared by mixing 5 g of peracetic acid, 30 g of etidronic acid, and 5 g of potassium peroxymonosulfate in 1 L of purified water.
<실시예 1><Example 1>
제1버블세척기(성진 하이쿨)에 상기 제조예 1을 통해 제조된 제1세척액을 채우고 블랙사파이어 포도 1송이를 침지한 후에 14℃의 온도에서 30초 동안 버블세척하고, 세척된 블랙사파이어 포도를 컨베이어 벨트를 이용하여 상기 제조예 2를 통해 제조된 제2세척액이 채워진 제2버블세척기(성진 하이쿨)로 이송하고 14℃의 온도에서 30초 동안 버블세척한 후에 컨베이어 벨트에 구비된 송풍기를 이용하여 20℃의 온도로 건조하였다.The first bubble washing machine (Seongjin Hi-Cool) was filled with the first washing solution prepared in Preparation Example 1, immersed in 1 bunch of black sapphire grapes, followed by bubble washing at a temperature of 14° C. for 30 seconds, and washed black sapphire grapes Using a conveyor belt, transfer to the second bubble washer (Seongjin High Cool) filled with the second washing solution prepared in Preparation Example 2, and after bubble washing at a temperature of 14° C. for 30 seconds, use a blower provided on the conveyor belt and dried at a temperature of 20 °C.
<실시예 2><Example 2>
제1버블세척기(성진 하이쿨)에 상기 제조예 1을 통해 제조된 제1세척액을 채우고 블랙사파이어 포도 1송이를 침지한 후에 14℃의 온도에서 30초 동안 버블세척하고, 세척된 블랙사파이어 포도를 컨베이어 벨트를 이용하여 상기 제조예 2를 통해 제조된 제2세척액이 채워진 제2버블세척기(성진 하이쿨)로 이송하고 14℃의 온도에서 30초 동안 버블세척한 후에, 세척된 블랙사파이어 포도를 컨베이어 벨트를 이용하여 상기 제조예 3을 통해 제조된 과초산 수용액이 채워진 살균조로 이송하고 15초 동안 침지한 후에 컨베이어 벨트에 구비된 송풍기를 이용하여 20℃의 온도로 건조하였다.The first bubble washing machine (Seongjin Hi-Cool) was filled with the first washing solution prepared in Preparation Example 1, immersed in 1 bunch of black sapphire grapes, followed by bubble washing at a temperature of 14° C. for 30 seconds, and washed black sapphire grapes Using a conveyor belt, transfer to the second bubble washer (Seongjin High Cool) filled with the second washing solution prepared in Preparation Example 2, and bubble washing at a temperature of 14° C. for 30 seconds, and then convey the washed black sapphire grapes to the conveyor. Using a belt, it was transferred to a sterilization tank filled with the aqueous peracetic acid solution prepared in Preparation Example 3, immersed for 15 seconds, and then dried at a temperature of 20° C. using a blower provided on the conveyor belt.
<비교예 1><Comparative Example 1>
블랙사파이어 포도.Black sapphire grapes.
상기 실시예 1 내지 2를 통해 세척된 블랙사파이어 포도와 및 비교예 1의 블랙사파이어 포도의 외관품질 및 잔류농약 농도를 측정하여 아래 표 1에 나타내었다.The appearance quality and residual pesticide concentration of the black sapphire grapes washed through Examples 1 and 2 and the black sapphire grapes of Comparative Example 1 were measured and shown in Table 1 below.
{단, 상기 실시예 1 내지 2 및 비교예 1에 사용되는 블랙사파이어 포도는 농약(제품명 : 강타자, 제조사 : 성보화학주식회사) 1mL를 증류수 1L로 희석시켜 농약희석액을 제조한 후에, 상기 농약희석액에 2분 동안 침지하고, 암소에서 4시간 건조한 후에 사용하였다.{However, the black sapphire grapes used in Examples 1 to 2 and Comparative Example 1 were prepared by diluting 1 mL of a pesticide (product name: Kangtaja, manufacturer: Seongbo Chemical Co., Ltd.) with 1 L of distilled water to prepare a pesticide diluent, and then added to the pesticide diluent. It was used after soaking for 2 minutes and drying in the dark for 4 hours.
또한, 블랙사파이어 포도의 외관품질은 육안으로 관찰하여 양호 또는 불량으로 나타내었다.In addition, the appearance quality of the black sapphire grapes was observed with the naked eye and indicated as good or bad.
또한, 잔류농약의 농도는 잔류농약측정 키트(제품명 : TK-16, 제조사 : ITS)를 이용하여 저해율(농약의 신경전달효소의 저해정도를 통해 농약의 잔류 정도를 파악하는 기준)을 3회 측정하고 평균값으로 나타내었다.In addition, the concentration of pesticide residue was measured three times using the pesticide residue measurement kit (product name: TK-16, manufacturer: ITS). and expressed as an average value.
<표 1><Table 1>
상기 표 1에 나타낸 것처럼, 본 발명의 실시예 1 내지 2를 통해 세척된 블랙사파이어 포도는 외관 품질이 양호할 뿐만 아니라, 비교예 1의 블랙사파이어 포도에 비해 잔류농약의 농도가 낮은 것을 알 수 있다.As shown in Table 1, it can be seen that the black sapphire grapes washed through Examples 1 and 2 of the present invention not only have good appearance quality, but also have a lower concentration of residual pesticides compared to the black sapphire grapes of Comparative Example 1. .
따라서, 본 발명에 따른 블랙사파이어 포도의 세척방법은 포도의 당도나 외관품질을 저하시키지 않으면서도, 포도 표면에 잔존하는 이물질과 잔류농액에 대해 우수한 제거효과를 나타내며, 과초산의 분해가 억제되는 과초산 수용액을 사용하여 우수한 살균효과를 나타낸다.Therefore, the washing method of black sapphire grapes according to the present invention exhibits an excellent removal effect on foreign substances and residual concentrate remaining on the grape surface without degrading the sugar content or appearance quality of the grapes, and the decomposition of peracetic acid is suppressed. It shows an excellent sterilization effect by using an aqueous acetic acid solution.
S101 ; 제1세척단계
S103 ; 제2세척단계
S104 ; 살균단계
S105 ; 건조단계S101; 1st washing step
S103; 2nd washing step
S104; Sterilization step
S105 ; drying stage
Claims (8)
상기 제1세척단계를 통해 세척된 블랙사파이어 포도를 베이킹파우더 및 산화칼슘을 함유하는 제2세척액이 채워진 제2버블세척기에서 세척하는 제2세척단계; 및
상기 제2세척단계를 통해 세척된 블랙사파이어 포도를 건조하는 건조단계;로 이루어지는 것을 특징으로 하는 블랙사파이어 포도의 세척방법.
a first washing step of washing the black sapphire grapes in a first bubble washing machine filled with a first washing solution containing baking powder and vinegar;
a second washing step of washing the black sapphire grapes washed through the first washing step in a second bubble washing machine filled with a second washing solution containing baking powder and calcium oxide; and
A method of washing black sapphire grapes, comprising: a drying step of drying the black sapphire grapes washed through the second washing step.
상기 제1세척액은 정제수 100 중량부, 베이킹 파우더 0.05 내지 0.15 중량부 및 식초 0.05 내지 0.15 중량부로 이루어지는 것을 특징으로 하는 블랙사파이어 포도의 세척방법.
The method according to claim 1,
The first washing liquid is 100 parts by weight of purified water, 0.05 to 0.15 parts by weight of baking powder, and 0.05 to 0.15 parts by weight of vinegar.
상기 제1세척단계는 20 내지 30℃의 온도에서 20 내지 40초 동안 이루어지는 것을 특징으로 하는 블랙사파이어 포도의 세척방법.
The method according to claim 1,
The first washing step is a method of washing black sapphire grapes, characterized in that for 20 to 40 seconds at a temperature of 20 to 30 ℃.
상기 제2세척액은 정제수 100 중량부, 베이킹 파우더 0.05 내지 0.15 중량부 및 산화칼슘 0.05 내지 0.15 중량부로 이루어지는 것을 특징으로 하는 블랙사파이어 포도의 세척방법.
The method according to claim 1,
The second washing solution is 100 parts by weight of purified water, 0.05 to 0.15 parts by weight of baking powder, and 0.05 to 0.15 parts by weight of calcium oxide.
상기 산화칼슘은 질량농도가 97 내지 99%인 것을 특징으로 하는 블랙사파이어 포도의 세척방법.
5. The method of claim 1 or 4,
The method of washing black sapphire grapes, characterized in that the calcium oxide has a mass concentration of 97 to 99%.
상기 제2세척단계는 13 내지 15℃의 온도에서 20 내지 40초 동안 이루어지는 것을 특징으로 하는 블랙사파이어 포도의 세척방법.
The method according to claim 1,
The second washing step is a washing method of black sapphire grapes, characterized in that made for 20 to 40 seconds at a temperature of 13 to 15 ℃.
상기 제2세척단계와 상기 건조단계 사이에는 상기 제2세척단계를 통해 세척된 블랙사파이어 포도를 과초산 수용액으로 살균하는 살균단계가 더 진행되는 것을 특징으로 하는 블랙사파이어 포도의 세척방법.
The method according to claim 1,
A method of washing black sapphire grapes, characterized in that a sterilization step of sterilizing the black sapphire grapes washed through the second washing step with an aqueous peracetic acid solution is further performed between the second washing step and the drying step.
상기 과초산 수용액은 정제수 100 중량부, 과초산 0.01 내지 1 중량부, 에티드론산 0.1 내지 5 중량부 및 포타슘퍼옥시모노설페이트 0.1 내지 1 중량부로 이루어지는 것을 특징으로 하는 블랙사파이어 포도의 세척방법.8. The method of claim 7,
The peracetic acid aqueous solution comprises 100 parts by weight of purified water, 0.01 to 1 parts by weight of peracetic acid, 0.1 to 5 parts by weight of etidronic acid, and 0.1 to 1 parts by weight of potassium peroxymonosulfate.
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