KR20220107730A - Plasticizer composition, and vinylchloride resin composition comprising the same - Google Patents
Plasticizer composition, and vinylchloride resin composition comprising the same Download PDFInfo
- Publication number
- KR20220107730A KR20220107730A KR1020210010734A KR20210010734A KR20220107730A KR 20220107730 A KR20220107730 A KR 20220107730A KR 1020210010734 A KR1020210010734 A KR 1020210010734A KR 20210010734 A KR20210010734 A KR 20210010734A KR 20220107730 A KR20220107730 A KR 20220107730A
- Authority
- KR
- South Korea
- Prior art keywords
- based compound
- epoxidized
- compound
- cyclohexane
- vinyl chloride
- Prior art date
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- 239000004014 plasticizer Substances 0.000 title claims abstract description 85
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 239000000203 mixture Substances 0.000 title claims abstract description 58
- 239000011342 resin composition Substances 0.000 title claims abstract description 40
- 150000001875 compounds Chemical class 0.000 claims abstract description 113
- 239000000463 material Substances 0.000 claims abstract description 30
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims abstract description 25
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 25
- DFIIJEHQGUKXKU-UHFFFAOYSA-N 1,3-bis(2-ethylhexyl)cyclohexane Chemical compound CCCCC(CC)CC1CCCC(CC(CC)CCCC)C1 DFIIJEHQGUKXKU-UHFFFAOYSA-N 0.000 claims abstract description 15
- -1 diethyl hexyl cyclohexane compound Chemical class 0.000 claims description 33
- 229920005989 resin Polymers 0.000 claims description 20
- 239000011347 resin Substances 0.000 claims description 20
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims description 18
- HOQGHOMLEVKTBY-UHFFFAOYSA-N bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate Chemical compound CCCCC(CC)COC(=O)C1CCC(C(=O)OCC(CC)CCCC)CC1 HOQGHOMLEVKTBY-UHFFFAOYSA-N 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- 239000003381 stabilizer Substances 0.000 claims description 9
- 239000000945 filler Substances 0.000 claims description 8
- 239000003549 soybean oil Substances 0.000 claims description 7
- 235000012424 soybean oil Nutrition 0.000 claims description 7
- 239000004604 Blowing Agent Substances 0.000 claims description 6
- 239000004088 foaming agent Substances 0.000 claims description 6
- PZTAGFCBNDBBFZ-UHFFFAOYSA-N tert-butyl 2-(hydroxymethyl)piperidine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCCCC1CO PZTAGFCBNDBBFZ-UHFFFAOYSA-N 0.000 claims description 6
- NXQMCAOPTPLPRL-UHFFFAOYSA-N 2-(2-benzoyloxyethoxy)ethyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCCOCCOC(=O)C1=CC=CC=C1 NXQMCAOPTPLPRL-UHFFFAOYSA-N 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 235000019482 Palm oil Nutrition 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 239000002666 chemical blowing agent Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000000944 linseed oil Substances 0.000 claims description 3
- 235000021388 linseed oil Nutrition 0.000 claims description 3
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 239000002540 palm oil Substances 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- VMKMZRBPOSNUMX-UHFFFAOYSA-N 2-(1-hydroxypropan-2-yloxy)propan-1-ol Chemical compound OCC(C)OC(C)CO VMKMZRBPOSNUMX-UHFFFAOYSA-N 0.000 claims description 2
- OKGUXCUCCABSEP-UHFFFAOYSA-N 2-propylheptyl benzoate Chemical compound CCCCCC(CCC)COC(=O)C1=CC=CC=C1 OKGUXCUCCABSEP-UHFFFAOYSA-N 0.000 claims description 2
- BBVARVTURNYWGV-UHFFFAOYSA-N 7-methyloctyl benzoate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1 BBVARVTURNYWGV-UHFFFAOYSA-N 0.000 claims description 2
- HNDYULRADYGBDU-UHFFFAOYSA-N 8-methylnonyl benzoate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1 HNDYULRADYGBDU-UHFFFAOYSA-N 0.000 claims description 2
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 229910052570 clay Inorganic materials 0.000 claims description 2
- SZLIWAKTUJFFNX-UHFFFAOYSA-N dihydrocitronellol benzoate Natural products CC(C)CCCC(C)CCOC(=O)C1=CC=CC=C1 SZLIWAKTUJFFNX-UHFFFAOYSA-N 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 229940049918 linoleate Drugs 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- 229940049964 oleate Drugs 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 2
- 239000004299 sodium benzoate Substances 0.000 claims description 2
- 235000010234 sodium benzoate Nutrition 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- APVVRLGIFCYZHJ-UHFFFAOYSA-N trioctyl 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CCCCCCCCOC(=O)CC(O)(C(=O)OCCCCCCCC)CC(=O)OCCCCCCCC APVVRLGIFCYZHJ-UHFFFAOYSA-N 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 2
- OYHQOLUKZRVURQ-HZJYTTRNSA-M 9-cis,12-cis-Octadecadienoate Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC([O-])=O OYHQOLUKZRVURQ-HZJYTTRNSA-M 0.000 claims 1
- BFNQYORFBJZBBT-UHFFFAOYSA-N bis(2-ethylhexyl) cyclohexane-1,3-dicarboxylate Chemical compound CCCCC(CC)COC(=O)C1CCCC(C(=O)OCC(CC)CCCC)C1 BFNQYORFBJZBBT-UHFFFAOYSA-N 0.000 claims 1
- 239000003925 fat Substances 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- NXOLNYGHFNUTHC-UHFFFAOYSA-N tridodecan-5-yl 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CCCCCCCC(CCCC)OC(=O)CC(O)(C(=O)OC(CCCC)CCCCCCC)CC(=O)OC(CCCC)CCCCCCC NXOLNYGHFNUTHC-UHFFFAOYSA-N 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 description 54
- 230000005012 migration Effects 0.000 description 21
- 238000013508 migration Methods 0.000 description 21
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 12
- 229920001944 Plastisol Polymers 0.000 description 10
- 239000004999 plastisol Substances 0.000 description 10
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 9
- 230000002401 inhibitory effect Effects 0.000 description 7
- 230000000704 physical effect Effects 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 239000013589 supplement Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000003247 decreasing effect Effects 0.000 description 5
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 4
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 description 4
- BJAJDJDODCWPNS-UHFFFAOYSA-N dotp Chemical compound O=C1N2CCOC2=NC2=C1SC=C2 BJAJDJDODCWPNS-UHFFFAOYSA-N 0.000 description 4
- 238000009408 flooring Methods 0.000 description 4
- 239000002649 leather substitute Substances 0.000 description 4
- 230000001502 supplementing effect Effects 0.000 description 4
- WZLFPVPRZGTCKP-UHFFFAOYSA-N 1,1,1,3,3-pentafluorobutane Chemical compound CC(F)(F)CC(F)(F)F WZLFPVPRZGTCKP-UHFFFAOYSA-N 0.000 description 3
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 description 3
- BHNZEZWIUMJCGF-UHFFFAOYSA-N 1-chloro-1,1-difluoroethane Chemical compound CC(F)(F)Cl BHNZEZWIUMJCGF-UHFFFAOYSA-N 0.000 description 3
- BOUGCJDAQLKBQH-UHFFFAOYSA-N 1-chloro-1,2,2,2-tetrafluoroethane Chemical compound FC(Cl)C(F)(F)F BOUGCJDAQLKBQH-UHFFFAOYSA-N 0.000 description 3
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 3
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- ASRMWYDEZPXXBA-UHFFFAOYSA-N (sulfonylamino)urea Chemical compound NC(=O)NN=S(=O)=O ASRMWYDEZPXXBA-UHFFFAOYSA-N 0.000 description 2
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 2
- KDWQLICBSFIDRM-UHFFFAOYSA-N 1,1,1-trifluoropropane Chemical compound CCC(F)(F)F KDWQLICBSFIDRM-UHFFFAOYSA-N 0.000 description 2
- WXGNWUVNYMJENI-UHFFFAOYSA-N 1,1,2,2-tetrafluoroethane Chemical compound FC(F)C(F)F WXGNWUVNYMJENI-UHFFFAOYSA-N 0.000 description 2
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 2
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 2
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 2
- FAQMMOBPQGSELZ-UHFFFAOYSA-N 1-o,3-o-diethyl 2-o-hexyl 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CCCCCCOC(=O)C(O)(CC(=O)OCC)CC(=O)OCC FAQMMOBPQGSELZ-UHFFFAOYSA-N 0.000 description 2
- KLUXYTDCIPYJPB-UHFFFAOYSA-N 8,12-dibutyl-9-dodecan-5-yl-10-hydroxynonadecane-8,9,10-tricarboxylic acid Chemical compound CCCCCCCC(CCCC)C(C(C(C(CCCC)CCCCCCC)(C(CCCC)CCCCCCC)C(O)=O)(C(O)=O)O)C(O)=O KLUXYTDCIPYJPB-UHFFFAOYSA-N 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 2
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 2
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 2
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- VRFNYSYURHAPFL-UHFFFAOYSA-N [(4-methylphenyl)sulfonylamino]urea Chemical compound CC1=CC=C(S(=O)(=O)NNC(N)=O)C=C1 VRFNYSYURHAPFL-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 2
- 229940042935 dichlorodifluoromethane Drugs 0.000 description 2
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 239000000598 endocrine disruptor Substances 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 229960003750 ethyl chloride Drugs 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- WMIYKQLTONQJES-UHFFFAOYSA-N hexafluoroethane Chemical compound FC(F)(F)C(F)(F)F WMIYKQLTONQJES-UHFFFAOYSA-N 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229940050176 methyl chloride Drugs 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 description 2
- GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 description 2
- 239000002952 polymeric resin Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 2
- CZGWDPMDAIPURF-UHFFFAOYSA-N (4,6-dihydrazinyl-1,3,5-triazin-2-yl)hydrazine Chemical compound NNC1=NC(NN)=NC(NN)=N1 CZGWDPMDAIPURF-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 1
- DQCMWCVJSOFDSA-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl.CC(Cl)(Cl)Cl DQCMWCVJSOFDSA-UHFFFAOYSA-N 0.000 description 1
- YOORICCYTBZAIX-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F.CC(F)(F)F YOORICCYTBZAIX-UHFFFAOYSA-N 0.000 description 1
- JSEUKVSKOHVLOV-UHFFFAOYSA-N 1,2-dichloro-1,1,2,3,3,3-hexafluoropropane Chemical compound FC(F)(F)C(F)(Cl)C(F)(F)Cl JSEUKVSKOHVLOV-UHFFFAOYSA-N 0.000 description 1
- KNKRKFALVUDBJE-UHFFFAOYSA-N 1,2-dichloropropane Chemical compound CC(Cl)CCl KNKRKFALVUDBJE-UHFFFAOYSA-N 0.000 description 1
- XXSZLFRJEKKBDJ-UHFFFAOYSA-N 1-chloro-1,1,2,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)(F)C(F)(F)Cl XXSZLFRJEKKBDJ-UHFFFAOYSA-N 0.000 description 1
- YZXSQDNPKVBDOG-UHFFFAOYSA-N 2,2-difluoropropane Chemical compound CC(C)(F)F YZXSQDNPKVBDOG-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- VXRUADVCBZMFSV-UHFFFAOYSA-N 2-acetyloxypropane-1,2,3-tricarboxylic acid Chemical compound CC(=O)OC(CC(O)=O)(CC(O)=O)C(O)=O VXRUADVCBZMFSV-UHFFFAOYSA-N 0.000 description 1
- XFDQLDNQZFOAFK-UHFFFAOYSA-N 2-benzoyloxyethyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCCOC(=O)C1=CC=CC=C1 XFDQLDNQZFOAFK-UHFFFAOYSA-N 0.000 description 1
- ZRNSSRODJSSVEJ-UHFFFAOYSA-N 2-methylpentacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC(C)C ZRNSSRODJSSVEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- MMSRGTFKTWPKGF-UHFFFAOYSA-N CN(C(C1=CC=C(C(=O)N(N=O)C)C=C1)=O)N=O.CN(C(C1=CC=C(C(=O)N(N=O)C)C=C1)=O)N=O Chemical compound CN(C(C1=CC=C(C(=O)N(N=O)C)C=C1)=O)N=O.CN(C(C1=CC=C(C(=O)N(N=O)C)C=C1)=O)N=O MMSRGTFKTWPKGF-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- SOSBHPVTRIOLCE-UHFFFAOYSA-N FC(C)(C)F.FC(C)(C)F Chemical compound FC(C)(C)F.FC(C)(C)F SOSBHPVTRIOLCE-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- 241001400033 Omia Species 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- VJRITMATACIYAF-UHFFFAOYSA-N benzenesulfonohydrazide Chemical compound NNS(=O)(=O)C1=CC=CC=C1 VJRITMATACIYAF-UHFFFAOYSA-N 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- PXGZQGDTEZPERC-UHFFFAOYSA-L cyclohexane-1,4-dicarboxylate Chemical compound [O-]C(=O)C1CCC(C([O-])=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-L 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 229940087091 dichlorotetrafluoroethane Drugs 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- XLNZHTHIPQGEMX-UHFFFAOYSA-N ethane propane Chemical compound CCC.CCC.CC.CC XLNZHTHIPQGEMX-UHFFFAOYSA-N 0.000 description 1
- UHCBBWUQDAVSMS-UHFFFAOYSA-N fluoroethane Chemical compound CCF UHCBBWUQDAVSMS-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
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- 239000005556 hormone Substances 0.000 description 1
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- 230000003993 interaction Effects 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N monofluoromethane Natural products FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- BCCOBQSFUDVTJQ-UHFFFAOYSA-N octafluorocyclobutane Chemical compound FC1(F)C(F)(F)C(F)(F)C1(F)F BCCOBQSFUDVTJQ-UHFFFAOYSA-N 0.000 description 1
- 235000019407 octafluorocyclobutane Nutrition 0.000 description 1
- QYSGYZVSCZSLHT-UHFFFAOYSA-N octafluoropropane Chemical compound FC(F)(F)C(F)(F)C(F)(F)F QYSGYZVSCZSLHT-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- KAVGMUDTWQVPDF-UHFFFAOYSA-N perflubutane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)F KAVGMUDTWQVPDF-UHFFFAOYSA-N 0.000 description 1
- 229950003332 perflubutane Drugs 0.000 description 1
- 229960004065 perflutren Drugs 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 150000004291 polyenes Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910001868 water Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0023—Use of organic additives containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1515—Three-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
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- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
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- Materials Engineering (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
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Abstract
Description
본 발명은 가소제 조성물 및 이를 포함하는 염화비닐 수지 조성물에 관한 것이다. The present invention relates to a plasticizer composition and a vinyl chloride resin composition comprising the same.
염화비닐계 수지는 염화비닐의 단독 중합체 및 염화비닐을 50% 이상 함유한 혼성 중합체로서, 현탁중합과 유화 중합으로 제조되는 5대 범용 열가소성 플라스틱 수지 중의 하나이다. Vinyl chloride-based resin is a homopolymer of vinyl chloride and a hybrid polymer containing 50% or more of vinyl chloride, and is one of five general-purpose thermoplastic resins manufactured by suspension polymerization and emulsion polymerization.
그 중에서 유화중합으로 제조되는 폴리염화비닐 수지는 가소제(Plasticizer), 안정제(Stabilizer), 충전재(Filler), 발포제(Blowing Agent), 안료(Pigment), 점도 조절제(Viscosity Depressant), 지당(TiO2) 및 특수한 기능을 갖는 부원료를 혼합하여 플라스티졸(Plastisol) 형태로 코팅 성형과 몰드 코팅 성형 가공법을 통해 바닥재, 벽지, 타포린, 인조피혁, 장난감, 자동차 하부 코팅재 등의 광범위한 분야에 사용되고 있다. Among them, polyvinyl chloride resin prepared by emulsion polymerization is a plasticizer, a stabilizer, a filler, a blowing agent, a pigment, a viscosity depressant, and a fat sugar (TiO 2 ) And it is used in a wide range of fields such as flooring, wallpaper, tarpaulin, artificial leather, toys, and automobile undercoating materials through coating molding and mold coating molding processing in the form of plastisol by mixing auxiliary materials with special functions.
벽지용 염화비닐계 수지 조성물 중에서 가소제는 가장 많은 함량을 차지하는 액상 성분이며, 이러한 가소제의 예로 프탈레이트계 제품인 DEHP(Di-2-EthylHexyl Phthalate), DINP(Di-IsoNonyl Phthalate), DIDP(Di-Iso-Decyl Phthalate), BBP(Butyl Benzyl Phthalate), DBP(Di-n-butyl phthalate)를 들 수 있으며, 특히 DINP가 널리 사용되어 왔다. Among the vinyl chloride-based resin compositions for wallpaper, the plasticizer is a liquid component that occupies the most content, and examples of such plasticizers include phthalate-based products such as DEHP (Di-2-EthylHexyl Phthalate), DINP (Di-IsoNonyl Phthalate), DIDP (Di-Iso- Decyl Phthalate), BBP (Butyl Benzyl Phthalate), DBP (Di-n-butyl phthalate), and in particular DINP has been widely used.
그러나, 프탈레이트계 가소제는 사회적으로 사람의 호르몬 작용을 방해하거나 혼란시키는 내분비계 교란물질(endocrine disrupter)로서 환경호르몬으로 의심받고 있어, 이를 규제하는 움직임이 있다. However, phthalate plasticizers are socially suspected as endocrine disrupters as endocrine disrupters that interfere with or disrupt human hormones, and there is a movement to regulate them.
이와 관련하여, 프탈레이트계 가소제를 대체하는 친환경 비-프탈레이트계 가소제가 연구되고 있지만, 현재까지 연구된 바로는 프탈레이트계 가소제에 대비하여 표면 이행이 증가하는 문제가 있다.In this regard, although eco-friendly non-phthalate plasticizers that replace phthalate plasticizers have been studied, there is a problem in that surface migration is increased compared to phthalate plasticizers.
본 발명은 친환경적면서도, 내오염성, 휘발 감량, 겔링 속도, 연신율, 및 열 안정성 등의 특성이 우수하게 발현되되는 염화비닐 수지 조성물을 제공하기 위한 것이다.An object of the present invention is to provide a vinyl chloride resin composition that is environmentally friendly and exhibits excellent properties such as stain resistance, loss of volatilization, gelling rate, elongation, and thermal stability.
본 발명에서, 제1, 제2 등의 용어는 다양한 구성 요소들을 설명하는데 사용되며, 상기 용어들은 하나의 구성 요소를 다른 구성 요소와 구별하기 위한 목적으로만 사용된다. In the present invention, terms such as first and second are used to describe various components, and the terms are used only for the purpose of distinguishing one component from another.
또한, 본 명세서에서 사용되는 용어는 단지 예시적인 실시예들을 설명하기 위해 사용된 것으로, 본 발명을 한정하려는 의도는 아니다. In addition, the terminology used herein is used only to describe exemplary embodiments, and is not intended to limit the present invention.
단수의 표현은 문맥상 명백하게 다르게 뜻하지 않는 한, 복수의 표현을 포함한다. The singular expression includes the plural expression unless the context clearly dictates otherwise.
본 명세서에서, "포함하다", "구비하다" 또는 "가지다" 등의 용어는 실시된 특징, 숫자, 단계, 구성 요소 또는 이들을 조합을 설명하기 위한 것이며, 하나 또는 그 이상의 다른 특징들이나 숫자, 단계, 구성 요소, 이들의 조합 또는 부가 가능성을 배제하는 것은 아니다. In this specification, terms such as "comprises", "comprising" or "having" are intended to describe embodied features, numbers, steps, components, or combinations thereof, and include one or more other features, numbers, or steps. , components, combinations or additions thereof are not excluded.
본 발명은 다양한 변경을 가할 수 있고 여러 가지 형태를 가질 수 있는 바, 특정 실시예들을 예시하고 하기에서 상세하게 설명하고자 한다. 그러나, 이는 본 발명을 특정한 개시 형태로 한정하는 것이 아니며, 본 발명의 사상 및 기술 범위에 포함되는 모든 변경, 균등물 내지 대체물을 포함하는 것으로 이해되어야 한다.Since the present invention may have various modifications and various forms, specific embodiments will be illustrated and described in detail below. However, this is not intended to limit the present invention to the specific disclosed form, and should be understood to include all modifications, equivalents, and substitutes included in the spirit and scope of the present invention.
이하, 본 발명의 구현예들을 상세히 설명한다.Hereinafter, embodiments of the present invention will be described in detail.
가소제 조성물plasticizer composition
본 발명의 일 구현예에서는, 디에틸 헥실 사이클로헥산계 화합물; 시트레이트계 화합물; 에폭시화 물질; 및 벤조에이트계 화합물;을 포함하는 4성분계 가소제 조성물을 제공한다.In one embodiment of the present invention, diethyl hexyl cyclohexane-based compound; citrate-based compounds; epoxidized materials; and a benzoate-based compound; provides a four-component plasticizer composition comprising.
구체적으로, 가소제의 이행(migration)이란, 고분자 수지와 혼합된 가소제 중 일부가 고분자 수지 외부로 유출되는 현상을 의미하는데, 유출된 가소제가 체내에 유입되면 생명활동에 직접 관여하는 내분비계의 정상적인 활동을 저해하거나 비정상적인 반응을 촉발시켜 치명적인 해를 가하기 때문에, 가소제의 이행(migration)을 최대한 억제하여야 한다. Specifically, the plasticizer migration (migration) refers to a phenomenon in which some of the plasticizer mixed with the polymer resin flows out of the polymer resin. Because it inhibits or triggers an abnormal reaction to inflict fatal harm, the migration (migration) of the plasticizer should be suppressed as much as possible.
상기 디에틸 헥실 사이클로헥산(ethyl hexyl cyclohexane, 이하, 경우에 따라서는 DEHCH"로 약칭함)계 화합물은 상온 및 저온 점도가 낮아 우수한 코팅 특성을 구현할 수 있으며, 겔링 속도가 빠르고, 발포 물성이 우수하다. 특히, 기존 프탈레이트계 가소제에 비하여 휘발성 유기 화합물의 발생을 최소화할 수 있기 때문에, 기존 가소제를 대체할 수 있다. The diethyl hexyl cyclohexane (hereinafter, abbreviated as "DEHCH" in some cases)-based compound can implement excellent coating properties due to low viscosity at room temperature and low temperature, and has a fast gelling rate and excellent foaming properties In particular, since generation of volatile organic compounds can be minimized compared to conventional phthalate-based plasticizers, it can replace existing plasticizers.
또한, DEHCH계 화합물은 가소화 효율이 우수하여, 염화비닐 수지 조성물의 연신율을 보완할 수 있는 화합물이다. In addition, the DEHCH-based compound has excellent plasticization efficiency, and is a compound capable of supplementing the elongation of the vinyl chloride resin composition.
염화비닐 수지의 가소제로서 DEHCH계 화합물을 단독으로 사용하는 경우에도 희망하는 염화비닐 수지의 물성을 구현할 수 있으나, 다만 DEHCH계 화합물은 이행(migration)의 문제가 있다. Even when the DEHCH-based compound is used alone as a plasticizer for the vinyl chloride resin, desired physical properties of the vinyl chloride resin can be realized, but the DEHCH-based compound has a problem of migration.
상기 DEHCH계 화합물의 이행은, 상기 시트레이트계 화합물을 통해 최소화할 수 있다.The migration of the DEHCH-based compound can be minimized through the citrate-based compound.
구체적으로, 상기 시트레이트계 화합물은 상기 DEHCH계 화합물과의 수소 결합 등 상호 작용을 통해, 이들을 포함하는 가소제 조성물이 염화비닐 수지 외부로 유출되지 않도록 하며, 우수한 내오염성을 구현할 수 있다.Specifically, the citrate-based compound prevents the plasticizer composition including them from leaking out of the vinyl chloride resin through interactions such as hydrogen bonding with the DEHCH-based compound, and can implement excellent stain resistance.
한편, 상기 벤조에이트계 화합물은, 겔링 속도를 개선하면서, 기계적 물성을 보완할 수 있는 화합물이다.On the other hand, the benzoate-based compound is a compound capable of supplementing mechanical properties while improving the gelling rate.
구체적으로, 상기 벤조에이트계 화합물은 Fast-Fusion 가소제로서 염화비닐 수지 조성물의 겔링 속도를 개선할 수 있으며, 염화비닐 수지와의 상용성이 우수하여 염화비닐 수지 조성물의 기계적 물성을 보완할 수 있다.Specifically, the benzoate-based compound can improve the gelling rate of the vinyl chloride resin composition as a Fast-Fusion plasticizer, and has excellent compatibility with the vinyl chloride resin, thereby supplementing the mechanical properties of the vinyl chloride resin composition.
또한, 상기 에폭시화 물질은 내열성 및 휘발 감량을 보완할 수 있는 물질이다.In addition, the epoxidized material is a material capable of supplementing heat resistance and loss of volatilization.
구체적으로, 상기 에폭시화 물질은 에폭시 구조를 통해 내열성을 보완할 수 있다. 또한, 상기 에폭시화 물질은 분자량이 높아, 염화비닐 수지 조성물의 휘발 감량을 연신율을 보완할 수 있다.Specifically, the epoxidized material may supplement heat resistance through an epoxy structure. In addition, since the epoxidized material has a high molecular weight, it is possible to compensate for the elongation loss of the vinyl chloride resin composition.
종합적으로, 상기 일 구현예의 가소제 조성물에 있어서, 상기 DEHCH계 화합물은 우수한 코팅 특성, 겔링 속도, 발포 물성 등이 우수한 친환경 가소제 조성물을 구현하고, 상기 시트레이트계 화합물은 표면 이행을 억제하며, 상기 벤조에이트계 화합물은 연신율을 보완하고, 상기 에폭시화 물질은 내열성 및 휘발 감량을 보완할 수 있다.Overall, in the plasticizer composition of one embodiment, the DEHCH-based compound implements an eco-friendly plasticizer composition having excellent coating properties, gelling speed, foaming properties, etc., and the citrate-based compound inhibits surface migration, and the benzo The eight-based compound may supplement elongation, and the epoxidized material may supplement heat resistance and loss of volatilization.
따라서, 상기 일 구현예의 가소제 조성물은 프탈레이트계 가소제를 대체하여, 바닥재, 벽지, 타포린, 인조피혁, 장난감, 자동차 하부 코팅재 등으로 사용될 수 있다.Accordingly, the plasticizer composition of one embodiment may be used as a flooring material, wallpaper, tarpaulin, artificial leather, toys, automobile undercoating, etc., replacing the phthalate-based plasticizer.
이하, 상기 일 구현예의 가소제 조성물을 상세히 설명한다.Hereinafter, the plasticizer composition of the embodiment will be described in detail.
DEHCH계 화합물DEHCH compounds
상기 디에틸 헥실 사이클로헥산계 화합물은 비스(2-에틸헥실)사이클로헥산-1,2-디카르복실레이트(Bis(2-ethylhexyl)cyclohexane-1,2-dicarboxylate), 비스(2-에틸헥실)사이클로헥산-1,3-디카르복실레이트(Bis(2-ethylhexyl)cyclohexane-1,3-dicarboxylate), 및 비스(2-에틸헥실)사이클로헥산-1,4-디카르복실레이트(Bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate)로 이루어진 군에서 선택되는 1종 이상일 수 있다.The diethylhexyl cyclohexane-based compound is bis(2-ethylhexyl)cyclohexane-1,2-dicarboxylate (Bis(2-ethylhexyl)cyclohexane-1,2-dicarboxylate), bis(2-ethylhexyl) Cyclohexane-1,3-dicarboxylate (Bis(2-ethylhexyl)cyclohexane-1,3-dicarboxylate), and bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate (Bis(2) -ethylhexyl) cyclohexane-1,4-dicarboxylate) may be at least one selected from the group consisting of.
예컨대, 상기 디에틸 헥실 사이클로헥산계 화합물은 하기 식으로 표시되는 비스(2-에틸헥실)사이클로헥산-1,4-디카르복실레이트(Bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate)일 수 있다: For example, the diethylhexyl cyclohexane-based compound is bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate (Bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate)yl represented by the following formula can:
시트레이트계 화합물Citrate-based compounds
상기 시트레이트계 화합물은 시트르산과 C2-8 알코올의 에스테르 화합물로서, 하기 화학식 1로 표시될 수 있다.The citrate-based compound is an ester compound of citric acid and C 2-8 alcohol, and may be represented by Formula 1 below.
[화학식 1][Formula 1]
상기 화학식 1에서, R1은 수소 또는 아세틸이고, R2 내지 R4는 각각 독립적으로 C2-8 알킬이다. In Formula 1, R 1 is hydrogen or acetyl, and R 2 to R 4 are each independently C 2-8 alkyl.
상기 화학식 1에서, 상기 R2 내지 R4는 각각 독립적으로 부틸 또는 옥틸일 수 있다. In Formula 1, R 2 to R 4 may each independently be butyl or octyl.
구체적으로, 상기 시트레이트계 화합물은, 트리부틸시트레이트(tributylcitrate), 트리(부틸옥틸)시트레이트(tri(butyloctyl)citrate), 트리옥틸시트레이트(trioctylcitrate) 및 아세틸트리부틸시트레이트(acetyltributylcitrate)로 이루어진 군에서 선택되는 1종 이상일 수 있다. 여기서, 트리(부틸옥틸)시트레이트는, 상기 화학식 1의 R2 내지 R4 중 일부는 부틸이고, 일부는 옥틸인 화합물들을 총칭하는 것을 의미한다. Specifically, the citrate-based compound is tributylcitrate, tri(butyloctyl)citrate, trioctylcitrate, and acetyltributylcitrate. It may be at least one selected from the group consisting of. Here, tri(butyloctyl)citrate refers to compounds in which some of R 2 to R 4 in Formula 1 are butyl and some are octyl.
예컨대, 상기 시트레이트계 화합물은 트리부틸시트레이트(tributylcitrate), 일 수 있다.For example, the citrate-based compound may be tributylcitrate.
상기 화학식 1로 표시되는 화합물은 상업적으로 구입하여 사용할 수 있으며, 또한 하기 반응식 1과 같은 방법으로 제조할 수 있다. The compound represented by Chemical Formula 1 can be purchased and used commercially, and can also be prepared in the same manner as in Scheme 1 below.
[반응식 1][Scheme 1]
상기 반응은 시트르산 또는 아세틸시트르산과 C2-8 알코올의 에스테르화 반응으로, R2 내지 R4의 구조에 따라 한 번의 반응으로 또는 반응물을 달리하여 상기 반응을 순차적으로 수행하여 제조할 수 있다. 상기 반응의 조건은 당업계의 통상적인 에스테르화 반응 조건을 사용할 수 있다. The reaction is an esterification reaction of citric acid or acetyl citric acid and C 2-8 alcohol, and may be prepared by one reaction according to the structure of R 2 to R 4 or by sequentially performing the reaction by changing the reactants. As the conditions for the reaction, conventional esterification reaction conditions in the art may be used.
에폭시화 물질epoxidized material
상기 에폭시화 물질은 에폭시화 식물성 오일일 수 있다.The epoxidized material may be an epoxidized vegetable oil.
구체적으로, 상기 에폭시화 물질은 에폭시화 대두유(epoxidized soybean oil, ESO), 에폭시화 피마자유(epoxidized castor oil), 에폭시화 아마인유(epoxidized linseed oil, ELO), 에폭시화 팜유(epoxidized palm oil), 에폭시화 스테아레이트(epoxidized stearate), 에폭시화 올리에이트(epoxidized oleate), 에폭시화 톨리에이트(epoxidized tallate), 에폭시화 리놀리에이트(epoxidized linoleate), 및 이들의 에폭시화 에스테르 유도체로 이루어진 군에서 선택된 1종 이상일 수 있다.Specifically, the epoxidized material is epoxidized soybean oil (ESO), epoxidized castor oil, epoxidized linseed oil (ELO), epoxidized palm oil (epoxidized palm oil), 1 selected from the group consisting of epoxidized stearate, epoxidized oleate, epoxidized tallate, epoxidized linoleate, and epoxidized ester derivatives thereof may be more than one species.
예컨대, 에폭시화 대두유(ESO), 에폭시화 아마인유(ELO), 및 이들의 에폭시화 에스테르 유도체로 이루어진 군에서 선택된 1종 이상이 적용될 수 있다. For example, at least one selected from the group consisting of epoxidized soybean oil (ESO), epoxidized linseed oil (ELO), and epoxidized ester derivatives thereof may be applied.
벤조에이트계 화합물benzoate compound
상기 벤조에이트계 화합물은, 소듐 벤조에이트, 이소노닐 벤조에이트, 이소데실 벤조에이트, 2-프로필헵틸 벤조에이트, 디에틸렌 글리콜 디벤조 에이트, 디프로필렌 글리콜 디벤조에이트, 1,2-디프로필렌 글리콜 디벤조에이트 및 디부틸렌 글리콜 디벤조에이트로 이루어진 군에서 선택되는 1종 이상일 수 있다.The benzoate-based compound is sodium benzoate, isononyl benzoate, isodecyl benzoate, 2-propylheptyl benzoate, diethylene glycol dibenzoate, dipropylene glycol dibenzoate, 1,2-dipropylene glycol di It may be at least one selected from the group consisting of benzoate and dibutylene glycol dibenzoate.
예컨대, 디프로필렌 글리콜 디벤조에이트일 수 있다. For example, it may be dipropylene glycol dibenzoate.
조성물의 배합formulation of the composition
상기 시트레이트계 화합물에 대한 상기 디에틸 헥실 사이클로헥산계 화합물의 중량 비율(디에틸 헥실 사이클로헥산계 화합물/시트레이트계 화합물)은 1/25 내지 25일 수 있다. The weight ratio of the diethyl hexyl cyclohexane compound to the citrate compound (diethyl hexyl cyclohexane compound/citrate compound) may be 1/25 to 25.
상기 범위 내에서, 가소제 조성물의 이행이 효과적으로 억제될 수 있다. 다만, 상기 범위를 초과하는 경우에는 상기 시트레이트계 화합물의 함량이 상대적으로 적어 가소제의 이행을 억제하기 역부족일 수 있고, 상기 범위 미만인 경우에는 상기 디에틸 헥실 사이클로헥산계 화합물의 함량이 상대적으로 적어 열 안정성 및 발포성이 감소할 수 있다. Within the above range, the migration of the plasticizer composition can be effectively suppressed. However, when it exceeds the above range, the content of the citrate-based compound is relatively small, which may be insufficient to suppress the migration of the plasticizer, and when it is less than the above range, the content of the diethylhexyl cyclohexane-based compound is relatively small. Thermal stability and foamability may decrease.
이와 같은 경향성을 고려하여, 1/25 이상, 1/10 이상, 1/2 이상, 또는 1 이상이면서, 25 이하, 23 이하, 20 이하, 또는 18 이하인 범위 내에서 상기 사이클로헥산계 화합물/시트레이트계 화합물의 중량비를 조절할 수 있다.In consideration of this tendency, the cyclohexane-based compound/citrate within the range of 1/25 or more, 1/10 or more, 1/2 or more, or 1 or more, and 25 or less, 23 or less, 20 or less, or 18 or less. The weight ratio of the system compound can be adjusted.
상기 에폭시화 물질에 대한 상기 디에틸 헥실 시트레이트계 화합물의 중량 비율(디에틸 헥실 사이클로헥산계 화합물/ 에폭시화 물질)은 1/25 내지 25일 수 있다.The weight ratio of the diethyl hexyl citrate-based compound to the epoxidized material (diethyl hexyl cyclohexane-based compound/epoxidized material) may be 1/25 to 25.
상기 범위 내에서, 가소제 조성물을 포함하는 포함하는 염화비닐 수지의 내열성을 보완할 수 있다. 다만, 상기 범위를 초과하는 경우에는 상기 벤조에이트계 화합물의 함량이 상대적으로 적어 염화비닐 수지의 내열성을 보완하기에 역부족일 수 있고, 상기 범위 미만인 경우에는 상기 사이클로헥산계 화합물의 함량이 상대적으로 적어 열 안정성 및 발포성이 감소할 수 있다. Within the above range, the heat resistance of the vinyl chloride resin including the plasticizer composition may be supplemented. However, when it exceeds the above range, the content of the benzoate-based compound is relatively small, which may be insufficient to supplement the heat resistance of the vinyl chloride resin, and when it is less than the above range, the content of the cyclohexane-based compound is relatively small. Thermal stability and foamability may decrease.
이와 같은 경향성을 고려하여, 1/25 이상, 1/10 이상, 1/2 이상, 또는 1 이상이면서, 25 이하, 23 이하, 20 이하, 또는 18 이하인 범위 내에서 상기 디에틸 헥실 사이클로헥산계 화합물/ 에폭시화 물질의 중량비를 조절할 수 있다.In consideration of this tendency, the diethylhexyl cyclohexane-based compound within the range of 1/25 or more, 1/10 or more, 1/2 or more, or 1 or more, and 25 or less, 23 or less, 20 or less, or 18 or less. / The weight ratio of the epoxidized material can be adjusted.
상기 벤조에이트계 화합물에 대한 상기 디에틸 헥실 시트레이트계 화합물의 중량 비율(디에틸 헥실 사이클로헥산계 화합물/ 벤조에이트계 화합물)은 1/25 내지 25일 수 있다.The weight ratio of the diethyl hexyl citrate-based compound to the benzoate-based compound (diethyl hexyl cyclohexane-based compound/benzoate-based compound) may be 1/25 to 25.
상기 범위 내에서, 가소제 조성물을 포함하는 포함하는 염화비닐 수지의 연신율을 보완할 수 있다. 다만, 상기 범위를 초과하는 경우에는 상기 벤조에이트계 화합물의 함량이 상대적으로 적어 염화비닐 수지의 연신율을 보완하기에 역부족일 수 있고, 상기 범위 미만인 경우에는 상기 사이클로헥산계 화합물의 함량이 상대적으로 적어 열 안정성 및 발포성이 감소할 수 있다. Within the above range, the elongation of the vinyl chloride resin including the plasticizer composition may be supplemented. However, when it exceeds the above range, the content of the benzoate-based compound is relatively small, which may be insufficient to supplement the elongation of the vinyl chloride resin, and when it is less than the above range, the content of the cyclohexane-based compound is relatively small. Thermal stability and foamability may decrease.
이와 같은 경향성을 고려하여, 1/25 이상, 1/10 이상, 1/2 이상, 또는 1 이상이면서, 25 이하, 23 이하, 20 이하, 또는 18 이하인 범위 내에서 상기 디에틸 헥실 사이클로헥산계 화합물/ 벤조에이트계 화합물의 중량비를 조절할 수 있다.In consideration of this tendency, the diethylhexyl cyclohexane-based compound within the range of 1/25 or more, 1/10 or more, 1/2 or more, or 1 or more, and 25 or less, 23 or less, 20 or less, or 18 or less. / The weight ratio of the benzoate-based compound can be adjusted.
종합하여, 상기 가소제 조성물 총량 (100 중량%) 중, 상기 시트레이트계 화합물을 1 내지 40 중량% 포함하고, 상기 에폭시화 물질을 1 내지 40 중량% 포함하고, 상기 벤조에이트계 화합물을 1 내지 40 중량% 포함하고, 상기 디에틸 헥실 사이클로헥산계 화합물을 잔부로 포함할 수 있다. In sum, in the total amount (100% by weight) of the plasticizer composition, 1 to 40% by weight of the citrate-based compound, 1 to 40% by weight of the epoxidized material, and 1 to 40% by weight of the benzoate-based compound % by weight, and the diethylhexyl cyclohexane-based compound may be included as the balance.
구체적으로, 상기 가소제 조성물 총량 (100 중량%) 중, 상기 시트레이트계 화합물은 1 중량% 이상, 2 중량% 이상, 3 중량% 이상, 4 중량% 이상, 또는 5 중량% 이상이면서, 40 중량% 이하, 35 중량% 이하, 30 중량% 이하, 25 중량% 이하, 20 중량% 이하, 15 중량% 이하, 또는 10 중량% 이하인 범위로 조절할 수 있다.Specifically, in the total amount (100 wt%) of the plasticizer composition, the citrate-based compound is 1 wt% or more, 2 wt% or more, 3 wt% or more, 4 wt% or more, or 5 wt% or more, and 40 wt% or less, 35 wt% or less, 30 wt% or less, 25 wt% or less, 20 wt% or less, 15 wt% or less, or 10 wt% or less.
또한, 상기 가소제 조성물 총량 (100 중량%) 중, 상기 에폭시화 물질은 1 중량% 이상, 2 중량% 이상, 3 중량% 이상, 4 중량% 이상, 또는 5 중량% 이상이면서, 40 중량% 이하, 35 중량% 이하, 30 중량% 이하, 25 중량% 이하, 또는 20 중량% 이하인 범위로 조절할 수 있다.In addition, in the total amount (100% by weight) of the plasticizer composition, the epoxidized material is 1% by weight or more, 2% by weight or more, 3% by weight or more, 4% by weight or more, or 5% by weight or more, and 40% by weight or less, 35% by weight or less, 30% by weight or less, 25% by weight or less, or 20% by weight or less.
또한, 상기 가소제 조성물 총량 (100 중량%) 중, 상기 벤조에이트계 화합물은 1 중량% 이상, 2 중량% 이상, 3 중량% 이상, 4 중량% 이상, 또는 5 중량% 이상이면서, 40 중량% 이하, 35 중량% 이하, 30 중량% 이하, 25 중량% 이하, 20 중량% 이하, 15 중량% 이하, 또는 10 중량% 이하인 범위로 조절할 수 있다.In addition, in the total amount (100 wt%) of the plasticizer composition, the benzoate-based compound is 1 wt% or more, 2 wt% or more, 3 wt% or more, 4 wt% or more, or 5 wt% or more, and 40 wt% or less , 35 wt% or less, 30 wt% or less, 25 wt% or less, 20 wt% or less, 15 wt% or less, or 10 wt% or less.
상기 디에틸 헥실 사이클로헥산계 화합물의 함량은, 상기 가소제 조성물 총량 (100 중량%) 중 상기 시트레이트계 화합물의 함량, 상기 벤조에이트계 화합물의 함량 및 상기 에폭시화 화합물의 함량을 제외한 "잔부"에 해당되며, 전술한 디에틸 헥실 사이클로헥산계 화합물/시트레이트계 화합물의 중량 비율, 디에틸 헥실 사이클로헥산계 화합물/에폭시화 화학물의 중량 비율 및 디에틸 헥실 사이클로헥산 화합물/ 벤조에이트계 화합물의 중량 비율을 만족한다.The content of the diethylhexyl cyclohexane-based compound is the amount of the citrate-based compound, the content of the benzoate-based compound, and the content of the epoxidized compound in the total amount (100 wt%) of the plasticizer composition. If applicable, the weight ratio of the aforementioned diethyl hexyl cyclohexane compound/citrate compound, the weight ratio of the diethyl hexyl cyclohexane compound/epoxidation chemical, and the weight ratio of the diethyl hexyl cyclohexane compound/benzoate compound is satisfied with
염화비닐 수지 조성물Vinyl chloride resin composition
본 발명의 다른 일 구현예에서는, 염화비닐 수지; 및 전술한 일 구현예의 가소제 조성물;을 포함하는 염화비닐 수지 조성물을 제공한다.In another embodiment of the present invention, a vinyl chloride resin; and the plasticizer composition of the above-described embodiment; provides a vinyl chloride resin composition comprising.
이는, 전술한 일 구현예의 가소제 조성물을 포함함으로써, 친환경적면서도, 내오염성, 겔링 속도, 연신율 등의 특성이 우수하게 발현되고, 표면 이행이 최소화된 염화비닐 수지 조성물에 해당된다.This, by including the plasticizer composition of the above-described embodiment, is environmentally friendly, excellent properties such as stain resistance, gelling rate, elongation, etc., and corresponds to a vinyl chloride resin composition with minimal surface migration.
구체적으로, 상기 일 구현예의 염화비닐 수지 조성물은, 상기 염화비닐 수지 100 중량부; 및 상기 가소제 조성물 40 내지 120 중량부;를 포함할 수 있다.Specifically, the vinyl chloride resin composition of the embodiment, 100 parts by weight of the vinyl chloride resin; and 40 to 120 parts by weight of the plasticizer composition.
상기 염화비닐 수지는 폴리비닐클로라이드(PVC)로서, 중합도가 700 내지 1,200인 것을 사용할 수 있으나, 이에 한정되는 것은 아니다.The vinyl chloride resin may be polyvinyl chloride (PVC) having a polymerization degree of 700 to 1,200, but is not limited thereto.
상기 염화비닐 수지 조성물은 첨가제, 예를 들어 안정제, 발포제, 충전재 및 지당(TiO2)으로 구성되는 군으로부터 선택되는 어느 하나 이상을 추가로 포함할 수 있다. 상기 첨가제는 염화비닐 수지 조성물에서 향상시키고자 하는 물성에 따라 적합하게 선택될 수 있다. The vinyl chloride resin composition may further include any one or more selected from the group consisting of additives, for example, a stabilizer, a foaming agent, a filler, and a fat sugar (TiO 2 ). The additive may be appropriately selected according to the physical properties to be improved in the vinyl chloride resin composition.
상기 안정제는 염화비닐 수지에서 HCl이 분리되어 발색단인 폴리엔 구조를 형성하여 주쇄의 절단, 가교 현상을 일으켜 발생하는 여러 가지 물성 변화를 예방하는 목적으로 첨가되는 것으로, Ca-Zn계 화합물, K-Zn계 화합물, Ba-Zn계 화합물, 유기 Tin계 화합물; 메탈릭 비누계 화합물, 페놀계 화합물, 인산 에스테르계 화합물 또는 아인산 에스테르계 화합물로 이루어진 군으로부터 선택되는 어느 하나 이상인 것을 포함한다. 본 발명에서 사용될 수 있는 안정제로 보다 구체적인 예는 Ca-Zn계 화합물; K-Zn계 화합물; Ba-Zn계 화합물; 머캡티드 (Mercaptide)계 화합물, 말레인산계 화합물 또는 카르복실산계 화합물과 같은 유기 Tin계 화합물; Mg-스테아레이트, Ca-스테아레이트, Pb-스테아레이트, Cd-스테아레이트, 또는 Ba-스테아레이트 등과 같은 메탈릭 비누계 화합물; 페놀계 화합물; 인산 에스테르계 화합물; 또는 아인산 에스테르계 화합물 등이며, 사용 목적에 따라 선택적으로 포함된다. 본 발명에서는 특히 K-Zn계 화합물, 바람직하게는 K-Zn계 복합 유기화합물을 사용하는 것이 바람직하다. The stabilizer is added for the purpose of preventing various changes in physical properties caused by cleavage and crosslinking of the main chain by separating HCl from the vinyl chloride resin to form a polyene structure that is a chromophore, Ca-Zn-based compound, K- Zn-based compounds, Ba-Zn-based compounds, organic tin-based compounds; It includes any one or more selected from the group consisting of a metallic soap-based compound, a phenol-based compound, a phosphoric acid ester-based compound, or a phosphorous acid ester-based compound. More specific examples of the stabilizer that can be used in the present invention include Ca—Zn-based compounds; K-Zn-based compounds; Ba-Zn-based compounds; an organic tin-based compound such as a mercaptide-based compound, a maleic acid-based compound, or a carboxylic acid-based compound; metallic soap-based compounds such as Mg-stearate, Ca-stearate, Pb-stearate, Cd-stearate, or Ba-stearate; phenolic compounds; phosphoric acid ester compounds; Or a phosphorous acid ester-based compound, and the like, and optionally included depending on the purpose of use. In the present invention, it is particularly preferable to use a K-Zn-based compound, preferably a K-Zn-based complex organic compound.
상기 안정제는 염화비닐계 수지 100 중량부에 대하여 바람직하게는 0.5 내지 7 중량부, 더욱 바람직하게는 1 내지 4 중량부가 포함된다. 안정제의 함량이 0.5 중량부 미만이면, 열 안정성이 떨어지는 문제점이 있고, 7 중량부를 초과하면 필요 이상의 열 안정성이 발현될 수 있다.The stabilizer is preferably included in an amount of 0.5 to 7 parts by weight, more preferably 1 to 4 parts by weight, based on 100 parts by weight of the vinyl chloride-based resin. If the content of the stabilizer is less than 0.5 parts by weight, there is a problem of poor thermal stability, and if it exceeds 7 parts by weight, more than necessary thermal stability may be expressed.
본 발명에서 사용되는 발포제는 화학적 발포제, 물리적 발포제 또는 이들의 혼합물 중에서 선택되는 어느 하나 이상인 것을 포함한다. The blowing agent used in the present invention includes any one or more selected from a chemical blowing agent, a physical blowing agent, or a mixture thereof.
상기 화학적 발포제로는 특정온도 이상에서 분해되어 가스를 생성하는 화합물이면 특별히 제한하지 않으며, 아조디카본아미드(azodicarbonamide), 아조디이소부티로니트릴(azodiisobutyro-nitrile), 벤젠설포닐하이드라지드(benzenesulfonhydrazide), 4,4-옥시벤젠설포닐-세미카바자이드(4,4-oxybenzene sulfonyl-semicarbazide), p-톨루엔 설포닐 세미-카바자이드(p-toluene sulfonyl semi-carbazide), 바륨아조디카복실레이트(barium azodicarboxylate), N,N'-디메틸-N,N'-디니트로소테레프탈아미드(N,N'-dimethyl-N,N'-dinitrosoterephthalamide), 트리하이드라지노 트리아진(trihydrazino triazine) 등을 예로 들 수 있다. 또한 중탄산나트륨, 중탄산칼륨, 중탄산암모늄, 탄산나트륨, 탄산암모늄 등을 예로 들 수 있다. 또한, 물리적 발포제로는 이산화탄소, 질소, 아르곤, 물, 공기, 헬륨 등의 무기발포제 또는 1 내지 9개의 탄소원자를 포함하는 지방족 탄화수소화합물(aliphatic hydrocarbon), 1 내지 3개의 탄소원자를 포함하는 지방족 알코올(aliphatic alcohol), 1 내지 4개의 탄소원자를 포함하는 할로겐화 지방족 탄화수소화합물(halogenated aliphatic hydrocarbon) 등의 유기발포제를 들 수 있다. The chemical blowing agent is not particularly limited as long as it is a compound that decomposes above a specific temperature to generate gas, azodicarbonamide, azodiisobutyro-nitrile, benzenesulfonylhydrazide ), 4,4-oxybenzene sulfonyl-semicarbazide (4,4-oxybenzene sulfonyl-semicarbazide), p-toluene sulfonyl semi-carbazide (p-toluene sulfonyl semi-carbazide), barium azodicarboxylate ( barium azodicarboxylate), N,N'-dimethyl-N,N'-dinitrosoterephthalamide (N,N'-dimethyl-N,N'-dinitrosoterephthalamide), trihydrazino triazine, etc. can be heard Also exemplified are sodium bicarbonate, potassium bicarbonate, ammonium bicarbonate, sodium carbonate, ammonium carbonate and the like. In addition, the physical foaming agent includes an inorganic foaming agent such as carbon dioxide, nitrogen, argon, water, air, and helium, or an aliphatic hydrocarbon compound containing 1 to 9 carbon atoms, and an aliphatic alcohol containing 1 to 3 carbon atoms. alcohol) and an organic foaming agent such as a halogenated aliphatic hydrocarbon containing 1 to 4 carbon atoms.
상기와 같은 화합물들의 구체적인 예를 들면, 지방족 탄화수소화합물로서 메탄, 에탄 프로판, 노말부탄, 아이소부탄, 노말펜탄, 아이소펜탄, 네오펜탄 등이 있으며, 지방족 알코올로서 메탄올, 에탄올, 노말프로판올, 아이소프로판올 등이 있고, 할로겐화 지방족 탄화수소화합물로서 메틸플루오라이드(methyl fluoride), 퍼플루오로메탄(perfluoromethane), 에틸 플루오라이드(ethyl fluoride), 1,1-디플루오로에탄(1,1-difluoroethane, HFC-152a), 1,1,1-트리플루오로에탄(1,1,1-trifluoroethane, HFC-143a), 1,1,1,2-테트라플루오로에탄(1,1,1,2-tetrafluoroethane, HFC-134a), 1,1,2,2-테트라플루오로에탄(1,1,2,2-tetrafluoromethane, HFC-134), 1,1,1,3,3-펜타플루오로부탄(1,1,1,3,3-pentafluorobutane, HFC-365mfc), 1,1,1,3,3-펜타플루오로프로판(1,1,1,3,3-pentafluoropropane, HFC.sub.13 245fa), 펜타플루오로에탄(pentafluoroethane), 디플루오로메탄(difluoromethane), 퍼플루오로에탄(perfluoroethane), 2,2-디플루오로프로판(2,2-difluoropropane), 1,1,1-트리플루오로프로판(1,1,1-trifluoropropane), 퍼플루오로프로판(perfluoropropane), 디클로로프로판(dichloropropane), 디플루오로프로판(difluoropropane), 퍼플루오로부탄(perfluorobutane), 퍼플루오로사이클로부탄(perfluorocyclobutane), 메틸 클로라이드(methyl chloride), 메틸렌 클로라이드(methylene chloride), 에틸 클로라이드(ethyl chloride), 1,1,1-트리클로로에탄(1,1,1-trichloroethane), 1,1-디클로로-1-플루오로에탄(1,1-dichloro-1-fluoroethane, HCFC-141b), 1-클로로-1,1-디플루오로에탄(1-chloro-1,1-difluoroethane, HCFC-142b), 클로로디플루오로메탄(chlorodifluoromethane, HCFC-22), 1,1-디클로로-2,2,2-트리플루오로에탄(1,1-dichloro-2,2,2-trifluoroethane, HCFC-123), 1-클로로-1,2,2,2-테트라플루오로에탄(1-chloro-1,2,2,2-tetrafluoroethane, HCFC-124), 트리클로로모노플루오로메탄(trichloromonofluoromethane, CFC-11), 디클로로디플루오로메탄(dichlorodifluoromethane, CFC-12), 트리클로로트리플루오로에탄(trichlorotrifluoroethane, CFC-113), 1,1,1-트리플루오로에탄(1,1,1-trifluoroethane),펜타플루오로에탄(pentafluoroethane), 디클로로테트라플루오로에탄(dichlorotetrafluoroethane, CFC-114), 클루오로헵타플루오로프로판(chloroheptafluoropropane), 디클로로헥사플루오로프로판(dichlorohexafluoropropane) 등을 들 수 있다. 상기와 같은 발포제의 함량은 염화비닐계 수지 100 중량부에 대하여 0.5 내지 5 중량부인 것이 바람직한데, 발포제의 함량이 너무 적은 경우에는 발포를 하기 위한 가스의 생성량이 너무 적어 발포효과가 미미하거나 전혀 기대할 수가 없고, 너무 많은 경우에는 가스의 생성량이 너무 많아 요구되는 물성을 기대하기 어렵다.Specific examples of the above compounds include methane, ethane-propane, n-butane, isobutane, normal pentane, isopentane, neopentane, etc. as aliphatic hydrocarbon compounds, and methanol, ethanol, n-propanol, isopropanol, etc. as aliphatic alcohols. methyl fluoride, perfluoromethane, ethyl fluoride, and 1,1-difluoroethane (HFC-152a) as halogenated aliphatic hydrocarbon compounds ), 1,1,1-trifluoroethane (1,1,1-trifluoroethane, HFC-143a), 1,1,1,2-tetrafluoroethane (1,1,1,2-tetrafluoroethane, HFC) -134a), 1,1,2,2-tetrafluoroethane (1,1,2,2-tetrafluoromethane, HFC-134), 1,1,1,3,3-pentafluorobutane (1,1 ,1,3,3-pentafluorobutane, HFC-365mfc), 1,1,1,3,3-pentafluoropropane (1,1,1,3,3-pentafluoropropane, HFC.sub.13 245fa), pentafluoropropane Fluoroethane (pentafluoroethane), difluoromethane (difluoromethane), perfluoroethane (perfluoroethane), 2,2-difluoropropane (2,2-difluoropropane), 1,1,1-trifluoropropane ( 1,1,1-trifluoropropane, perfluoropropane, dichloropropane, difluoropropane, perfluorobutane, perfluorocyclobutane, methyl chloride (methyl chloride), methylene chloride (methylene chloride), ethyl chloride (ethyl chloride), 1,1,1-trichloroethane (1,1,1-trichloroethane), 1,1-dichloro-1-poly Luoroethane (1,1-dichloro-1-fluoroethane, HCFC-141b), 1-chloro-1,1-difluoroethane (1-chloro-1,1-difluoroethane, HCFC-142b), chlorodifluoro chlorodifluoromethane (HCFC-22), 1,1-dichloro-2,2,2-trifluoroethane (1,1-dichloro-2,2,2-trifluoroethane, HCFC-123), 1-chloro- 1,2,2,2-tetrafluoroethane (1-chloro-1,2,2,2-tetrafluoroethane, HCFC-124), trichloromonofluoromethane (CFC-11), dichlorodifluoro Methane (dichlorodifluoromethane, CFC-12), trichlorotrifluoroethane (CFC-113), 1,1,1-trifluoroethane (1,1,1-trifluoroethane), pentafluoroethane, and dichlorotetrafluoroethane (CFC-114), chloroheptafluoropropane, and dichlorohexafluoropropane. The content of the blowing agent as described above is preferably 0.5 to 5 parts by weight based on 100 parts by weight of the vinyl chloride-based resin. There is no number, and when there are too many, it is difficult to expect the required physical properties because the amount of gas is too large.
본 발명의 충전재는 염화비닐계 수지 조성물의 생산성, 건조 상태의 감촉(Dry touch)감을 향상시키는 목적으로 사용되며, 탄산칼슘, 탈크, 이산화티탄, 카올린, 실리카, 알루미나, 수산화마그네슘 또는 점토로 이루어진 군에서 선택되는 어느 하나 이상인 것을 포함한다.The filler of the present invention is used for the purpose of improving the productivity of the vinyl chloride-based resin composition and the feeling of dry touch, and is composed of calcium carbonate, talc, titanium dioxide, kaolin, silica, alumina, magnesium hydroxide or clay. Including any one or more selected from.
상기 본 발명에 따른 염화비닐계 수지 조성물에서 상기 충전재는 바람직하게는 30 내지 150 중량부, 더욱 바람직하게는 50 내지 130 중량부 포함될 수 있다. 충전재가 50 중량부 미만으로 포함된 경우, 치수안정성과 경제성이 낮아지는 문제점이 있고, 130 중량부 초과하여 포함된 경우, 발포 표면이 좋지 않으며, 가공성이 저하되는 문제점이 있다.In the vinyl chloride-based resin composition according to the present invention, the filler may be included in preferably 30 to 150 parts by weight, more preferably 50 to 130 parts by weight. When the filler is included in less than 50 parts by weight, there is a problem in that dimensional stability and economic efficiency are lowered, and when it is included in more than 130 parts by weight, there is a problem in that the foamed surface is not good and workability is reduced.
본 발명의 염화비닐계 수지 조성물은 지당(TiO2)을 첨가하여 백색도 및 은폐성을 향상시킬 수 있다. 상기 지당은 염화비닐 수지 100 중량부에 대하여 바람직하게는 1 내지 20 중량부, 더욱 바람직하게는 3 내지 15 중량부가 포함될 수 있다. 지당이 3 중량부 미만으로 포함된 경우, 백색도 및 은폐성이 떨어져 인쇄 후 색깔이 제대로 나오지 않으며, 15 중량부 초과하여 포함된 경우, 발포 표면이 저하되는 문제점이 있다.The vinyl chloride-based resin composition of the present invention can improve whiteness and hiding properties by adding lipid sugar (TiO 2 ). The fat sugar may be included in an amount of preferably 1 to 20 parts by weight, more preferably 3 to 15 parts by weight, based on 100 parts by weight of the vinyl chloride resin. When the fat sugar is included in less than 3 parts by weight, the color does not come out properly after printing due to poor whiteness and hiding properties.
본 발명에 따른 염화비닐 수지 조성물은 염화비닐계 수지, 상기 가소제 및 선택적으로 첨가제를 사용하여 당업계에 일반적으로 알려진 방법에 의하여 제조될 수 있으며, 그 방법에 있어서 특별히 한정되지는 않는다.The vinyl chloride resin composition according to the present invention may be prepared by a method generally known in the art using a vinyl chloride-based resin, the plasticizer and optionally an additive, and the method is not particularly limited.
상기 염화비닐 수지 조성물은, 바닥재, 벽지, 타포린, 인조피혁, 장난감, 자동차 하부 코팅재 등으로 사용될 수 있으며, 특히 가소제의 migration 특성이 개선되어 환경적인 문제가 적다.The vinyl chloride resin composition can be used as a flooring material, wallpaper, tarpaulin, artificial leather, toys, automobile undercoating, etc. In particular, the migration characteristics of the plasticizer are improved, so that there are few environmental problems.
상기 일 구현예의 가소제 조성물에 있어서, 상기 DEHCH계 화합물은 우수한 코팅 특성, 겔링 속도, 발포 물성 등이 우수한 친환경 가소제 조성물을 구현하고, 상기 시트레이트계 화합물은 표면 이행을 억제하며, 상기 벤조에이트계 화합물은 연신율 등의 물성을 보완할 수 있다.In the plasticizer composition of one embodiment, the DEHCH-based compound implements an eco-friendly plasticizer composition having excellent coating properties, gelling rate, foaming properties, etc., and the citrate-based compound inhibits surface migration, and the benzoate-based compound can supplement physical properties such as elongation.
따라서, 상기 일 구현예의 가소제 조성물은 프탈레이트계 가소제를 대체하여, 바닥재, 벽지, 타포린, 인조피혁, 장난감, 자동차 하부 코팅재 등으로 사용될 수 있다.Accordingly, the plasticizer composition of one embodiment may be used as a flooring material, wallpaper, tarpaulin, artificial leather, toys, automobile undercoating, etc., replacing the phthalate-based plasticizer.
이하, 하기 실시예에 의하여 본 발명을 더욱 상세하게 설명하고자 한다. 단, 하기 실시예는 본 발명을 예시하기 위한 것일 뿐 본 발명의 범위가 이들만으로 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail by way of Examples. However, the following examples are only for illustrating the present invention, and the scope of the present invention is not limited thereto.
실시예 1Example 1
(1) 가소제 조성물의 제조(1) Preparation of plasticizer composition
하기 표 1에 따라, 비스(2-에틸헥실)사이클로헥산-1,4-디카르복실레이트, 트리부틸시트레이트, 에폭시화 대두유 및 디프로필렌 글리콜 디벤조에이트를 혼합하여, 실시예 1의 가소제 조성물을 제조하였다. According to Table 1 below, by mixing bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate, tributylcitrate, epoxidized soybean oil and dipropylene glycol dibenzoate, the plasticizer composition of Example 1 was prepared.
(2) 염화비닐 수지 조성물의 제조(2) Preparation of vinyl chloride resin composition
폴리염화비닐 100 중량부, 상기 실시예 1의 가소제 조성물 60 중량부, 안정제(KKZ102PF, 우창실업) 3 중량부, 발포제(DWPX03, 동진세미켐) 3 중량부, 점도저하제(V5125, BYK사) 10 중량부, 지당(R902, Dupont사) 10 중량부 및 충전재(OM-10, 한국오미아) 100 중량부를 Mathis mixer에서 10분 동안 혼합하여, 실시예 1의 플라스티졸(염화비닐 수지 조성물)을 제조하였다. 100 parts by weight of polyvinyl chloride, 60 parts by weight of the plasticizer composition of Example 1, 3 parts by weight of a stabilizer (KKZ102PF, Woochang Industries), 3 parts by weight of a foaming agent (DWPX03, Dongjin Semichem), 10 parts by weight of a viscosity reducing agent (V5125, BYK company) The plastisol (vinyl chloride resin composition) of Example 1 was prepared by mixing 10 parts by weight of parts, fat sugar (R902, Dupont) and 100 parts by weight of a filler (OM-10, Omia Korea) in a Mathis mixer for 10 minutes. .
실시예 2 내지 4Examples 2 to 4
하기 표 1에 따라 비스(2-에틸헥실)사이클로헥산-1,4-디카르복실레이트, 트리부틸시트레이트, 에폭시화 대두유 및 디프로필렌 글리콜 디벤조에이트의 사용량을 변경한 점을 제외하고는, 실시예 1과 동일한 방법으로, 실시예 2 내지 7의 각 가소제 조성물 및 염화비닐 수지 조성물을 제조하였다.Except for changing the amount of bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate, tributylcitrate, epoxidized soybean oil and dipropylene glycol dibenzoate according to Table 1 below, In the same manner as in Example 1, each plasticizer composition and vinyl chloride resin composition of Examples 2 to 7 were prepared.
비교예 1Comparative Example 1
가소제로서 디옥틸 테레프탈레이트를 단독으로 사용한 점을 제외하고는, 실시예 1과 동일한 방법으로, 비교예 1의 염화비닐 수지 조성물을 제조하였다. A vinyl chloride resin composition of Comparative Example 1 was prepared in the same manner as in Example 1, except that dioctyl terephthalate was used alone as a plasticizer.
비교예 2Comparative Example 2
가소제로서 디이소노닐 프탈레이트를 단독으로 사용한 점을 제외하고는, 실시예 1과 동일한 방법으로, 비교예 1의 가소제 조성물 및 염화비닐 수지 조성물을 제조하였다. A plasticizer composition and a vinyl chloride resin composition of Comparative Example 1 were prepared in the same manner as in Example 1, except that diisononyl phthalate was used alone as a plasticizer.
비교예 3Comparative Example 3
가소제로서 비스(2-에틸헥실)사이클로헥산-1,4-디카르복실레이트를 단독으로 사용한 점을 제외하고는, 실시예 1과 동일한 방법으로, 비교예 3의 염화비닐 수지 조성물을 제조하였다. A vinyl chloride resin composition of Comparative Example 3 was prepared in the same manner as in Example 1, except that bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate was used alone as a plasticizer.
비교예 4Comparative Example 4
하기 표 1에 따라 비스(2-에틸헥실)사이클로헥산-1,4-디카르복실레이트 및 트리부틸시트레이트를 혼합하여 가소제 조성물로 사용한 점을 제외하고는, 실시예 1과 동일한 방법으로, 비교예 4의 염화비닐 수지 조성물을 제조하였다.In the same manner as in Example 1, except that bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate and tributylcitrate were mixed and used as a plasticizer composition according to Table 1 below, in the same manner as in Example 1, A vinyl chloride resin composition of Example 4 was prepared.
비교예 5Comparative Example 5
하기 표 1에 따라 비스(2-에틸헥실)사이클로헥산-1,4-디카르복실레이트 및 디프로필렌 글리콜 디벤조에이트를 혼합하여 가소제 조성물로 사용한 점을 제외하고는, 실시예 1과 동일한 방법으로, 비교예 5의 염화비닐 수지 조성물을 제조하였다.In the same manner as in Example 1, except that bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate and dipropylene glycol dibenzoate were mixed and used as a plasticizer composition according to Table 1 below. , a vinyl chloride resin composition of Comparative Example 5 was prepared.
비교예 6 Comparative Example 6
하기 표 1에 따라 비스(2-에틸헥실)사이클로헥산-1,4-디카르복실레이트 및 트리부틸시트레이트를 혼합하여 가소제 조성물로 사용한 점을 제외하고는, 실시예 1과 동일한 방법으로, 비교예 6의 염화비닐 수지 조성물을 제조하였다.In the same manner as in Example 1, except that bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate and tributylcitrate were mixed and used as a plasticizer composition according to Table 1 below, in the same manner as in Example 1, A vinyl chloride resin composition of Example 6 was prepared.
비교예 6Comparative Example 6
하기 표 1에 따라 비스(2-에틸헥실)사이클로헥산-1,4-디카르복실레이트, 트리부틸시트레이트 및 에폭시화 대두유를 혼합하여 가소제 조성물로 사용한 점을 제외하고는, 실시예 1과 동일한 방법으로, 비교예 7의 염화비닐 수지 조성물을 제조하였다.The same as in Example 1, except that bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate, tributylcitrate, and epoxidized soybean oil were mixed and used as a plasticizer composition according to Table 1 below. By the method, a vinyl chloride resin composition of Comparative Example 7 was prepared.
상기 실시예 및 비교예의 각 가소제 조성물을 하기 표 1에 정리하였다. 참고로, 하기 표 1에 기재된 물질의 약칭은 다음과 같다. Each plasticizer composition of Examples and Comparative Examples is summarized in Table 1 below. For reference, the abbreviations of the substances listed in Table 1 are as follows.
1) DEHCH: 비스(2-에틸헥실)사이클로헥산-1,4-디카르복실레이트(Bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate), 제조사: Hanwha solutions, Mw: 396.6 g/mol1) DEHCH: bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate (Bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate), manufacturer: Hanwha solutions, Mw: 396.6 g/mol
2) TBC: 트리부틸시트레이트(tributylcitrate), 제조사: Lemon-flex, Mw: 360.5 g/mol2) TBC: tributylcitrate, Manufacturer: Lemon-flex, Mw: 360.5 g/mol
3) BF 9-88: 디프로필렌 글리콜 디벤조에이트(Dipropylene glycol dibenzonate), 제조사: Eastman, Mw: 342.4 g/mol3) BF 9-88: Dipropylene glycol dibenzonate, manufacturer: Eastman, Mw: 342.4 g/mol
4) ESO: 에폭시화 대두유(제품명: E-700), 제조사: 송원산업4) ESO: epoxidized soybean oil (product name: E-700), manufacturer: Songwon Industrial
5) DOTP: 디옥틸 테레프탈레이트(Dioctyl Terephthalate)5) DOTP: Dioctyl Terephthalate
6) DINP: 디이소노닐 프탈레이트(Diisononyl phthalate)6) DINP: Diisononyl phthalate
(중량부)DEHCH
(parts by weight)
(중량부)TBC
(parts by weight)
(중량부)ESO
(parts by weight)
(중량부)BF 9-88
(parts by weight)
(중량부)DOTP
(parts by weight)
(중량부)DINP
(parts by weight)
실험예Experimental example
상기 실시예 및 비교예의 각 플라스티졸(염화비닐 수지 조성물)에 대해, 다음과 같은 방법으로 내오염성(가소제 이행성), 휘발 감량, 겔링 속도, 점도 및 내열성을 평가하였다. For each plastisol (vinyl chloride resin composition) of Examples and Comparative Examples, stain resistance (plasticizer transferability), loss of volatilization, gelling rate, viscosity, and heat resistance were evaluated in the following manner.
1) 내오염성(가소제 이행성): 플라스티졸(5 g)을 종이 위에 올려 놓고, 유출된 가소제의 양을 측정하고, 표면과 종이에서 관찰되는 가소제 량을 점수화하여(매우 우수 5>4>3>2>1 매우 열세), 이행 특성을 평가하였으며, 그 결과를 하기 표 2에 나타내었다. 1) Staining resistance (plasticizer transferability): Place plastisol (5 g) on paper, measure the amount of spilled plasticizer, and score the amount of plasticizer observed on the surface and paper (very good 5>4> 3>2>1 very poor), the transition characteristics were evaluated, and the results are shown in Table 2 below.
2) 휘발 감량: 플라스티졸을 200 ℃, 1시간 방치 후, 전/후의 무게 변화를 측정하였다. 휘발 감량을 다음과 같이 계산하였다. 2) Loss of volatilization: After leaving the plastisol at 200° C. for 1 hour, the weight change before/after was measured. The loss on volatilization was calculated as follows.
휘발 감량 (%) = [(초기 가소제 조성물 무게 - 방치 후 가소제 조성물 무게)/ 초기 가소제 조성물 무게] * 100Loss of volatilization (%) = [(weight of initial plasticizer composition - weight of plasticizer composition after standing) / weight of initial plasticizer composition] * 100
3) 겔링 속도: 플라스티졸을 SVNC 장비를 이용하여 110℃에서 겔링 속도를 측정하였다. SVNC 장비에서 겔링이 진행될수록 진폭(amplitude)이 감소하는데 이의 감소 속도를 이용하여 겔링 속도를 비교 측정하였다. 또한, 겔링 속도를 점수화하여 하기 표 2에 나타내었다(매우 우수 5>4>3>2>1 매우 열세).3) Geling rate: The gelling rate of plastisol was measured at 110° C. using SVNC equipment. As the gelling progresses in the SVNC equipment, the amplitude decreases, and the gelling rate was compared and measured using the decrease rate. In addition, the gelling rate was scored and shown in Table 2 below (excellent 5>4>3>2>1 very poor).
4) 점도: 플라스티졸을 25℃ 항온 오븐에서 1시간 동안 숙성시킨 후 Brookfield 점도계(spindle #6, 20 RPM)를 이용하여 초기점도를 측정하였으며, 그 결과를 하기 표 2에 나타내었다.4) Viscosity: After aging the plastisol in a constant temperature oven at 25° C. for 1 hour, the initial viscosity was measured using a Brookfield viscometer (spindle #6, 20 RPM), and the results are shown in Table 2 below.
5) 내열성: 상기 실시예 및 비교예의 각 플라스티졸(염화비닐 수지 조성물)을 PET 필름에 250㎛두께로 코팅 후 200℃에서 변색 시정을 평가한다. 또한, 내열성을 점수화하여 하기 표 2에 나타내었다(매우 우수 5>4>3>2>1 매우 열세). 5) Heat resistance: After coating each of the plastisols (vinyl chloride resin composition) of the above Examples and Comparative Examples to a thickness of 250 μm on a PET film, the color change correction was evaluated at 200°C. In addition, the heat resistance was scored and shown in Table 2 below (excellent 5>4>3>2>1 very poor).
이와 독립적으로, 상기 실시예 및 비교예의 각 플라스티졸(염화비닐 수지 조성물)을 시트 형태로 성형한 뒤, 연신율을 평가하였다. Independently, each plastisol (vinyl chloride resin composition) of the Examples and Comparative Examples was molded into a sheet, and then elongation was evaluated.
6) 연신율: 상기 실시예 및 비교예의 각 플라스티졸(염화비닐 수지 조성물)을 PET 필름에 250㎛두께로 코팅 후 200℃에서 100초간 Gelling하여 Sheet를 제작 한다. 제작한 Sheet를 ASTM D412(Type C) 규격으로 제작한 후 500mm/min의 Crosshead Speed로 측정한다. 측정한 후, 연신율을 다음과 같이 계산하였다:6) Elongation: Each plastisol (vinyl chloride resin composition) of Examples and Comparative Examples was coated on a PET film to a thickness of 250 μm, and then gelled at 200° C. for 100 seconds to prepare a sheet. Manufactured sheet according to ASTM D412 (Type C) standard, and then measured with crosshead speed of 500mm/min. After the measurement, the elongation was calculated as follows:
연신율 (%) = [신장 후 길이 / 초기 길이] x 100Elongation (%) = [Length after stretching / Initial length] x 100
(가소제
이행성)stain resistance
(plasticizer
transitional)
(20 rpm, cps)viscosity
(20 rpm, cps)
(%)elongation
(%)
구체적으로, 가소제로서 DINP를 단독으로 사용한 비교예 2의 경우, 대부분의 물성이 비교적 우수하게 나타난다.Specifically, in the case of Comparative Example 2 in which DINP was used alone as a plasticizer, most of the physical properties were relatively excellent.
다만, DINP는 프탈레이트계 가소제로서, 친환경성 가소제로 분류되지 않으며, 규제가 많아 사용이 제한되고 있다.However, DINP, as a phthalate-based plasticizer, is not classified as an eco-friendly plasticizer, and its use is limited due to many regulations.
한편, 친환경 가소제로서 DOTP를 단독으로 사용한 비교예 1은, 디이소노닐 프탈레이트(DINP)를 단독으로 사용하는 비교예 2에 대비하여, 동등 이상의 내열성 및 연신율을 나타내지만, 휘발 감량, 겔링 속도 및 표면 이행 억제 특성은 열등하다.On the other hand, Comparative Example 1 using DOTP alone as an eco-friendly plasticizer showed equivalent or higher heat resistance and elongation compared to Comparative Example 2 using diisononyl phthalate (DINP) alone, but loss on volatilization, gelling rate and surface The transition-inhibiting properties are inferior.
또 다른 친환경 가소제로서 DEHCH를 단독으로 사용한 비교예 3의 경우, DOTP를 단독으로 사용하는 비교예 1보다는 개선된 겔링 속도를 나타내고, DINP를 단독으로 사용하는 비교예 2보다 낮은 점도를 나타내지만, 상기 비교예 2보다는 표면 이행 억제 특성이 열등하며 휘발 감량이 높다.In the case of Comparative Example 3 using DEHCH alone as another eco-friendly plasticizer, it shows an improved geling rate than Comparative Example 1 using DOTP alone, and shows a lower viscosity than Comparative Example 2 using DINP alone, but the above It is inferior to the comparative example 2 in the surface migration suppression property, and volatilization loss is high.
DEHCH와 함께 시트레이트계 화합물을 혼합 사용한 비교예 4는, DEHCH를 단독으로 사용한 비교예 3에 대비하여, 표면 이행 억제 특성 및 겔링 속도가 개선되었으나, 휘발 감량이 증가하고, 내열성 및 연신율이 감소하였다.In Comparative Example 4, in which a citrate-based compound was mixed with DEHCH, compared to Comparative Example 3 in which DEHCH was used alone, the surface migration inhibitory property and the gelling rate were improved, but the volatilization loss increased, and the heat resistance and elongation were decreased. .
이와 달리, DEHCH와 함께 벤조에이트계 화합물을 혼합 사용한 비교예 5는, DEHCH를 단독으로 사용한 비교예 3에 대비하여, 연신율이 소폭 증가하였으나, 휘발 감량이 증가하고, 내열성이 감소하였다.On the other hand, Comparative Example 5 in which a benzoate-based compound was mixed with DEHCH was slightly increased in elongation, compared to Comparative Example 3 in which DEHCH was used alone, but volatilization loss increased and heat resistance was decreased.
또한, DEHCH와 함께 에폭시화 물질을 혼합 사용한 비교예 7은, DEHCH를 단독으로 사용한 비교예 3에 대비하여, 내열성이 증가하며 휘발 감량이 감소하였으나, 표면 이행 억제 특성은 감소하고, 겔링 속도 등은 동등 수준에 머물렀다.In addition, in Comparative Example 7, in which an epoxidized material was mixed with DEHCH, compared to Comparative Example 3 in which DEHCH was used alone, the heat resistance increased and the volatilization loss decreased, but the surface migration inhibitory property decreased, and the gelling rate, etc. remained at the same level.
DEHCH와 함께 시트레이트계 화합물 및 벤조에이트계 화합물을 혼합 사용한 비교예 6은, DEHCH를 단독으로 사용한 비교예 3에 대비하여, 휘발 감량이 일부 감소하였으나, 표면 이행 억제 특성, 겔링 속도, 내열성 등은 동등 수준에 머물렀다.Comparative Example 6 in which a citrate-based compound and a benzoate-based compound were mixed with DEHCH, compared with Comparative Example 3 in which DEHCH was used alone, had a partial decrease in volatilization loss, but surface migration inhibitory properties, gelling speed, heat resistance, etc. remained at the same level.
DEHCH와 함께 시트레이트계 화합물 및 벤조에이트계 화합물을 혼합 사용한 비교예 8은, DEHCH를 단독으로 사용한 비교예 3에 대비하여, 표면 이행 억제 특성이 소폭 증가하였으나, 휘발 감량이 증가하며 내열성이 감소하고, 겔링 속도 등은 동등 수준에 머물렀다.Comparative Example 8, in which a citrate-based compound and a benzoate-based compound were mixed with DEHCH, slightly increased surface migration inhibitory properties, compared to Comparative Example 3, in which DEHCH was used alone, but increased volatilization loss and decreased heat resistance, , gelling speed, etc. remained at the same level.
DEHCH와 함께 에폭시화 물질 및 벤조에이트계 화합물을 혼합 사용한 비교예 9는, DEHCH를 단독으로 사용한 비교예 3에 대비하여, 대부분의 물성이 동등 수준에 머물렀다.Comparative Example 9 using a mixture of an epoxidized material and a benzoate-based compound with DEHCH, compared to Comparative Example 3 using DEHCH alone, most of the physical properties remained at the same level.
그에 반면, DEHCH와 함께 시트레이트계 화합물, 에폭시화 물질 및 벤조에이트계 화합물을 모두 혼합 사용한 실시예 1 내지 4는, 표면 이행 억제 특성, 휘발 감량, 겔링 속도, 점도, 내열성, 및 연신율이 두루 우수하게 나타났다.On the other hand, Examples 1 to 4 in which both a citrate-based compound, an epoxidized material, and a benzoate-based compound were mixed with DEHCH were excellent in surface migration inhibiting properties, volatilization loss, gelling rate, viscosity, heat resistance, and elongation. showed up
이는, 친환경적이면서도 겔링 속도가 빠른 DEHCH계 화합물과 함께, 표면 이행을 억제하는 시트레이트계 화합물, 내열성 및 휘발 감량을 보완하는 에폭시화 물질, 및 연신율을 보완하는 벤조에이트계 화합물을 동시에 포함함에 따른 효과이다.This is the effect of simultaneously including a citrate-based compound that suppresses surface migration, an epoxidized material that compensates heat resistance and loss of volatilization, and a benzoate-based compound that compensates for elongation, along with an environmentally friendly DEHCH-based compound with a fast gelling rate to be.
또한, 상기 실시예 1 내지 4를 참고하여, 전술한 일 구현예의 범위 내에서 DEHCH계 화합물, 시트레이트계 화합물, 에폭시화 물질 및 벤조에이트계 화합물의 배합비를 조절함으로써, 표면 이행 억제 특성, 휘발 감량, 겔링 속도, 점도, 내열성, 및 연신율을 제어할 수 있음을 알 수 있다.In addition, with reference to Examples 1 to 4, by adjusting the compounding ratio of the DEHCH-based compound, the citrate-based compound, the epoxidized material and the benzoate-based compound within the scope of the above-described embodiment, the surface migration inhibiting property, the loss of volatilization , it can be seen that the gelling rate, viscosity, heat resistance, and elongation can be controlled.
Claims (17)
시트레이트계 화합물;
에폭시화 물질; 및
벤조에이트계 화합물;을 포함하는,
가소제 조성물.
diethyl hexyl cyclohexane compound;
citrate-based compounds;
epoxidized materials; and
containing; benzoate-based compounds;
plasticizer composition.
상기 디에틸 헥실 사이클로헥산계 화합물은,
비스(2-에틸헥실)사이클로헥산-1,2-디카르복실레이트(Bis(2-ethylhexyl)cyclohexane-1,2-dicarboxylate), 비스(2-에틸헥실)사이클로헥산-1,3-디카르복실레이트(Bis(2-ethylhexyl)cyclohexane-1,3-dicarboxylate), 및 비스(2-에틸헥실)사이클로헥산-1,4-디카르복실레이트(Bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate)로 이루어진 군에서 선택되는 1종 이상인,
가소제 조성물.
According to claim 1,
The diethyl hexyl cyclohexane compound is
Bis(2-ethylhexyl)cyclohexane-1,2-dicarboxylate (Bis(2-ethylhexyl)cyclohexane-1,2-dicarboxylate), bis(2-ethylhexyl)cyclohexane-1,3-dicarboxylate carboxylate (Bis(2-ethylhexyl)cyclohexane-1,3-dicarboxylate), and bis(2-ethylhexyl)cyclohexane-1,4-dicarboxylate (Bis(2-ethylhexyl)cyclohexane-1,4- at least one selected from the group consisting of dicarboxylate)
plasticizer composition.
상기 시트레이트계 화합물은,
하기 화학식 1로 표시되는,
가소제 조성물:
[화학식 1]
상기 화학식 1에서,
R1은 수소 또는 아세틸이고,
R2 내지 R4는 각각 독립적으로 C2-8 알킬이다.
The method of claim 1,
The citrate-based compound is
Represented by the following formula (1),
Plasticizer composition:
[Formula 1]
In Formula 1,
R 1 is hydrogen or acetyl,
R 2 to R 4 are each independently C 2-8 alkyl.
상기 R2 내지 R4는 각각 독립적으로 부틸 또는 옥틸인,
가소제 조성물.
4. The method of claim 3,
The R 2 To R 4 are each independently butyl or octyl,
plasticizer composition.
상기 시트레이트계 화합물은,
트리부틸시트레이트, 트리(부틸옥틸)시트레이트, 트리옥틸시트레이트 및 아세틸트리부틸시트레이트로 이루어진 군에서 선택되는 1종 이상인,
가소제 조성물.
According to claim 1,
The citrate-based compound is
At least one selected from the group consisting of tributyl citrate, tri (butyloctyl) citrate, trioctyl citrate and acetyl tributyl citrate;
plasticizer composition.
상기 에폭시화 물질은,
에폭시화 대두유(epoxidized soybean oil), 에폭시화 피마자유(epoxidized castor oil), 에폭시화 아마인유(epoxidized linseed oil), 에폭시화 팜유(epoxidized palm oil), 에폭시화 스테아레이트(epoxidized stearate), 에폭시화 올리에이트(epoxidized oleate), 에폭시화 톨리에이트(epoxidized tallate) 및 에폭시화 리놀리에이트(epoxidized linoleate), 및 이들의 에폭시화 에스테르 유도체로 이루어진 군에서 선택된 1종 이상인,
가소제 조성물.
According to claim 1,
The epoxidized material is
Epoxidized soybean oil, epoxidized castor oil, epoxidized linseed oil, epoxidized palm oil, epoxidized stearate, epoxidized oligo At least one selected from the group consisting of epoxidized oleate, epoxidized tallate and epoxidized linoleate, and epoxidized ester derivatives thereof,
plasticizer composition.
상기 벤조에이트계 화합물은,
소듐 벤조에이트, 이소노닐 벤조에이트, 이소데실 벤조에이트, 2-프로필헵틸 벤조에이트, 디에틸렌 글리콜 디벤조 에이트, 디프로필렌 글리콜 디벤조에이트, 1,2-디프로필렌 글리콜 디벤조에이트 및 디부틸렌 글리콜 디벤조에이트로 이루어진 군에서 선택되는 1종 이상인,
가소제 조성물.
According to claim 1,
The benzoate-based compound is
Sodium benzoate, isononyl benzoate, isodecyl benzoate, 2-propylheptyl benzoate, diethylene glycol dibenzoate, dipropylene glycol dibenzoate, 1,2-dipropylene glycol dibenzoate and dibutylene glycol At least one selected from the group consisting of dibenzoate,
plasticizer composition.
상기 시트레이트계 화합물에 대한 상기 디에틸 헥실 사이클로헥산계 화합물의 중량 비율(디에틸 헥실 사이클로헥산계 화합물/시트레이트계 화합물)은,
1/25 내지 25인,
가소제 조성물.
According to claim 1,
The weight ratio of the diethyl hexyl cyclohexane compound to the citrate compound (diethyl hexyl cyclohexane compound/citrate compound) is,
1/25 to 25 people;
plasticizer composition.
상기 에폭시화 물질에 대한 상기 디에틸 헥실 사이클로헥산계 화합물의 중량 비율(디에틸 헥실 사이클로헥산계 화합물/ 에폭시화 물질)은,
1/25 내지 25인,
가소제 조성물.
According to claim 1,
The weight ratio of the diethyl hexyl cyclohexane-based compound to the epoxidized material (diethyl hexyl cyclohexane-based compound/epoxidized material) is,
1/25 to 25 people;
plasticizer composition.
상기 벤조에이트계 화합물에 대한 상기 디에틸 헥실 시트레이트계 화합물의 중량 비율(디에틸 헥실 사이클로헥산계 화합물/ 벤조에이트계 화합물)은,
1/25 내지 25인,
가소제 조성물.
According to claim 1,
The weight ratio of the diethyl hexyl citrate compound to the benzoate compound (diethyl hexyl cyclohexane compound / benzoate compound) is,
1/25 to 25 people;
plasticizer composition.
상기 가소제 조성물 총량 (100 중량%) 중,
상기 시트레이트계 화합물을 1 내지 40 중량% 포함하고,
상기 에폭시화 물질을 1 내지 40 중량% 포함하고,
상기 벤조에이트계 화합물을 1 내지 40 중량% 포함하고,
상기 디에틸 헥실 사이클로헥산계 화합물을 잔부로 포함하는
가소제 조성물.
According to claim 1,
Of the total amount (100% by weight) of the plasticizer composition,
1 to 40% by weight of the citrate-based compound,
1 to 40% by weight of the epoxidized material,
1 to 40% by weight of the benzoate-based compound,
containing the diethyl hexyl cyclohexane-based compound as a balance
plasticizer composition.
제1항 내지 제11항 중 어느 한 항의 가소제 조성물;을 포함하는,
염화비닐 수지 조성물.
vinyl chloride resin; and
The plasticizer composition of any one of claims 1 to 11;
A vinyl chloride resin composition.
상기 염화비닐 수지 100 중량부; 및
상기 가소제 조성물 40 내지 120 중량부;를 포함하는,
염화비닐 수지 조성물.
13. The method of claim 12,
100 parts by weight of the vinyl chloride resin; and
40 to 120 parts by weight of the plasticizer composition; containing,
A vinyl chloride resin composition.
안정제, 발포제, 충전재 및 지당(TiO2)으로 구성되는 군으로부터 선택되는 어느 하나 이상을 추가로 포함하는,
염화비닐 수지 조성물.
13. The method of claim 12,
Stabilizers, foaming agents, fillers and fat sugar (TiO 2 ) Further comprising any one or more selected from the group consisting of,
A vinyl chloride resin composition.
상기 안정제는, Ca-Zn계 화합물, K-Zn계 화합물, Ba-Zn계 화합물, 유기 Tin계 화합물, 메탈릭 비누계 화합물, 페놀계 화합물, 인산 에스테르계 화합물 또는 아인산 에스테르계 화합물로 이루어진 군으로부터 선택되는 어느 하나 이상인,
염화비닐 수지 조성물.
15. The method of claim 14,
The stabilizer is selected from the group consisting of a Ca-Zn-based compound, a K-Zn-based compound, a Ba-Zn-based compound, an organic tin-based compound, a metallic soap-based compound, a phenol-based compound, a phosphoric acid ester-based compound, or a phosphorous acid ester-based compound any one or more of
A vinyl chloride resin composition.
상기 발포제는 화학적 발포제, 물리적 발포제 또는 이들의 혼합물 중에서 선택되는 어느 하나 이상인,
염화비닐 수지 조성물.
15. The method of claim 14,
The blowing agent is at least one selected from a chemical blowing agent, a physical blowing agent, or a mixture thereof,
A vinyl chloride resin composition.
상기 충전재는 탄산칼슘, 탈크, 이산화티탄, 카올린, 실리카, 알루미나, 수산화마그네슘 또는 점토로 이루어진 군에서 선택되는 어느 하나 이상인,
염화비닐 수지 조성물.
15. The method of claim 14,
The filler is at least one selected from the group consisting of calcium carbonate, talc, titanium dioxide, kaolin, silica, alumina, magnesium hydroxide or clay,
A vinyl chloride resin composition.
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