KR20220085514A - Paint With Enhanced Friction Coefficient - Google Patents

Paint With Enhanced Friction Coefficient Download PDF

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Publication number
KR20220085514A
KR20220085514A KR1020200175656A KR20200175656A KR20220085514A KR 20220085514 A KR20220085514 A KR 20220085514A KR 1020200175656 A KR1020200175656 A KR 1020200175656A KR 20200175656 A KR20200175656 A KR 20200175656A KR 20220085514 A KR20220085514 A KR 20220085514A
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South Korea
Prior art keywords
present
friction
paint
powder
coefficient
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KR1020200175656A
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Korean (ko)
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신아리
이경록
문환균
류민호
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일진다이아몬드(주)
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Publication of KR20220085514A publication Critical patent/KR20220085514A/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/06Treatment with inorganic compounds
    • C09C3/063Coating
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds

Abstract

고경도 세라믹스 입자를 함유하는 향상된 마찰계수를 갖는 도료에 관한 것이다. 본 발명은 경질 세라믹스 분말, 바인더 수지 및 안료를 포함하는 고마찰 계수를 갖는 도료 조성물을 제공한다. 본 발명의 도료 조성물을 강구조물의 접합부에 적용하면 사용되는 볼트 사용량을 줄여 비용 절감이 가능하며, 높은 마찰계수로 볼트 풀림을 방지하여 안전을 도모할 수 있게 된다.It relates to a paint having an improved coefficient of friction containing high hardness ceramic particles. The present invention provides a coating composition having a high coefficient of friction comprising a hard ceramic powder, a binder resin, and a pigment. When the coating composition of the present invention is applied to the joint part of a steel structure, it is possible to reduce the amount of bolts used, thereby reducing costs, and preventing bolt loosening with a high coefficient of friction to promote safety.

Description

향상된 마찰계수를 갖는 도료{Paint With Enhanced Friction Coefficient}Paint With Enhanced Friction Coefficient

본 발명은 고경도 세라믹스 입자를 함유하는 향상된 마찰계수를 갖는 도료에 관한 것이다. The present invention relates to a paint having an improved coefficient of friction containing high hardness ceramic particles.

기계, 플랜트 또는 자동차 분야의 볼트 체결 또는 클램프 체결 구조물에서 진동 등에 의한 볼트 풀림을 방지하거나 정지 마찰 계수를 증가시키기 위하여 고마찰 중간층을 사용하고 있다. 예컨대 이런 구조물은 금속 기재와 금속 기재 상에 경질 입자층을 포함하여 정지 마찰 계수를 증가시키는 구조를 가질 수 있다. A high friction interlayer is used to prevent bolt loosening due to vibration or the like or to increase a static friction coefficient in bolted or clamped structures in machinery, plants, or automobiles. For example, such a structure may have a structure that increases the static friction coefficient by including a metal substrate and a hard particle layer on the metal substrate.

한편, 종래의 볼트 체결 구조물에서 기존 방청 목적으로 사용되는 아연말계 도료의 결합밀도를 높여 마찰계수를 증가시킨 에폭시계 아연말계 도료가 사용되고 있다. 그러나, 아연말계 도료에 의해서는 볼트 체결 구조에서 요구되는 높은 마찰계수를 달성하는 데 한계가 있다. On the other hand, in the conventional bolt fastening structure, an epoxy-based zinc powder-based coating material having an increased friction coefficient by increasing the bonding density of the zinc powder coating material used for the purpose of preventing rust is used. However, there is a limit to achieving a high coefficient of friction required in a bolted fastening structure by using a zinc powder-based paint.

(1) 한국공개특허 제2008-23885호(1) Korean Patent Publication No. 2008-23885 (2) 한국공개특허 제2009-95401호(2) Korean Patent Publication No. 2009-95401

상기 종래 기술의 문제점을 해결하기 위하여, 본 발명은 경질 세라믹스 분말을 함유하여 고마찰 계수를 갖는 도료 및 그 제조 방법을 제공하는 것을 목적으로 한다.In order to solve the problems of the prior art, an object of the present invention is to provide a coating material containing hard ceramic powder and having a high coefficient of friction, and a method for manufacturing the same.

상기 기술적 과제를 달성하기 위하여 본 발명은, 경질 세라믹스 분말, 바인더 수지 및 안료를 포함하는 고마찰 계수를 갖는 도료 조성물을 제공한다. 또한, 본 발명에서 상기 도료 조성물은 아연 분말 또는 마그네슘 분말 중 최소한 1종의 금속 분말을 더 포함할 수 있다. In order to achieve the above technical object, the present invention provides a coating composition having a high friction coefficient comprising a hard ceramic powder, a binder resin, and a pigment. In addition, in the present invention, the coating composition may further include at least one metal powder among zinc powder and magnesium powder.

본 발명의 도료 조성물을 강구조물의 접합부에 적용하면 사용되는 볼트 사용량을 줄여 비용 절감이 가능하며, 높은 마찰계수로 볼트 풀림을 방지하여 시공물의 안전을 도모할 수 있다.When the coating composition of the present invention is applied to the joint of a steel structure, it is possible to reduce costs by reducing the amount of bolts used, and to prevent bolt loosening with a high coefficient of friction, thereby promoting the safety of the construction.

이하 도면을 참조하여 본 발명의 바람직한 실시예를 설명함으로써 본 발명을 상술한다.Hereinafter, the present invention will be described in detail by describing preferred embodiments of the present invention with reference to the drawings.

강구조물의 접합부에 안전하게 적용하고 비용절감 등의 효과를 극대화하기 위해서는 0.6 이상의 고마찰계수가 요구되는데, 본 발명은 종래 도료의 마찰 계수를 개선하기 위하여 경질입자를 사용한다.A high friction coefficient of 0.6 or more is required in order to safely apply it to the joint of a steel structure and maximize the effect of cost reduction, and the present invention uses hard particles to improve the friction coefficient of the conventional paint.

본 발명은 기존에 프레임의 방청을 위해 사용되는 아연계 도료에서 착안하여 아연 분말에 Diamond, Cubic Boron Nitride, Al2O3, SiC 및 B4C 로 이루어지는 그룹 중에서 선택된 최소한 1종의 경질 입자 분말을 아연 분말과 혼합하거나 또는 아연 입자를 최소한 일부 또는 전부 대체하여 고마찰계수를 갖는 도료를 제공한다. The present invention focuses on the zinc-based paint used for the conventional anti-rust of the frame, and at least one hard particle powder selected from the group consisting of Diamond, Cubic Boron Nitride, Al 2 O 3 , SiC and B 4 C is added to zinc powder. To provide a paint having a high coefficient of friction by mixing with zinc powder or replacing at least part or all of zinc particles.

본 발명은 경질 세라믹스 분말, 바인더 수지 및 안료를 포함하는 고마찰 계수를 갖는 도료를 제공한다. 또한, 본 발명의 도료는 금속 분말을 추가로 포함할 수 있다. 예컨대, 상기 금속 분말로는 아연 분말 또는 마그네슘 분말이 사용될 수 있다. The present invention provides a paint having a high coefficient of friction comprising a hard ceramic powder, a binder resin and a pigment. In addition, the paint of the present invention may further include a metal powder. For example, zinc powder or magnesium powder may be used as the metal powder.

본 발명에서 상기 경질 세라믹스 분말은 다이아몬드, 입방정 질화붕소, 산화알루미늄, 탄화규소 및 탄화붕소로 이루어진 그룹 중에서 선택된 최소한 1종의 입자를 포함할 수 있다. In the present invention, the hard ceramic powder may include at least one particle selected from the group consisting of diamond, cubic boron nitride, aluminum oxide, silicon carbide, and boron carbide.

상기 경질 세라믹스 분말은 입자 평균 입경이 약 0.1~100㎛, 바람직하게는 약 1~10 ㎛일 수 있다. The hard ceramic powder may have an average particle diameter of about 0.1 to 100 μm, preferably about 1 to 10 μm.

본 발명에서 상기 경질 세라믹스 분말은 표면 개질될 수 있다. 예컨대, 상기 경질 세라믹스 분말 표면은 Al, Si, B, Mn, Cr, Si, Zr, Co, Ti, Zn, Mg, Ni 및 W으로 이루어진 그룹 중에서 선택된 최소한 1종의 금속 또는 그 합금이나 이들 금속의 탄화물(TiC, SiC 등), 이들 금속의 질화물(AlN, TiN, SiN 등) 및 이들 금속의 산화물 (SiO2, TiO2 등)로 이루어진 그룹 중에서 선택된 최소한 1종의 물질로 코팅될 수 있다. In the present invention, the hard ceramic powder may be surface-modified. For example, the surface of the hard ceramics powder is at least one metal selected from the group consisting of Al, Si, B, Mn, Cr, Si, Zr, Co, Ti, Zn, Mg, Ni, and W, or an alloy thereof, or an alloy of these metals. It may be coated with at least one material selected from the group consisting of carbides (TiC, SiC, etc.), nitrides of these metals (AlN, TiN, SiN, etc.), and oxides of these metals (SiO 2 , TiO 2 , etc.).

본 발명에서 상기 바인더 수지로는 에폭시 수지 또는 우레탄 수지가 사용될 수 있다. 예컨데, 상기 에폭시 수지로는 일반 비스페놀 A형 에폭시, 비스페놀 F형 에폭시, 노블락형 에폭시, 브롬화 에폭시, 지환족형 에폭시, 고무변성 에폭시 및 글리시딜 아민형 에폭시로 이루어진 그룹 중에서 선택된 최소한 1종이 사용될 수 있다. In the present invention, an epoxy resin or a urethane resin may be used as the binder resin. For example, as the epoxy resin, at least one selected from the group consisting of general bisphenol A type epoxy, bisphenol F type epoxy, novolak type epoxy, brominated epoxy, alicyclic type epoxy, rubber-modified epoxy, and glycidyl amine type epoxy may be used. .

상기 바인더 수지는 경화제에 의해 경화될 수 있다. 예컨대, 바인더 수지가 에폭시 수지인 경우, 경화제로는 고분자 폴리아미드(polyamide) 또는 에폭시 어덕트 타입의 폴리아미드(polyamide)가 사용될 수 있다. The binder resin may be cured by a curing agent. For example, when the binder resin is an epoxy resin, a polymer polyamide or an epoxy adduct type polyamide may be used as the curing agent.

본 발명에서 상기 도료는 유기 실란과 같은 커플링제를 더 포함할 수 있다. 이와 같은 커플링제는 무기 재료 및 유기 바인더와의 친화성을 제공할 수 있다.In the present invention, the paint may further include a coupling agent such as organic silane. Such coupling agents can provide compatibility with inorganic materials and organic binders.

본 발명의 도료는 Specification for Structural Joints Using ASTM A235 or A490 Bolts의 규격 및 시험방법에 따라 시편제작 후 측정된 마찰계수 값이 바람직하게는 0.5 이상, 더 바람직하게는 0.6 이상의 값을 갖는다.The paint of the present invention preferably has a value of the coefficient of friction measured after specimen production according to the specification and test method of Specification for Structural Joints Using ASTM A235 or A490 Bolts of 0.5 or more, more preferably 0.6 or more.

이상 본 발명의 바람직한 실시예에 대하여 설명하였지만, 본 발명의 기술적 사상이 상술한 바람직한 실시예에 한정되는 것은 아니며, 특허청구범위에 구체화된 본 발명의 기술적 사상을 벗어나지 않는 범주에서 다양하게 구현될 수 있다.Although the preferred embodiment of the present invention has been described above, the technical spirit of the present invention is not limited to the above-described preferred embodiment, and can be implemented in various ways without departing from the technical spirit of the present invention embodied in the claims. have.

Claims (2)

경질 세라믹스 분말, 바인더 수지 및 안료를 포함하는 고마찰 계수를 갖는 도료 조성물. A coating composition having a high coefficient of friction comprising a hard ceramic powder, a binder resin, and a pigment. 제1항에 있어서,
상기 도료 조성물은 아연 분말 또는 마그네슘 분말 중 최소한 1종의 금속 분말을 더 포함하는 것을 특징으로 하는 도료 조성물.
The method of claim 1,
The coating composition further comprises at least one metal powder of zinc powder or magnesium powder.
KR1020200175656A 2020-12-15 2020-12-15 Paint With Enhanced Friction Coefficient KR20220085514A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20080023885A (en) 2006-09-12 2008-03-17 삼화페인트공업주식회사 Epoxy zinc coating composition having high friction coefficient
KR20090095401A (en) 2008-03-05 2009-09-09 브이에스텍 주식회사 Eco-friendly air conditioning duct connector

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20080023885A (en) 2006-09-12 2008-03-17 삼화페인트공업주식회사 Epoxy zinc coating composition having high friction coefficient
KR20090095401A (en) 2008-03-05 2009-09-09 브이에스텍 주식회사 Eco-friendly air conditioning duct connector

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