KR20220067232A - Structure of oxygen generation sticker with antibacterial - Google Patents

Abstract

The present invention relates to an oxygen-generating antibacterial sticker structure, which maintains a solid shape having a sticker structure, gradually reacts with the surrounding carbon dioxide or moisture to discharge oxygen, and continuously maintains a function of removing harmful substances and an antibacterial function when the discharge of oxygen has finished, thereby enabling a short amount of lung capacity while removing excessive moisture from the surroundings or enabling a quick recovery with respect to exhausted physical strength after exercise, and helps improve health by removing surrounding viruses, harmful substances, and the like. The oxygen-generating antibacterial sticker structure includes: an oxygen container having an overall hemispherical shape and having a concave center, in which one or more through-holes are uniformly formed; an oxygen-generating composition in which one side surface forming the same curved surface as the concave inner surface of the oxygen container comes into close contact with the concave inner surface of the oxygen container and the other side surface is formed to be flat; and a double-sided tape unit in a circular shape, in which one side surface comes into close contact with the other side surface of the oxygen generating composition.

Description

Oxygen generation antibacterial sticker structure {Structure of oxygen generation sticker with antibacterial}

The present invention relates to an oxygen-generating antibacterial sticker structure having a sticker structure, removing harmful substances while generating oxygen, and discharging antibacterial substances, and more particularly, to a sticker structure that maintains the solid shape of the sticker structure while maintaining the It reacts slowly to release oxygen, and when oxygen is released, it continues to remove harmful substances and maintains antibacterial functions. It relates to an oxygen generating antibacterial sticker structure that helps to promote health by removing harmful substances.

Fine dust naturally generated by sand storms in desertification areas accelerated by climate change such as global warming and yellow sand generated in wasteland fields, etc. Living in the air polluted by various harmful substances can be the daily life of modern people. Hereinafter, it will be explained and understood that fine dust includes various harmful substances such as NOX, which is nitrogen oxide, and SOX, which is sulfur oxide.

Human bronchial tubes are directly exposed to fine dust due to breathing, causing respiratory diseases such as cough, asthma, and bronchitis. , Seoul's atmosphere is well known to have a higher concentration of fine dust compared to other large cities due to the effects of yellow dust, etc.

According to the contents published in the 2013 Air Environment Annual Report of the Ministry of Environment, the fine dust concentration in Seoul is 45 μg/m ³ among other large cities, which is about three times that of 18 μg/m ³ in London, and 30 μg/m ³ in LA. It can be seen that the concentration of fine dust is about 1.5 times higher than that of other cities.

Therefore, it is necessary to protect the bronchial tubes of humans (humans) from fine dust and various harmful substances.

The mask protects the respiratory system from fine dust by blocking the inflow of dust and fine dust suspended in the air (atmosphere). On the other hand, dust-proof masks and masks with a high KF number have a much higher rate of blocking fine dust compared to general masks, and in order to reduce the gap for fine dust to enter, they further include a metal implant whose shape is adjusted to fit the curved surface of the face. A filter that blocks the inflow of harmful substances is provided inside or part of the air conditioner to increase the blocking ratio of fine dust and harmful substances contained in the outside air.

However, only wearing a mask can block the inflow of harmful substances into the respiratory tract to some extent, but there are still problems that cannot be solved, such as delay in physical recovery due to lack of oxygen.

As a prior art that partially solves these problems, there is a 'portable oxygen generator for emergency treatment' according to Korean Patent Registration No. 10-1577931 (2015. 12. 09.).

1 is a block diagram of an oxygen generator according to an embodiment of the prior art.

Hereinafter, when the prior art is described in detail with reference to the accompanying drawings, the control signal transmitted by the intake port 7 and the exhaust port 8, the pump housing 1 and the coil wires 5 and 6 with an empty inside Permanent magnet piston (2) and a flexible diaphragm (flexible diaphragm) (4) for pumping operation by the included to configure the pump.

The air flow containing oxygen introduced from the HEPA filter 10 according to the control signal of the signal input unit 11 is controlled by the air inlet valve 9 and the oxygen concentrator bottles 21 and 22 are collected oxygen. save the

The control valve 27 controls opening/closing of the path of oxygen air supplied to the patient, the pressure sensor 29 measures the pressure of the air, and the supply port 32 is coupled to a breathing aid or the like. An oximeter 33 monitors the patient's oxygen level and delivers it from an embedded computer, an LED 35 lights up to indicate warning conditions that may occur while oxygen is supplied to the patient with a ventilator, and a push motor ( 37 includes a telescoping tube 36 and raises or lowers the position at which the LEDs 35 are visible.

The prior art has the advantage of supplying concentrated oxygen air to the patient, but it is a relatively bulky and heavy mechanical device, and it takes a lot of cost to secure, operate and maintain, and it still solves problems such as relatively difficult to move with the user or the patient There remains a problem that cannot be done.

Therefore, there is a need to develop a technology capable of supplying clean oxygen to a user at a relatively low price, which is small and light, and is easy to move by quickly and conveniently attached to a location required by the user.

Republic of Korea Patent Registration No. 10-1577931 (2015. 12. 09.) ‘Portable Oxygen Generator for Emergency Treatment’

The present invention devised to solve the problems and necessity of the prior art as described above is manufactured in a sticker shape and is conveniently attached to the user's surroundings in need of oxygen supply. It is an object to provide an oxygen generating antibacterial sticker structure.

In addition, an object of the present invention is to provide an oxygen generating antibacterial sticker structure that increases stamina while increasing user preference because a sticker for supplying oxygen can serve as an accessory.

On the other hand, the present invention rapidly recovers the user's headache and physical deterioration due to lack of oxygen while stably releasing oxygen for a long time and removing harmful substances, bacteria and infectious pathogens including NoX and SoX in the air. It is an object to provide an oxygen generating antibacterial sticker structure.

The oxygen generating antibacterial sticker structure of the present invention devised to achieve the above object is an oxygen container unit 1000 having a hemispherical shape as a whole, a concave center, and one or more through-holes 1010 formed uniformly; Oxygen generating composition 2000 in which one side forming the same curved surface as the concave inner surface of the oxygen container part 1000 is in close contact with the concave inner surface of the oxygen container part 1000 and the other side is flat; a double-sided tape part 3000 having one side adhered to the other side of the oxygen generating composition 2000 in a close contact state and having a circular shape; may include

It has the same shape as the concave inner surface of the oxygen container part 1000, has a thickness in the range of 500 to 1000 micrometers, and is inserted between the oxygen container part 1000 and the oxygen generating composition 2000 to prevent external moisture. an oxygen non-woven part 4000 that blocks direct contact with the oxygen generating composition 2000 and allows carbon dioxide to pass therethrough; may further include.

A composition cover 5000 that is fusion-bonded installed on the edge of the oxygen container unit 1000 in the open direction so that the oxygen generating composition 2000 is not leaked into the open portion of the oxygen container unit 1000; may further include.

It forms the same curved surface as the convex outer surface of the oxygen container part 1000 and is adhered to the convex outer surface of the oxygen container part 1000 in close contact to block and block the through hole 1010 and separate by an external force. a protective label unit 6000 for opening the through-hole 1010; may further include.

On the surface of the oxygen container part 1000, a photocatalyst titanium dioxide (TiO2) having a size of 30-50 nanometers (nm) or less is dispersed and coated in an inorganic silica binder.

a release paper part 7000 having the same circular shape as the double-sided tape part 3000 and being adhered to the other side of the double-sided tape part 3000 and separated and removed by an external force; may further include.

The oxygen generating composition 2000 may be prepared by mixing 10 to 30 parts by weight of a porous inorganic material with respect to 100 parts by weight of the oxygen generating agent.

It may be formulated by further mixing 1 to 5 parts by weight of a binder based on 100 parts by weight of the oxygen generator.

It may be formulated by further mixing 2 to 8 parts by weight of the antimicrobial composition with respect to 100 parts by weight of the oxygen generator.

The oxygen generating agent may be made of any one or any one or more selected from potassium superoxide, sodium peroxide, and calcium peroxide.

The porous inorganic material may be made of any one or any one or more selected from zeolite, alumina, silica and diatomaceous earth.

The antimicrobial composition may consist of a mixture of cyclosilicate and phyllosilicate, and any one selected from illite, silver, zinc, and platinum, or a mixture of any one or more.

The antimicrobial composition may further include titanium dioxide.

The mixture of cyclosilicate and phyllosilicate may be made by mixing cyclosilicate and phyllosilicate in the same weight ratio.

The binder may be composed of a mixture of a cured resin and rosin.

The weight ratio of the cured resin and rosin may be 1: 9 to 4: 6 to be mixed composition.

The zeolite, alumina, silica, and diatomaceous earth may be formed of particles having a diameter of 5 to 10 micrometers.

The cyclosilicate, phyllosilicate, illite, silver, zinc, and platinum may be formed of particles having a diameter of less than 1 micrometer.

The titanium dioxide may be formed of particles having a diameter of less than 100 nanometers.

The cured resin may be made of any one or any one or more selected from urethane acrylate, epoxy acrylate, and polyester acrylate.

The binder may further include 1 to 10 parts by weight of the antimicrobial composition based on 100 parts by weight of the cured resin.

The cured resin may further contain 10 to 30 parts by weight of a reactive monomer diluent based on 100 parts by weight.

The diluent is 2-ethylhexyl (meth) acrylate, 2-dicaprolactone ethyl acrylate, cyclohexyl (meth) acrylate, phenoxyethyl (meth) acrylate, isobornyl (meth) acrylate, acrylo Sunpoline, N-vinylpyrrolidone, N-vinylcaprolactam, dimethylaminoethyl (meth) acrylate, tripropylene glycol di (meth) acrylate, cyclopentenyl (meth) acrylate, tricyclodecane dimethyloldi ( It may be made of any one or any one or more selected from among meth) acrylate and trimethylolpropane tri (meth) acrylate.

The silver, zinc, and platinum may be selected from any one or a mixture of any one or more.

In the antimicrobial composition, the mixture of cyclosilicate and phyllosilicate is 70 to 90% by weight, the illite is 5 to 25% by weight, and any one selected from silver, zinc, and platinum, or a mixture of any one or more can

The silver, zinc, and platinum may be mixed in an equal weight ratio.

The silver, zinc, and platinum may each be formed of ions.

A configuration in which photocatalyst titanium dioxide (TiO2) having a size in the range of 30 to 50 nanometers (nm) or less is dispersed and applied to a silica inorganic binder on one or both surfaces of the inner surface and the outer surface of the oxygen container unit 1000 can be made with

Photocatalyst titanium dioxide (TiO2) having a size in the range of 30 to 50 nanometers (nm) or less in the range of 30 to 50 nanometers (nm) is dispersed and applied to a silica inorganic binder on one or both surfaces of the inner surface and the outer surface of the oxygen container part 1000 It may consist of a structure to which a membrane is attached.

The present invention having the above configuration has the advantage of smoothly and quickly supplying fresh oxygen while removing moisture and carbon dioxide in the vicinity of the user in need of oxygen supply because it is manufactured in a sticker shape and is conveniently attached.

In addition, the present invention has the advantage of increasing stamina and resistance while increasing user preference because the sticker for oxygen supply can also serve as an accessory.

On the other hand, the present invention rapidly recovers the user's headache and physical deterioration due to lack of oxygen while stably releasing oxygen for a long time and removing harmful substances, bacteria and infectious pathogens including NoX and SoX in the air. There is an advantage to

1 is a block diagram of an oxygen generator according to an embodiment of the prior art;
2 is an explanatory view of various diseases that may occur due to the absorption of fine dust into the human body for explaining the present invention;
3 is an explanatory view of the state in which the photocatalyst affects antibacterial and deodorization for explaining the present invention;
4 is an explanatory diagram of the state affecting the antifouling and water purification of the photocatalyst for explaining the present invention;
5 is a conceptual explanatory diagram for decomposing Knox and Sachs of primary fine addresses generated in thermal power plants and automobiles with a photocatalyst for explaining the present invention;
6 is an exploded perspective view of an oxygen generating antibacterial sticker structure according to an embodiment of the present invention;
and
7 is a cross-sectional view of an oxygen generating antibacterial sticker structure according to an embodiment of the present invention.

Since the present invention can apply various transformations and can have various embodiments, specific embodiments are illustrated in the drawings and described in detail in the detailed description. However, this is not intended to limit the present invention to specific embodiments, it should be understood to include all modifications, equivalents and substitutes included in the spirit and scope of the present invention. In describing the present invention, if it is determined that a detailed description of a related known technology may obscure the gist of the present invention, the detailed description thereof will be omitted.

In the following description, titanium oxide or titanium dioxide (TiO2) has the same meaning and will be used selectively as appropriate for the context.

2 is an explanatory diagram of various diseases that may occur due to the absorption of fine dust into the human body to explain the present invention, and FIG. , Figure 4 is for explaining the present invention, and is an explanatory diagram of the state affecting the antifouling and water purification of the photocatalyst, and Figure 5 is for explaining the present invention. is a conceptual explanatory view of decomposing into a photocatalyst, FIG. 6 is an exploded perspective view of an oxygen generating antibacterial sticker structure according to an embodiment of the present invention, and FIG. 7 is an oxygen generating antibacterial sticker structure according to an embodiment of the present invention It is a cross section.

Hereinafter, it will be described with reference to all the accompanying drawings.

Photocatalyst is a combination of photochemistry and catalyst, and refers to a catalyst that exhibits activity by light energy. In general, a catalyst serves to speed up or slow down the rate of a chemical reaction without changing the catalyst itself. In the process of a chemical reaction, heat or other energy sources are used. In the case of a photocatalyst, it is the energy used for chemical reaction. use light When light energy from sunlight or artificial light is irradiated to the catalyst, the catalyst that absorbs the light energy is activated and plays a role in oxidizing or reducing organic matter.

In order for the photocatalyst to act as a photocatalyst by redox, it is necessary to absorb light energy, and the wavelength of sunlight (light) that titanium oxide or titanium dioxide (TiO2), which is a photocatalyst according to an example, can absorb is about 380 Ultraviolet radiation below nm. In this photocatalytic reaction of titanium oxide, only when sunlight or ultraviolet rays or light is irradiated, the reaction takes place as much as the amount of ultraviolet rays.

In the following description, sunlight, ultraviolet light, and light have the same meaning and are selectively used according to the context, and titanium oxide and titanium dioxide (TiO 2 ) have the same meaning and are selectively used appropriately in the context.

When a potential of 3.2 electron volts (eV) is applied, titanium dioxide is excited and functions as a photocatalyst, and when it is irradiated with ultraviolet rays contained in the sun, it is excited to generate a photocatalytic function by oxidation and reduction.

Electron volt or electron volt (eV: electron volt) represents the unit of kinetic energy. It is often used to express the mass of elementary particles by converting them into energy, and 1 electron volt corresponds to 1.602 * 10 to the minus 19th power of joule d, and the symbol is eV.

That is, the oxidation-reduction potential (ORP, Oxidation-Reduction Potential) of titanium dioxide is 3.2 eV, and this value is one of the important variables for measuring the oxidation and reduction of water.

Titanium dioxide is widely used as an optical material such as a white pigment, a high-frequency capacitor material, a low-reflection coating, etc., a sensor and a protective material. have.

Titanium mineral is the ninth most common mineral on Earth, accounting for 0.6% of the lei and about 1% of the surface.

The method of manufacturing such a photocatalyst material is according to the prior art, Republic of Korea Patent Registration No. 10-1450389 (October 6, 2014), and is well described in detail in 'Photocatalyst, its manufacturing method and photocatalyst device'.

It is known that the photocatalyst material (raw material) includes titanium oxide, tungsten oxide, zinc oxide, niobium oxide, and the like. Hereinafter, titanium oxide will be mainly described for easy explanation and understanding.

Research on the photoactivity of titanium dioxide, a semiconductor material, has its beginnings in the Honda-Fujishima effect announced by Professor Fujishima in 1972. When a battery composed of a titanium dioxide electrode and a platinum electrode is irradiated with light, water decomposition occurs at about -0.5 V, and oxygen is generated on the surface of the titanium dioxide electrode and hydrogen is generated around the platinum electrode. This is a peculiar phenomenon that occurs at a potential that is significantly lower than +1.23 V, which is the normal oxidative decomposition potential of water. Professor Fujishima transferred this phenomenon to the conduction band of the valance band of titanium dioxide by ultraviolet light It has been explained that the oxidation of water is caused by the holes generated at this time to generate hydrogen.

Band energy unique to semiconductor-type photocatalyst materials - In semiconductor materials, it is a linear combination of atomic orbitals called the conduction band (E cb) without electrons and the valaence band (E vb) filled with electrons. There are molecular orbitals. Accordingly, there is a forbidden space between these two bands that electrons cannot occupy. This is called band energy (Eg), and its magnitude corresponds to E cb -E vb . The photochemical system in which the electron (e-) and hole (h+) pair generated after receiving light energy and the electron (e-) is excited (excitation) can be beneficially used to deliver light that can overcome the limitations of the existing reactor design make it

Converting light energy into chemical energy or electrical energy through the process of photochemical reaction means that the generated electrons/holes are adsorbed to the photocatalyst, reduce/oxidize the material in the diffusion layer, or generate current through the configured electrode circuit. It is possible by creating If this is used, it has the advantage that it can be used for environmental purification by decomposing surrounding organic substances, as well as water decomposition hydrogen production, solar cells, etc.

In order for the photocatalyst to operate as a photocatalyst by oxidation and reduction, light is used as energy for excitation of electrons (e-). It is one of the technical ideas of the present invention to act as a photocatalyst.

That is, in the case of titanium dioxide, in order to operate as a photocatalyst, a potential of 3.2 eV must be applied by irradiation of light energy to operate as a photocatalyst by oxidation and reduction, but in the present invention, electrons (e-) are excited without irradiation of light. (Excitation) One of the technical ideas is to quickly generate a photocatalytic function even in a dark place because the necessary energy is supplied.

On the other hand, fine dust (fine dust, particle dust matter) is less than 10 micrometers (um), which is about 1/10 the size of a hair with a diameter of 50 - 70 micrometers (um), and penetrates into cells or breathes. In some cases, children and the elderly as well as healthy people may face serious diseases with reduced immunity. On the other hand, ultrafine dust refers to dust having a particle size of 2.5 micrometers (um) or less.

Recently, due to the rapid industrialization and acceleration of desertification in neighboring countries and some regions, there are research cases that contain a large amount of dust and fine dust in the atmosphere and cause respiratory diseases when directly breathing air containing such dust. It has been reported a lot. In addition, the fine dust may include various harmful bacteria, germs, mold, and the like.

Therefore, the need for the development of an eco-friendly technology to purify the air in the surrounding environment including fine dust is very high, and it is one of the tasks to be solved very urgently in reality.

2 is an explanatory diagram of various diseases that may occur due to the absorption of fine dust into the human body for explaining the present invention.

Referring to the accompanying drawings, fine dust with a diameter of 10 micrometers or less penetrates the eye and causes allergic conjunctivitis, keratitis, and the like. And fine dust of 2 to 5 micrometers in size penetrates into the bronchial tubes, fine dust of 1 to 2 micrometers in size is deposited in the lungs, and fine dust in the size of 0.1 to 1 micrometer is deposited in the alveoli. The fine dust that penetrates into the bronchial tubes causes bronchitis, emphysema, and asthma, and the fine dust that settles in the lungs or alveoli causes damage to the alveoli.

3 is a diagram illustrating the state in which a photocatalyst affects antibacterial and deodorization for explaining the present invention.

Referring to the accompanying drawings, the photocatalyst has a strong oxidizing effect on single-celled organisms such as bacteria, fungi, and viruses, so it has a sterilizing power that destroys the cell membrane, and it has a sterilizing power 1.5 times stronger than that of chlorine or ozone.

The OH radical by photocatalyst activation sterilizes various spoilage bacteria through strong oxidative action, and it has relatively excellent purification ability to decompose and sterilize substances that cause bad odor to keep the surrounding environment clean.

4 is a diagram for explaining the present invention, and is an explanatory diagram of the state affecting the antifouling and water purification of the photocatalyst.

When described with reference to the accompanying drawings, since the photocatalyst decomposes and removes organic matter from the surface, it is possible to reduce social costs by using the photocatalyst with an antifouling function that naturally removes dirty dust.

And when the photocatalyst is included in the filter for water purification, viruses and organic matter in water can be decomposed and removed.

5 is a conceptual explanatory diagram for decomposing Knox and Sachs of primary micro-addresses generated in thermal power plants and automobiles with a photocatalyst for explaining the present invention.

When described with reference to all the accompanying drawings, the primary fine dust generated in the state of being included in the smoke emitted from the chimney of a thermal power plant using coal and exhaust gas from automobiles includes nitrogen compounds (NOx, rust) and sulfuric acid. Cargo (SOx, Sachs) is included, and these primary fine dusts meet with water vapor in the atmosphere to generate secondary fine dust.

Since these primary or secondary fine dust are decomposed by a photocatalyst by titanium oxide, the surrounding air environment is environmentally friendly.

On the other hand, the oxygen generating antibacterial sticker structure 900 according to an embodiment of the present invention includes an oxygen container part 1000, an oxygen generating composition 2000, a double-sided tape part 3000, an oxygen non-woven fabric part 4000, and a composition cover ( 5000) and a configuration including a protective label unit 6000 and a release paper portion 7000.

The oxygen container part 1000 has a hemispherical or dome shape as a whole, a concave center, and one or more through-holes 1010 are uniformly formed. The oxygen container unit 1000 functions as a container for containing the oxygen generating composition 2000 and is made of a well-known material selected from among bendable materials. The oxygen container unit 1000 allows the user to feel the overall soft texture.

Various patterns and designs may be printed or etched on the convex surface of the oxygen container unit 1000 in selected colors, and these patterns may be used as advertisements, information messages, and the like.

Oxygen container unit 1000 is uniformly made of a thickness of 1 to 1.5 millimeters as a whole, preferably made of a thickness of 1 millimeter, and the through hole 1010 is made of a through hole having a diameter of 0.4 to 0.6 millimeter, preferably consists of a 0.5 millimeter diameter perforated hole.

On one or both surfaces of the inner and outer surfaces of the oxygen container unit 1000, titanium dioxide (TiO2) having a photocatalytic function of 30 to 50 nanometers (nm) or less in size is dispersed in a silica inorganic binder and applied. .

On the other hand, if necessary, titanium dioxide (TiO2), which has a photocatalytic function, is dispersed and applied to a film (screen) having a thickness of 500 to 1000 micrometers (um) in a silica inorganic binder, and then the inner and outer surfaces of the oxygen container part 1000 It can be attached to any one or both surfaces of the selected one.

On the convex surface of the oxygen container unit 1000, a plurality of hemispherical protrusions having a diameter of 1 millimeter are formed at uniform intervals to form a good grip.

Oxygen generating composition 2000 is a configuration in which one side forming the same curved surface as the concave inner surface of the oxygen container part 1000 is in close contact with the concave inner surface of the oxygen container part 1000 and the other side is formed flat.

The oxygen generating composition 2000 is made of an oxygen generating agent, a porous inorganic material, and an antimicrobial composition, and may further include a binder if necessary.

The binder is made by mixing 60 to 90 weight ratio (wt%) of rosin (rosin) with 10w% to 40w% of cured resin. When the mixing ratio of rosin (resin) is less than 60 wr%, the flexibility of the sticker form is lowered in the dry state, and thus it is easily broken.

Cured resin is urethane acrylate, epoxy acrylate, polyester acrylate, any one or more of 100 parts by weight of a resin mixed with 1 part by weight to 10 parts by weight of an antibacterial agent having antibacterial and sterilizing power (sterilizing power) more can be completed including

The antimicrobial composition comprises a mixture of cyclosilicate and phyllosilicate; illite; A composition comprising any one selected from silver, zinc, and platinum ions or a mixture of any one or more is used. When any one or more of silver, zinc, and platinum ions are included, the same amount may be mixed in a weight ratio, or any selected one may be used alone. On the other hand, if necessary, titanium dioxide (TiO2) particles having a size of 40 nanometers (nm) or less are further included.

The reason for using a mixture of a plurality of resins in the cured resin is that urethane acrylate has good reactivity, so it is easy to cure, maintains flexibility after curing, and has relatively little yellowing.

In addition, in the case of epoxy acrylate, it has high reactivity, so high hardness and abrasiveness are good, hardening is easy, it has excellent flexibility, and the cured state is stably maintained even in contact with oxygen.

In addition, in the case of polyester acrylate, it has excellent reactivity and has a lower viscosity than urethane acrylate and epoxy acrylate, so that it has the advantage of excellent dispersibility of the powder material for antibacterial and oxygen generation.

In addition, 10 to 30 parts by weight of a reactive monomer diluent is further mixed with the cured resin to adjust the viscosity of the oligomeric resin, and the diluents include 2-ethylhexyl (meth) acrylate, 2-dicaprolactone ethyl acrylate, cyclo Hexyl (meth) acrylate, phenoxyethyl (meth) acrylate, isobornyl (meth) acrylate, acryloylmorpholine, N-vinylpyrrolidone, N-vinylcaprolactam, dimethylaminoethyl (meth)acrylate , one or two types from the group consisting of tripropylene glycol di(meth) acrylate, cyclopentenyl (meth) acrylate, tricyclodecanedimethanol di(meth) acrylate, and trimethylolpropane tri(meth) acrylate Mix and apply the above.

Resin (rosin) mixed with cured resin is a non-toxic substance, and it is a sticky liquid substance that comes out when the bark of a pine tree is injured. Also called rosin or rosin.

Clean rosin is colorless and transparent liquid, but over time, it becomes cloudy and sticky, and white solid from resin acid is precipitated.

Resin is mainly produced in North America, where more than 50% of the world's output is produced, and it is produced in Mexico and France. The extraction method is to receive rosin from the cut part of the tree with a cup, etc., and more rosin can be obtained by spraying sulfuric acid on the wound.

Resin is soluble in ethanol, chloroform, acetic acid, etc., but insoluble in water. When turpentine is obtained by distillation, rosin remains.

The composition of rosin is 70 to 75% of resin (rosin), 18 to 22% of essential oil (turpentine), and 5 to 7% of water and other impurities. It consists of maric acid and neoabietic acid. Turpentine is mainly used as a solvent in ointments, paint solvents, leather products, shoe polish, rubber and waterproofing agents.

Rosin is mainly used as pharmaceuticals such as soap, paint desiccant, insecticide, printing ink, additive for papermaking, and band-aid.

The antibacterial and antiseptic substance or antimicrobial composition is a mixture of cyclosilicate and phyllosilicate; illite; A composition comprising a mixture of silver, zinc and platinum ions is used.

Cyclosilicate and phyllosilicate are mixed in the same weight ratio (wt%), cyclosilicate and phyllosilicate are mixed in 70 wt% to 90 wt%, illite is mixed in 5 wt% to 25 wt%, and the remainder is It consists of silver, zinc and platinum ions. The antimicrobial composition may further include a composition of various combinations if necessary. Preferably, it may further include titanium dioxide (titanium dioxide, TiO2).

The antimicrobial composition is a composition having an inorganic antibacterial, antifungal, and deodorizing function, and the composition disclosed in Korean Patent Registration No. 10-1303503 (Title of the Invention: Inorganic antibacterial, antifungal and deodorant composition and manufacturing method thereof) is the antimicrobial composition of this embodiment and the critical significance of each component can be verified through the Examples and Comparative Examples described in the detailed description of the invention described in the specification of Korean Patent Registration No. 10-1303503.

The oxygen generating antibacterial sticker composition generates oxygen by reacting with carbon dioxide or moisture, and includes an oxygen generating compound selected from potassium superoxide (KO ₂ ) or sodium peroxide (Na ₂ O ₂ ) or calcium peroxide (CaO2) and an antimicrobial composition, etc. After mixing with powdery porous inorganic material, it is applied to the nonwoven fabric layer and dried before use. The oxygen generating antibacterial sticker composition has the advantage of continuing to maintain the antibacterial function by the antibacterial agent composition in the state that oxygen is released.

Potassium superoxide (KO ₂ ) or sodium peroxide (Na ₂ O ₂ ) has a good oxygen generation efficiency, and calcium peroxide (CaO2) has a good oxygen generation amount, respectively. In the present invention, potassium superoxide (KO ₂ ) or sodium peroxide (Na ₂ O ₂ ) Any one or a mixture may be mixed in a weight ratio of 30%, and calcium peroxide (CaO2) may be mixed in a weight ratio of 70%.

The double-sided tape part 3000 has one side adhered to the other side of the oxygen generating composition 2000 in a close contact state and has a circular shape, and the thickness is in the range of 500 to 1000 micrometers. The double-sided tape part 3000 has adhesive force on both sides, and it can be used sufficiently if there is an adhesive force that is maintained by adhering an object of 1 kilogram or more per cubic centimeter for 30 to 60 seconds.

The oxygen nonwoven part 4000 has the same shape as the concave inner surface of the oxygen container part 1000 and has a thickness in the range of 500 to 1000 micrometers, and is inserted between the oxygen container part 1000 and the oxygen generating composition 2000 . It is installed to block direct contact with the oxygen generating composition 2000 from external moisture and to allow carbon dioxide to pass therethrough.

The oxygen nonwoven part 4000 is made of any one selected from PE, PP, and PV, or fibers (thread, yarn, 絲) made of at least one selected from among PE, PP, and PV, and fibers having a diameter of 50 to 150 micrometers are laminated.

The composition cover 5000 has a circular shape and the edge portion is fusion-bonded to the open direction edge portion of the oxygen container unit 1000 so that the filled oxygen generating composition 2000 flows out or It is a structure that is fixed so as not to be discharged.

The composition cover 5000 has an average thickness of 400 micrometers, has a film shape made of any one selected from PE, PP, and PV, or has a photocatalyst size of 30 to 50 nanometers (nm) or less on the surface of the film. It is applied by dispersing phosphorus titanium dioxide (TiO2) in the silica inorganic binder.

The protective label part 6000 forms the same curved surface as the convex outer surface of the oxygen container part 1000 and is adhered in close contact to the convex outer surface of the oxygen container part 1000 to block and block the through hole 1010, and to protect against external force. It is configured to open the through-hole 1010 while being separated by the

On the exposed surface of the protective label unit 6000, various patterns of characters, pictures, designs, etc. may be printed or etched in a selected color.

It is very natural that the patterns formed on the protective label unit 6000 and the oxygen container unit 1000 can be used for advertising purposes only.

The release support part 7000 has the same circular shape as the double-sided tape part 3000, is adhered to the other side of the double-sided tape part 3000, and is configured to be separated and removed by an external force.

On the surface where the release paper part 7000 is not adhered to the double-sided tape part 3000, various patterns of characters, pictures, designs, etc. may be printed or etched in a selected color, and may be used for advertising purposes only.

The protective label unit 6000 and the release support unit 7000 may each have protrusions protruding from a portion of the rim in order to facilitate separation.

The other side of the double-sided tape part 3000 may further include an adhesive protrusion having a hemispherical shape with a radius of 0.5 millimeters in order to increase the adhesive force.

The oxygen generating antibacterial sticker structure according to the present invention having the above configuration provides oxygen to quickly recover physical strength while removing pollutants of NoX and SoX contained in the air (atmosphere) and also entering the respiratory system There are advantages such as preventing it from happening.

In the above, the present invention has been described in detail with respect to the described embodiments, but it is apparent to those skilled in the art that various changes and modifications are possible within the scope of the technical spirit of the present invention.

900: oxygen generation antibacterial sticker structure
1000: oxygen container 1010: through hole
2000: oxygen generating composition 3000: double-sided tape part
4000: oxygen non-woven fabric 5000: composition cover
6000: protective label part 7000: release part

Claims (7)

Oxygen container unit 1000 having a hemispherical shape as a whole, a concave center, and having one or more through-holes 1010 uniformly formed;
Oxygen generating composition 2000, in which one side forming the same curved surface as the concave inner surface of the oxygen container part 1000 is in close contact with the concave inner surface of the oxygen container part 1000 and the other side is formed flat;
a double-sided tape part 3000 having one side adhered to the other side of the oxygen generating composition 2000 in a close contact state and having a circular shape; Oxygen generating antibacterial sticker structure comprising a.
The method of claim 1,
It has the same shape as the concave inner surface of the oxygen container part 1000, has a thickness in the range of 500 to 1000 micrometers, and is inserted and installed between the oxygen container part 1000 and the oxygen generating composition 2000 to prevent external moisture. an oxygen non-woven part 4000 that blocks direct contact with the oxygen generating composition 2000 and allows carbon dioxide to pass therethrough; Oxygen generating antibacterial sticker structure further comprising.
3. The method of claim 2,
A composition cover 5000 that is fusion-bonded installed on the edge of the oxygen container 1000 in the open direction so that the oxygen generating composition 2000 is not leaked into the open part of the oxygen container part 1000; Oxygen generating antibacterial sticker structure further comprising.
4. The method of claim 3,
It forms the same curved surface as the convex outer surface of the oxygen container part 1000 and is adhered in close contact to the convex outer surface of the oxygen container part 1000 to block and block the through hole 1010 and separate by an external force. a protective label unit 6000 for opening the through hole 1010; Oxygen generating antibacterial sticker structure further comprising.
5. The method of claim 4,
a release paper part 7000 having the same circular shape as the double-sided tape part 3000 and being adhered to the other side of the double-sided tape part 3000 and being separated and removed by an external force; Oxygen generating antibacterial sticker structure further comprising.
6. The method of claim 5,
A configuration in which a photocatalyst titanium dioxide (TiO2) having a size in the range of 30 to 50 nanometers (nm) or less in the range of 30 to 50 nanometers (nm) is dispersed and applied to a silica inorganic binder on one or both surfaces of the inner surface and the outer surface of the oxygen container unit 1000 Oxygen generating antibacterial sticker structure, characterized in that consisting of.
6. The method of claim 5,
Photocatalyst titanium dioxide (TiO2) having a size in the range of 30 to 50 nanometers (nm) or less in the range of 30 to 50 nanometers (nm) is dispersed and applied to a silica inorganic binder on one or both surfaces of the inner surface and the outer surface of the oxygen container part 1000 Oxygen generating antibacterial sticker structure, characterized in that it consists of a membrane attached.

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