KR20220023929A - Shock absorbing member composition for vehicle leat spring with excellent elasticity and durability - Google Patents

Shock absorbing member composition for vehicle leat spring with excellent elasticity and durability Download PDF

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KR20220023929A
KR20220023929A KR1020200105678A KR20200105678A KR20220023929A KR 20220023929 A KR20220023929 A KR 20220023929A KR 1020200105678 A KR1020200105678 A KR 1020200105678A KR 20200105678 A KR20200105678 A KR 20200105678A KR 20220023929 A KR20220023929 A KR 20220023929A
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durability
leaf spring
rubber
member composition
weight
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이대인
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이대인
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60GVEHICLE SUSPENSION ARRANGEMENTS
    • B60G11/00Resilient suspensions characterised by arrangement, location or kind of springs
    • B60G11/02Resilient suspensions characterised by arrangement, location or kind of springs having leaf springs only
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/01Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013Fillers, pigments or reinforcing additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/06Sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02Copolymers with acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60GVEHICLE SUSPENSION ARRANGEMENTS
    • B60G2202/00Indexing codes relating to the type of spring, damper or actuator
    • B60G2202/10Type of spring
    • B60G2202/11Leaf spring

Abstract

The present invention relates to a buffer member composition for a vehicle leaf spring having excellent elasticity and durability. More specifically, the present invention consists of a rubber-based resin, a filler material, an antioxidant, and a vulcanization accelerator. The buffer member composition for a vehicle leaf spring composed of the components exhibits an effect of improving the riding comfort of a vehicle by having excellent durability and improving elasticity.

Description

신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물 {SHOCK ABSORBING MEMBER COMPOSITION FOR VEHICLE LEAT SPRING WITH EXCELLENT ELASTICITY AND DURABILITY}A cushioning member composition for a vehicle leaf spring with excellent elasticity and durability {SHOCK ABSORBING MEMBER COMPOSITION FOR VEHICLE LEAT SPRING WITH EXCELLENT ELASTICITY AND DURABILITY}

본 발명은 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물에 관한 것으로, 내구성이 우수할 뿐만 아니라, 신축성이 향상되어 차량의 승차감을 향상시키는 효과를 나타내는 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물에 관한 것이다.The present invention relates to a cushioning member composition for a vehicle leaf spring having excellent elasticity and durability. to the composition.

차량에는 차체의 중량을 지지하면서 노면으로부터 진동 및 충격을 흡수하여 차체로 전달되는 것을 완화시킴으로써 승차감 및 주행 안정성을 확보하는 현가장치가 마련되어 있다.The vehicle is provided with a suspension device for securing riding comfort and driving stability by absorbing vibration and shock from the road surface while supporting the weight of the vehicle body and reducing transmission to the vehicle body.

이러한 현가장치 중 대형 차량에 이용되는 현가장치는 스프링 강판을 여러 겹 겹쳐서 고정시킨 판 스프링 방식이 주로 사용되는데, 각각 프레임과 차축에 판스프링이 결합되어 짐 적재에 따른 하중 및 노면으로부터의 충격을 완화하는 기능을 행한다.Among these suspensions, the suspension used in large vehicles mainly uses the leaf spring method in which several layers of spring steel plates are stacked and fixed. perform the function

상기의 판 스프링에는 스프링 강판 사이에 완충부재를 적용하여 짐 적재에 따른 하중이나 노면으로부터 발생하는 충격을 완화하여 탑승자의 승차감을 개선하고자 하는 노력이 이루어지고 있다.Efforts have been made to improve the riding comfort of the occupant by applying a buffer member between the spring steel plates to the leaf spring to alleviate the load caused by the load or the impact generated from the road surface.

일반적으로 대형 차량은 양측의 바퀴가 하나의 차축으로 연결되는 방식으로 형성되고 차축의 양측 상부에 판스프링 장치가 각각 결착되며, 판스프링 장치는 양끝단이 차체 프레임과 힌지결합되어 바퀴로부터의 충격을 흡수하는 구조이다.In general, large vehicles are formed in such a way that the wheels on both sides are connected to one axle, and the plate spring devices are attached to the upper portions of both sides of the axle, respectively. It is an absorbing structure.

종래에는 상기 판스프링 사이에 충격을 흡수할 수 있는 완충부재를 적용하여 차량의 승차감을 개선하고자 하는 노력이 이루어졌는데, 종래에 판스프링용 완충부재의 경우 압력 등과 같은 외부의 충격에 대한 내구성이 약하고 신축성이 낮아 쉽게 파손될 뿐만 아니라, 승차감 개선효과가 미미하였다. Conventionally, efforts have been made to improve the riding comfort of a vehicle by applying a cushioning member capable of absorbing shock between the leaf springs. Not only was it easily damaged due to its low elasticity, but also the effect of improving the riding comfort was insignificant.

아래 도 1에는 중 대형 차량에 이용되는 현가장치인 스프링 강판을 여러 겹 겹쳐서 고정시킨 판 스프링을 촬영하여 나타낸 것으로, 붉은색 박스는 완충부재가 적용될 수 있는 부위를 도시한 것이다.1 below shows a leaf spring in which a spring steel plate, which is a suspension device used in a medium-large vehicle, is stacked and fixed in multiple layers, and a red box shows a portion to which a buffer member can be applied.

한국특허등록 제10-1429462호(2014.08.06)Korean Patent Registration No. 10-1429462 (2014.08.06) 한국특허등록 제10-1462239호(2014.11.10)Korean Patent Registration No. 10-1462239 (2014.11.10)

본 발명의 목적은 내구성이 우수할 뿐만 아니라, 신축성이 향상되어 차량의 승차감을 향상시키는 효과를 나타내는 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물을 제공하는 것이다.It is an object of the present invention to provide a cushioning member composition for a vehicle leaf spring excellent in elasticity and durability, which not only has excellent durability, but also has improved elasticity and thus improves the riding comfort of a vehicle.

본 발명의 목적은 고무계 수지, 충전재, 산화방지제 및 가황 촉진제로 이루어지는 것을 특징으로 하는 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물을 제공함에 의해 달성된다.An object of the present invention is achieved by providing a cushioning member composition for a vehicle leaf spring having excellent elasticity and durability, characterized in that it consists of a rubber-based resin, a filler, an antioxidant and a vulcanization accelerator.

본 발명의 바람직한 특징에 따르면, 상기 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물은 고무계 수지 100 중량부, 충전재 30 내지 40 중량부, 산화방지제 2 내지 10 중량부 및 가황 촉진제 1 내지 3 중량부로 이루어지는 것으로 한다.According to a preferred feature of the present invention, the cushioning member composition for a vehicle leaf spring having excellent elasticity and durability comprises 100 parts by weight of a rubber-based resin, 30 to 40 parts by weight of a filler, 2 to 10 parts by weight of an antioxidant, and 1 to 3 parts by weight of a vulcanization accelerator. to be done

본 발명의 더 바람직한 특징에 따르면, 상기 고무계 수지는 네츄럴러버에 부타디엔러버, 니트릴부타디엔러버, 스티렌부타디엔러버 및 에틸렌프로필렌디엔모노머로 이루어진 그룹에서 선택된 하나 이상을 혼합하로 이루어지는 것으로 한다.According to a more preferred feature of the present invention, the rubber-based resin is made by mixing at least one selected from the group consisting of butadiene rubber, nitrile butadiene rubber, styrene butadiene rubber and ethylene propylene diene monomer with natural rubber.

본 발명의 더욱 바람직한 특징에 따르면, 상기 고무계 수지는 상기 네츄럴러버의 함량이 40 중량% 이상인 것으로 한다.According to a more preferred feature of the present invention, in the rubber-based resin, the content of the natural rubber is 40% by weight or more.

본 발명의 더욱 바람직한 특징에 따르면, 상기 충전재는 실리카, 바륨 및 카본블랙으로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것으로 한다.According to a more preferred feature of the present invention, the filler is made of at least one selected from the group consisting of silica, barium and carbon black.

본 발명의 더욱 더 바람직한 특징에 따르면, 상기 가황 촉진제는 유황으로 이루어지는 것으로 한다.According to an even more preferred feature of the present invention, the vulcanization accelerator is made of sulfur.

본 발명의 더욱 더 바람직한 특징에 따르면, 상기 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물에는 손실계수 향상을 위해 상기 고무계 수지 100 중량부 대비 첨가제 10 내지 40 중량부가 더 함유되며, 상기 첨가제는 로진 수지, 테르펜계 수지, 석유 수지, 석탄 수지, 페놀수지 및 크실렌 수지로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것으로 한다.According to an even more preferred feature of the present invention, the buffer member composition for a vehicle leaf spring having excellent elasticity and durability further contains 10 to 40 parts by weight of an additive relative to 100 parts by weight of the rubber-based resin to improve the loss factor, and the additive is rosin. It shall be made of at least one selected from the group consisting of resins, terpene-based resins, petroleum resins, coal resins, phenolic resins and xylene resins.

본 발명에 따른 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물은 내구성이 우수할 뿐만 아니라, 신축성이 향상되어 차량의 승차감을 향상시키는 탁월한 효과를 나타낸다.The cushioning member composition for a vehicle leaf spring having excellent elasticity and durability according to the present invention exhibits an excellent effect of improving the riding comfort of a vehicle by improving elasticity as well as having excellent durability.

도 1은 중 대형 차량에 이용되는 현가장치인 스프링 강판을 여러 겹 겹쳐서 고정시킨 판 스프링을 촬영하여 나타낸 것이다.
도 2는 본 발명의 실시예 1을 통해 제조된 완충부재의 외관을 촬영하여 나타낸 것이다.
도 3은 본 발명의 실시예 1을 통해 제조된 완충부재가 적용된 판 스프링을 촬영하여 나타낸 것이다.
1 is a photograph showing a leaf spring in which a spring steel plate, which is a suspension device used in a medium-large vehicle, is stacked and fixed in several layers.
2 is a photograph showing the appearance of the buffer member manufactured in Example 1 of the present invention.
3 is a photograph showing the leaf spring to which the buffer member manufactured in Example 1 of the present invention is applied.

이하에는, 본 발명의 바람직한 실시예와 각 성분의 물성을 상세하게 설명하되, 이는 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 발명을 용이하게 실시할 수 있을 정도로 상세하게 설명하기 위한 것이지, 이로 인해 본 발명의 기술적인 사상 및 범주가 한정되는 것을 의미하지는 않는다.Hereinafter, a preferred embodiment of the present invention and the physical properties of each component will be described in detail, which is intended to describe in detail enough that a person of ordinary skill in the art to which the present invention pertains can easily carry out the invention, This does not mean that the technical spirit and scope of the present invention is limited.

본 발명에 따른 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물은 고무계 수지, 충전재, 산화방지제 및 가황 촉진제로 이루어지며, 고무계 수지 100 중량부, 충전재 30 내지 40 중량부, 산화방지제 2 내지 10 중량부 및 가황 촉진제 1 내지 3 중량부로 이루어지는 것이 바람직하다.The cushioning member composition for a vehicle leaf spring having excellent elasticity and durability according to the present invention consists of a rubber-based resin, a filler, an antioxidant and a vulcanization accelerator, 100 parts by weight of a rubber-based resin, 30 to 40 parts by weight of a filler, 2 to 10 parts by weight of an antioxidant and 1 to 3 parts by weight of the vulcanization accelerator.

상기 고무계 수지는 본 발명에 따른 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물을 구성하는 주재료로, 완충부재 조성물에 내충격성 및 신축성을 부여하는 역할을 하는데, 네츄럴러버에 부타디엔러버, 니트릴부타디엔러버, 스티렌부타디엔러버 및 에틸렌프로필렌디엔모노머로 이루어진 그룹에서 선택된 하나 이상을 혼합하여 이루어지는 것이 바람직하다.The rubber-based resin is a main material constituting the cushioning member composition for a vehicle leaf spring having excellent elasticity and durability according to the present invention, and serves to impart impact resistance and elasticity to the cushioning member composition. , it is preferably made by mixing at least one selected from the group consisting of styrene butadiene rubber and ethylene propylene diene monomer.

상기 네츄럴러버(natural rubber)는 인장력이 높아 인장강도가 우수한 완충부재를 제공하는 역할을 하는데, 상기 고무계 수지 중 상기 네츄럴러버의 함량이 40 중량% 이상인 것이 바람직한데, 상기 내츄럴러버의 함량이 40 중량부 미만이면 완충부재의 내구성이 저하될 수 있다.The natural rubber serves to provide a cushioning member having a high tensile strength and excellent tensile strength. Preferably, the content of the natural rubber among the rubber-based resin is 40% by weight or more, and the content of the natural rubber is 40% by weight If it is less than negative, the durability of the buffer member may be reduced.

또한, 상기 부타디엔러버(BR, Butadiene Rubber)는 부타디엔을 용액 중합법으로 제조한 합성고무 제품으로, 높은 cis 함량과 낮은 cis 함량의 두 가지로 생산이 가능하며, 투명하거, 내마모성이 우수할 뿐만 아니라, 반발탄성이 우수하며 동적 성질이 좋고 내굴곡성, 내한성이 우수하다.In addition, the butadiene rubber (BR, Butadiene Rubber) is a synthetic rubber product manufactured by solution polymerization of butadiene. It can be produced in two types of high cis content and low cis content. It is transparent and has excellent wear resistance as well as , It has excellent rebound elasticity, good dynamic properties, and excellent bending resistance and cold resistance.

또한, 상기 니트릴부타디엔러버(NBR, Nitrile-butadiene rubber)는 아크릴로니트릴과 부타디엔을 유화중합법으로 만든 합성고무 제품으로, 고무 100 중량부에 아크릴로니트릴이 35 내지 45 중량부가 혼합되어 이루어지는데, 내유성, 내마모성, 내노화성이 우수하다.In addition, the nitrile-butadiene rubber (NBR, Nitrile-butadiene rubber) is a synthetic rubber product made by emulsion polymerization of acrylonitrile and butadiene, and 35 to 45 parts by weight of acrylonitrile is mixed with 100 parts by weight of rubber. It has excellent oil resistance, abrasion resistance and aging resistance.

또한, 상기 스티렌부타디엔러버(SBR, Styrene Butadiene Rubber)는 Styrene과 Butadiene을 유화 중합법으로 제조한 합성고무 제품으로, 비닐 결합 등의 혼합적인(불규칙적인) 구조를 가지는데, sis형 1,4결합, trans형 1,4결합, 비닐(vi-nyl) 1,2결합의 세 가지로 합성되며, 천연고무에 비해 품질이 균일, 내열성과 내마모성이 우수하다.In addition, the styrene butadiene rubber (SBR, Styrene Butadiene Rubber) is a synthetic rubber product manufactured by emulsion polymerization of styrene and butadiene, and has a mixed (irregular) structure such as vinyl bonds, sis type 1,4 bonds , trans type 1,4 bonds, and vinyl (vi-nyl) 1,2 bonds are synthesized in three types, and compared to natural rubber, the quality is uniform, and the heat resistance and abrasion resistance are excellent.

또한, 상기 에틸렌프로필렌디엔모노머(EPDM)는 삼원 공중합체로, 에틸렌, 프로필렌 이원 공중합체에 제3성분인 Diene이 포함되어 있는 구조로, 내노화성, 균열성, 내수성이 우수하다.In addition, the ethylene propylene diene monomer (EPDM) is a terpolymer, and has a structure in which the third component, Diene, is included in the ethylene and propylene binary copolymer, and has excellent aging resistance, cracking resistance, and water resistance.

상기 충전재는 30 내지 40 중량부가 함유되며, 실리카, 바륨 및 카본블랙으로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는데, 본 발명에 따른 완충부재 조성물의 내충격성과 내마모성 등을 향상시키는 역할을 한다.The filler contains 30 to 40 parts by weight, and is made of at least one selected from the group consisting of silica, barium and carbon black, and serves to improve impact resistance and abrasion resistance of the cushioning member composition according to the present invention.

상기 충전재의 함량이 30 중량부 미만이면 상기의 효과가 미미하며, 상기 충전재의 함량이 40 중량부를 초과하게 되면 상대적으로, 고무계 수지의 함량이 줄어들어 완충부재의 신축성이 저하될 수 있다.When the content of the filler is less than 30 parts by weight, the above effect is insignificant, and when the content of the filler exceeds 40 parts by weight, the content of the rubber-based resin is relatively reduced, so that the elasticity of the cushioning member may be reduced.

상기 산화방지제는 2 내지 10 중량부가 함유되며, 3C(N-PHENYL-N'-ISOPROPYL-P-PHENYLENEDIAMINE) 또는 RD(POLYMERIZED 2,2,4-TRIMETHYL-1,2- DIHYDROQUINOLINE)로 이루어지는데, 본 발명에 따른 완충부재의 산화를 억제하여 물성이 유지될 수 있도록 하는 역할을 한다.The antioxidant contains 2 to 10 parts by weight, and consists of 3C (N-PHENYL-N'-ISOPROPYL-P-PHENYLENEDIAMINE) or RD (POLYMERIZED 2,2,4-TRIMETHYL-1,2-DIHYDROQUINOLINE), It serves to suppress the oxidation of the buffer member according to the invention so that the physical properties can be maintained.

상기 산화방지제의 함량이 2 중량부 미만이면 완충부재의 산화방비 효과가 미미하며, 상기 산화방지제의 함량이 10 중량부를 초과하게 되면 상대적으로 주재료인 고무계 수지의 함량이 줄어들어 완충부재의 신축성이 저하될 수 있다.When the content of the antioxidant is less than 2 parts by weight, the antioxidant effect of the buffer member is insignificant, and when the content of the antioxidant exceeds 10 parts by weight, the content of the rubber-based resin, which is the main material, is relatively reduced, so that the elasticity of the buffer member is lowered. can

상기 가황 촉진제는 1 내지 3 중량부가 함유되며, 유황으로 이루어지는데, 본 발명에 따른 완충부재 조성물을 제조하는 과정에서 가황반응을 촉진하여 가교구조로 인해 인장강도나 내마모성과 같은 우수한 물성을 나타내는 완충부재가 제공될 수 있도록 하는 역할을 한다.The vulcanization accelerator contains 1 to 3 parts by weight and consists of sulfur, which promotes the vulcanization reaction in the process of preparing the buffer member composition according to the present invention and exhibits excellent physical properties such as tensile strength and abrasion resistance due to the cross-linked structure. plays a role in providing

상기 가황 촉진제의 함량이 1 주량부 미만이면 금형 내에서 완충패드를 제조하는 과정에서 가황 촉진의 효과가 미미하며, 상기 가황 촉진제의 함량이 3 중량부를 초과하게 되면 고무계 수지의 함량이 줄어들어 완충부재의 신축성이 저하될 수 있다.If the content of the vulcanization accelerator is less than 1 part by weight, the effect of accelerating vulcanization in the process of manufacturing the buffer pad in the mold is insignificant, and when the content of the vulcanization accelerator exceeds 3 parts by weight, the content of the rubber-based resin is reduced and Elasticity may be reduced.

또한, 본 발명에 따른 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물에는 손실계수 향상을 위해 상기 고무계 수지 100 중량부 대비 첨가제 10 내지 40 중량부가 더 함유될 수 있으며, 상기 첨가제는 로진 수지, 테르펜계 수지, 석유 수지, 석탄 수지, 페놀수지 및 크실렌 수지로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것이 바람직하다.In addition, the cushioning member composition for a vehicle leaf spring having excellent elasticity and durability according to the present invention may further contain 10 to 40 parts by weight of additives relative to 100 parts by weight of the rubber-based resin to improve the loss factor, and the additives include rosin resin and terpene. It is preferably made of at least one selected from the group consisting of a resin-based resin, a petroleum resin, a coal resin, a phenol resin, and a xylene resin.

이때, 상기 손실계수란, 제진 재료의 제진 특성의 평가 지표의 하나로, 일반적으로 손실계수가 큰 물질일수록 진동을 보다 저감하기 때문에, 상기와 같이 손실계수를 향상시키는 첨가제가 함유되면 완충부재의 손실계수가 향상되어 차량의 진동 저감을 통해 승차감을 더욱 향상시킬 수 있다.At this time, the loss factor is one of the evaluation indicators of the vibration damping properties of the damping material. In general, the larger the loss coefficient is, the more vibration is reduced. can further improve the riding comfort through the reduction of vibration of the vehicle.

상기 첨가제의 함량이 10 중량부 미만이면 상기의 효과가 미미하며, 상기 첨가제의 함량이 40 중량부를 초과하게 되면 상대적으로 고무계 수지의 함량이 줄어들어 완충부재의 신축성이 저하될 수 있다.When the content of the additive is less than 10 parts by weight, the above effect is insignificant, and when the content of the additive exceeds 40 parts by weight, the content of the rubber-based resin is relatively reduced, so that the elasticity of the buffer member may be reduced.

상기의 성분으로 이루어지는 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물은 아래 도 3에 나타낸 것처럼, 완충부재 조성물이 차량 판스프링에 구비된 홈에 고정될 수 있도록 원판형의 하부 디스크 상에 상기 하부 디스크 보다 작은 직경을 갖는 원판형의 상부 디스크가 형성되는 형태로 성형되는데, 상부 디스크는 직경이 10 내지 20mm, 바람직하게는 13mm, 15mm 및 16mm로 형성되는 것이 바람직하며, 높이는 4 내지 6mm, 바람직하게는 5mm로 성형되는 것이 바람직하다.As shown in FIG. 3 below, the cushioning member composition for a vehicle leaf spring having excellent elasticity and durability made of the above components is placed on a disk-shaped lower disk so that the cushioning member composition can be fixed to a groove provided in the vehicle leaf spring. It is molded to form a disk-shaped upper disk having a smaller diameter than the disk, and the upper disk has a diameter of 10 to 20 mm, preferably 13 mm, 15 mm and 16 mm, and a height of 4 to 6 mm, preferably is preferably molded to 5 mm.

또한, 하부 디스크는 직경이 52 내지 60mm이며, 적용되는 판스프링의 종류에 따라 각각 52mm, 56mm 및 60mm의 직경을 갖도록 다양하게 적용될 수 있고, 두께는 6 내지 12mm를 나타내는 것이 바람직하며, 적용되는 판스프링의 종류에 따라 각각 6mm, 8mm, 10mm, 12mm의 직경을 갖도록 다양하게 적용될 수 있다.In addition, the lower disk has a diameter of 52 to 60 mm, and can be variously applied to have diameters of 52 mm, 56 mm and 60 mm, respectively, depending on the type of the applied plate spring, and the thickness is preferably 6 to 12 mm, and the applied plate Depending on the type of spring, it can be applied in various ways to have diameters of 6mm, 8mm, 10mm, and 12mm, respectively.

또한, 상부 디스크나 하부 디스크 모두 원형으로 적용되는 것이 일반적이나, 경우에 따라 하부 디스크는 사각판형으로 적용될 수도 있다.In addition, although both the upper disk and the lower disk are generally applied in a circular shape, in some cases, the lower disk may be applied in a square plate shape.

이하에서는, 본 발명에 따른 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물의 제조방법 및 그 제조방법을 통해 제조된 완충부재 조성물의 물성을 실시예를 들어 설명하기로 한다.Hereinafter, a method for manufacturing a cushioning member composition for a vehicle leaf spring having excellent elasticity and durability according to the present invention and physical properties of the cushioning member composition prepared through the manufacturing method will be described with reference to Examples.

<실시예 1><Example 1>

고무계 수지(NR 40 중량%, BR 60 중량%) 100 중량부, 충전재(실리카) 35 중량부, 산화방지제(3C) 6 중량부 및 가황 촉진제(유황) 2 중량부를 교반기가 구비된 혼합장치에 투입하고 150rpm에서 10분 동안 교반하여 혼합물을 제조한 후에, 상기 혼합물을 사출성형장치로 성형(하부디스크:직경 56mm, 높이 8mm, 상부디스크:직경 16mm, 높이 5mm)하여 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물을 제조하였다.100 parts by weight of rubber-based resin (NR 40% by weight, BR 60% by weight), 35 parts by weight of filler (silica), 6 parts by weight of antioxidant (3C), and 2 parts by weight of vulcanization accelerator (sulfur) are put into a mixing device equipped with a stirrer After preparing a mixture by stirring at 150 rpm for 10 minutes, the mixture was molded with an injection molding device (lower disk: diameter 56 mm, height 8 mm, upper disk: diameter 16 mm, height 5 mm), so that the vehicle leaf spring with excellent elasticity and durability A buffering member composition was prepared.

<실시예 2><Example 2>

상기 실시예 1과 동일하게 진행하되, 고무계 수지(NR 40%, NBR 60%)를 사용하여 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물을 제조하였다.The same procedure as in Example 1 was performed, except that a rubber-based resin (NR 40%, NBR 60%) was used to prepare a cushioning member composition for a vehicle leaf spring having excellent elasticity and durability.

<실시예 3><Example 3>

상기 실시예 1과 동일하게 진행하되, 고무계 수지(NR 40%, SBR 60%)를 사용하여 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물을 제조하였다.The same procedure as in Example 1 was performed, except that a rubber-based resin (NR 40%, SBR 60%) was used to prepare a cushioning member composition for a vehicle leaf spring having excellent elasticity and durability.

<실시예 4><Example 4>

상기 실시예 1과 동일하게 진행하되, 고무계 수지(NR 40%, EPDM 60%)를 사용하여 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물을 제조하였다.The same procedure as in Example 1 was performed, except that a rubber-based resin (NR 40%, EPDM 60%) was used to prepare a cushioning member composition for a vehicle leaf spring having excellent elasticity and durability.

상기 실시예 1 내지 4를 통해 제조된 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물의 신축성 및 내구성을 측정하여 아래 표 1에 나타내었다.The elasticity and durability of the cushioning member compositions for vehicle leaf springs having excellent elasticity and durability prepared in Examples 1 to 4 were measured and shown in Table 1 below.

{단, 신축성은 인장신율로 확인하였고, 내구성은 압축강도와 휨강도를 확인하는 방법을 이용하였는데, 인장신율은 ASTM D638의 시험방법을 이용하였으며, 압축강도는 KS F 2206의 시험방법을 이용하였고, 휨강도는 KS F 2326의 시험방법을 이용하였다.}{However, the elasticity was confirmed by tensile elongation, and the method of confirming compressive and flexural strength was used for durability. For tensile elongation, the test method of ASTM D638 was used, and for the compressive strength, the test method of KS F 2206 was used, The test method of KS F 2326 was used for flexural strength.}

<표 1><Table 1>

Figure pat00001
Figure pat00001

상기 표 1에 나타낸 것처럼, 본 발명의 실시예 1 내지 4를 통해 제조된 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물은 내구성과 신축성이 우수한 것을 알 수 있다.As shown in Table 1, it can be seen that the cushioning member composition for a vehicle leaf spring having excellent elasticity and durability prepared in Examples 1 to 4 of the present invention has excellent durability and elasticity.

따라서, 본 발명에 따른 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물은 내구성이 우수할 뿐만 아니라, 신축성이 향상되어 차량의 승차감을 향상시킬 수 있다.Therefore, the cushioning member composition for a vehicle leaf spring having excellent elasticity and durability according to the present invention not only has excellent durability, but also has improved elasticity to improve the riding comfort of a vehicle.

Claims (7)

고무계 수지, 충전재, 산화방지제 및 가황 촉진제로 이루어지는 것을 특징으로 하는 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물.
A cushioning member composition for a vehicle leaf spring having excellent elasticity and durability, characterized in that it consists of a rubber-based resin, a filler, an antioxidant and a vulcanization accelerator.
청구항 1에 있어서,
상기 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물은 고무계 수지 100 중량부, 충전재 30 내지 40 중량부, 산화방지제 2 내지 10 중량부 및 가황 촉진제 1 내지 3 중량부로 이루어지는 것을 특징으로 하는 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물.
The method according to claim 1,
The cushioning member composition for a vehicle leaf spring having excellent elasticity and durability comprises 100 parts by weight of a rubber-based resin, 30 to 40 parts by weight of a filler, 2 to 10 parts by weight of an antioxidant, and 1 to 3 parts by weight of a vulcanization accelerator. This excellent cushioning member composition for a vehicle leaf spring.
청구항 1 또는 2에 있어서,
상기 고무계 수지는 네츄럴러버에 부타디엔러버, 니트릴부타디엔러버, 스티렌부타디엔러버 및 에틸렌프로필렌디엔모노머로 이루어진 그룹에서 선택된 하나 이상을 혼합하여 이루어지는 것을 특징으로 하는 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물.
The method according to claim 1 or 2,
The rubber-based resin is a natural rubber, butadiene rubber, nitrile butadiene rubber, styrene butadiene rubber, and a buffer member composition for a vehicle leaf spring excellent in elasticity and durability, characterized in that made by mixing at least one selected from the group consisting of ethylene propylene diene monomer.
청구항 3에 있어서,
상기 고무계 수지는 상기 네츄럴러버의 함량이 40 중량% 이상인 것을 특징으로 하는 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물.
4. The method according to claim 3,
The rubber-based resin is a cushioning member composition for a vehicle leaf spring excellent in elasticity and durability, characterized in that the content of the natural rubber is 40% by weight or more.
청구항 1 또는 2에 있어서,
상기 충전재는 실리카, 바륨 및 카본블랙으로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것을 특징으로 하는 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물.
The method according to claim 1 or 2,
The cushioning member composition for a vehicle leaf spring having excellent elasticity and durability, characterized in that the filler is made of at least one selected from the group consisting of silica, barium and carbon black.
청구항 1 또는 2에 있어서,
상기 가황 촉진제는 유황으로 이루어지는 것을 특징으로 하는 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물.
The method according to claim 1 or 2,
The vulcanization accelerator is a cushioning member composition for a vehicle leaf spring excellent in elasticity and durability, characterized in that consisting of sulfur.
청구항 1에 있어서,
상기 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물에는 손실계수 향상을 위해 상기 고무계 수지 100 중량부 대비 첨가제 10 내지 40 중량부가 더 함유되며,
상기 첨가제는 로진 수지, 테르펜계 수지, 석유 수지, 석탄 수지, 페놀수지 및 크실렌 수지로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것을 특징으로 하는 신축성과 내구성이 우수한 차량 판스프링용 완충부재 조성물.
The method according to claim 1,
The cushioning member composition for a vehicle leaf spring having excellent elasticity and durability further contains 10 to 40 parts by weight of additives compared to 100 parts by weight of the rubber-based resin in order to improve the loss factor,
The additive is a buffer member composition for a vehicle leaf spring having excellent elasticity and durability, characterized in that it consists of at least one selected from the group consisting of rosin resin, terpene-based resin, petroleum resin, coal resin, phenol resin and xylene resin.
KR1020200105678A 2020-08-21 2020-08-21 Shock absorbing member composition for vehicle leat spring with excellent elasticity and durability KR20220023929A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101429462B1 (en) 2013-05-10 2014-08-13 경상대학교산학협력단 Composite Leaf Spring for Vehicle
KR101462239B1 (en) 2013-06-21 2014-11-20 경상대학교산학협력단 Composite Leaf Spring for Vehicle having Reinforced Connector

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101429462B1 (en) 2013-05-10 2014-08-13 경상대학교산학협력단 Composite Leaf Spring for Vehicle
KR101462239B1 (en) 2013-06-21 2014-11-20 경상대학교산학협력단 Composite Leaf Spring for Vehicle having Reinforced Connector

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