KR20200142260A - Corrosion resistance and high strength/Al alloy plate and wire - Google Patents

Corrosion resistance and high strength/Al alloy plate and wire Download PDF

Info

Publication number
KR20200142260A
KR20200142260A KR1020190069291A KR20190069291A KR20200142260A KR 20200142260 A KR20200142260 A KR 20200142260A KR 1020190069291 A KR1020190069291 A KR 1020190069291A KR 20190069291 A KR20190069291 A KR 20190069291A KR 20200142260 A KR20200142260 A KR 20200142260A
Authority
KR
South Korea
Prior art keywords
alloy
mos
wse
mose
graphene
Prior art date
Application number
KR1020190069291A
Other languages
Korean (ko)
Inventor
이성균
이혜경
이연수
Original Assignee
이성균
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 이성균 filed Critical 이성균
Priority to KR1020190069291A priority Critical patent/KR20200142260A/en
Publication of KR20200142260A publication Critical patent/KR20200142260A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B21/00—Obtaining aluminium
    • C22B21/0084—Obtaining aluminium melting and handling molten aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/16—Remelting metals
    • C22B9/18—Electroslag remelting
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/02—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
    • H01B1/023—Alloys based on aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/04—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of carbon-silicon compounds, carbon or silicon

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Alloys Or Alloy Compounds (AREA)

Abstract

The present invention provides a corrosion resistance and high strength Al alloy plate and a corrosion resistance and high strength Al alloy wire, which are more effective than a prior corrosion resistance and high strength Al alloy plate and a prior corrosion resistance and high strength Al alloy wire, manufactured by the following steps of: forming MoS_2 (WS_2, MoSe_2, WSe_2)·CNT (graphene) by additively mixing CNT (graphene), formed by selecting one or more between CNT and graphene, with MoS_2 (WS_2, MoSe_2, WSe_2) formed by selecting one or more among molybdenum disulfide (MoS_2), tungsten disulfide (WS_2), molybdenum diselenide (MoSe_2) and tungsten diselenide (WSe_2) formed of nano-powder or nano-sheet; and embedding MOS_2 (WS_2, MoSe_2, WSe_2)·CNT (graphene) in an Al alloy plate or an Al alloy wire such that the Al alloy plate or the Al alloy wire can show characteristics of the MOS_2 (WS_2, MoSe_2, WSe_2)·CNT (graphene).

Description

내식 및 고강도/Al합금 판재 및 선재{omitted}Corrosion resistance and high strength/Al alloy plate and wire{omitted}

본 발명은 내식 및 고강도의 Al합금 판재 및 Al합금 선재를 구성하고자.The present invention to construct a corrosion-resistant and high-strength Al alloy plate and Al alloy wire.

1. 1) 나노 분말이나 나노 시트로 구성된 ① 이황화 몰리브덴(MoS2) ② 이황화 텅스텐(WS2) ③ 이셀렌화 몰리브덴(MoSe2) ④ 이셀레늄 텅스텐(WSe2) 중에서 1가지 이상을 선택하여 구성한 MOS2(WS2, MoSe2, WSe2)에 2) CNT나 그래핀 중에서 1가지 이상을 구성한 CNT(그래핀)을 첨가하고 혼합시켜서 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 구성한 후1. 1) Composition of nano-powder or nano-sheet ① Molybdenum disulfide (MoS 2 ) ② Tungsten disulfide (WS 2 ) ③ Molybdenum diselenide (MoSe 2 ) ④ Tungsten diselenium (WSe 2 ). To MOS 2 (WS 2 , MoSe 2 , WSe 2 ) 2) CNT or CNT (graphene) consisting of one or more of graphene was added and mixed a. After configuring MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene)

2. Al합금 판재나 Al합금 선재내에 a. MOS2(WS2, MoSe2, WSe2)·CNT(그래핀)이 내재되도록 구성하여 Al합금 판재나 Al합금 선재가 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성이 나타나도록 구성하여-기존의 Al합금 판재나 Al합금 선재보다 내식성, 강도성, 전기전도성, 방열성, 항균성, 내화학성, 내마모성, 내열성등이 우수하고 원적외선 및 음이온을 방출하면서 전자파 차폐기능이 우수한 특성을 나타내는 보다 효능적인 '내식 및 고강도/Al합금 판재' 및 '내식 및 고강도/Al합금 선재'를 구성하고자 하는 것이다.2. In Al alloy plate or Al alloy wire, a. MOS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is built-in so that Al alloy plate or Al alloy wire is a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) characteristics are shown-Corrosion resistance, strength, electrical conductivity, heat dissipation, antibacterial, and chemical resistance than the existing Al alloy plate or Al alloy wire It is intended to construct more effective'corrosion and high strength/Al alloy plate'and'corrosion and high strength/Al alloy wire' that exhibit excellent characteristics of electromagnetic wave shielding function while emitting far-infrared rays and negative ions while having excellent wear resistance and heat resistance.

기존의 Al합금 판재 및 Al합금 선재는 부식이 되고 강도성, 내화학성, 내마모성, 항균성이 낮으며 또한 전자파 차폐기능도 낮은 문제점이 있는바.Existing Al alloy plate and Al alloy wire are corroded and have low strength, chemical resistance, abrasion resistance, antibacterial properties, and low electromagnetic shielding function.

본 발명은 이러한 문제점을 해결하여 기존의 Al합금 판재나 Al합금 선재보다 내식성, 강도성, 전기전도성, 방열성, 항균성, 내화학성, 내마모성, 내열성등이 우수하고 원적외선 및 음이온을 방출하면서 전자파 차폐기능을 나타내는 보다 효능적인 내식 및 고강도/Al합금 판재 및 내식 및 고강도/Al합금 선재를 구성하는 것이 목적으로.The present invention solves these problems and is superior in corrosion resistance, strength, electrical conductivity, heat dissipation, antibacterial properties, chemical resistance, abrasion resistance, heat resistance, etc., than the existing Al alloy plate or Al alloy wire, and emits far infrared rays and negative ions while providing electromagnetic wave shielding function. Its purpose is to construct more effective corrosion resistance and high strength/Al alloy plate and corrosion resistance and high strength/Al alloy wire.

본 발명을 구성하는데 있어In constructing the present invention

1) 나노 시트나 나노 분말로 구성된 ① 이황화 몰리브덴(MoS2) ② 이황화 텅스텐(WS2) ③ 이셀렌화 몰리브덴(MoSe2) ④ 이셀레늄 텅스텐(WSe2) 중에서 1가지 이상을 선택하여 구성한 MoS2(WS2, MoSe2, WSe2)의 특성: 광촉매이며 반도체로써, 내식성, 강도성, 전기전도성, 방열성, 항균성, 내화학성, 내마모성, 내열성, 열전도성, 윤활성이 우수하다1) Composed of nano sheet or nano powder ① Molybdenum disulfide (MoS 2 ) ② Tungsten disulfide (WS 2 ) ③ Molybdenum diselenide (MoSe 2 ) ④ Characteristics of MoS 2 (WS 2 , MoSe 2 , WSe 2 ) composed of more than one selected from iselenium tungsten (WSe 2 ): As a photocatalyst and semiconductor, corrosion resistance, strength, electrical conductivity, heat dissipation, antibacterial, and chemical resistance , Excellent wear resistance, heat resistance, thermal conductivity, and lubrication

2) CNT나 그래핀 중에서 1가지 이상을 선택하여 구성한 CNT(그래핀)의 특성: 전기전도성, 강도성, 방열성, 열전도성이 우수하고, 원적외선 및 음이온을 방출하여 전자파 차폐기능이 우수하다.2) Characteristics of CNT (graphene) composed by selecting one or more of CNT or graphene: excellent electrical conductivity, strength, heat dissipation, thermal conductivity, and excellent electromagnetic wave shielding function by emitting far infrared rays and negative ions.

3) MoS2(WS2, MoSe2, WSe2)에 CNT(그래핀)을 첨가하고 혼합시켜 구성한 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성: 내식성, 강도성, 전기전도성, 방열성, 항균성, 내화학성, 내마모성, 내열성이 우수하고 원적외선 및 음이온을 방출하면서 전자파 차폐기능이 우수하다3) MoS 2 (WS 2 , MoSe 2 , WSe 2 ) added to CNT (graphene) and mixed with a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · Characteristics of CNT (graphene): Excellent corrosion resistance, strength, electrical conductivity, heat dissipation, antibacterial, chemical resistance, abrasion resistance, heat resistance, and electromagnetic wave shielding function while emitting far-infrared rays and negative ions.

본 발명은 위에서 서술한 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성을 Al합금 판재 및 Al합금 선재에 나타나도록 구성하고자.The present invention is a. To configure the characteristics of MoS 2 (WS 2 , MoSe 2, WSe 2 )·CNT (graphene) to appear in Al alloy plate and Al alloy wire.

Al합금 판재나 Al합금 선재내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)이 내재되도록 구성하여 Al합금 판재나 Al합금 선재가 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성을 나타나도록 구성하여-기존의 Al합금 판재나 Al합금 선재보다 내식성, 강도성, 전기전도성, 방열성, 항균성, 내화학성, 내마모성, 내열성, 열전도성이 우수하고 원적외선 및 음이온을 방출하면서 전자파 차폐기능이 우수한 특성을 나타내는 보다 효능적인 Al합금 판재 및 Al합금 선재인 '내식 및 고강도/Al합금 판재' 및 '내식 및 고강도/Al합금 선재'를 구성하고자 하는 것이다In Al alloy plate or Al alloy wire a. MoS 2 (WS 2 , MoSe 2, WSe 2 ) · CNT (graphene) is built-in so that Al alloy plate or Al alloy wire is a. MoS 2 (WS 2 , MoSe 2, WSe 2 ) · CNT (graphene) features-Corrosion resistance, strength, electrical conductivity, heat dissipation, antibacterial and chemical resistance than conventional Al alloy plate or Al alloy wire , Abrasion resistance, heat resistance, thermal conductivity, and more efficient Al alloy plate and Al alloy wire that exhibit excellent characteristics of electromagnetic wave shielding function while emitting far-infrared rays and negative ions,'corrosion and high strength/Al alloy plate'and'corrosion and high strength/ It is to constitute'Al alloy wire rod'

..

따라서 본 발명은Therefore, the present invention

1. < 내식 및 고강도/Al합금 판재 제조방법 >1. <Corrosion resistance and high strength/Al alloy plate manufacturing method>

1단계: a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀) 제조단계Step 1: a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) manufacturing step

1) 나노 시트나 나노 분말로 구성된 ① 이황화 몰리브덴(MoS2) ② 이황화 텅스텐(WS2) ③ 이셀렌화 몰리브덴(MoSe2) ④ 이셀레늄 텅스텐(WSe2) 중에서 1가지 이상을 선택하여 구성한 MoS2(WS2, MoSe2, WSe2)에 2) CNT나 그래핀 중에서 1가지 이상을 선택하여 구성한 CNT(그래핀)을 첨가하고 혼합시켜서 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 구성한 후1) MoS 2 consisting of nanosheets or nano powders ① Molybdenum disulfide (MoS 2 ) ② Tungsten disulfide (WS 2 ) ③ Molybdenum diselenide (MoSe 2 ) ④ MoS 2 consisting of one or more iselenium tungsten (WSe 2 ). (WS 2 , MoSe 2, WSe 2 ) 2) CNT (graphene) composed by selecting one or more of CNT or graphene was added and mixed a. After configuring MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene)

2단계: MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재 제조단계(1방법, 2방법)Step 2: MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene)/Al alloy casting material manufacturing step (1 method, 2 method)

1방법1 way

1. Al을 용탕로에서 융해시킨 Al용탕에 1) Mg, Si, Zn, Cu, Fe, Ni, Mn, Be, Cr, B중에서 1가지 이상을 선택하여(예: Si과 Mg을 첨가하고 필요시 Fe, Cu, Ti, Ni, Be, B중에서 1가지 이상을 선택하여 추가 첨가) 첨가하여 융해시켜 구성한 Al합금 용탕에 2) a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 첨가 교반시켜서 MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 용탕을 구성한 후 3) 연속주조기에서 연속주조하여 Al합금 주조내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)이 내재되도록 구성하는 1방법.1. In the Al molten metal in which Al is melted in a melting furnace, 1) Select one or more of Mg, Si, Zn, Cu, Fe, Ni, Mn, Be, Cr, and B (e.g., add Si and Mg and At least one of Fe, Cu, Ti, Ni, Be, and B is selected and added) to the molten Al alloy composed by adding and melting 2) a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is added and stirred to form MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene)/Al alloy molten metal 3) Continuous Continuous casting in a casting machine and in Al alloy casting a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is one way to be configured to be embedded.

2방법2 way

2. Al분말에 1) Mg, Si, Zn, Cu, Fe, Ni, Mn, Be, Cr, B 분말 중에서 1가지 이상을 선택하여(예: Si과 Mg을 첨가하고 필요시 Fe, Cu, Ti, Ni, Be, B중에서 1가지 이상을 선택하여 추가 첨가) 첨가하여 혼합시켜 구성한 Al합금 분말에 2) a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 첨가 혼합시켜서 MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 분말을 구성한 후 4) 금속캔에 장입하고 분말 압축시킨 후 5) 연속주조하여 Al합금 주조내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)이 내재되도록 구성하는 2방법.2. Al powder 1) Select one or more of Mg, Si, Zn, Cu, Fe, Ni, Mn, Be, Cr, and B powders (eg Si and Mg are added, and if necessary, Fe, Cu, Ti , Ni, Be, and B, select one or more of them and add) to the Al alloy powder composed by adding and mixing 2) a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is added and mixed to form MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene)/Al alloy powder 4) Metal After charging in a can and compacting the powder, 5) continuous casting and in the Al alloy casting a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is a two-way configuration to be embedded.

-위에서 서술한 1방법이나 2방법 중에서 1방법으로 Al합금 주조재내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)를 내재시켜서 ⓐ MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재를 구성한 후.-In the Al alloy casting material by one of the above methods 1 or 2, a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) embedded in ⓐ MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) / After the Al alloy cast material.

* Al합금 용탕이나 Al합금 분말에 있어 Al합금은* Al alloy in molten Al alloy or Al alloy powder

Cu-Al계 합금, Cu-Mg-Al계 합금 Cu-Si-Al계 합금 Cu-Mg-Ni-Al계 합금, Fe-Al계 합금, Si-Al계 합금, Si-Mg-Al계 합금, Si-Cu-Al계 합금 Si-Mg-Cu-Al계 합금, Si-Cu-Mg-Ni-Al계 합금 Si-Mg-Fe-Cu-Al계 합금, Mg-Al계 합금, Cr-Zn-Al계 합금, Zn-Mg-Cu-Al계 합금, Ti-(Si)-Al계 합금 중에서 1가지를 선택하여 구성한 Al합금.Cu-Al alloy, Cu-Mg-Al alloy Cu-Si-Al alloy Cu-Mg-Ni-Al alloy, Fe-Al alloy, Si-Al alloy, Si-Mg-Al alloy, Si-Cu-Al alloy Si-Mg-Cu-Al alloy, Si-Cu-Mg-Ni-Al alloy Si-Mg-Fe-Cu-Al alloy, Mg-Al alloy, Cr-Zn- Al alloy composed by selecting one of Al alloy, Zn-Mg-Cu-Al alloy, and Ti-(Si)-Al alloy.

3단계: 1) 내식 및 고강도/Al합금 판재 2) 내식 및 고강도/Al합금 선재 제조단계Step 3: 1) Corrosion resistance and high strength/Al alloy plate 2) Corrosion resistance and high strength/Al alloy wire manufacturing stage

1) 내식 및 고강도/Al합금 판재 구성-Al합금 판재 제조공정1) Corrosion resistance and high strength/Al alloy plate composition-Al alloy plate manufacturing process

ⓐ MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재를 ① 균질화 공정 ② 열간압연 공정 ③ 냉각 ④ 열처리 ⑤ 냉간 압연 공정을 거쳐서 Al합금 판재내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)이 내재되어서 Al합금 판재가 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성이 나타나도록 구성하여-기존의 Al합금 판재보다 내식성, 강도성, 전기전도성, 방열성, 내열성, 항균성, 내화학성, 내마모성, 열전도성이 우수하고, 원적외선 및 음이온을 방출하면서 전자파 차폐기능이 우수한 특성을 나타내는 보다 효능적인 Al합금 판재로 구성한 내식 및 고강도/Al합금 판재.Ⓐ MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene)/Al alloy cast material ① homogenization process ② hot rolling process ③ cooling ④ heat treatment ⑤ cold rolling process in Al alloy plate a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is embedded, so the Al alloy plate is a. MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene) characteristics are shown-Corrosion resistance, strength, electrical conductivity, heat dissipation, heat resistance, antibacterial, chemical resistance, and abrasion resistance than the existing Al alloy plate , Corrosion-resistant and high-strength/Al alloy plate composed of a more efficient Al alloy plate that has excellent thermal conductivity and exhibits excellent electromagnetic wave shielding function while emitting far-infrared rays and negative ions.

2) 내식 및 고강도/Al합금 선재 구성-Al합금 선재 제조공정2) Corrosion resistance and high strength/Al alloy wire construction-Al alloy wire manufacturing process

ⓐ MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재를 ① 균질화 공정 ② 냉각 ③ 열처리 ④ 신선·인발 ⑤ 연화 공정을 거쳐서 직경 0.1mm~2mm의 Al 합금 선재내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)이 내재되어서 Al합금 선재가 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성이 나타나도록 구성하여-기존의 Al 합금 선재보다 내식성, 강도성, 전기전도성, 방열성, 내열성, 항균성, 내화학성, 내마모성, 열전도성이 우수하고, 원적외선 및 음이온을 방출하면서 전자파 차폐기능이 우수한 특성을 나타내는 보다 효능적인 Al 합금 선재로 구성한 내식 및 고강도/Al합금 선재Ⓐ MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene)/Al alloy cast material ① homogenization process ② cooling ③ heat treatment ④ wire drawing/drawing ⑤ Al alloy wire with a diameter of 0.1mm~2mm through a softening process Within a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is embedded, so the Al alloy wire is a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) characteristics are displayed-Corrosion resistance, strength, electrical conductivity, heat dissipation, heat resistance, antibacterial properties, chemical resistance, abrasion resistance than the existing Al alloy wire , Corrosion-resistant and high-strength/Al alloy wire composed of a more efficient Al alloy wire that exhibits excellent characteristics of shielding electromagnetic waves while emitting far-infrared rays and anions while having excellent thermal conductivity.

본 발명인 내식 및 고강도/Al합금 판재나 내식 및 고강도/Al합금 선재는Corrosion resistance and high strength / Al alloy plate or corrosion resistance and high strength / Al alloy wire rod of the present invention

Al합금 판재나 Al합금 선재내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)이 내재되어 Al합금 판재나 Al합금 선재가 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성이 나타나도록 구성되어서-기존의 Al합금 판재나 Al합금 선재보다 내식성, 강도성, 전기전도성, 방열성, 항균성, 내화학성, 내마모성, 내열성등이 우수하고, 원적외선 및 음이온을 방출하면서 전자파 차폐기능이 우수한 특성을 나타내는 보다 효능적인 Al합금 판재나 Al합금 선재로 구성되어져 효과적으로In Al alloy plate or Al alloy wire a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is embedded, so that Al alloy plate or Al alloy wire is a. MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene) is constructed to exhibit the characteristics of -corrosion resistance, strength, electrical conductivity, heat dissipation, antibacterial, and chemical resistance than conventional Al alloy plate or Al alloy wire. , Abrasion resistance, heat resistance, etc., emitting far-infrared rays and negative ions while being composed of a more efficient Al alloy plate or Al alloy wire that exhibits excellent electromagnetic wave shielding function.

1) 내식 및 고강도/Al합금 판재는 보다 내식성, 강도성, 전기전도성, 방열성, 항균성, 내화학성, 내마모성, 내열성등이 우수하고, 원적외선 및 음이온 방출하면서 전자파 차폐기능이 우수한 ① 전자기기의 외장 ② 핸드폰이나 노트북 또는 태블릿 PC의 외장 ③ 방열판 ④ 후라이팬이나 냄비등을 구성할 수 있어 효과적이며1) Corrosion resistance and high strength/Al alloy plate is superior in corrosion resistance, strength, electrical conductivity, heat dissipation, antibacterial, chemical resistance, abrasion resistance, heat resistance, and has excellent electromagnetic wave shielding function while emitting far-infrared rays and negative ions. ① Exterior of electronic equipment ② It is effective because it can configure the exterior of a mobile phone, notebook or tablet PC ③ heat sink ④ frying pan or pot.

4) 내식 및 고강도/Al합금 선재는 기존의 Al합금 선재보다 내식성, 강도성, 전기전도성, 방열성, 항균성, 내화학성, 내마모성, 내열성등이 우수하고, 원적외선 및 음이온을 방출하면서 전자파 차폐기능이 우수한 보다 효능적인 송전용 Al합금 전선이나 자동차내에 내장되는 Al합금 전선 등을 구성할 수 있어 효과적이다.4) Corrosion resistance and high strength/Al alloy wire has superior corrosion resistance, strength, electrical conductivity, heat dissipation, antibacterial, chemical resistance, abrasion resistance, heat resistance, etc., and has excellent electromagnetic wave shielding function while emitting far-infrared rays and negative ions. It is effective because it can construct more efficient Al alloy wires for transmission or Al alloy wires that are embedded in automobiles.

기존의 Al합금 판재나 Al합금 선재는 부식이 되고, 강도성, 내화학성, 내마모성, 항균성이 낮으며 또한 전자파 차폐기능도 낮은 문제점이 있는바,Existing Al alloy plate or Al alloy wire is corroded, and has low strength, chemical resistance, abrasion resistance, antibacterial properties, and low electromagnetic shielding function.

본 발명은 이러한 문제점을 해결하여 기존의 Al합금 판재나 Al합금 선재보다 내식성, 강도성, 전기전도성, 방열성, 항균성, 내화학성, 내마모성, 내열성등이 우수하고, 원적외선 및 음이온을 방출하면서 전자파 차폐기능이 우수한 보다 효능적인 Al합금 판재 및 Al합금 선재인 '내식 및 고강도/Al합금 판재' 및 '내식 및 고강도/Al 합금 선재'를 구성하는 것이 목적으로The present invention solves these problems and has superior corrosion resistance, strength, electrical conductivity, heat dissipation, antibacterial properties, chemical resistance, abrasion resistance, heat resistance, etc., than the existing Al alloy plate or Al alloy wire, and has a function of shielding electromagnetic waves while emitting far infrared rays and negative ions. Its purpose is to construct'corrosion and high strength/Al alloy plate' and'corrosion and high strength/Al alloy wire', which are superior and more efficient Al alloy plate and Al alloy wire.

본 발명을 구성하는데 있어In constructing the present invention

1) 나노 시트나 나노 분말로 구성된 ① 이황화 몰리브덴(MoS2) ② 이황화 텅스텐(WS2) ③ 이셀렌화 몰리브덴(MoSe2) ④ 이셀레늄 텅스텐(WSe2) 중에서 1가지 이상을 선택하여 구성한 MoS2(WS2, MoSe2, WSe2)의 특성: 광촉매이며 반도체로써 내식성, 강도성, 전기전도성, 방열성, 항균성, 내화학성, 내마모성, 열전도성, 내열성, 윤활성이 우수하다.1) MoS 2 consisting of nanosheets or nano powders ① Molybdenum disulfide (MoS 2 ) ② Tungsten disulfide (WS 2 ) ③ Molybdenum diselenide (MoSe 2 ) ④ MoS 2 consisting of one or more iselenium tungsten (WSe 2 ). Characteristics of (WS 2 , MoSe 2, WSe 2 ): As a photocatalyst, it is a semiconductor and has excellent corrosion resistance, strength, electrical conductivity, heat dissipation, antibacterial properties, chemical resistance, abrasion resistance, thermal conductivity, heat resistance, and lubricity.

2) CNT나 그래핀 중에서 1가지 이상을 선택하여 구성한 CNT(그래핀)의 특성: 전기전도성, 강도성, 방열성, 열전도성이 우수하고, 원적외선 및 음이온을 방출하면서 전자파 차폐기능이 우수하다.2) Characteristics of CNT (graphene) composed by selecting one or more of CNT or graphene: excellent electrical conductivity, strength, heat dissipation, thermal conductivity, and excellent electromagnetic wave shielding function while emitting far infrared rays and negative ions.

3) MoS2(WS2, MoSe2, WSe2)에 CNT(그래핀)을 첨가하고 볼밀 처리하여 혼합시켜 구성한 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성: 내식성, 강도성, 전기전도성, 방열성, 항균성, 내화학성, 내마모성, 열전도성, 내열성, 윤활성이 우수하고 원적외선 및 음이온을 방출하면서 전자파 차폐기능이 우수하다.3) MoS 2 (WS 2 , MoSe 2 , WSe 2 ) added CNT (graphene) and mixed by ball mill treatment a. Characteristics of MoS 2 (WS 2 , MoSe 2, WSe 2 )·CNT (graphene): Corrosion resistance, strength, electrical conductivity, heat dissipation, antibacterial, chemical resistance, abrasion resistance, thermal conductivity, heat resistance, lubrication, and far infrared rays and negative ions It has excellent electromagnetic shielding function while emitting radiation.

본 발명은 위에서 서술한 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성을 Al합금 판재나 Al합금 선재에 나타나도록 구성하고자.The present invention is a. To configure the characteristics of MoS 2 (WS 2 , MoSe 2, WSe 2 )·CNT (graphene) to appear in Al alloy plate or Al alloy wire.

1) ① Al합금 용탕에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 첨가 교반시켜서 MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 용탕을 구성한 후 ② 연속 주조기에서 연속 주조하여 MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재를 구성하거나 또는.1) ① In molten Al alloy a. After adding MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene) and stirring it to form MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene)/Al alloy molten metal ② Continuous casting machine MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) / Al alloy cast material is composed of or.

2) ① Al합금 분말에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 첨가 교반시켜서 MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 분말을 구성한 후 ② 금속캔에 장입하고 압출시킨 후 ③ 연속주조기에서 연속 주조하여 MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재를 구성한 후2) ① In the Al alloy powder, a. After adding MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene) and stirring to form MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene)/Al alloy powder ② Metal can After charging in and extruding, ③ After continuous casting in a continuous casting machine to form MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene)/Al alloy cast material

2. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재를 ① 균질화 ② 열간압연 ③ 냉각 ④ 열처리 ⑤ 냉간 압연 시켜서 Al합금 판재내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 내재시켜서 Al합금 판재가 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성이 나타나도록 구성하여-기존의 Al합금 판재보다 내식성, 강도성, 전기전도성, 방열성, 내화학성, 내마모성, 내열성, 항균성, 열전도성이 우수하고, 원적외선 및 음이온을 방출하면서 전자파 차폐기능이 우수한 특성을 나타내는 보다 효능적인 Al합금 판재인 '내식 및 고강도/Al합금 판재'를 구성하거나 또는.2. MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene)/Al alloy cast material is ① homogenized ② hot-rolled ③ cooling ④ heat treated ⑤ cold-rolled in the Al alloy plate a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is embedded so that the Al alloy plate is a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) characteristics are shown-Corrosion resistance, strength, electrical conductivity, heat dissipation, chemical resistance, abrasion resistance, heat resistance, antibacterial properties than conventional Al alloy plates , It constitutes'corrosion resistance and high strength/Al alloy plate', which is a more efficient Al alloy plate material that exhibits excellent characteristics of electromagnetic wave shielding function while having excellent thermal conductivity, emitting far infrared rays and negative ions, or.

3. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재를 ① 균질화 ② 냉각 ③ 열처리 ④ 신선·인발 ⑤ 연화시켜서 직경 0.1mm~2mm의 Al합금 선재내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 내재시켜서 Al합금 선재가 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성이 나타나도록 구성하여-기존의 Al합금 선재보다 내식성, 강도성, 전기전도성, 방열성, 내화학성, 내마모성, 내열성, 항균성, 열전도성이 우수하고, 원적외선 및 음이온을 방출하면서 전자파 차폐기능이 우수한 특성을 나타내는 보다 효능적인 Al합금 선재인 '내식 및 고강도/Al합금 선재'를 구성하고자 하는 것이다.3. MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene)/Al alloy cast material is ① homogenized ② cooled ③ heat treated ④ wire drawn/drawn ⑤ softened and softened to a within 0.1mm~2mm diameter Al alloy wire . MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is embedded so that the Al alloy wire is a. MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene) characteristics are shown-Corrosion resistance, strength, electrical conductivity, heat dissipation, chemical resistance, abrasion resistance, heat resistance, antibacterial properties than conventional Al alloy wire rods , It is to construct a more effective Al alloy wire,'corrosion resistance and high strength/Al alloy wire', which has excellent thermal conductivity and exhibits excellent electromagnetic wave shielding function while emitting far-infrared rays and negative ions.

따라서 본 발명은Therefore, the present invention

1. < 내식 및 고강도/Al합금 판재 제조방법 >1. <Corrosion resistance and high strength/Al alloy plate manufacturing method>

1단계: a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀) 제조단계Step 1: a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) manufacturing step

1) 나노 시트나 나노 분말로 구성된 ① 이황화 몰리브덴(MoS2) ② 이황화 텅스텐(WS2) ③ 이셀렌화 몰리브덴(MoSe2) ④ 이셀레늄 텅스텐(WSe2) 중에서 1가지 이상을 선택하여 구성한 MoS2(WS2, MoSe2, WSe2)에 2) CNT나 그래핀 중에서 1가지 이상을 선택하여 구성한 CNT(그래핀)을 (99~50:1~50 중량비로) 첨가 혼합시켜서 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 구성한 후.1) MoS 2 consisting of nanosheets or nano powders ① Molybdenum disulfide (MoS 2 ) ② Tungsten disulfide (WS 2 ) ③ Molybdenum diselenide (MoSe 2 ) ④ MoS 2 consisting of one or more iselenium tungsten (WSe 2 ). (WS 2 , MoSe 2, WSe 2 ) 2) CNT (graphene) composed of at least one selected from CNT or graphene was added and mixed (in a weight ratio of 99-50:1-50) a. After configuring MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene).

2단계: ⓐ MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재Step 2: ⓐ MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene)/Al alloy casting material

1방법1 way

1. Al을 용탕로(850℃~930℃)에서 용융시킨 Al용탕에 1) Cu, Si, Zn, Cu, Fe, Ni, Ti, Mn, Be, Cr, B중에서 1가지 이상을 선택하여 첨가(예: Si(0.2~0.8중량%)과 Mg(0.5~5중량%)을 첨가하고 필요시 Fe, Cu, Ti, Ni, Be, B중에서 1가지 이상을 선택하여 (0~1.2중량%)를 추가 첨가) 하여 융해시켜 구성한 Al합금 용탕에 3) a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 첨가 교반시켜 MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 용탕을 구성한 후 4) 연속주조기에서 연속주조(450℃~550℃)하여 Al합금 주조재 내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)이 내재되도록 구성하는 1방법.1. Add Al to molten Al melted in a melting furnace (850℃~930℃) 1) Select one or more of Cu, Si, Zn, Cu, Fe, Ni, Ti, Mn, Be, Cr, and B (Example: Si (0.2 to 0.8% by weight) and Mg (0.5 to 5% by weight) are added, and if necessary, select one or more of Fe, Cu, Ti, Ni, Be, and B (0 to 1.2% by weight) 3) a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is added and stirred to form MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene)/Al alloy molten metal 4) Continuous Continuous casting (450℃~550℃) in a casting machine and in the Al alloy casting a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is one way to be configured to be embedded.

2방법2 way

2. Al분말에 1) Mg, Si, Zn, Cu, Fe, Ni, Mn, Be, Cr, B 분말 중에서 1가지 이상을 선택하여 첨가(예: Si(0.2~0.8중량%)과 Mg(0.5~5중량%)을 첨가하고 필요시 Fe, Cu, Ti, Ni, Be, B중에서 1가지 이상을 선택하여 (0~1.2 중량%)를 추가 첨가) 하여 혼합시켜서 구성한 Al합금 분말에 2) a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 첨가 혼합시켜서 MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 분말을 구성한 후 4) 금속캔에 장입시키고 분말 압출(850℃~930℃)후 4) 연속주조(450℃~550℃)하여 Al합금 주조재 내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)이 내재되도록 구성하는 2방법.2. To Al powder 1) Select one or more of Mg, Si, Zn, Cu, Fe, Ni, Mn, Be, Cr, and B powders to add (eg Si(0.2~0.8% by weight) and Mg(0.5) ~5% by weight), and if necessary, select one or more of Fe, Cu, Ti, Ni, Be, and B (additionally add 0 to 1.2% by weight) and mix 2) a . MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is added and mixed to form MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene)/Al alloy powder 4) Metal It is charged into a can, and powder is extruded (850℃~930℃). MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is a two-way configuration to be embedded.

-위에서 서술한 1방법이나 2방법 중에서 1가지 방법으로 Al합금 주조재내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)를 내재시켜서 ⓐ MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재를 구성한 후-In the Al alloy casting material by one of the above-described 1 method or 2 methods a. After MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene) is embedded ⓐ MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene)/Al alloy cast material

* Al합금 용탕이나 Al합금 분말에 있어 Al합금은* Al alloy in molten Al alloy or Al alloy powder

Cu-Al계 합금, Cu-Mg-Al계 합금, Cu-Si-Al계 합금, Cu-Mg-Ni-Al계 합금, Fe-Al계 합금, Si-Al계 합금, Si-Mg-Al계 합금, Si-Cu-Al계 합금 Si-Mg-Cu-Al계 합금 Si-Cu-Mg-Ni-Al계 합금, Si-Mg-Fe-Cu-Al계 합금, Mg-Al계 합금, Cr-Zn-Al계 합금, Zn-Mg-Cu-Al계 합금 Ti-(Si)-Al계 합금 중에서 1가지를 선택하여 구성한 Al합금.Cu-Al alloy, Cu-Mg-Al alloy, Cu-Si-Al alloy, Cu-Mg-Ni-Al alloy, Fe-Al alloy, Si-Al alloy, Si-Mg-Al Alloy, Si-Cu-Al alloy Si-Mg-Cu-Al alloy Si-Cu-Mg-Ni-Al alloy, Si-Mg-Fe-Cu-Al alloy, Mg-Al alloy, Cr- Al alloy composed by selecting one of Zn-Al alloy and Zn-Mg-Cu-Al alloy and Ti-(Si)-Al alloy.

3단계: 1) 내식 및 고강도/Al합금 판재 2) 내식 및 고강도 / Al합금 선재 제조단계Step 3: 1) Corrosion resistance and high strength/Al alloy plate 2) Corrosion resistance and high strength/Al alloy wire manufacturing stage

1) 내식 및 고강도/Al합금 판재 구성-Al합금 판재 제조공정1) Corrosion resistance and high strength/Al alloy plate composition-Al alloy plate manufacturing process

ⓐ MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재를 ① 균질화 공정(500℃) ② 열간압연(490℃~550℃) ③ 냉각(100℃, 냉각속도 15℃~20℃/sec) ④ 열처리(220℃~280℃) ⑤ 냉간압연(23℃~30℃) 시켜서 Al합금 판재를 구성하는데 있어, Al합금 판재내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 내재시켜 Al합금 판재가 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성이 나타나도록 구성하여-기존의 Al합금 판재보다 내식성, 강도성, 전기전도성, 방열성, 내열성, 내화학성, 내마모성등이 우수하고, 원적외선 및 음이온을 방출하면서 전자파 차폐기능이 우수한 특성을 나타내는 보다 효능적인 Al합금 판재로 구성한 A. 내식 및 고강도/Al합금 판재.Ⓐ MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene)/Al alloy cast material ① homogenization process (500℃) ② hot rolling (490℃~550℃) ③ cooling (100℃, cooling rate 15℃~20℃/sec) ④ Heat treatment (220℃~280℃) ⑤ Cold rolling (23℃~30℃) to form Al alloy plate, in Al alloy plate a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is embedded so that the Al alloy plate is a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) characteristics are displayed-Corrosion resistance, strength, electrical conductivity, heat dissipation, heat resistance, chemical resistance, abrasion resistance, etc. are better than conventional Al alloy plates. A. Corrosion resistance and high strength/Al alloy plate made of a more efficient Al alloy plate that is excellent and exhibits excellent characteristics of electromagnetic wave shielding function while emitting far infrared rays and negative ions.

2) 내식 및 고강도/Al합금 선재 구성-Al합금 선재 제조공정2) Corrosion resistance and high strength/Al alloy wire construction-Al alloy wire manufacturing process

ⓐ MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재를 ① 균질화 공정(500℃) ② 냉각(100℃, 냉각속도 15℃~20℃/sec) ③ 열처리(350℃~550℃) ④ (신선 다이스기에서 여러 다이스를 통과하고 인발시키는)신선·인발공정 ⑤ 연화(260℃~360℃)시켜서 직경 0.1mm~2mm의 Al합금 선재를 구성하는데 있어, Al합금 선재내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 내재시켜서 Al합금 선재가 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성이 나타나도록 구성하여-기존의 Al합금 선재보다 내식성, 강도성, 전기전도성, 방열성, 내열성, 내화학성, 내마모성등이 우수하고, 원적외선 및 음이온을 방출하면서 전자파 차폐기능이 우수한 특성을 나타내는 보다 효능적인 Al합금 선재로 구성한 B. 내식 및 고강도/Al합금 선재.Ⓐ MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene)/Al alloy cast material ① homogenization process (500℃) ② cooling (100℃, cooling rate 15℃~20℃/sec) ③ heat treatment (350℃~550℃) ④ Drawing and drawing process (passing and drawing through several dice in a drawing machine) ⑤ Softening (260℃~360℃) to form an Al alloy wire with a diameter of 0.1mm~2mm, Al In the alloy wire a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is embedded so that the Al alloy wire is a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) characteristics are shown-Corrosion resistance, strength, electrical conductivity, heat dissipation, heat resistance, chemical resistance, abrasion resistance, etc. than the existing Al alloy wire rod B. Corrosion-resistant and high-strength/Al alloy wire, which is composed of a more efficient Al alloy wire that exhibits excellent characteristics of shielding electromagnetic waves while emitting far-infrared rays and negative ions.

Claims (3)

본 발명은
1단계: a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀) 제조단계
1) 나노 시트나 나노 분말로 구성된 ① 이황화 몰리브덴(MoS2) ② 이황화 텅스텐(WS2) ③ 이셀렌화 몰리브덴(MoSe2) ④ 이셀레늄 텅스텐(WSe2) 중에서 1가지 이상을 선택하여 구성한 MoS2(WS2, MoSe2, WSe2)에 2) CNT나 그래핀 중에서 1가지 이상을 선택하여 구성한 CNT(그래핀)을 첨가하고 볼 밀 처리하여 혼합시켜서 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 구성하는 1단계.
2단계: MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재 제조단계.
1) Al을 용탕로에서 융해시킨 Al용탕에 1) Cu, Si, Zn, Cu, Fe, Ni, Ti, Mn, Be, Cr, B중에서 1가지 이상을 선택하여 첨가하고 (예: Si과 Mg을 첨가하고 필요시 Fe, Cu, Ti, Ni, Be, B중에서 1가지 이상을 선택하여 추가 첨가하고) 융해시켜서 구성한 Al합금 용탕에 2) a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 첨가 교반시켜서 MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 용탕을 구성한 후 3) 연속주조기에서 연속주조하여 Al합금 주조재 내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 내재시켜서 Al합금 주조재가 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성을 나타나는 보다 효능적인 Al합금 주조재인 MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재를 구성하는 2단계.
본 발명은 1단계, 2단계 제조공정을 거쳐서 Al합금 주조재내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 내재시켜서 Al합금 주조재가 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성을 나타나도록 구성하여 기존 Al합금 주조재보다 효능적인 Al합금 주조재로 구성한 MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재The present invention
Step 1: a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) manufacturing step
1) MoS 2 consisting of nanosheets or nano powders ① Molybdenum disulfide (MoS 2 ) ② Tungsten disulfide (WS 2 ) ③ Molybdenum diselenide (MoSe 2 ) ④ MoS 2 consisting of one or more iselenium tungsten (WSe 2 ). (WS 2 , MoSe 2 , WSe 2 ) 2) CNT (graphene), which is composed of at least one selected from CNT or graphene, was added and mixed by ball mill treatment a. MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene) in 1st step.
Step 2: MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene)/Al alloy casting material manufacturing step.
1) Al melted in a melting furnace 1) Cu, Si, Zn, Cu, Fe, Ni, Ti, Mn, Be, Cr, B. Select and add one or more of them (e.g., Si and Mg Is added and, if necessary, one or more of Fe, Cu, Ti, Ni, Be, and B are added and added) to the molten Al alloy composed by melting 2) a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is added and stirred to form MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene)/Al alloy molten metal 3) Continuous Continuous casting in a casting machine and in the Al alloy casting a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is embedded in the Al alloy cast material a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) MoS 2 (WS 2 , MoSe 2 , WSe 2 ), CNT (graphene)/Al alloy, which is a more efficient Al alloy casting material showing the characteristics of CNT (graphene) The second stage of constructing the cast material.
According to the present invention, a. a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is embedded in the Al alloy cast material a. MoS 2 (WS 2, MoSe 2 , WSe 2) · CNT ( graphene) characteristics to configure the MoS 2 (WS 2, configured with efficacy of Al alloy cast material than the conventional Al alloy cast material shown MoSe of 2, WSe 2 )·CNT (graphene)/Al alloy casting material 본 발명은
청구항 1에서 구성한 MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재를 ① 균질화 ② 열간압연 ③ 냉각 ④ 열처리 ⑤ 냉간 압연 시켜서 Al합금 판재내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 내재시켜서 Al합금 판재가 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성을 나타나도록 구성하여 기존 Al합금 판재보다 효능적인 Al합금 판재로 구성한 내식 및 고강도/Al합금 판재.The present invention
The MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene)/Al alloy cast material constituted in claim 1 is ① homogenized ② hot rolled ③ cooling ④ heat treated ⑤ cold rolled in the Al alloy plate a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is embedded so that the Al alloy plate is a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · Corrosion-resistant and high-strength/Al alloy plate composed of Al alloy plate that is more effective than existing Al alloy plate by constructing to show the characteristics of CNT (graphene). 본 발명은
청구항 1에서 구성한 MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)/Al합금 주조재를 ① 균질화 ② 냉각 ③ 열처리 ④ 신선·인발 ⑤ 연화시켜서 직경 0.1mm~2mm의 Al합금 선재 내에 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)을 내재시켜서 Al합금 선재가 a. MoS2(WS2, MoSe2, WSe2)·CNT(그래핀)의 특성을 나타나도록 구성하여 기존 Al합금 선재보다 효능적인 Al합금 선재로 구성한 내식 및 고강도/Al합금 선재.The present invention
MoS 2 (WS 2 , MoSe 2 , WSe 2 )·CNT (graphene)/Al alloy cast material composed in claim 1 ① homogenization ② cooling ③ heat treatment ④ drawing/drawing ⑤ softened Al alloy wire with a diameter of 0.1mm~2mm Within a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · CNT (graphene) is embedded so that the Al alloy wire is a. MoS 2 (WS 2 , MoSe 2 , WSe 2 ) · Corrosion-resistant and high-strength/Al alloy wire made of Al alloy wire, which is more effective than existing Al alloy wire by configuring to show the characteristics of CNT (graphene).
KR1020190069291A 2019-06-12 2019-06-12 Corrosion resistance and high strength/Al alloy plate and wire KR20200142260A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020190069291A KR20200142260A (en) 2019-06-12 2019-06-12 Corrosion resistance and high strength/Al alloy plate and wire

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020190069291A KR20200142260A (en) 2019-06-12 2019-06-12 Corrosion resistance and high strength/Al alloy plate and wire

Publications (1)

Publication Number Publication Date
KR20200142260A true KR20200142260A (en) 2020-12-22

Family

ID=74086823

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020190069291A KR20200142260A (en) 2019-06-12 2019-06-12 Corrosion resistance and high strength/Al alloy plate and wire

Country Status (1)

Country Link
KR (1) KR20200142260A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115873397A (en) * 2022-10-10 2023-03-31 中国人民解放军海军工程大学 Polyurethane-based friction material based on three-phase composite system and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115873397A (en) * 2022-10-10 2023-03-31 中国人民解放军海军工程大学 Polyurethane-based friction material based on three-phase composite system and preparation method thereof
CN115873397B (en) * 2022-10-10 2024-05-03 中国人民解放军海军工程大学 Polyurethane-based friction material based on three-phase composite system and preparation method thereof

Similar Documents

Publication Publication Date Title
EP2246448B1 (en) High-strength high-conductive copper wire
CN104726749B (en) A kind of aluminium alloy conductor material
CN101474903B (en) Bismuth bronze-steel composite bimetallic bearing material and method for producing the same
AU2017239455A1 (en) Lightweight, high-conductivity, heat-resistant, iron-containing aluminum wire and preparation process therefor
CN100411062C (en) Contact line of bronze in use for electrified railroad in high speed, and preparation method
CN104294146B (en) Hot-rolled base plate for steel aluminum composite plate and production method of hot-rolled base plate
KR20130035439A (en) Leadless free cutting copper alloy and process of production same
CN102855956B (en) Copper-coated aluminum alloy composite lead and production technology thereof
CN105112804A (en) AISI410SS martensite stainless steel for valve and preparation process of AISI410SS martensite stainless steel
KR20200142260A (en) Corrosion resistance and high strength/Al alloy plate and wire
CN103352142B (en) High-strength high-heat resistance aluminum alloy wire rod and preparation method
CN104946925A (en) Treatment technology of copper aluminum alloy material for bus duct
CN106916992A (en) A kind of Al2O3TiC Cu-base composites and preparation method thereof
CN106399751A (en) Preparing method for high-strength and high-conductivity copper alloy
CN104195365B (en) Low-lead brass alloy and preparing method thereof
CN104032173A (en) High-strength tin-brass alloy material and preparation method thereof
CN107130147A (en) The aluminium alloy conductor material and preparation method of a kind of high conductivity
CN104733071B (en) A kind of wire containing albronze
CN101890499B (en) Manufacturing method of special-shaped component of gearshift mechanism of automotive transmission
KR20180109213A (en) Composition and manufacture method for iron and tin and copper alloy
CN108342625A (en) A kind of environment-friendly type aluminum alloy wire and its production method
CN104532066A (en) Heat-resistant oxidation-resistant aluminum power transmission wire
CN105006302A (en) Manufacture process of environment-friendly cable with low power consumption
CN101818287B (en) Universal aluminium alloy air-conditioner foil and manufacturing method thereof
CN101818288B (en) Full applicability air conditioning foil and manufacturing method thereof

Legal Events

Date Code Title Description
E902 Notification of reason for refusal
E601 Decision to refuse application