KR20200113891A - How to make alcohol fuel - Google Patents

How to make alcohol fuel Download PDF

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KR20200113891A
KR20200113891A KR1020190034738A KR20190034738A KR20200113891A KR 20200113891 A KR20200113891 A KR 20200113891A KR 1020190034738 A KR1020190034738 A KR 1020190034738A KR 20190034738 A KR20190034738 A KR 20190034738A KR 20200113891 A KR20200113891 A KR 20200113891A
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weight
parts
alcohol fuel
present
fuel
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KR1020190034738A
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영 욱 김
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영 욱 김
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/12Inorganic compounds
    • C10L1/1216Inorganic compounds metal compounds, e.g. hydrides, carbides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/02Use of additives to fuels or fires for particular purposes for reducing smoke development
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00Components of fuel compositions
    • C10L2200/02Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0204Metals or alloys
    • C10L2200/0209Group I metals: Li, Na, K, Rb, Cs, Fr, Cu, Ag, Au
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00Components of fuel compositions
    • C10L2200/02Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0204Metals or alloys
    • C10L2200/0231Group VI metals: Cr, Mo, W, Po
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00Components of fuel compositions
    • C10L2200/02Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0204Metals or alloys
    • C10L2200/0236Group VII metals: Mn, To, Re
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00Components of fuel compositions
    • C10L2200/02Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0254Oxygen containing compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00Components of fuel compositions
    • C10L2200/02Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/029Salts, such as carbonates, oxides, hydroxides, percompounds, e.g. peroxides, perborates, nitrates, nitrites, sulfates, and silicates

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The present invention relates to a method for producing alcohol fuel having low soot and high calorific value. According to the present invention, the alcohol fuel is manufactured at a mixing ratio of 10 to 85 parts by weight of methanol, 5 to 35 parts by weight of ethanol, 1 to 20 parts by weight of acetone, 0.3 to 5 parts by weight of potassium dichromate, 0.1 to 5 parts by weight of potassium permanganate, 3 to 10 parts by weight of toluene, 0.1 to 5 parts by weight of nucleic acid, and 0.1 to 5 parts by weight of solvent. The above-described alcohol fuel can be used as an alternative energy fuel at the same time as the fuel obtains high caloric energy, and generates less soot and has excellent thermal power.

Description

알코올연료 제조방법{How to make alcohol fuel}How to make alcohol fuel

본 발명은 매연발생이 적고 높은 열량을 갖는 알코올 연료제조방법에 관한 것이다.The present invention relates to a method for producing alcohol fuel having low soot and high calorific value.

종래의 알코올 연료는 낮은 열량, 유독가스 발생, 연소시 액화로 인한 취급 부주의에 의한 화재의 위험 등 여러가지 문제점을 가지고 있었다. 이 문제를 해결하기 위하여 파라핀계 고체연료를 사용하기도 하나, 이것 역시 연소시 파라핀이 액상으로 되어 연소함으로서 악취가 발생하고 취급 부주의에 의한 화재 위험성이 매우 크며, 고체상이기 때문에 편리할 것 같으나 그 용도가 한정되는 결점이 있었다.Conventional alcohol fuel has various problems such as low calorific value, generation of toxic gas, and risk of fire due to careless handling due to liquefaction during combustion. In order to solve this problem, paraffin-based solid fuel is sometimes used. However, this is also a liquid paraffin during combustion, which generates an odor due to combustion, and there is a very high risk of fire due to careless handling, and it seems to be convenient because it is in a solid state. There were limited shortcomings.

본 발명의 목적은 높은 열량의 에너지를 얻음과 동시에 대체 에너지 연료로 사용이 가능한 알코올 연료를 제공하는데 있다.An object of the present invention is to provide an alcohol fuel that can be used as an alternative energy fuel while obtaining energy of a high calorific value.

본 발명의 목적은 매연 발생이 적고 열량이 많은 알코올 연료를 제조방법을 제공하는데 있다. 본 발명의 목적은 여기에 제한되지 않으며, 언급되지 않은 다른 목적들은 아래의 기재로부터 당업자에게 명확하게 이해될 수 있을 것이다.It is an object of the present invention to provide a method for producing alcohol fuel with low soot and high calorific value. The object of the present invention is not limited thereto, and other objects not mentioned will be clearly understood by those skilled in the art from the following description.

본 발명에 대한 과제를 해결하기 위하여 알코올 주성분인 메탄올, 중크롬산칼륨, 과망간산 칼륨을 포함한다. 본 발명의 실시예에 따르면 상기 메탄올의 중량은 상기 에탄올 중량보다 많은 것이 바람직하다. 본 발명의 실시예에 따르면 메탄올 10내지 85 중량부, 에탄올 5내지 35 중량부, 아세톤 1내지 20 중량부, 중크롬산칼륨 0.3내지 5중량부, 과망간산칼륨 0.1내지 5 중량부, 토루엔 3 내지 10 중량부, 핵산 0.1 내지 5 중량부, 솔벤트 0.1내지 5 중량부를 혼합하여 제조한다.In order to solve the problem of the present invention, the alcohol main components include methanol, potassium dichromate, and potassium permanganate. According to an embodiment of the present invention, the weight of methanol is preferably greater than the weight of ethanol. According to an embodiment of the present invention, methanol 10 to 85 parts by weight, ethanol 5 to 35 parts by weight, acetone 1 to 20 parts by weight, potassium dichromate 0.3 to 5 parts by weight, potassium permanganate 0.1 to 5 parts by weight, toluene 3 to 10 parts by weight Parts, 0.1 to 5 parts by weight of nucleic acid, and 0.1 to 5 parts by weight of solvent are mixed and prepared.

본 발명의 효과는 높은 열량의 에너지를 얻음과 동시에 대체 에너지 연료로 활용할수 있다.The effect of the present invention can be utilized as an alternative energy fuel while obtaining energy of a high amount of heat.

1은 본 발명의 실시예에 따른 알코올 연료 발열량 시험 성적서이다.
2는 본 발명 실시예의 따른 알코올 연료의 이산화탄소 발생 시험성적서.
3은본 발명의 실시예에 따른 알코올 연료의 어는점 시함 성적서이다.
1 is an alcohol fuel calorific value test report according to an embodiment of the present invention.
2 is a test report of carbon dioxide generation of alcohol fuel according to an embodiment of the present invention.
3 is a test report on the freezing point of alcohol fuel according to an embodiment of the present invention.

이하 본 발명의 실시 예의 따른 알코올 연로 제조방법을 상세히 설명하기로 한다. 또한 본 발명을 설명함에 있어, 관련된 공지 구성 또는 기능에 대한 구체적인 설명이 본 발명의 요지를 흐릴 수 있다고 판단되는 경우 그 상세한 설명은 생략한다.Hereinafter, a method of manufacturing an alcohol fuel according to an embodiment of the present invention will be described in detail. In addition, in describing the present invention, if it is determined that a detailed description of a related known configuration or function may obscure the subject matter of the present invention, the detailed description thereof will be omitted.

(실시 예)(Example)

본 발명의 알코올 연료 주성분인 메탄올, 에탄올, 아세톤, 중크롬산칼륨, 과망간산칼륨를 혼합하여 제조하며, 첨가제로 토루엔, 핵산, 솔벤트 중에서 적어도 하나 이상을 포함시킬 수 있다. 여기서 메탄올은 에탄올보다 대략 2배정도 함량비를 갖는 것이 바람직하다.It is prepared by mixing methanol, ethanol, acetone, potassium dichromate, and potassium permanganate, which are the alcohol fuel main components of the present invention, and may include at least one or more of toluene, nucleic acid, and solvent as an additive. Here, it is preferable that methanol has a content ratio of about twice that of ethanol.

본 발명의 알코올 연료 제조 조성비는 다음과 같다.The composition ratio for producing alcohol fuel of the present invention is as follows.

(알코올 연료 혼합비)(Alcohol fuel mixing ratio)

메탄올 → 10 내지 60 중량부Methanol → 10 to 60 parts by weight

에탄올 → 5 내지 25 중량부Ethanol → 5 to 25 parts by weight

아세톤 → 1 내지 20 중량부Acetone → 1 to 20 parts by weight

중크롬산칼륨 → 0.3 내지 0.5 중량부Potassium dichromate → 0.3 to 0.5 parts by weight

과망간산칼륨 → 0.1 내지 0.3 중량부Potassium permanganate → 0.1 to 0.3 parts by weight

토로엔 → 3 내지 5 중량부Toroene → 3 to 5 parts by weight

헥산 → 0.1 내지 0.2 중량부Hexane → 0.1 to 0.2 parts by weight

솔벤트 → 0.1 내지 0.2 중량부Solvent → 0.1 to 0.2 parts by weight

참고적으로 메탄올의 인화점의 주변온도는 -1~32℃이다. 본 발명은 상기와 같은 메탄올을 대체 에너지로 활용하기 위하여 메탄올 대비1/2 중량의 에탄올을 혼합하고, 가장 중요한 성분인 아세톤은 열량을 높이고 첨가물들이 혼합이 잘 되도록 하는 역할 뿐만 아니라 중크롬산칼륨이 혼합되는데 중크롬산칼륨과의 반응에 의한 폭발력을 제공한다. 중크롬산칼륨은 열량증가 및 아세톤과의 발화에 의한 강력한 폭발력으로 촉매제 역할을 위해 혼합한다. 그리고 과망간산칼륨은 부식방지를 위해 혼합한다. 또한 토루엔, 헥산, 솔벤트는 적어도 하나 이상이 선택적으로 사용될 수 있는 부수적인 첨가물로서, 그 용도는 열량을 높이기 위한 것이다.For reference, the ambient temperature of the flash point of methanol is -1~32℃. In the present invention, in order to utilize methanol as an alternative energy as described above, 1/2 weight of ethanol is mixed with respect to methanol, and acetone, which is the most important component, not only plays a role in increasing calorie content and mixing additives well, but also potassium dichromate is mixed It provides explosive power by reaction with potassium dichromate. Potassium dichromate is mixed to act as a catalyst due to its strong explosive power due to increase in calories and ignition with acetone. And potassium permanganate is mixed to prevent corrosion. In addition, toluene, hexane, and solvent are ancillary additives in which at least one or more can be selectively used, and their use is to increase the amount of heat.

본 발명에서는 메탄올과 에탄올의 연소에 의한 1차 열에너지와, 아세톤과 중크롬산칼륨의 연소(폭발)에 의한 2차 연소를 열에너지 및 화학반응을 이용한다.In the present invention, thermal energy and chemical reactions are used for primary thermal energy by combustion of methanol and ethanol and secondary combustion by combustion (explosion) of acetone and potassium dichromate.

Claims (2)

알코올 연료에 있어서
메탄올 10내지 85 중량부, 에탄올 5내지 35 중량부, 아세톤 1내지 20 중량부, 중크롬산칼륨 0.3내지 5중량부, 과망간산칼륨 0.1내지 5 중량부 를 포함하는 것을 특징으로 하는 알코올 연료 제조방법.
In alcohol fuel
10 to 85 parts by weight of methanol, 5 to 35 parts by weight of ethanol, 1 to 20 parts by weight of acetone, 0.3 to 5 parts by weight of potassium dichromate, 0.1 to 5 parts by weight of potassium permanganate.
제1항에 있어서
상기 알코올 연료는
토루엔 3 내지 10 중량부, 핵산 0.1 내지 5 중량부, 솔벤트 0.1내지 5 중량부 중에 적어도 하나 이상을 포함하는 것을 특징으로 하는 알코올 연료 제조방법
According to claim 1
The alcohol fuel is
Alcohol fuel production method comprising at least one of 3 to 10 parts by weight of toluene, 0.1 to 5 parts by weight of nucleic acid, and 0.1 to 5 parts by weight of solvent
KR1020190034738A 2019-03-27 2019-03-27 How to make alcohol fuel KR20200113891A (en)

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